The urea nitrogen adsorbent of complex type, which consists of chitosan coated dialdehyde cellulose （CDAC） and immobilized urease in gelatin membrane （IE）, was prepared. The cellulose, the dialdehyde cellulose （...The urea nitrogen adsorbent of complex type, which consists of chitosan coated dialdehyde cellulose （CDAC） and immobilized urease in gelatin membrane （IE）, was prepared. The cellulose, the dialdehyde cellulose （DAC） and the CDAC were characterized by scanning electronic microscope. The results indicate that the cellulose C2-C3 bond was broken under the oxidation of periodate and it was oxidated to DAC. The DAC was coated with chitosan and the CDAC was obtained. The adsorption of urea nitrogen onto the adsorbent in Na2HPO4-NaH2PO4 buffer solution was studied in batch system. The effects of the experiment parameters, including degree of oxidation of CDAC, initial urea nitrogen concentration, pH and temperature, on the adsorption capacity of urea nitrogen onto the adsorbent at CDAC/IE weight ratio 10：1 were investigated. The results indicate that these parameters affected significantly the adsorption capacity. The adsorption capacity of urea nitrogen onto the adsorbent was 36.7 mg/g at the degree of oxidation of CDAC 88%, initial urea nitrogen concentration 600 mg/L, pH 7.4 and temperature 37℃.展开更多
Mikbi intrusion(MI) is a part of the Neoproterozoic Nubian Shield located along the NE-SW trending major fracture zones prevailing southern Eastern Desert of Egypt. In this study, we present for the first time detaile...Mikbi intrusion(MI) is a part of the Neoproterozoic Nubian Shield located along the NE-SW trending major fracture zones prevailing southern Eastern Desert of Egypt. In this study, we present for the first time detailed mineralogical and bulk-rock geochemical data to infer some constraints on the parental magma genesis and to understand the tectonic processes contributed to MI formation. Lithologically, it is composed of fresh peridotite, clinopyroxenite, hornblendite, anorthosite, gabbronorite, pyroxene amphibole gabbro, amphibole gabbro and diorite. All rocks have low Th/La ratios(mostly <0.2) and lack positive Zr and Th anomalies excluding significant crustal contamination. They show very low concentrations of Nb, Ta, Zr and Hf together with sub-chondritic ratios of Nb/Ta(2-15) and Zr/Hf(19-35),suggesting that their mantle source was depleted by earlier melting extraction event. The oxygen fugacity(logfO_2) estimated from diorite biotite is around the nickel-nickel oxide buffer(NNO) indicating crystallization from a relatively oxidized magma. Amphiboles in the studied mafic-ultramafic rocks indicate relative oxygen fugacity(i.e. ΔNNO; nickel-nickel oxide) of 0.28-3 and were in equilibrium mostly with 3.77-8.24 wt.% H_2 O_(melt)(i.e. water content in the melt), consistent with the typical values of subduction-related magmas. Moreover, pressure estimates(0.53-6.79 kbar) indicate polybaric crystallization and suggest that the magma chamber(s) was located at relatively shallow crustal levels. The enrichment in LILE(e.g., Cs, Ba, K and Sr) and the depletion in HFSE(e.g., Th and Nb) relative to primitive mantle are consistent with island arc signature. The olivine, pyroxene and amphibole compositions also reflect arc affinity. These inferences suggest that their primary magma was derived from partial melting of a mantle source that formerly metasomatized in a subduction zone setting. Clinopyroxene and bulkrock data are consistent with orogenic tholeiitic affinity. Consequently, the mineral and bulk-rock chemistry strongly indicate crystallization from hydrous tholeiitic magma. Moreover, their trace element patterns are subparallel indicating that the various rock types possibly result from differentiation of the same primary magma. These petrological, mineralogical and geochemical characteristics show that the MI is a typical Alaskan-type complex.展开更多
The new polydentate mixed-N,P,O chiral ligands have been synthesized by the condensation of bis（o-formylphenyl）- phenylphosphane and R-phenylglycinol in CHCl_3,and fully characterized by IR,NMR and EIMS spectra.Thes...The new polydentate mixed-N,P,O chiral ligands have been synthesized by the condensation of bis（o-formylphenyl）- phenylphosphane and R-phenylglycinol in CHCl_3,and fully characterized by IR,NMR and EIMS spectra.These ligands were employed with a simple Ni complex Ni（PPh_s）_2Cl_2 in situ as catalytic systems for asymmetric transfer hydrogenation of ketones,and the corresponding optical alcohols were obtained with up to 84%ee under mild conditions.展开更多
