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Prestack Gaussian beam depth migration under complex surface conditions 被引量:11
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作者 岳玉波 李振春 +2 位作者 张平 周学锋 秦宁 《Applied Geophysics》 SCIE CSCD 2010年第2期143-148,194,共7页
In areas with a complex surface,the acquisition and processing of seismic data is a great challenge.Although elevation-static corrections can be used to eliminate the influences of topography,the distortions of seismi... In areas with a complex surface,the acquisition and processing of seismic data is a great challenge.Although elevation-static corrections can be used to eliminate the influences of topography,the distortions of seismic wavefields caused by simple vertical time shifts still greatly degrade the quality of the migrated images.Ray-based migration methods which can extrapolate and image the wavefields directly from the rugged topography are efficient ways to solve the problems mentioned above.In this paper,we carry out a study of prestack Gaussian beam depth migration under complex surface conditions.We modify the slant stack formula in order to contain the information of surface elevations and get an improved method with more accuracy by compositing local plane-wave components directly from the complex surface.First,we introduce the basic rules and computational procedures of conventional Gaussian beam migration.Then,we give the original method of Gaussian beam migration under complex surface conditions and an improved method in this paper.Finally,we validate the effectiveness of the improved method with trials of model and real data. 展开更多
关键词 complex surface local plane-wave Gaussian beam migration
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Programmable robotized‘transfer-and-jet’printing for large,3D curved electronics on complex surfaces 被引量:8
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作者 YongAn Huang Hao Wu +14 位作者 Chen Zhu Wennan Xiong Furong Chen Lin Xiao Jianpeng Liu Kaixin Wang Huayang Li Dong Ye Yongqing Duan Jiankui Chen Hua Yang Wenlong Li Kun Bai Zhouping Yin Han Ding 《International Journal of Extreme Manufacturing》 SCIE EI 2021年第4期74-87,共14页
Large,3D curved electronics are a trend of the microelectronic industry due to their unique ability to conformally coexist with complex surfaces while retaining the electronic functions of 2D planar integrated circuit... Large,3D curved electronics are a trend of the microelectronic industry due to their unique ability to conformally coexist with complex surfaces while retaining the electronic functions of 2D planar integrated circuit technologies.However,these curved electronics present great challenges to the fabrication processes.Here,we propose a reconfigurable,mask-free,conformal fabrication strategy with a robot-like system,called robotized‘transfer-and-jet’printing,to assemble diverse electronic devices on complex surfaces.This novel method is a ground-breaking advance with the unique capability to integrate rigid chips,flexible electronics,and conformal circuits on complex surfaces.Critically,each process,including transfer printing,inkjet printing,and plasma treating,are mask-free,digitalized,and programmable.The robotization techniques,including measurement,surface reconstruction and localization,and path programming,break through the fundamental constraints of 2D planar microfabrication in the context of geometric shape and size.The transfer printing begins with the laser lift-off of rigid chips or flexible electronics from donor substrates,which are then transferred onto a curved surface via a dexterous robotic palm.Then the robotic electrohydrodynamic printing directly writes submicrometer structures on the curved surface.Their permutation and combination allow versatile conformal microfabrication.Finally,robotized hybrid printing is utilized to successfully fabricate a conformal heater and antenna on a spherical surface and a flexible smart sensing skin on a winged model,where the curved circuit,flexible capacitive and piezoelectric sensor arrays,and rigid digital–analog conversion chips are assembled.Robotized hybrid printing is an innovative printing technology,enabling additive,noncontact and digital microfabrication for 3D curved electronics. 展开更多
关键词 conformal printing curved electronics complex surfaces inkjet printing robotic fabrication
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COMPLEX SURFACE RECONSTRUCTION BASED ON OBJECT-ORIENTED DEVELOPING TOOL VBA 被引量:5
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作者 Li Yupeng Wang Hong School of Mechanical Engineering, Yanshan University, Qinhuangdao 066004, China 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2002年第3期248-251,共4页
