Recently,inspired by a modified generalized shift-splitting iteration method for complex symmetric linear systems,we propose two variants of the modified generalized shift-splitting iteration(MGSS)methods for solving ...Recently,inspired by a modified generalized shift-splitting iteration method for complex symmetric linear systems,we propose two variants of the modified generalized shift-splitting iteration(MGSS)methods for solving com-plex symmetric linear systems.One is a parameterized MGSS iteration method and the other is a modified parameterized MGSS iteration method.We prove that the proposed methods are convergent under appropriate constraints on the parameters.In addition,we also give the eigenvalue distributions of differ-ent preconditioned matrices to verify the effectiveness of the preconditioners proposed in this paper.展开更多
Europium ternary complex of Eu(NNA) 3(NNA=α-naphthylacetic acid) was embedded in silica matrix at different ratios by sol-gel method. The luminescence properties of silica composites were studied by comparing them wi...Europium ternary complex of Eu(NNA) 3(NNA=α-naphthylacetic acid) was embedded in silica matrix at different ratios by sol-gel method. The luminescence properties of silica composites were studied by comparing them with those of corresponding pure complex by means of excitation, emission spectra and lifetimes. The fluorescence lifetime was prolonged when the pure complex was incorporated in silica matrix. The relative fluorescence intensity and fluorescence lifetimes increased simultaneously with the increase of (Eu(NNA) 3.)展开更多
Nanometer ZrO2 - 8% Y2O3 (mole fraction, % ) powders were prepared by the EDTA (ethylenediaminetetraacetic acid) sol-gel process. Effects of the addition of ethylene glycol on agglomerate control was investigated. The...Nanometer ZrO2 - 8% Y2O3 (mole fraction, % ) powders were prepared by the EDTA (ethylenediaminetetraacetic acid) sol-gel process. Effects of the addition of ethylene glycol on agglomerate control was investigated. The results showed that because of the replacement of hydrogen bonds with ethylene glycol in the polymerized gel, gel stabilization and homogeneity were improved and close approach of gel particles was prevented, which led to reduction of hard agglomerates to some extent. Calcined at 4OO t for 2 h and 700 C for 2 h, the powders had a specific surface area of 35 m2/g, average particle size of 28 nm, and median particle size (d50) of 0. 44um with very sharp distribution, mostly being soft agglomerates.展开更多
We prepared Co_(x)Pt_(100-x)(x=40,45,50,55,60)nanoparticles by the sol-gel method.The phase composition and crystal structure,morphology and microstructure,and magnetic properties of the samples were characterized and...We prepared Co_(x)Pt_(100-x)(x=40,45,50,55,60)nanoparticles by the sol-gel method.The phase composition and crystal structure,morphology and microstructure,and magnetic properties of the samples were characterized and tested using X-ray diffraction(XRD),transmission electron microscopy(TEM),and vibrating sample magnetometer(VSM),respectively.The results demonstrate that the coercivity of CoPt nanoparticles can be effectively controlled by adjusting the atomic ratio of Co and Pt in the samples.Among the compositions studied,the Co_(45)Pt_(55)sample synthesized by the sol-gel method exhibits smaller grain size and a coercivity as high as 6.65×10^(5) A/m is achieved.The morphology and microstructure of the nanoparticles were analyzed by TEM images,indicating that a slight excess of Pt can effectively enhance the coercivity of CoPt nanoparticles.展开更多
The precursor sol of alumina was prepared by sol-gel method with aluminum nitrate and malic acid as raw materials.The effects of content of malic acid and polyvinylpyrrolidone （PVP） on sol spinnability were explored...The precursor sol of alumina was prepared by sol-gel method with aluminum nitrate and malic acid as raw materials.The effects of content of malic acid and polyvinylpyrrolidone （PVP） on sol spinnability were explored.The gel fibers with above 80 cm in length were obtained by mixing aluminum nitrate,malic acid and PVP on mass ratio of 10 3 1.5.Thermogravimetry-differential scanning calorimetry （TG-DSC）,Fourier transform infrared （FTIR） spectrum,X-ray diffractometry （XRD）,and scanning electron microscopy （SEM） were used to characterize the properties of the gel and ceramic fibers.The alumina fibers with a smooth surface and about 20μm in diameter were obtained by sintering at 1 200℃,and their main phase was indentified to be α-Al2O3.展开更多
The LiMnPO4/C composite material was synthesized via a sol-gel method based on the citric acid. The X-ray diffraction （XRD）, scanning electron microscopy （SEM） and electrochemical performance tests were adopted to...The LiMnPO4/C composite material was synthesized via a sol-gel method based on the citric acid. The X-ray diffraction （XRD）, scanning electron microscopy （SEM） and electrochemical performance tests were adopted to characterize the properties of LiMnPO4/C. The XRD studies show that the pure olivine phase LiMnPO4 can be obtained at a low temperature of 500 °C. The SEM analyses illustrate that the citric acid used as the chelating reagent and carbon source can restrain the particle size of LiMnPO4/C well. The LiMnPO4/C sample synthesized at 500 °C for 10 h performs the highest initial discharge capacity of 122.6 mA-h/g, retaining 112.4 mA-h/g over 30 cycles at 0.05C rate. The citric acid based sol-gel method is favor to obtain the high electrochemical performance of LiMnPO4/C.展开更多