The compound [Cd（L）2（NO3）]NO3·0.5H2O （L = N-benzyl-2-（quinolin-8-yloxy）aceta- mide） 1 has been synthesized and structurally determined by single-crystal X-ray diffraction, elemental analysis, IR and UV sp...The compound [Cd（L）2（NO3）]NO3·0.5H2O （L = N-benzyl-2-（quinolin-8-yloxy）aceta- mide） 1 has been synthesized and structurally determined by single-crystal X-ray diffraction, elemental analysis, IR and UV spectroscopy. The crystal belongs to the triclinic system, space group P1 with a = 11.7175（13）, b = 11.8873（13）, c = 14.0958（16） A, α = 74.889（2）, β= 78.228（2）, γ = 78.831（2）°, V= 1835.0（4） A3, Z= 1, Dc= 1.502 Mg/m3, Mr = 1660.17,μ = 0.662 mm-1, F（000） = 846, 2（MoKa） = 0.71073 A, the final R = 0.0585 and wR = 0.0577 for all observed reflections. The results show that the Cd（II） ion with a square antiprismatic geometry is coordinated by a N206 donor set, two NO2 sets from two ligands and two O atoms from a bidendate nitrate group. In the crystal, the O-H...O and N-H...O hydrogen bonds are helpful to consolidate the three- dimensional network.展开更多
Four polyoxometalate complexes, (CPFX·HCl)_3H_4SiW_~12 O_~40 , (CPFX·HCl)_3H_3PW_~12 O_~40 , (CPFX·HCl)_3H_3PMo_~12 O_~40 and (CPFX·HCl)_4H_4SiMo_~12 O_~40 , were prepared from ciprofloxacin hydroc...Four polyoxometalate complexes, (CPFX·HCl)_3H_4SiW_~12 O_~40 , (CPFX·HCl)_3H_3PW_~12 O_~40 , (CPFX·HCl)_3H_3PMo_~12 O_~40 and (CPFX·HCl)_4H_4SiMo_~12 O_~40 , were prepared from ciprofloxacin hydrochloride(CPFX·HCl) reacting with H_nXM_~12 O_~40 ·nH_2O(X=P,Si; M=W,Mo) in an aqueous solution, and characterized by elemental analysis, IR spectrometry and TG-DTA. The IR spectrum confirms the presence of Keggin-type anions of heteropoly acids and the characteristic functional groups of ciprofloxacin. The TG/DTA curves show that their thermal decomposition is a multi-step process including simultaneous collapse of the Keggin-type structure. At first, these compounds had a mass loss of water molecules, then several other mass losses occured due to the decomposition of ciprofloxacin hydrochloride and its fragments with the degradation of Keggin anions. The end product of decomposition is the mixture of WO_3(or MoO_3) and SiO_2(or P_2O_5), identified by X-ray diffraction and IR spectroscopy. The possible thermal decomposition mechanisms of these complexes are proposed. This study exemplified that the thermal stability of the complexes containing tungsten is much better than that of the complexes containing molybdenum.展开更多
We report the lithium ionic conductivities of closo –type complex hydrides synthesized from various molar ratios of lithium borohydride(LiBH4) and decaborane(B10H14) as starting materials. The prepared closo –type c...We report the lithium ionic conductivities of closo –type complex hydrides synthesized from various molar ratios of lithium borohydride(LiBH4) and decaborane(B10H14) as starting materials. The prepared closo –type complex hydrides comprised [B12H12]^2-, [B11H11]^2-, and [B10H10]^2- complex anions. In addition, increasing the LiBH4 content in the starting materials increased the amounts of [B11H11]^2- and [B10H10]^2-, leading to an improved ion conductivity of the prepared sample. The present study offers useful insights into strategies for controlling the complex anion composition in emerging solid electrolytes of closo-type complex hydrides at the molecular level, and improving their ionic conductivities.展开更多
