The indirect voltammetric determination of trace sulfate (2.0×10^(-6)～4.0×10^(-5) mol/L ) with the adsorptive complex wave of lead(Ⅱ)-tetrakis (4-trimethylammonium phenyl) porphyrin (PbTTMAPP) is reported....The indirect voltammetric determination of trace sulfate (2.0×10^(-6)～4.0×10^(-5) mol/L ) with the adsorptive complex wave of lead(Ⅱ)-tetrakis (4-trimethylammonium phenyl) porphyrin (PbTTMAPP) is reported.This method has been used for the analysis of natural waters with satisfactory results.展开更多
Terbium can form a ternary complex having a ratio of 1:1:1 with acetylacetone and EDTA. By adding cetyl pyridinium chloride into the above system, a marked enhancement of fluorescence intensity is observed and the ter...Terbium can form a ternary complex having a ratio of 1:1:1 with acetylacetone and EDTA. By adding cetyl pyridinium chloride into the above system, a marked enhancement of fluorescence intensity is observed and the ternary complex becomes more stable than before. For analytical application, the derivative spectrofluorimetric method has high sensitivity and the effect of foreign ions is very low. The optimum conditions were obtained. The calibration graph is linear over 5～100μg/mL.展开更多
A gabbro-diorite plutonic complex from the Southeast Obudu Plateau, representing limited volumes of magma, was studied for its trace and rare-earth element characteristics, in an attempt to document its genetic and ge...A gabbro-diorite plutonic complex from the Southeast Obudu Plateau, representing limited volumes of magma, was studied for its trace and rare-earth element characteristics, in an attempt to document its genetic and geodynamic history. Geochemical studies indicate that the gabbro samples are characterized by variable concentrations and low averages of such index elements as Cr (40×10-6–200×10-6; av. 80×10-6), Ni (40×10-6–170×10-6; 53.33×10-6) and Zr (110×10-6–240×10-6; 116.67×10-6); variable and high averages of Rb (3×10-6–270×10-6; 80.67×10-6), Sr (181×10-6–1610×10-6; 628.17×10-6) and U (0.14×10-6–3.46×10-6; 1.51×10-6), and fairly uniform Co (34×10-6–49×10-6; 36.33×10-6) and Sc (23×10-6–39×10-6; 34.5×10-6), while the diorite samples exhibit higher trace element compositions. The range of REE contents and distinctive chondrite-normalized patterns indicate moderate fractionation with slight positive Eu anomaly in the diorites to very low fractionation with flat patterns and slight positive Eu anomaly in the gabbros. However, the general element systematics of the samples, especially LILE (Ba, Rb, Sr, Cs and Pb), HFSE (Zr, Th, U, Hf, Mo, W, Nb and Sn), relatively immobile elements (Zr, Ni, Cr) and REE, suggests a differentiation model, involving fractional crystallization of olivine and clinopyroxene from a partial melt generated beneath an island arc complex. A possible model for the complex is therefore an island arc setting, the development of which was dominated by calc-alkaline magmatism across the Obudu Plateau.展开更多
Unlike the real-valued plane wave reflection coefficient(PRC)at the pre-critical incident angles,the frequency-and depth-dependent spherical-wave reflection coefficient(SRC)is more accurate and always a complex value,...Unlike the real-valued plane wave reflection coefficient(PRC)at the pre-critical incident angles,the frequency-and depth-dependent spherical-wave reflection coefficient(SRC)is more accurate and always a complex value,which contains more reflection amplitude and phase information.In near field,the imaginary part of complex SRC(phase)cannot be ignored,but it is rarely considered in seismic inversion.To promote the practical application of spherical-wave seismic inversion,a novel spherical-wave inversion strategy is implemented.The complex-valued spherical-wave synthetic seismograms can be obtained by using a simple harmonic superposition model.It is assumed that geophone can only record the real part of complex-valued seismogram.The imaginary part can be further obtained by the Hilbert transform operator.We also propose the concept of complex spherical-wave elastic impedance(EI)and the complex spherical-wave EI equation.Finally,a novel complex spherical-wave EI inversion approach is proposed,which can fully use the reflection information of amplitude,phase,and frequency.With the inverted complex spherical-wave EI,the velocities and density can be further extracted.Synthetic data and field data examples show that the elastic parameters can be reasonably estimated,which illustrate the potential of our spherical-wave inversion approach in practical applications.展开更多
Semblance,a measure of multi-trace coherence,has been used extensively in seismic data processing and interpretation such as velocity analysis and fault detection. The traditional algorithm has a difficulty at zero-cr...Semblance,a measure of multi-trace coherence,has been used extensively in seismic data processing and interpretation such as velocity analysis and fault detection. The traditional algorithm has a difficulty at zero-crossings of seismic recordings. This problem is alleviated by applying a smoothing window at the cost of losing vertical resolutions. In this paper,we improve the algorithm by computing semblance from complex traces. Our initial results show that the complex semblance is smooth at zero-crossings. Because the smoothing time window becomes unnecessary,the higher vertical resolution can be achieved by using small windows or none. Some geological features,like faults and unconformities,appear clearer and easier to identify with the complex semblance. As the advantages are obvious and the implementation is straight-forward with the Hilbert transform,this new algorithm may replace the traditional one in future applications.展开更多