Taking AutoCAD2000 as platform, an algorithm for the reconstruction ofsurface from scattered data points based on VBA is presented. With this core technology customerscan be free from traditional AutoCAD as an electro... Taking AutoCAD2000 as platform, an algorithm for the reconstruction ofsurface from scattered data points based on VBA is presented. With this core technology customerscan be free from traditional AutoCAD as an electronic board and begin to create actual presentationof real-world objects. VBA is not only a very powerful tool of development, but with very simplesyntax. Associating with those solids, objects and commands of AutoCAD 2000, VBA notably simplifiesprevious complex algorithms, graphical presentations and processing, etc. Meanwhile, it can avoidappearance of complex data structure and data format in reverse design with other modeling software.Applying VBA to reverse engineering can greatly improve modeling efficiency and facilitate surfacereconstruction. 展开更多
关键词 Reverse designing Scattered data points Topological mesh VBAenvironment complex surface reconstruction
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Research on ultrasonic detection of complex surfaces
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作者 江健 周晓军 +1 位作者 郭天太 吴思源 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第10期1146-1151,共6页
Parts of complex surface are widely used now in many fields, and their detection has caused much concern. In China many manufactories still carry on the traditional way of manual detection, which requires highly skill... Parts of complex surface are widely used now in many fields, and their detection has caused much concern. In China many manufactories still carry on the traditional way of manual detection, which requires highly skilled personnel and efficiency is low. Some large manufactories have imported auto-detecting equipments, which require CAD data on the parts, or just divide the surface into several approximate planes for automatic detection. Phased-array system is seldom used, and the cost is high. Besides, most of the systems have not considered the automatic sensitivity compensation of parts with varying thickness. To improve the detection quality and efficiency of nondestructive test (NDT) of parts of complex surface, this paper puts forward an integrated ultrasonic NDT system characterized by: (1) Use of ultrasonic measurement and reverse of curved surface to solve the CAD data problem; (2) Use of an automatic sensitivity compensation algorithm (based on the part’s modelling information obtained in surface reverse) to fit the variety of the thickness; (3) Use of template matching and pseudo-color imaging to improve the quality of detection results. The system features integration of low cost mature technologies, and is suitable for detection of various parts of different complex surfaces in medium-and-small enterprises. The test results showed that the system can automatically detect parts of complex surface successfully, and that the inspection result is good and reliable. 展开更多
关键词 Ultrasonic NDT complex surface Automatic sensitivity compensation Ultrasonic measurement surface reverse Template matching Pseudo-color imaging
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Traveltime tomography and prestack depth migration for vertical seismic profiling of an angle-domain walkaway on a complex surface
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作者 Li Jian-Guo Cui Xiao-Jie +2 位作者 Huang Jian-Hua Zhang Xiao-Lu Li Yan-Peng 《Applied Geophysics》 SCIE CSCD 2019年第3期358-366,397,共10页
Walkaway VSP cannot obtain accurate velocity field,as it asymmetrically reflects ray path and provides uneven coverage to underground target,thereby presenting issues related to imaging quality.In this study,we propos... Walkaway VSP cannot obtain accurate velocity field,as it asymmetrically reflects ray path and provides uneven coverage to underground target,thereby presenting issues related to imaging quality.In this study,we propose combining traveltime tomography and prestack depth migration for VSP of an angle-domain walkaway,in a bid to establish accurate two-dimensional and three-dimensional(3 D)velocity models.First,residual curvature was defined to update velocity,and an accurate velocity field was established.To establish a high-precision velocity model,we deduced the relationship between the residual depth and traveltime of common imaging gathers(CIGs)in walkaway VSP.Solving renewal velocity using the least squares method,a four-parameter tomographic inversion equation was derived comprising formation dip angle,incidence angle,residual depth,and sensitivity matrix.In the angle domain,the reflected wave was divided into up-and down-transmitted waves and their traveltimes were calculated.The systematic cumulative method was employed in prestack depth migration of a complex surface.Through prestack depth migration,the offset-domain CIGs were obtained,and dip angle was established by defining the stack section horizon.Runge–Kutta ray tracing was employed to calculate the ray path from the reflection point to the detection point,to determine the incident angle,and to subsequently calculate the ray path from the reflection point to the irregular surface.The offset-domain residual depths were mapped to the angle domain,and a new tomographic equation was established and solved.Application in the double complex area of the Tarim Basin showed the four-parameter tomographic inversion equation derived in this paper to be both correct and practical and that the migration algorithm was able to adapt to the complex surface. 展开更多
