Enhancing soil organic carbon(SOC)stocks is a key aspect of modern agriculture,but whether this can be achieved by incorporating legume green manure crops in cereal production to substitute synthetic N fertilizers is ...Enhancing soil organic carbon(SOC)stocks is a key aspect of modern agriculture,but whether this can be achieved by incorporating legume green manure crops in cereal production to substitute synthetic N fertilizers is unknown.This study used a six-year(2017-2022)field study to explore the impacts of intercropping green manure with maize and reducing nitrogen fertilization on SOC stocks,while specifically focusing on the relationship between aggregate composition and carbon sequestration.Maize intercropped with common vetch(M/V),maize intercropped with rapeseed(M/R),and sole maize(M),were each tested at conventional(N2,360 kg ha^(-1))and reduced(N1,270 kg ha^(-1),25% reduced)N application rates.Soil was sampled in 2020,2021,and 2022.Compared with sole maize,intercropping with green manure(M/V and M/R)significantly increased SOC stocks which compensated for any negative effect due to the 25% reduction in N application.Based on 3-year averages,intercropping with M/V and M/R increased the SOC content compared to sole maize(M)by 12.1 and 9.1%,respectively,with intercropping further mitigating the negative impact of reduced nitrogen application.There was no significant difference between M/V and M/R.The SOC content at N1 was reduced by 9.3-10.5%compared to that at N2 in sole maize,but the differences in SOC stocks between N1 and N2 were not significant in the intercropping patterns(M/V and M/R).The intercropped M/V and M/R showed 20.9 and 16.3% higher SOC contents compared to sole maize at N1,with no differences at N2.Intercropping green manure led to a 5.3% greater SOC in the 0-20 cm depth soil in 2022 compared to that in 2020,due to the cumulative effect of two years of green manure intercropping.Intercropping green manure(M/V and M/R)increased the proportion of macroaggregates(>0.25 mm)and aggregate stability while reducing the proportion of microaggregates compared to sole maize under the N1 application.Structural equation modeling indicated that cropping patterns and nitrogen application levels mainly affect SOC indirectly by regulating the composition of macroaggregates and aggregate organic carbon(AOC).Correlation analysis further revealed that the composition of macroaggregates is significantly and positively correlated with the SOC content(R^(2)=0.64).In addition,intercropping green manure can maintain high crop yields by increasing SOC under reduced chemical nitrogen application.The results of this study show that intercropping green manure with grain crops can be a viable measure for increasing SOC sinks and maize productivity by optimizing the aggregate composition with reduced N application in the Hexi Oasis Irrigation Area.展开更多
The characteristics of surface appearances,mass loss,relative dynamic modulus of elasticity and strength loss of different recycled aggregate concretes(RAC) exposed to freeze-thaw cycles were analyzed.It was found tha...The characteristics of surface appearances,mass loss,relative dynamic modulus of elasticity and strength loss of different recycled aggregate concretes(RAC) exposed to freeze-thaw cycles were analyzed.It was found that the freeze-thaw resistance of RAC could be determined by the recycled aggregate compositions and admixtures.Both the saturation degree and the air void structure were the key factors influencing the freeze-thaw damage on concrete.Some major proposed freeze-thaw deterioration mechanisms were utilized to interpret the freeze-thaw damage on recycled aggregate concrete.Meanwhile,some potential measures to enhance the freeze-thaw resistance of concrete were summarized and discussed.展开更多
Monolithic refractory castables comprising a hydraulic bond are still used in a vast majority of cases because of their flexibility and robustness,despite many developments for chemical as well as non-cement castable ...Monolithic refractory castables comprising a hydraulic bond are still used in a vast majority of cases because of their flexibility and robustness,despite many developments for chemical as well as non-cement castable binders.The drying can however be a challenge,in particular for deflocculated dense castables of the low cement castable range.Many publications have been released on this topic for the last ten years,but they often focused on the drying mechanisms or on the addition of drying aids.This paper presents some experimental results on the effect of the composition on the drying properties,especially on the effect of silicon carbide,used for its high thermal conductivity,and on the matrix system.It also introduces two laboratory tests to study and iteratively improve the drying schedule of a given castable lining.The results show that the spalling resistance and the vapor pressure build-up are significantly influenced by the formulation.It is also shown that the castable properties after drying can be altered if the heating rate is very high.展开更多