Based on the observation of outcrops and cores,thin section identification,restoration of paleogeomorphology by residual thickness method,fine description of seismic facies,etc.,the coupling relationships between the ...Based on the observation of outcrops and cores,thin section identification,restoration of paleogeomorphology by residual thickness method,fine description of seismic facies,etc.,the coupling relationships between the development patterns of various types of Cambrian platform margin mound-shoal complexes and paleogeomorphology in the Gucheng area of Tarim Basin have been examined.The Cambrian platform margin mound-shoal complex is divided into mound base,mound core,mound front,mound back and mound flat microfacies,which are composed of dolomites of seven textures with facies indication.The different paleogeomorphology before the deposition of mound-shoal complex in each period was reconstructed,and three types of mound-shoal complex sedimentary models corresponding to the paleogeomorphologies of four stages were established:namely,the first stage of gentle slope symmetric accretion type,the second stage of steep slope asymmetric accretion type and the third and fourth stages of steep slope asymmetric progradation type.Their microfacies are respectively characterized by-mound base-mound back+(small)mound core+mound front-mound flat"symmetric vertical accretion structure,"mound base-(large)mound core+mound front-mound flat"asymmetric vertical accretion structure,"mound base-(small)mound core+mound front-mound flat"asymmetric lateral progradation structure.With most developed favorable reservoir facies belt,the steep slope asymmetric accretion type mound-shoal complex with the characteristics of"large mound and large shoal"is the exploration target for oil and gas reservoir.展开更多
Hybrid materials incorporating Eu-(TTA)(3). 2H(2)O (7hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impreg...Hybrid materials incorporating Eu-(TTA)(3). 2H(2)O (7hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of EU3+ under UV light excitation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.展开更多
In the present article, we deal with the so-called overconvergence phenomenon in C of a slightly modified Post-Widder operator of real variable, that is with the extension of its approximation properties from the real...In the present article, we deal with the so-called overconvergence phenomenon in C of a slightly modified Post-Widder operator of real variable, that is with the extension of its approximation properties from the real axis in the complex plane.In this sense, error estimates in approximation and a quantitative Voronovskaya-type asymptotic formula are established.展开更多
In this paper we investigate simultaneous approximation for arbitrary system of nodes on smooth domain in complex plane. Some results which are better than those of known theorems are obtained.
Two charge-transfer complexes of 2a and 2b of Keggin type were synthesized and characterized by elemental analysis, IR spectra, UV spectra, XRD, TG-DSC; and were compared with Hquin-PW12. The primary structure of the...Two charge-transfer complexes of 2a and 2b of Keggin type were synthesized and characterized by elemental analysis, IR spectra, UV spectra, XRD, TG-DSC; and were compared with Hquin-PW12. The primary structure of the heteropolyanions had not been changed after the formation of the charge transfer complexes.展开更多
Polyoxometalates（POMs） with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block（polyanion） is generally established on termin...Polyoxometalates（POMs） with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block（polyanion） is generally established on terminal O-atoms, but scarcely via bridging O-atoms. By introducing liquid small organic molecule（pyridine, C5NH5） as assistant ＂structure-directing agent＂, we obtained a novel organic-inorganic hybrid polytungstate,（Hpy）4[Cd（phen）2（P2W18O62）]·nH2O（1, n ≈ 3, py = pyridine, phen = 1,10-phenanthroline）, under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 is the first compound containing an asymmetric heteropolyanion, [Cd（phen）2（P2W18O62）]4–, a Wells-Dawson-type polyanion monosupported by Cd-coordination complex via di-bridging O-atoms.展开更多
The mafic-ultramafic complexes and associated formationsare wide spread within the Ural folded belt,which is located on the boundary of the East European plate and West Siberian sedimentary basin.Two main