关键词 complex surface angle domain travel time tomography VSP one-way wave prestack depth migration
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Research on Ultrasonic NDT System for Complex Surface Parts
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作者 MA Hong-wei, ZHANG Xu-hui, WEI Juan (Department of Mechanical Engineering, Xi’an University of Science and Technology, Xi’an 710054, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期12-,共1页
Aimed at inner quality controlling for complex surface parts, an ultrasonic testing system for complex surface parts has been developed using ultrasonic NDT(Non-destructive Testing)which has features of strong penetra... Aimed at inner quality controlling for complex surface parts, an ultrasonic testing system for complex surface parts has been developed using ultrasonic NDT(Non-destructive Testing)which has features of strong penetration, well direction, high sensitivity, low cost, and harmless to people and material. The technologies of the computer, NC (Numerical control), precision mechanism, signal analysis and processing were integrated in the testing system. The system includes a PC, system software, ultrasonic data acquisition card, stepper motor drive card and five-axis precision mechanical device, etc. The software was developed using WIN98-based VC++. According to CAD data of the parts and interpolation methods, the scanning programs can be programmed. The five-axis scanning system is driven by the CNC(computer numerical control) system to control the attitude of ultrasonic probes. The system’s automatic scanning for complex surface parts, real-time acquiring ultrasonic data and automatic identifying flaw signal have been realized. This system can be used not only for testing complex surface parts, but for testing random curve parts. With fast testing speed, high sensitivity, high testing precision and high reliability, the system has a wide adaptability. 展开更多
关键词 complex surface ultrasonic non-destructive testing SYSTEM
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Key technologies for complex surface seismic acquisition in the Sichuan Basin and their application effect
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作者 Wang Xiaoyang Zhang Xiaobin +7 位作者 Zhao Xiaohong Hu Feng Ren Cong Wang Guangyin Li Shuqin Sun Siyi Wang Shuyan Luo Wen 《Natural Gas Industry B》 2021年第6期552-561,共10页
The earth surface in the Sichuan Basin and its periphery is geologically complex,which causes low signal-to-noise ratio of seismic data,poor imaging quality of seismic profiles and great difficulty in data acquisition... The earth surface in the Sichuan Basin and its periphery is geologically complex,which causes low signal-to-noise ratio of seismic data,poor imaging quality of seismic profiles and great difficulty in data acquisition.In order to ensure high-quality operation of the seismic survey project in the complex surface of the Sichuan Basin,researchers have been working continuously to solve the bottleneck problems in the seismic acquisition technology for complex surface in recent years.In addition,the upgrading of acquisition technology and operation capacity is promoted effectively by means of technical innovation,and a series of key technologies for seismic acquisition are developed.And the following application results of this series of technologies are obtained.First,the optimization design technology of the geometry based on wave equation forward modeling and actual data,combined with prestack migration imaging can show the influence of different acquisition schemes on the prestack imaging effect of complex targets more directly,which makes the seismic acquisition scheme more economic and effective.Second,by extracting landform risks and surface obstacle information intelligently,combined with field fine reconnaissance,landform risk identification and hierarchical evaluation and indoors intelligent optimization of well-shot physical point deployment are conducted,and thus the GISt intelligent deployment technology of shot point in complex surface is formed,which effectively reduces the risks of operation.Third,the cavity excitation technology which reduces the initial pressure of explosive pulse and extends the explosive action time of explosives can increase the conversion rate of rock excitation energy into effective elastic wave energy and the