[Objective] This paper aims to study a new method of extracting pumpkin polysaccharide from pumpkin. Single factor experiments were conducted to examine the effects of extracting time,temperature,the solid-liquid rati...[Objective] This paper aims to study a new method of extracting pumpkin polysaccharide from pumpkin. Single factor experiments were conducted to examine the effects of extracting time,temperature,the solid-liquid ratio and pH value on the extraction yield of polysaccharide from pumpkin. [Method] The best enzyme ratio and extraction conditions for complex enzymes extraction were determined through orthogonal tests. Scavenging ·OH and O-2 activities of pumpkin polysaccharides were also investigated by salicylic acid and improved self-oxidation of o-pheno methods respectively. [Results] The results showed that the biggest extraction yield of polysaccharide from pumpkin can be got when adding 1% cellulose enzyme,1.5% pectinase,1.0% papain and Na2HPO4-citric acid buffer solution (pH was 4.6),and oscillating for 30 min under water at 40 ℃ with the solid-liquid ratio of 1:30. In addition,pumpkin polysaccharides had a strong activity of eliminating ·OH,but very weak activity to scavenge O-2. [Conclusion] This study provided basic data for research and application of Pumpkin polysaccharide.展开更多
Porous ZnO films are synthesized by inorganic chelating sol-gel method,which is a novel sol-gel technique using zinc nitrate as starting materials and citric acid as the chelating reagent.The crystal structure,surface...Porous ZnO films are synthesized by inorganic chelating sol-gel method,which is a novel sol-gel technique using zinc nitrate as starting materials and citric acid as the chelating reagent.The crystal structure,surface morphology,porous and optical properties of the deposited films are investigated.X-ray diffraction pattern analysis shows that crystal structure of the ZnO films is hexagonal wurtzite.Scanning electron microscopy (SEM) shows that the ZnO film is porous.The curve of pore size distribution has two peak values at about 2.02nm and 4.97nm and BET surface area of the ZnO film is 27.57m2/g.In addition,the transmittance spectrum gives a high transmittance of 85% in the visible region and optical bandgap of the ZnO film (fired at 500℃) is 3.25eV.展开更多
The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and t...The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and the pH of the solutions were also investigated. A timed complexatian colorimetric analysis method of Al-Fe-ferron in view of the total concentration of {AI + Fe} was then established to determine the species distribution of polymeric Al-Fe. The testing wavelength was recommended at 362 net and the testing pH value was 5. With a comparison of the ratios of n(Al)/n(Fe), the standard adsorption curves of the polymeric Al-Fe solutions were derived from the experimental results. Furthermore, the solutions' composition were carious in both the molar n(Al)/n(Fe) ratios, i.e. 0/0, 5/5, 9/1 and 0/10, and the concentrations associated with the total ( Al + Fe which ranged from 10(-5) to 10(-4) mol/L..展开更多
Nanosized ZnWO4 photocatalysts were successfully synthesized via the sol-gel process in a temperature range of 450-800℃. The grain size, crystal size, and crystallinity of ZnWO4 particles increased with the increase ...Nanosized ZnWO4 photocatalysts were successfully synthesized via the sol-gel process in a temperature range of 450-800℃. The grain size, crystal size, and crystallinity of ZnWO4 particles increased with the increase of calcina- tion temperature and prolonging calcination time. The photocatalytic activity was measured for the degradation of an aqueous Rhodamine-B（RhB） solution and gaseous formaldehyde（FAD）. With the increase of calcination temperature and time, the activities increased to a maximum and then decreased. ZnWO4 photocatalyst prepared at 550℃ for I0 h showed the highest activity, which is similar to the photocatalytic activity of P25TiO2 for the degradation of gase-ous FAD. High crystallinity, large surface area, and good dispersion are responsible for the high photocatalytic per- formance of the prepared ZnWO4.展开更多
The support of catalyst for the direct synthesis of diphenyl carbonate （DPC） by heterogeneous catalytic reaction was prepared by the sol-gel method. Compared with activated charcoal, molecular sieve, porous ceramics...The support of catalyst for the direct synthesis of diphenyl carbonate （DPC） by heterogeneous catalytic reaction was prepared by the sol-gel method. Compared with activated charcoal, molecular sieve, porous ceramics, hopcalite, the support prepared by the sol-gel method has higher activity. The characterization of the support by X-ray diffraction （XRD） and transmission electron microscope （TEM） show that the mare crystal phase is Co2MnO4 and the average particle diameter is about 40 nm. The optimum conditions for synthesis of the support were determined by orthogonal experiments, which indicate that the proportion of Cu, Mn, and Co is the first important factor influencing the yield and selectivity of DPC. Temperature of calcination is the second one. The optimum conditions are： molar proportion of Cu, Mn, and Co being 1 ： 1 ： 1, temperature of calcination 700℃, drying at 100~C, temperature of water bath 85~C. The yield and selectivity of DPC in the process can reach 38% and 99% in the batch operation, respectively. The copper cobalt manganese mixed oxides chosen as the support contribute more to the high catalytic activity than the sol-gel method.展开更多