A novel hybrid approach for earthquake location is proposed which uses a combined coarse global search and fine local inversion with a minimum search routine, plus an examination of the root mean squares （RMS） error...A novel hybrid approach for earthquake location is proposed which uses a combined coarse global search and fine local inversion with a minimum search routine, plus an examination of the root mean squares （RMS） error distribution. The method exploits the advantages of network ray tracing and robust formulation of the Frrchet derivatives to simultaneously update all possible initial source parameters around most local minima （including the global minimum） in the solution space, and finally to determine the likely global solution. Several synthetic examples involving a 3-D complex velocity model and a challenging source-receiver layout are used to demonstrate the capability of the newly-developed method. This new global-local hybrid solution technique not only incorporates the significant benefits of our recently published hypocenter determination procedure for multiple earthquake parameters, but also offers the attractive features of global optimal searching in the RMS travel time error distribution. Unlike the traditional global search method, for example, the Monte Carlo approach, where millions of tests have to be done to fmd the final global solution, the new method only conducts a matrix inversion type local search but does it multiple times simultaneously throughout the model volume to seek a global solution. The search is aided by inspection of the RMS error distribution. Benchmark tests against two popular approaches, the direct grid search method and the oct-tree important sampling method, indicate that the hybrid global-local inversion yields comparable location accuracy and is not sensitive to modest level of noise data, but more importantly it offers two-order of magnitude speed-up in computational effort. Such an improvement, combined with high accuracy, make it a promising hypocenter determination scheme in earthquake early warning, tsunami early warning, rapid hazard assessment and emergency response after strong earthquake occurrence.展开更多
提出了一种基于Vulkan架构的弹跳射线(shooting and bouncing ray,SBR)加速计算方法,用于电大复杂目标雷达散射截面的快速计算。设计了高效的Vulkan计算着色器,充分利用GPU硬件光追,显著提升了SBR法中光线求交的计算速度;引入了双命令...提出了一种基于Vulkan架构的弹跳射线(shooting and bouncing ray,SBR)加速计算方法,用于电大复杂目标雷达散射截面的快速计算。设计了高效的Vulkan计算着色器,充分利用GPU硬件光追,显著提升了SBR法中光线求交的计算速度;引入了双命令缓冲机制,使得CPU与GPU能够高效协同工作,从而加速多角度扫描任务的执行;在虚拟孔径面上划分互不干扰的子任务,进一步提升了多GPU并行的利用效率。实验结果表明:所提出方法在计算电大复杂目标雷达散射截面时相较于FEKO RL-GO方法实现了40倍以上的加速;双命令缓冲机制提升了约42%的多角度扫描速度;双GPU计算并行效率超过90%。展开更多
文摘The indirect voltammetric determination of trace sulfate (2.0×10^(-6)～4.0×10^(-5) mol/L ) with the adsorptive complex wave of lead(Ⅱ)-tetrakis (4-trimethylammonium phenyl) porphyrin (PbTTMAPP) is reported.This method has been used for the analysis of natural waters with satisfactory results.
基金Project supported by the National Natural Science Foundation of China
文摘Terbium can form a ternary complex having a ratio of 1:1:1 with acetylacetone and EDTA. By adding cetyl pyridinium chloride into the above system, a marked enhancement of fluorescence intensity is observed and the ternary complex becomes more stable than before. For analytical application, the derivative spectrofluorimetric method has high sensitivity and the effect of foreign ions is very low. The optimum conditions were obtained. The calibration graph is linear over 5～100μg/mL.
文摘A gabbro-diorite plutonic complex from the Southeast Obudu Plateau, representing limited volumes of magma, was studied for its trace and rare-earth element characteristics, in an attempt to document its genetic and geodynamic history. Geochemical studies indicate that the gabbro samples are characterized by variable concentrations and low averages of such index elements as Cr (40×10-6–200×10-6; av. 80×10-6), Ni (40×10-6–170×10-6; 53.33×10-6) and Zr (110×10-6–240×10-6; 116.67×10-6); variable and high averages of Rb (3×10-6–270×10-6; 80.67×10-6), Sr (181×10-6–1610×10-6; 628.17×10-6) and U (0.14×10-6–3.46×10-6; 1.51×10-6), and fairly uniform Co (34×10-6–49×10-6; 36.33×10-6) and Sc (23×10-6–39×10-6; 34.5×10-6), while the diorite samples exhibit higher trace element compositions. The range of REE contents and distinctive chondrite-normalized patterns indicate moderate fractionation with slight positive Eu anomaly in the diorites to very low fractionation with flat patterns and slight positive Eu anomaly in the gabbros. However, the general element systematics of the samples, especially LILE (Ba, Rb, Sr, Cs and Pb), HFSE (Zr, Th, U, Hf, Mo, W, Nb and Sn), relatively immobile elements (Zr, Ni, Cr) and REE, suggests a differentiation model, involving fractional crystallization of olivine and clinopyroxene from a partial melt generated beneath an island arc complex. A possible model for the complex is therefore an island arc setting, the development of which was dominated by calc-alkaline magmatism across the Obudu Plateau.