reflected energy and improve the quality of seismic single shot data.Fourth,combination of the automatic evaluation technology for field seismic data acquired in mountainous regions and the KL-GMLiveQC1.0 software can improve the evaluation efficiency,reduce the evaluation cost and ensure the high-quality acquisition of seismic data in complex surface.In conclusion,this series of key seismic acquisition technologies greatly improve the signal-to-noise ratio and resolution of seismic data,lay a foundation for fine reservoir prediction,and ensure the continuous important breakthrough of three-dimensional natural gas exploration and development in the gas fields of marine carbonate rock,shale gas,volcanic rock and shallow tight sandstone gas in the Sichuan Basin. 展开更多
关键词 Sichuan Basin complex surface Optimization design of geometry Intelligent deployment of shot points Cavity excitation Quality control and evaluation Signal-to-noise ratio of data
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A novel five-axis on-machine measurement optimization method for complex curved surfaces
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作者 GUO Yan-heng WAN Neng ZHUANG Qi-xin 《Journal of Central South University》 2025年第2期523-537,共15页
On-machine measurement(OMM)stands out as a pivotal technology in complex curved surface adaptive machining.However,the complex structure inherent in workpieces poses a significant challenge as the stylus orientation f... On-machine measurement(OMM)stands out as a pivotal technology in complex curved surface adaptive machining.However,the complex structure inherent in workpieces poses a significant challenge as the stylus orientation frequently shifts during the measurement process.Consequently,a substantial amount of time is allocated to calibrating pre-travel error and probe movement.Furthermore,the frequent movement of machine tools also increases the influence of machine errors.To enhance both accuracy and efficiency,an optimization strategy for the OMM process is proposed.Based on the kinematic chain of the machine tools,the relationship between the angle combination of rotary axes,the stylus orientation,and the calibration position of pre-travel error is disclosed.Additionally,an OMM efficiency optimization model for complex curved surfaces is developed.This model is solved to produce the optimal efficiency angle combinations for each to-be-measured point.Within each angle combination,the effects of positioning errors on measurement results are addressed by coordinate system offset and measurement result compensation method.Finally,the experiments on an impeller are used to demonstrate the practical utility of the proposed method. 展开更多
关键词 on-machine measurement complex curved surfaces efficiency optimization error compensation
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A review of recent advances in machining techniques of complex surfaces 被引量:3
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作者 LI Xiang Fei HUANG Tao +4 位作者 ZHAO Huan ZHANG XiaoMing YAN SiJie DAI Xing DING Han 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2022年第9期1915-1939,共25页
Complex surfaces are widely used in aerospace,energy,and national defense industries.As one of the major means of manufacturing such as complex surfaces,the multi-axis numerical control(NC)machining technique makes mu... Complex surfaces are widely used in aerospace,energy,and national defense industries.As one of the major means of manufacturing such as complex surfaces,the multi-axis numerical control(NC)machining technique makes much contribution.When the size of complex surfaces is large or the machining space is narrow,the multi-axis NC machining may not be a good choice because of its high cost and low dexterity.Robotic machining is a beneficial supplement to the NC machining.Since it has the advantages of large operating space,good dexterity,and easy to realize parallel machining,it is a promising technique to enhance the capability of traditional NC machining.However,whether it is the multi-axis NC machining or the robotic machining,owing to the complex geometric properties and strict machining requirements,high-efficiency and high-accuracy machining of complex surfaces has always been a great challenge and remains a cutting-edge problem in the current manufacturing field.In this paper,by surveying the machining of complex parts and large complex surfaces,the theory and technology of high-efficiency and high-accuracy machining of complex surfaces are reviewed thoroughly.Then,a series of typical applications are introduced to show the state-of-the-art on the machining of complex surfaces,especially the recently developed industrial software and equipment.Finally,the summary and prospect of the machining of complex surfaces are addressed.To the best of our knowledge,this may be the first attempt to systematically review the machining of complex surfaces by the multiaxis NC and robotic machining techniques,in order to promote the further research in related fields. 展开更多