Titanium dioxide nanoparticles modified with neodymium in the range of 1 mol% to 5 mol% were prepared with template-free sol-gel method.The structures of obtained samples were characterized by X-ray powder diffraction...Titanium dioxide nanoparticles modified with neodymium in the range of 1 mol% to 5 mol% were prepared with template-free sol-gel method.The structures of obtained samples were characterized by X-ray powder diffraction analysis.X-ray photoelectron spectroscopy,scanning electron microscopy,transmission electron microscopy and diffuse reflectance spectroscopy.The photocatalytic activity of the obtained samples was evaluated by photodegradation of methyl orange in aqueous solution under ultraviolet-visible(λ> 350 nm) and visible(λ> 420 nm) irradiation.The experimental results show that the 1 mol% Nd-doped TiO2 exhibits the highest photocatalytic activity,of which the degradation can reach to 96.5% under visible irradiation.According to the XRD results,the pristine samples are combined with anatase TiO2 and rutile TiO2.while the Nd-doped TiO2 samples are anatase TiO2 only.This transformation has made an obvious promotion of photocatalyst activity after modification.展开更多
In complex networks,identifying influential spreader is of great significance for improving the reliability of networks and ensuring the safe and effective operation of networks.Nowadays,it is widely used in power net...In complex networks,identifying influential spreader is of great significance for improving the reliability of networks and ensuring the safe and effective operation of networks.Nowadays,it is widely used in power networks,aviation networks,computer networks,and social networks,and so on.Traditional centrality methods mainly include degree centrality,closeness centrality,betweenness centrality,eigenvector centrality,k-shell,etc.However,single centrality method is onesided and inaccurate,and sometimes many nodes have the same centrality value,namely the same ranking result,which makes it difficult to distinguish between nodes.According to several classical methods of identifying influential nodes,in this paper we propose a novel method that is more full-scaled and universally applicable.Taken into account in this method are several aspects of node’s properties,including local topological characteristics,central location of nodes,propagation characteristics,and properties of neighbor nodes.In view of the idea of the multi-attribute decision-making,we regard the basic centrality method as node’s attribute and use the entropy weight method to weigh different attributes,and obtain node’s combined centrality.Then,the combined centrality is applied to the gravity law to comprehensively identify influential nodes in networks.Finally,the classical susceptible-infected-recovered(SIR)model is used to simulate the epidemic spreading in six real-society networks.Our proposed method not only considers the four topological properties of nodes,but also emphasizes the influence of neighbor nodes from the aspect of gravity.It is proved that the new method can effectively overcome the disadvantages of single centrality method and increase the accuracy of identifying influential nodes,which is of great significance for monitoring and controlling the complex networks.展开更多
In this paper, the improved complex variable moving least-squares （ICVMLS） approximation is presented. The ICVMLS approximation has an explicit physics meaning. Compared with the complex variable moving least-squar...In this paper, the improved complex variable moving least-squares （ICVMLS） approximation is presented. The ICVMLS approximation has an explicit physics meaning. Compared with the complex variable moving least-squares （CVMLS） approximations presented by Cheng and Ren, the ICVMLS approximation has a great computational precision and efficiency. Based on the element-free Galerkin （EFG） method and the ICVMLS approximation, the improved complex variable element-free Galerkin （ICVEFG） method is presented for two-dimensional elasticity problems, and the corresponding formulae are obtained. Compared with the conventional EFC method, the ICVEFG method has a great computational accuracy and efficiency. For the purpose of demonstration, three selected numerical examples are solved using the ICVEFG method.展开更多
In this paper, based on the element-free Galerkin （EFG） method and the improved complex variable moving least- square （ICVMLS） approximation, a new meshless method, which is the improved complex variable element-f...In this paper, based on the element-free Galerkin （EFG） method and the improved complex variable moving least- square （ICVMLS） approximation, a new meshless method, which is the improved complex variable element-free Galerkin （ICVEFG） method for two-dimensional potential problems, is presented. In the method, the integral weak form of control equations is employed, and the Lagrange multiplier is used to apply the essential boundary conditions. Then the corresponding formulas of the ICVEFG method for two-dimensional potential problems are obtained. Compared with the complex variable moving least-square （CVMLS） approximation proposed by Cheng, the functional in the ICVMLS approximation has an explicit physical meaning. Furthermore, the ICVEFG method has greater computational precision and efficiency. Three numerical examples are given to show the validity of the proposed method.展开更多