Poly(vinyl alcohol)(PVA)is biodegradable,recyclable,and has high tensile strength.Therefore,it is ideal for the development of environment-friendly sustainable bioplastics.However,at elevated humidity,the mechanical p...Poly(vinyl alcohol)(PVA)is biodegradable,recyclable,and has high tensile strength.Therefore,it is ideal for the development of environment-friendly sustainable bioplastics.However,at elevated humidity,the mechanical properties of PVA bioplastic films undergo degradation owing to their intrinsic hydrophilic and hygroscopic nature,hindering their applications.This study proposes a nanoconfined assembly strategy to produce humidity-adaptive,mechanically robust,and recyclable bioplastic film.The strong hydrogen bonds between PVA and cellulose nanofibrils inhibit the penetration of water molecules into the film to promote humidity resistance.Further,the robust coordination interactions between bentonite nanoplates,PVA,and cellulose nanofibrils restrict the slip of polymer chains during deformation,leading to enhanced mechanical properties.Benefiting from the nanoconfined assembly architecture in aggregated composites,the resulting reinforced PVA film simultaneously exhibits strength,stiffness,toughness,fracture energy,and tearing energy of 55.9 MPa,1,275.6 MPa,162.9 MJ m^(−3),630.9 kJ m^(−2),and 465.0 kJ m^(−2),respectively.Moreover,the film maintains a strength of approximately 48.7 MPa even at 80%relative humidity for 180 days.This efficient design strategy applies to diverse scales and structured cellulose biomacromolecules.Moreover,it facilitates the application of recyclable high-performance bioplastic films to settings that require high humidity tolerance.展开更多
基金supported by the National Key Research and Development Program of China(2021YFD1700204)the National Natural Science Foundation of China(U21A20218 and 32372238)+1 种基金the Modern Agro-Industry Technology Research System of China(CARS-22-G-12)the“Innovation Star”Program of Graduate Students in 2025 of Gansu Province,China(2025CXZX-749)。
文摘Enhancing soil organic carbon(SOC)stocks is a key aspect of modern agriculture,but whether this can be achieved by incorporating legume green manure crops in cereal production to substitute synthetic N fertilizers is unknown.This study used a six-year(2017-2022)field study to explore the impacts of intercropping green manure with maize and reducing nitrogen fertilization on SOC stocks,while specifically focusing on the relationship between aggregate composition and carbon sequestration.Maize intercropped with common vetch(M/V),maize intercropped with rapeseed(M/R),and sole maize(M),were each tested at conventional(N2,360 kg ha^(-1))and reduced(N1,270 kg ha^(-1),25% reduced)N application rates.Soil was sampled in 2020,2021,and 2022.Compared with sole maize,intercropping with green manure(M/V and M/R)significantly increased SOC stocks which compensated for any negative effect due to the 25% reduction in N application.Based on 3-year averages,intercropping with M/V and M/R increased the SOC content compared to sole maize(M)by 12.1 and 9.1%,respectively,with intercropping further mitigating the negative impact of reduced nitrogen application.There was no significant difference between M/V and M/R.The SOC content at N1 was reduced by 9.3-10.5%compared to that at N2 in sole maize,but the differences in SOC stocks between N1 and N2 were not significant in the intercropping patterns(M/V and M/R).The intercropped M/V and M/R showed 20.9 and 16.3% higher SOC contents compared to sole maize at N1,with no differences at N2.Intercropping green manure led to a 5.3% greater SOC in the 0-20 cm depth soil in 2022 compared to that in 2020,due to the cumulative effect of two years of green manure intercropping.Intercropping green manure(M/V and M/R)increased the proportion of macroaggregates(>0.25 mm)and aggregate stability while reducing the proportion of microaggregates compared to sole maize under the N1 application.Structural equation modeling indicated that cropping patterns and nitrogen application levels mainly affect SOC indirectly by regulating the composition of macroaggregates and aggregate organic carbon(AOC).Correlation analysis further revealed that the composition of macroaggregates is significantly and positively correlated with the SOC content(R^(2)=0.64).In addition,intercropping green manure can maintain high crop yields by increasing SOC under reduced chemical nitrogen application.The results of this study show that intercropping green manure with grain crops can be a viable measure for increasing SOC sinks and maize productivity by optimizing the aggregate composition with reduced N application in the Hexi Oasis Irrigation Area.