关键词 complex surfaces multi-axis NC machining robotic machining machining dynamics and control process optimization
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Precise 3D shape measurement of three-dimensional digital image correlation for complex surfaces 被引量:3
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作者 YAN TianHao SU Yong ZHANG QingChuan 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2018年第1期68-73,共6页
Three dimensional-digital image correlation (3D-DIC) is a widely used optical metrology in the experimental mechanics community because of its reliability, practicality, and flexibility. Although the precision of di... Three dimensional-digital image correlation (3D-DIC) is a widely used optical metrology in the experimental mechanics community because of its reliability, practicality, and flexibility. Although the precision of digital image correlation (DIC) has been thoroughly studied theoretically and numerically, verification experiments have seldom been performed, especially fbr complex surfaces with a small field of view (FOV). In this work, the shape of a 1-yuan coin was measured using 3D-DIC; the shape was complex due to the presence of many fine details, and the FOV was relatively small because the coin diameter was only 25 mm. During the experiment, a novel strategy for speckle production was developed: white paint was simply sprayed onto the surface. Black paint was not used; instead, taking advantage of the reflective nature of the coin surface, polarized light and a Polaroid filter were introduced, and the polarization direction was carefully adjusted, ensuring that the spray pattern was extremely thin and that high-quality speckle images with significant contrast were captured. The three-dimensional coin shape was also successfully determined for comparison using a stylus profiler. The results demonstrate that 3D-DIC provides high precision in shape measurement even for complex surfaces with small FOV. The precision of 3D-DIC can reach 1/7000 of the field of view, corresponding to about 6 ~tm in this experiment. 展开更多
关键词 three-dimensional digital image correlation(3D-DIC) measurement precision complex surfaces small field of view polarized light polaroid filter
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On a non-abelian invariant on complex surfaces of general type Dedicated to Professor Sheng GONG on the occasion of his 75th birthday
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作者 CHEUNG Wing-Sum WONG Bun 《Science China Mathematics》 SCIE 2006年第12期1897-1900,共4页
In this paper,we give certain homotopy and diffeomorphism versions as a generalization to an earlier result due to W.S.Cheung,Bun Wong and Stephen S.T.Yau concerning a local rigidity problem of the tangent bundle over... In this paper,we give certain homotopy and diffeomorphism versions as a generalization to an earlier result due to W.S.Cheung,Bun Wong and Stephen S.T.Yau concerning a local rigidity problem of the tangent bundle over compact surfaces of general type. 展开更多
关键词 Chern numbers complex surfaces of general type coholomogy group local moduli local deformation space Miyaoka-Yau inequality Yau's global rigidity theorem Yau's uniformization theorem.
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Structural Dimension Optimization of Robotic Belt Grinding System for Grinding Workpieces with Complex Shaped Surfaces Based on Dexterity Grinding Space 被引量:9
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作者 GAO Zhihui LAN Xiaodong BIAN Yushu 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2011年第3期346-354,共9页
To improve the grinding quality of robotic belt grinding systems for the workpieces with complex shaped surfaces, new concepts of the dexterity grinding point and the dexterity grinding space are proposed and their ma... To improve the grinding quality of robotic belt grinding systems for the workpieces with complex shaped surfaces, new concepts of the dexterity grinding point and the dexterity grinding space are proposed and their mathematical descriptions are defined. Factors influencing the dexterity grinding space are analyzed. And a method to determine the necessary dexterity grinding space is suggested. Based on particle swarm optimization (PSO) method, a strategy to optimize the grinding robot structural dimensions and position with respect to the grinding wheel is put forward to obtain the necessary dexterity grinding space. Finally, to grind an aerial engine blade, a dedicated PPPRRR (P: prismatic R: rotary) grinding robot structural dimensions and position with respect to the grinding wheel are optimized using the above strategy. According to simulation results, if the blade is placed within the dexterity grinding space, only one gripper and one grinding machine are needed to grind its complex shaped surfaces. 展开更多