A sodium sulfate （NaeSO4）/silica （SiO2） composite was prepared as a shape-stabilized solid-liquid phase change material by a sol-gel procedure using Na2SiO3 as the silica source. Na2SO4 in the composite acts as a ...A sodium sulfate （NaeSO4）/silica （SiO2） composite was prepared as a shape-stabilized solid-liquid phase change material by a sol-gel procedure using Na2SiO3 as the silica source. Na2SO4 in the composite acts as a latent heat storage substance for solid-liquid phase change, while SiO2 acts as a support material to provide structural strength and prevent leakage of melted NazSO4. The microstructure and composition of the prepared composite were characterized by the N2 adsorption, transmission electron microscope （TEM）, scanning electron microscope （SEM）, Fourier transform infrared spectroscopy （FTIR） and X-ray diffraction. The results show that the prepared Na2SOJSiO2 composite is a nanostructured hybrid of NazSO4 and SiO2 without new substances produced during the phase change. The macroscopic shape of the NazSO4/SiO2 composite after the melting and freezing cycles does not change and there is no leakage of Na2SO4. Determined by differential scanning calorimeter （DSC） analysis, the values of phase change latent heat of melting and freezing of the prepared NazSO4/SiO2 （50%, by mass） composite are 82.3 kJ.kg i and 83.7 kJ.kg-1, and temperatures of melting and freezing are 886.0 ℃ and 880.6 ℃, respectively. Furthermore, the Na2SOJSiO2 composite maintains good thermal energy storage and release ability even after 100 cycles of melting and freezing. The satisfactory thermal storage performance renders this composite a versatile tool for high-temperature thermal energy storage.展开更多
Nanocrystal SmBO3 powders were synthesized by nitrate-citrate sol-gel combustion method. The phase evolution, morphologies and absorbency of the synthesized powders were characterized by X-ray diffraction （XRD）, Fie...Nanocrystal SmBO3 powders were synthesized by nitrate-citrate sol-gel combustion method. The phase evolution, morphologies and absorbency of the synthesized powders were characterized by X-ray diffraction （XRD）, Field emission scanning electronic microscope （FESEM）, Fourier transform infrared spectroscopy （FFIR） and UV-3101PC spectrophotometer （UVPC）, respectively. XRD and FESEM results showed that pure SmBO3 phase was obtained at 750 ℃, with an average original particle size of about 100 nm. FTIR showed that there were apparently concentrated absorbent peaks between 500 and 1400 cm^-1. Moreover, the reflectivity of the powders apparently decreased at the wavelength between 1.05 and 1.15 μm. Therefore, SmBO3 might be a kind of absorbent material for infrared laser.展开更多
In this paper, based on the conjugate of the complex basis function, a new complex variable moving least-squares approximation is discussed. Then using the new approximation to obtain the shape function, an improved c...In this paper, based on the conjugate of the complex basis function, a new complex variable moving least-squares approximation is discussed. Then using the new approximation to obtain the shape function, an improved complex variable element-free Galerkin（ICVEFG） method is presented for two-dimensional（2D） elastoplasticity problems. Compared with the previous complex variable moving least-squares approximation, the new approximation has greater computational precision and efficiency. Using the penalty method to apply the essential boundary conditions, and using the constrained Galerkin weak form of 2D elastoplasticity to obtain the system equations, we obtain the corresponding formulae of the ICVEFG method for 2D elastoplasticity. Three selected numerical examples are presented using the ICVEFG method to show that the ICVEFG method has the advantages such as greater precision and computational efficiency over the conventional meshless methods.展开更多
Transparent anatase TiO2 nanometer thin films with photocatalytic activity were prepared via the sol-gel method on soda-lime glass. The thickness , crystalline phase, grain size, surface hydroxyl amount and so on were...Transparent anatase TiO2 nanometer thin films with photocatalytic activity were prepared via the sol-gel method on soda-lime glass. The thickness , crystalline phase, grain size, surface hydroxyl amount and so on were characterized by scanning electron microscopy (SEM) , X-ray diffraction (XRD), transmission electron microscopy ( TEM), X-ray photoelectron spectroscopy (XPS) and UV-visible spectrophotometer ( UV-VIS). The photocatalytic activity of TiO2 thin films was evaluated for the photocatalytic decolorization of aqueous methyl orange . The effects of film thickness on the crystalline phase, grain size, transmittance and photocatalytic activity of nanometer Ti02 thin films were discussed.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12371378)by the Natural Science Foundation of Fujian Province(Grant Nos.2024J01980,2024J08242).