We establish polynomial complexity corrector algorithms for linear programming over bounds of the Mehrotra-type predictor- symmetric cones. We first slightly modify the maximum step size in the predictor step of the s...We establish polynomial complexity corrector algorithms for linear programming over bounds of the Mehrotra-type predictor- symmetric cones. We first slightly modify the maximum step size in the predictor step of the safeguard based Mehrotra-type algorithm for linear programming, that was proposed by Salahi et al. Then, using the machinery of Euclidean Jordan algebras, we extend the modified algorithm to symmetric cones. Based on the Nesterov-Todd direction, we obtain O（r log ε1） iteration complexity bound of this algorithm, where r is the rank of the Jordan algebras and ε is the required precision. We also present a new variant of Mehrotra-type algorithm using a new adaptive updating scheme of centering parameter and show that this algorithm enjoys the same order of complexity bound as the safeguard algorithm. We illustrate the numerical behaviour of the methods on some small examples.展开更多
We prove the non-existence of Hopf real hypersurfaces in complex two-plane Grassmannians whose Jacobi operators or the Jacobi corresponding to the directions in the distribution are of Codazzi type if they satisfy a f...We prove the non-existence of Hopf real hypersurfaces in complex two-plane Grassmannians whose Jacobi operators or the Jacobi corresponding to the directions in the distribution are of Codazzi type if they satisfy a further condition. We obtain that that they must be either of type (A) or of type (B) (see [2]), but no one of these satisfies our condition. As a consequence, we obtain the non-existence of Hopf real hypersurfaces in such ambient spaces whose Jacobi operators corresponding to -directions are parallel with the same further condition.展开更多
Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed with...Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed within some continental LIPs are felsic and rnafic plutonic and volcanic rocks. Although their volumes are minor compared to the flood basalts, the plutonic rocks of continental LIPs are often associated with economic deposits of precious metals. Within the Permian Tarim LIP of NW China, there are at least two layered ultramafic-mafic intrusions （e.g. Wajilitag and Piqiang） contain economically important Fe- Ti-V oxide deposits. Spatially associated with these layered ultramafic-mafic intrusions are syenitic and granitic plutons, which have chemical characteristics of A- type granitoids.展开更多
In this paper, the multistability issue is discussed for delayed complex-valued recurrent neural networks with discontinuous real-imaginary-type activation functions. Based on a fixed theorem and stability definition,...In this paper, the multistability issue is discussed for delayed complex-valued recurrent neural networks with discontinuous real-imaginary-type activation functions. Based on a fixed theorem and stability definition, sufficient criteria are established for the existence and stability of multiple equilibria of complex-valued recurrent neural networks. The number of stable equilibria is larger than that of real-valued recurrent neural networks, which can be used to achieve high-capacity associative memories. One numerical example is provided to show the effectiveness and superiority of the presented results.展开更多
基金SUPPORTED BY NATURAL SCIENCE FOUNDATION OF TIANJIN ( NO. 033802011).
文摘The urea nitrogen adsorbent of complex type, which consists of chitosan coated dialdehyde cellulose （CDAC） and immobilized urease in gelatin membrane （IE）, was prepared. The cellulose, the dialdehyde cellulose （DAC） and the CDAC were characterized by scanning electronic microscope. The results indicate that the cellulose C2-C3 bond was broken under the oxidation of periodate and it was oxidated to DAC. The DAC was coated with chitosan and the CDAC was obtained. The adsorption of urea nitrogen onto the adsorbent in Na2HPO4-NaH2PO4 buffer solution was studied in batch system. The effects of the experiment parameters, including degree of oxidation of CDAC, initial urea nitrogen concentration, pH and temperature, on the adsorption capacity of urea nitrogen onto the adsorbent at CDAC/IE weight ratio 10：1 were investigated. The results indicate that these parameters affected significantly the adsorption capacity. The adsorption capacity of urea nitrogen onto the adsorbent was 36.7 mg/g at the degree of oxidation of CDAC 88%, initial urea nitrogen concentration 600 mg/L, pH 7.4 and temperature 37℃.