基金the sponsorship of the Marine S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology(Qingdao)(Grant No.2021QNLM0200016)National Natural Science Foundation of China(42030103,41974119)Science Foundation from Innovation and Technology Support Program for Young Scientists in Colleges of Shandong province and Ministry of Science and Technology of China(2019RA2136)
文摘Unlike the real-valued plane wave reflection coefficient(PRC)at the pre-critical incident angles,the frequency-and depth-dependent spherical-wave reflection coefficient(SRC)is more accurate and always a complex value,which contains more reflection amplitude and phase information.In near field,the imaginary part of complex SRC(phase)cannot be ignored,but it is rarely considered in seismic inversion.To promote the practical application of spherical-wave seismic inversion,a novel spherical-wave inversion strategy is implemented.The complex-valued spherical-wave synthetic seismograms can be obtained by using a simple harmonic superposition model.It is assumed that geophone can only record the real part of complex-valued seismogram.The imaginary part can be further obtained by the Hilbert transform operator.We also propose the concept of complex spherical-wave elastic impedance(EI)and the complex spherical-wave EI equation.Finally,a novel complex spherical-wave EI inversion approach is proposed,which can fully use the reflection information of amplitude,phase,and frequency.With the inverted complex spherical-wave EI,the velocities and density can be further extracted.Synthetic data and field data examples show that the elastic parameters can be reasonably estimated,which illustrate the potential of our spherical-wave inversion approach in practical applications.
基金supported by the National Natural Science Foundation of China (No. 41574134)the 100 Talents Program of the Chinese Academy of Science
文摘Semblance,a measure of multi-trace coherence,has been used extensively in seismic data processing and interpretation such as velocity analysis and fault detection. The traditional algorithm has a difficulty at zero-crossings of seismic recordings. This problem is alleviated by applying a smoothing window at the cost of losing vertical resolutions. In this paper,we improve the algorithm by computing semblance from complex traces. Our initial results show that the complex semblance is smooth at zero-crossings. Because the smoothing time window becomes unnecessary,the higher vertical resolution can be achieved by using small windows or none. Some geological features,like faults and unconformities,appear clearer and easier to identify with the complex semblance. As the advantages are obvious and the implementation is straight-forward with the Hilbert transform,this new algorithm may replace the traditional one in future applications.
基金funded by the National Natural Science Foundation of China (No.40774020)the Key Research Program from Ministry of Education of China (No.107137)
文摘A novel hybrid approach for earthquake location is proposed which uses a combined coarse global search and fine local inversion with a minimum search routine, plus an examination of the root mean squares （RMS） error distribution. The method exploits the advantages of network ray tracing and robust formulation of the Frrchet derivatives to simultaneously update all possible initial source parameters around most local minima （including the global minimum） in the solution space, and finally to determine the likely global solution. Several synthetic examples involving a 3-D complex velocity model and a challenging source-receiver layout are used to demonstrate the capability of the newly-developed method. This new global-local hybrid solution technique not only incorporates the significant benefits of our recently published hypocenter determination procedure for multiple earthquake parameters, but also offers the attractive features of global optimal searching in the RMS travel time error distribution. Unlike the traditional global search method, for example, the Monte Carlo approach, where millions of tests have to be done to fmd the final global solution, the new method only conducts a matrix inversion type local search but does it multiple times simultaneously throughout the model volume to seek a global solution. The search is aided by inspection of the RMS error distribution. Benchmark tests against two popular approaches, the direct grid search method and the oct-tree important sampling method, indicate that the hybrid global-local inversion yields comparable location accuracy and is not sensitive to modest level of noise data, but more importantly it offers two-order of magnitude speed-up in computational effort. Such an improvement, combined with high accuracy, make it a promising hypocenter determination scheme in earthquake early warning, tsunami early warning, rapid hazard assessment and emergency response after strong earthquake occurrence.
文摘提出了一种基于Vulkan架构的弹跳射线(shooting and bouncing ray,SBR)加速计算方法,用于电大复杂目标雷达散射截面的快速计算。设计了高效的Vulkan计算着色器,充分利用GPU硬件光追,显著提升了SBR法中光线求交的计算速度;引入了双命令缓冲机制,使得CPU与GPU能够高效协同工作,从而加速多角度扫描任务的执行;在虚拟孔径面上划分互不干扰的子任务,进一步提升了多GPU并行的利用效率。实验结果表明:所提出方法在计算电大复杂目标雷达散射截面时相较于FEKO RL-GO方法实现了40倍以上的加速;双命令缓冲机制提升了约42%的多角度扫描速度;双GPU计算并行效率超过90%。