文摘Recently,inspired by a modified generalized shift-splitting iteration method for complex symmetric linear systems,we propose two variants of the modified generalized shift-splitting iteration(MGSS)methods for solving com-plex symmetric linear systems.One is a parameterized MGSS iteration method and the other is a modified parameterized MGSS iteration method.We prove that the proposed methods are convergent under appropriate constraints on the parameters.In addition,we also give the eigenvalue distributions of differ-ent preconditioned matrices to verify the effectiveness of the preconditioners proposed in this paper.
文摘Europium ternary complex of Eu(NNA) 3(NNA=α-naphthylacetic acid) was embedded in silica matrix at different ratios by sol-gel method. The luminescence properties of silica composites were studied by comparing them with those of corresponding pure complex by means of excitation, emission spectra and lifetimes. The fluorescence lifetime was prolonged when the pure complex was incorporated in silica matrix. The relative fluorescence intensity and fluorescence lifetimes increased simultaneously with the increase of (Eu(NNA) 3.)
文摘Nanometer ZrO2 - 8% Y2O3 (mole fraction, % ) powders were prepared by the EDTA (ethylenediaminetetraacetic acid) sol-gel process. Effects of the addition of ethylene glycol on agglomerate control was investigated. The results showed that because of the replacement of hydrogen bonds with ethylene glycol in the polymerized gel, gel stabilization and homogeneity were improved and close approach of gel particles was prevented, which led to reduction of hard agglomerates to some extent. Calcined at 4OO t for 2 h and 700 C for 2 h, the powders had a specific surface area of 35 m2/g, average particle size of 28 nm, and median particle size (d50) of 0. 44um with very sharp distribution, mostly being soft agglomerates.
基金Funded by the National Natural Science Foundation of China(No.52371169)。
文摘We prepared Co_(x)Pt_(100-x)(x=40,45,50,55,60)nanoparticles by the sol-gel method.The phase composition and crystal structure,morphology and microstructure,and magnetic properties of the samples were characterized and tested using X-ray diffraction(XRD),transmission electron microscopy(TEM),and vibrating sample magnetometer(VSM),respectively.The results demonstrate that the coercivity of CoPt nanoparticles can be effectively controlled by adjusting the atomic ratio of Co and Pt in the samples.Among the compositions studied,the Co_(45)Pt_(55)sample synthesized by the sol-gel method exhibits smaller grain size and a coercivity as high as 6.65×10^(5) A/m is achieved.The morphology and microstructure of the nanoparticles were analyzed by TEM images,indicating that a slight excess of Pt can effectively enhance the coercivity of CoPt nanoparticles.
基金Project(2010K10-21) supported by the Natural Science Foundation of Shaanxi Province,China
文摘The precursor sol of alumina was prepared by sol-gel method with aluminum nitrate and malic acid as raw materials.The effects of content of malic acid and polyvinylpyrrolidone （PVP） on sol spinnability were explored.The gel fibers with above 80 cm in length were obtained by mixing aluminum nitrate,malic acid and PVP on mass ratio of 10 3 1.5.Thermogravimetry-differential scanning calorimetry （TG-DSC）,Fourier transform infrared （FTIR） spectrum,X-ray diffractometry （XRD）,and scanning electron microscopy （SEM） were used to characterize the properties of the gel and ceramic fibers.The alumina fibers with a smooth surface and about 20μm in diameter were obtained by sintering at 1 200℃,and their main phase was indentified to be α-Al2O3.