文摘Mikbi intrusion(MI) is a part of the Neoproterozoic Nubian Shield located along the NE-SW trending major fracture zones prevailing southern Eastern Desert of Egypt. In this study, we present for the first time detailed mineralogical and bulk-rock geochemical data to infer some constraints on the parental magma genesis and to understand the tectonic processes contributed to MI formation. Lithologically, it is composed of fresh peridotite, clinopyroxenite, hornblendite, anorthosite, gabbronorite, pyroxene amphibole gabbro, amphibole gabbro and diorite. All rocks have low Th/La ratios(mostly <0.2) and lack positive Zr and Th anomalies excluding significant crustal contamination. They show very low concentrations of Nb, Ta, Zr and Hf together with sub-chondritic ratios of Nb/Ta(2-15) and Zr/Hf(19-35),suggesting that their mantle source was depleted by earlier melting extraction event. The oxygen fugacity(logfO_2) estimated from diorite biotite is around the nickel-nickel oxide buffer(NNO) indicating crystallization from a relatively oxidized magma. Amphiboles in the studied mafic-ultramafic rocks indicate relative oxygen fugacity(i.e. ΔNNO; nickel-nickel oxide) of 0.28-3 and were in equilibrium mostly with 3.77-8.24 wt.% H_2 O_(melt)(i.e. water content in the melt), consistent with the typical values of subduction-related magmas. Moreover, pressure estimates(0.53-6.79 kbar) indicate polybaric crystallization and suggest that the magma chamber(s) was located at relatively shallow crustal levels. The enrichment in LILE(e.g., Cs, Ba, K and Sr) and the depletion in HFSE(e.g., Th and Nb) relative to primitive mantle are consistent with island arc signature. The olivine, pyroxene and amphibole compositions also reflect arc affinity. These inferences suggest that their primary magma was derived from partial melting of a mantle source that formerly metasomatized in a subduction zone setting. Clinopyroxene and bulkrock data are consistent with orogenic tholeiitic affinity. Consequently, the mineral and bulk-rock chemistry strongly indicate crystallization from hydrous tholeiitic magma. Moreover, their trace element patterns are subparallel indicating that the various rock types possibly result from differentiation of the same primary magma. These petrological, mineralogical and geochemical characteristics show that the MI is a typical Alaskan-type complex.
基金the National Natural Science Foundation of China(No21173176)the Natural Science Foundation of Guangxi Province of China(No0991016)for the financial support of this work
文摘The new polydentate mixed-N,P,O chiral ligands have been synthesized by the condensation of bis（o-formylphenyl）- phenylphosphane and R-phenylglycinol in CHCl_3,and fully characterized by IR,NMR and EIMS spectra.These ligands were employed with a simple Ni complex Ni（PPh_s）_2Cl_2 in situ as catalytic systems for asymmetric transfer hydrogenation of ketones,and the corresponding optical alcohols were obtained with up to 84%ee under mild conditions.
基金supported by the National Natural Science Foundation of China(21001040)
文摘The compound [Cd（L）2（NO3）]NO3·0.5H2O （L = N-benzyl-2-（quinolin-8-yloxy）aceta- mide） 1 has been synthesized and structurally determined by single-crystal X-ray diffraction, elemental analysis, IR and UV spectroscopy. The crystal belongs to the triclinic system, space group P1 with a = 11.7175（13）, b = 11.8873（13）, c = 14.0958（16） A, α = 74.889（2）, β= 78.228（2）, γ = 78.831（2）°, V= 1835.0（4） A3, Z= 1, Dc= 1.502 Mg/m3, Mr = 1660.17,μ = 0.662 mm-1, F（000） = 846, 2（MoKa） = 0.71073 A, the final R = 0.0585 and wR = 0.0577 for all observed reflections. The results show that the Cd（II） ion with a square antiprismatic geometry is coordinated by a N206 donor set, two NO2 sets from two ligands and two O atoms from a bidendate nitrate group. In the crystal, the O-H...O and N-H...O hydrogen bonds are helpful to consolidate the three- dimensional network.