基金Funded by the National Key Research and Development Program of China during the“13th Five-Year Plan”(No.2018 YFD1101001)。
文摘The characteristics of surface appearances,mass loss,relative dynamic modulus of elasticity and strength loss of different recycled aggregate concretes(RAC) exposed to freeze-thaw cycles were analyzed.It was found that the freeze-thaw resistance of RAC could be determined by the recycled aggregate compositions and admixtures.Both the saturation degree and the air void structure were the key factors influencing the freeze-thaw damage on concrete.Some major proposed freeze-thaw deterioration mechanisms were utilized to interpret the freeze-thaw damage on recycled aggregate concrete.Meanwhile,some potential measures to enhance the freeze-thaw resistance of concrete were summarized and discussed.
文摘Monolithic refractory castables comprising a hydraulic bond are still used in a vast majority of cases because of their flexibility and robustness,despite many developments for chemical as well as non-cement castable binders.The drying can however be a challenge,in particular for deflocculated dense castables of the low cement castable range.Many publications have been released on this topic for the last ten years,but they often focused on the drying mechanisms or on the addition of drying aids.This paper presents some experimental results on the effect of the composition on the drying properties,especially on the effect of silicon carbide,used for its high thermal conductivity,and on the matrix system.It also introduces two laboratory tests to study and iteratively improve the drying schedule of a given castable lining.The results show that the spalling resistance and the vapor pressure build-up are significantly influenced by the formulation.It is also shown that the castable properties after drying can be altered if the heating rate is very high.
基金National Natural Science Foundation of China,Grant/Award Number:31890774Forestry Science and Technology Innovation and Extension Project of Jiangsu Province,Grant/Award Number:LYKJ[2021]04。
文摘Poly(vinyl alcohol)(PVA)is biodegradable,recyclable,and has high tensile strength.Therefore,it is ideal for the development of environment-friendly sustainable bioplastics.However,at elevated humidity,the mechanical properties of PVA bioplastic films undergo degradation owing to their intrinsic hydrophilic and hygroscopic nature,hindering their applications.This study proposes a nanoconfined assembly strategy to produce humidity-adaptive,mechanically robust,and recyclable bioplastic film.The strong hydrogen bonds between PVA and cellulose nanofibrils inhibit the penetration of water molecules into the film to promote humidity resistance.Further,the robust coordination interactions between bentonite nanoplates,PVA,and cellulose nanofibrils restrict the slip of polymer chains during deformation,leading to enhanced mechanical properties.Benefiting from the nanoconfined assembly architecture in aggregated composites,the resulting reinforced PVA film simultaneously exhibits strength,stiffness,toughness,fracture energy,and tearing energy of 55.9 MPa,1,275.6 MPa,162.9 MJ m^(−3),630.9 kJ m^(−2),and 465.0 kJ m^(−2),respectively.Moreover,the film maintains a strength of approximately 48.7 MPa even at 80%relative humidity for 180 days.This efficient design strategy applies to diverse scales and structured cellulose biomacromolecules.Moreover,it facilitates the application of recyclable high-performance bioplastic films to settings that require high humidity tolerance.