基金Project (0991025) supported by Natural Science Foundation of Guangxi, ChinaProject (51164007) supported by the National Natural Science Foundation of ChinaProject (201101ZD008) supported by Educational Commission of Guangxi, China
文摘The LiMnPO4/C composite material was synthesized via a sol-gel method based on the citric acid. The X-ray diffraction （XRD）, scanning electron microscopy （SEM） and electrochemical performance tests were adopted to characterize the properties of LiMnPO4/C. The XRD studies show that the pure olivine phase LiMnPO4 can be obtained at a low temperature of 500 °C. The SEM analyses illustrate that the citric acid used as the chelating reagent and carbon source can restrain the particle size of LiMnPO4/C well. The LiMnPO4/C sample synthesized at 500 °C for 10 h performs the highest initial discharge capacity of 122.6 mA-h/g, retaining 112.4 mA-h/g over 30 cycles at 0.05C rate. The citric acid based sol-gel method is favor to obtain the high electrochemical performance of LiMnPO4/C.
基金Supported by the Key Scientific and Technological Project of Henan Province (102102110157)the Scientific Research Found Project of Henan University of Urban Construction (2010JZD008)~~
文摘[Objective] This paper aims to study a new method of extracting pumpkin polysaccharide from pumpkin. Single factor experiments were conducted to examine the effects of extracting time,temperature,the solid-liquid ratio and pH value on the extraction yield of polysaccharide from pumpkin. [Method] The best enzyme ratio and extraction conditions for complex enzymes extraction were determined through orthogonal tests. Scavenging ·OH and O-2 activities of pumpkin polysaccharides were also investigated by salicylic acid and improved self-oxidation of o-pheno methods respectively. [Results] The results showed that the biggest extraction yield of polysaccharide from pumpkin can be got when adding 1% cellulose enzyme,1.5% pectinase,1.0% papain and Na2HPO4-citric acid buffer solution (pH was 4.6),and oscillating for 30 min under water at 40 ℃ with the solid-liquid ratio of 1:30. In addition,pumpkin polysaccharides had a strong activity of eliminating ·OH,but very weak activity to scavenge O-2. [Conclusion] This study provided basic data for research and application of Pumpkin polysaccharide.
文摘Porous ZnO films are synthesized by inorganic chelating sol-gel method,which is a novel sol-gel technique using zinc nitrate as starting materials and citric acid as the chelating reagent.The crystal structure,surface morphology,porous and optical properties of the deposited films are investigated.X-ray diffraction pattern analysis shows that crystal structure of the ZnO films is hexagonal wurtzite.Scanning electron microscopy (SEM) shows that the ZnO film is porous.The curve of pore size distribution has two peak values at about 2.02nm and 4.97nm and BET surface area of the ZnO film is 27.57m2/g.In addition,the transmittance spectrum gives a high transmittance of 85% in the visible region and optical bandgap of the ZnO film (fired at 500℃) is 3.25eV.
基金TheNationalNaturalScienceFoundationofChina (No .2 96 770 0 4)
文摘The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and the pH of the solutions were also investigated. A timed complexatian colorimetric analysis method of Al-Fe-ferron in view of the total concentration of {AI + Fe} was then established to determine the species distribution of polymeric Al-Fe. The testing wavelength was recommended at 362 net and the testing pH value was 5. With a comparison of the ratios of n(Al)/n(Fe), the standard adsorption curves of the polymeric Al-Fe solutions were derived from the experimental results. Furthermore, the solutions' composition were carious in both the molar n(Al)/n(Fe) ratios, i.e. 0/0, 5/5, 9/1 and 0/10, and the concentrations associated with the total ( Al + Fe which ranged from 10(-5) to 10(-4) mol/L..
基金Supported by the National Natural Science Foundation of China(Nos.20433010and20571047)Specialized Research Fundfor the Doctoral Program of Higher Education(No.20060003082).
文摘Nanosized ZnWO4 photocatalysts were successfully synthesized via the sol-gel process in a temperature range of 450-800℃. The grain size, crystal size, and crystallinity of ZnWO4 particles increased with the increase of calcina- tion temperature and prolonging calcination time. The photocatalytic activity was measured for the degradation of an aqueous Rhodamine-B（RhB） solution and gaseous formaldehyde（FAD）. With the increase of calcination temperature and time, the activities increased to a maximum and then decreased. ZnWO4 photocatalyst prepared at 550℃ for I0 h showed the highest activity, which is similar to the photocatalytic activity of P25TiO2 for the degradation of gase-ous FAD. High crystallinity, large surface area, and good dispersion are responsible for the high photocatalytic per- formance of the prepared ZnWO4.