文摘Four polyoxometalate complexes, (CPFX·HCl)_3H_4SiW_~12 O_~40 , (CPFX·HCl)_3H_3PW_~12 O_~40 , (CPFX·HCl)_3H_3PMo_~12 O_~40 and (CPFX·HCl)_4H_4SiMo_~12 O_~40 , were prepared from ciprofloxacin hydrochloride(CPFX·HCl) reacting with H_nXM_~12 O_~40 ·nH_2O(X=P,Si; M=W,Mo) in an aqueous solution, and characterized by elemental analysis, IR spectrometry and TG-DTA. The IR spectrum confirms the presence of Keggin-type anions of heteropoly acids and the characteristic functional groups of ciprofloxacin. The TG/DTA curves show that their thermal decomposition is a multi-step process including simultaneous collapse of the Keggin-type structure. At first, these compounds had a mass loss of water molecules, then several other mass losses occured due to the decomposition of ciprofloxacin hydrochloride and its fragments with the degradation of Keggin anions. The end product of decomposition is the mixture of WO_3(or MoO_3) and SiO_2(or P_2O_5), identified by X-ray diffraction and IR spectroscopy. The possible thermal decomposition mechanisms of these complexes are proposed. This study exemplified that the thermal stability of the complexes containing tungsten is much better than that of the complexes containing molybdenum.
基金supported by METX,JSPS KAKENHI (Grant numbers, 16K0 676 6, 17H0 6519, 17K18972, 18H01727, and JP18H05513)Collaborative Research Center on Energy Materials in IMR (E-IMR)Target Project 4 of WPI-AIMR, Tohoku University
文摘We report the lithium ionic conductivities of closo –type complex hydrides synthesized from various molar ratios of lithium borohydride(LiBH4) and decaborane(B10H14) as starting materials. The prepared closo –type complex hydrides comprised [B12H12]^2-, [B11H11]^2-, and [B10H10]^2- complex anions. In addition, increasing the LiBH4 content in the starting materials increased the amounts of [B11H11]^2- and [B10H10]^2-, leading to an improved ion conductivity of the prepared sample. The present study offers useful insights into strategies for controlling the complex anion composition in emerging solid electrolytes of closo-type complex hydrides at the molecular level, and improving their ionic conductivities.
基金Supported by the National Natural Science Foundation of China(41772103)China National Science and Technology Major Project(2016ZX05007-002)Petrochina Science and Technology Major Project(2016E-0204)。
文摘Based on the observation of outcrops and cores,thin section identification,restoration of paleogeomorphology by residual thickness method,fine description of seismic facies,etc.,the coupling relationships between the development patterns of various types of Cambrian platform margin mound-shoal complexes and paleogeomorphology in the Gucheng area of Tarim Basin have been examined.The Cambrian platform margin mound-shoal complex is divided into mound base,mound core,mound front,mound back and mound flat microfacies,which are composed of dolomites of seven textures with facies indication.The different paleogeomorphology before the deposition of mound-shoal complex in each period was reconstructed,and three types of mound-shoal complex sedimentary models corresponding to the paleogeomorphologies of four stages were established:namely,the first stage of gentle slope symmetric accretion type,the second stage of steep slope asymmetric accretion type and the third and fourth stages of steep slope asymmetric progradation type.Their microfacies are respectively characterized by-mound base-mound back+(small)mound core+mound front-mound flat"symmetric vertical accretion structure,"mound base-(large)mound core+mound front-mound flat"asymmetric vertical accretion structure,"mound base-(small)mound core+mound front-mound flat"asymmetric lateral progradation structure.With most developed favorable reservoir facies belt,the steep slope asymmetric accretion type mound-shoal complex with the characteristics of"large mound and large shoal"is the exploration target for oil and gas reservoir.
基金financial supportfrom PRAMX 98-05 and helpful discussion with Dr.A.C.Franville.
文摘Hybrid materials incorporating Eu-(TTA)(3). 2H(2)O (7hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of EU3+ under UV light excitation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.
文摘In the present article, we deal with the so-called overconvergence phenomenon in C of a slightly modified Post-Widder operator of real variable, that is with the extension of its approximation properties from the real axis in the complex plane.In this sense, error estimates in approximation and a quantitative Voronovskaya-type asymptotic formula are established.
文摘In this paper we investigate simultaneous approximation for arbitrary system of nodes on smooth domain in complex plane. Some results which are better than those of known theorems are obtained.