文摘The support of catalyst for the direct synthesis of diphenyl carbonate （DPC） by heterogeneous catalytic reaction was prepared by the sol-gel method. Compared with activated charcoal, molecular sieve, porous ceramics, hopcalite, the support prepared by the sol-gel method has higher activity. The characterization of the support by X-ray diffraction （XRD） and transmission electron microscope （TEM） show that the mare crystal phase is Co2MnO4 and the average particle diameter is about 40 nm. The optimum conditions for synthesis of the support were determined by orthogonal experiments, which indicate that the proportion of Cu, Mn, and Co is the first important factor influencing the yield and selectivity of DPC. Temperature of calcination is the second one. The optimum conditions are： molar proportion of Cu, Mn, and Co being 1 ： 1 ： 1, temperature of calcination 700℃, drying at 100~C, temperature of water bath 85~C. The yield and selectivity of DPC in the process can reach 38% and 99% in the batch operation, respectively. The copper cobalt manganese mixed oxides chosen as the support contribute more to the high catalytic activity than the sol-gel method.
基金supported by the National Natural Science Foundation of China(51275203)Key Scientific and Technological Project of Jilin Province(20140204052GX,20180201074GX)+2 种基金China Postdoctoral Science Foundation(2017M611321)Project of Education Department of Jilin Province(JJKH20180130KJ)Open Project of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University(2019-8).
文摘Titanium dioxide nanoparticles modified with neodymium in the range of 1 mol% to 5 mol% were prepared with template-free sol-gel method.The structures of obtained samples were characterized by X-ray powder diffraction analysis.X-ray photoelectron spectroscopy,scanning electron microscopy,transmission electron microscopy and diffuse reflectance spectroscopy.The photocatalytic activity of the obtained samples was evaluated by photodegradation of methyl orange in aqueous solution under ultraviolet-visible(λ> 350 nm) and visible(λ> 420 nm) irradiation.The experimental results show that the 1 mol% Nd-doped TiO2 exhibits the highest photocatalytic activity,of which the degradation can reach to 96.5% under visible irradiation.According to the XRD results,the pristine samples are combined with anatase TiO2 and rutile TiO2.while the Nd-doped TiO2 samples are anatase TiO2 only.This transformation has made an obvious promotion of photocatalyst activity after modification.
基金Project support by the National Key Research and Development Program of China(Grant No.2018YFF0301000)the National Natural Science Foundation of China(Grant Nos.71673161 and 71790613)。
文摘In complex networks,identifying influential spreader is of great significance for improving the reliability of networks and ensuring the safe and effective operation of networks.Nowadays,it is widely used in power networks,aviation networks,computer networks,and social networks,and so on.Traditional centrality methods mainly include degree centrality,closeness centrality,betweenness centrality,eigenvector centrality,k-shell,etc.However,single centrality method is onesided and inaccurate,and sometimes many nodes have the same centrality value,namely the same ranking result,which makes it difficult to distinguish between nodes.According to several classical methods of identifying influential nodes,in this paper we propose a novel method that is more full-scaled and universally applicable.Taken into account in this method are several aspects of node’s properties,including local topological characteristics,central location of nodes,propagation characteristics,and properties of neighbor nodes.In view of the idea of the multi-attribute decision-making,we regard the basic centrality method as node’s attribute and use the entropy weight method to weigh different attributes,and obtain node’s combined centrality.Then,the combined centrality is applied to the gravity law to comprehensively identify influential nodes in networks.Finally,the classical susceptible-infected-recovered(SIR)model is used to simulate the epidemic spreading in six real-society networks.Our proposed method not only considers the four topological properties of nodes,but also emphasizes the influence of neighbor nodes from the aspect of gravity.It is proved that the new method can effectively overcome the disadvantages of single centrality method and increase the accuracy of identifying influential nodes,which is of great significance for monitoring and controlling the complex networks.
基金supported by the National Natural Science Foundation of China (Grant No.11026223)the Shanghai Leading Academic Discipline Project,China (Grant No.S30106)the Innovation Fund Project for Graduate Student of Shanghai University,China (Grant No.SHUCX112359)
文摘In this paper, the improved complex variable moving least-squares （ICVMLS） approximation is presented. The ICVMLS approximation has an explicit physics meaning. Compared with the complex variable moving least-squares （CVMLS） approximations presented by Cheng and Ren, the ICVMLS approximation has a great computational precision and efficiency. Based on the element-free Galerkin （EFG） method and the ICVMLS approximation, the improved complex variable element-free Galerkin （ICVEFG） method is presented for two-dimensional elasticity problems, and the corresponding formulae are obtained. Compared with the conventional EFC method, the ICVEFG method has a great computational accuracy and efficiency. For the purpose of demonstration, three selected numerical examples are solved using the ICVEFG method.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11171208)the Shanghai Leading Academic Discipline Project, China (Grant No. S30106)the Innovation Fund Project for Graduate Student of Shanghai University,China (Grant No. SHUCX112359)
文摘In this paper, based on the element-free Galerkin （EFG） method and the improved complex variable moving least- square （ICVMLS） approximation, a new meshless method, which is the improved complex variable element-free Galerkin （ICVEFG） method for two-dimensional potential problems, is presented. In the method, the integral weak form of control equations is employed, and the Lagrange multiplier is used to apply the essential boundary conditions. Then the corresponding formulas of the ICVEFG method for two-dimensional potential problems are obtained. Compared with the complex variable moving least-square （CVMLS） approximation proposed by Cheng, the functional in the ICVMLS approximation has an explicit physical meaning. Furthermore, the ICVEFG method has greater computational precision and efficiency. Three numerical examples are given to show the validity of the proposed method.
基金Supported by the National Natural Science Foundation of China(2107611)
文摘A sodium sulfate （NaeSO4）/silica （SiO2） composite was prepared as a shape-stabilized solid-liquid phase change material by a sol-gel procedure using Na2SiO3 as the silica source. Na2SO4 in the composite acts as a latent heat storage substance for solid-liquid phase change, while SiO2 acts as a support material to provide structural strength and prevent leakage of melted NazSO4. The microstructure and composition of the prepared composite were characterized by the N2 adsorption, transmission electron microscope （TEM）, scanning electron microscope （SEM）, Fourier transform infrared spectroscopy （FTIR） and X-ray diffraction. The results show that the prepared Na2SOJSiO2 composite is a nanostructured hybrid of NazSO4 and SiO2 without new substances produced during the phase change. The macroscopic shape of the NazSO4/SiO2 composite after the melting and freezing cycles does not change and there is no leakage of Na2SO4. Determined by differential scanning calorimeter （DSC） analysis, the values of phase change latent heat of melting and freezing of the prepared NazSO4/SiO2 （50%, by mass） composite are 82.3 kJ.kg i and 83.7 kJ.kg-1, and temperatures of melting and freezing are 886.0 ℃ and 880.6 ℃, respectively. Furthermore, the Na2SOJSiO2 composite maintains good thermal energy storage and release ability even after 100 cycles of melting and freezing. The satisfactory thermal storage performance renders this composite a versatile tool for high-temperature thermal energy storage.
基金supported by the 973 Research Project of China (6134502)
文摘Nanocrystal SmBO3 powders were synthesized by nitrate-citrate sol-gel combustion method. The phase evolution, morphologies and absorbency of the synthesized powders were characterized by X-ray diffraction （XRD）, Field emission scanning electronic microscope （FESEM）, Fourier transform infrared spectroscopy （FFIR） and UV-3101PC spectrophotometer （UVPC）, respectively. XRD and FESEM results showed that pure SmBO3 phase was obtained at 750 ℃, with an average original particle size of about 100 nm. FTIR showed that there were apparently concentrated absorbent peaks between 500 and 1400 cm^-1. Moreover, the reflectivity of the powders apparently decreased at the wavelength between 1.05 and 1.15 μm. Therefore, SmBO3 might be a kind of absorbent material for infrared laser.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11171208 and U1433104)
文摘In this paper, based on the conjugate of the complex basis function, a new complex variable moving least-squares approximation is discussed. Then using the new approximation to obtain the shape function, an improved complex variable element-free Galerkin（ICVEFG） method is presented for two-dimensional（2D） elastoplasticity problems. Compared with the previous complex variable moving least-squares approximation, the new approximation has greater computational precision and efficiency. Using the penalty method to apply the essential boundary conditions, and using the constrained Galerkin weak form of 2D elastoplasticity to obtain the system equations, we obtain the corresponding formulae of the ICVEFG method for 2D elastoplasticity. Three selected numerical examples are presented using the ICVEFG method to show that the ICVEFG method has the advantages such as greater precision and computational efficiency over the conventional meshless methods.
基金This work was financially supported by Foundation for Uni-versity Key Teacher by the Ministry of Education, the National Natu-ral Science Foundation of China (No. 50072016) and the Key Re-search Project of the Ministry of Education(No.99087)
文摘Transparent anatase TiO2 nanometer thin films with photocatalytic activity were prepared via the sol-gel method on soda-lime glass. The thickness , crystalline phase, grain size, surface hydroxyl amount and so on were characterized by scanning electron microscopy (SEM) , X-ray diffraction (XRD), transmission electron microscopy ( TEM), X-ray photoelectron spectroscopy (XPS) and UV-visible spectrophotometer ( UV-VIS). The photocatalytic activity of TiO2 thin films was evaluated for the photocatalytic decolorization of aqueous methyl orange . The effects of film thickness on the crystalline phase, grain size, transmittance and photocatalytic activity of nanometer Ti02 thin films were discussed.