文摘Two charge-transfer complexes of 2a and 2b of Keggin type were synthesized and characterized by elemental analysis, IR spectra, UV spectra, XRD, TG-DSC; and were compared with Hquin-PW12. The primary structure of the heteropolyanions had not been changed after the formation of the charge transfer complexes.
基金supported by the Foundation of Education Department of Fujian Province(Nos.JB12199 and JA11245)the National Natural Science Foundation of China(Nos.21233004 and 40972035)
文摘Polyoxometalates（POMs） with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block（polyanion） is generally established on terminal O-atoms, but scarcely via bridging O-atoms. By introducing liquid small organic molecule（pyridine, C5NH5） as assistant ＂structure-directing agent＂, we obtained a novel organic-inorganic hybrid polytungstate,（Hpy）4[Cd（phen）2（P2W18O62）]·nH2O（1, n ≈ 3, py = pyridine, phen = 1,10-phenanthroline）, under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 is the first compound containing an asymmetric heteropolyanion, [Cd（phen）2（P2W18O62）]4–, a Wells-Dawson-type polyanion monosupported by Cd-coordination complex via di-bridging O-atoms.
基金supported by the Program of UD RAS (project № 15-18-5-24)
文摘The mafic-ultramafic complexes and associated formationsare wide spread within the Ural folded belt,which is located on the boundary of the East European plate and West Siberian sedimentary basin.Two main
基金Supported by the National Natural Science Foundation of China(11471102,61301229)Supported by the Natural Science Foundation of Henan University of Science and Technology(2014QN039)
文摘We establish polynomial complexity corrector algorithms for linear programming over bounds of the Mehrotra-type predictor- symmetric cones. We first slightly modify the maximum step size in the predictor step of the safeguard based Mehrotra-type algorithm for linear programming, that was proposed by Salahi et al. Then, using the machinery of Euclidean Jordan algebras, we extend the modified algorithm to symmetric cones. Based on the Nesterov-Todd direction, we obtain O（r log ε1） iteration complexity bound of this algorithm, where r is the rank of the Jordan algebras and ε is the required precision. We also present a new variant of Mehrotra-type algorithm using a new adaptive updating scheme of centering parameter and show that this algorithm enjoys the same order of complexity bound as the safeguard algorithm. We illustrate the numerical behaviour of the methods on some small examples.
文摘We prove the non-existence of Hopf real hypersurfaces in complex two-plane Grassmannians whose Jacobi operators or the Jacobi corresponding to the directions in the distribution are of Codazzi type if they satisfy a further condition. We obtain that that they must be either of type (A) or of type (B) (see [2]), but no one of these satisfies our condition. As a consequence, we obtain the non-existence of Hopf real hypersurfaces in such ambient spaces whose Jacobi operators corresponding to -directions are parallel with the same further condition.
基金financially supported by the National Natural Science Foundation of China (Grant No.41703030)research grants from the East China University of Technology (Grants No.DHBK2015323 and RGET1504)the Jiangxi Provincial Department of Education (Grant No.GJJ150556)
文摘Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed within some continental LIPs are felsic and rnafic plutonic and volcanic rocks. Although their volumes are minor compared to the flood basalts, the plutonic rocks of continental LIPs are often associated with economic deposits of precious metals. Within the Permian Tarim LIP of NW China, there are at least two layered ultramafic-mafic intrusions （e.g. Wajilitag and Piqiang） contain economically important Fe- Ti-V oxide deposits. Spatially associated with these layered ultramafic-mafic intrusions are syenitic and granitic plutons, which have chemical characteristics of A- type granitoids.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61374094 and 61503338)the Natural Science Foundation of Zhejiang Province,China(Grant No.LQ15F030005)
文摘In this paper, the multistability issue is discussed for delayed complex-valued recurrent neural networks with discontinuous real-imaginary-type activation functions. Based on a fixed theorem and stability definition, sufficient criteria are established for the existence and stability of multiple equilibria of complex-valued recurrent neural networks. The number of stable equilibria is larger than that of real-valued recurrent neural networks, which can be used to achieve high-capacity associative memories. One numerical example is provided to show the effectiveness and superiority of the presented results.