关键词 GRINDING ROBOTS complex shaped surface particle swarm optimization dexterity grinding space
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Uranium sorption on oxyhydroxide minerals by surface complexation and precipitation 被引量:4
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作者 Jingyi Wang Wanqiang Zhou +4 位作者 Yanlin Shi Yao Li Dongfan Xian Ning Guo Chunli Liu 《Chinese Chemical Letters》 SCIE CAS CSCD 2022年第7期3461-3467,共7页
During the chemical weathering of the uranium mill tailings,released uranium could be immobilized by the newly formed secondary minerals such as oxyhydroxides.A deeper understanding of the interaction between uranium ... During the chemical weathering of the uranium mill tailings,released uranium could be immobilized by the newly formed secondary minerals such as oxyhydroxides.A deeper understanding of the interaction between uranium and common oxyhydroxides under environmental conditions is necessary.In this work,uranium sorption behaviors on Al-,Mn-and Fe-oxyhydroxide minerals(boehmite,manganite,goethite,and lepidocrocite)were investigated by batch experiments.Results showed that the uranium sorption on Al-oxyhydroxide behaved significantly differently from the other three minerals.The sorption edge of the Mn-and Fe-oxyhydroxides located around pH 5,while the sorption edge of boehmite shifted about 1.5 pH unit to near neutral.The sorption isotherms of uranium on manganite,goethite and lepidocrocite at pH 5.0 could be well fitted by the Langmuir model.Instead of surface complexation,sorption on boehmite happened mainly by uranium-bearing carbonates and hydroxides precipitation as illustrated by the characterization results.Both carbonate and phosphate strongly affected the uranium sorption behavior.The removal efficiency of uranium by boehmite exceeded 98%after three sorption-desorption cycles,indicating it may be a potential material for uranium removal and recovery. 展开更多
关键词 Uranium mill tailings Oxyhydroxides Uranium sorption surface complexation surface precipitation
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Effect of Phosphates on the Metal Ion Activated Surface Complexes at the SiO_2-H_2O Interface and in Quartz Deactivation in Flotation System 被引量:1
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作者 孙中溪 W.Forsling 陈荩 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1992年第3期163-172,共10页
The complexation of phosphates in the quartz-metal ion-H_2O-oleate system was studied. Computer assisted calculations with the aid of the advanced program SOLGASWATER and known equilibrium constants were used to evalu... The complexation of phosphates in the quartz-metal ion-H_2O-oleate system was studied. Computer assisted calculations with the aid of the advanced program SOLGASWATER and known equilibrium constants were used to evaluate the mechanism,The calculation results revealed that in the presence of a certain amount of phosphates, metal ions adsorbed at the quartz-H_2O interface will be transferred into solution.Thus the competi- tion for metal ions between phosphates and the quartz surface leads to surface deactivation and re- duced floatability.Various distribution diagrams clearly demonstrate the change of surface complexation as a function of added phosphate concentration.The deactivation products were also evaluated. 展开更多
关键词 complexATION PHOSPHATE quartz flotation activation DEACTIVATION surface complex
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Inhibiting Smooth Muscle Cell Proliferation via Immobilization of Heparin/Fibronectin Complexes on Titanium Surfaces 被引量:1
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作者 LI Gui Cai XU Qi Fei YANG Ping 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2015年第5期378-382,共5页
The aim of this study was to investigate the inhibitory effect of heparin/fibronectin (Hep/Fn) complexes on neointimal hyperplasia following endovascular intervention. Hep/Fn complexes were immobilized onto titanium... The aim of this study was to investigate the inhibitory effect of heparin/fibronectin (Hep/Fn) complexes on neointimal hyperplasia following endovascular intervention. Hep/Fn complexes were immobilized onto titanium (Ti) surfaces, with subsequent X-ray photoelectron spectroscopy (XPS), Toluidine Blue 0 (TBO) and immunohistochemistry methods were used to characterize surface properties. Smooth muscle cell (SMC) cultures were used to evaluate the effect of Hep/Fn complexes on SMC proliferation. Results showed that Hep/Fn complexes successfully immobilized onto Ti surfaces and resulted in an inhibition of SMC proliferation. This study suggests that Hep/Fn surface-immobilized biomaterials develop as a new generation of biomaterials to prevent neointimal hyperplasia, particularly for use in cardiovascular implants. 展开更多
关键词 Hep Inhibiting Smooth Muscle Cell Proliferation via Immobilization of Heparin/Fibronectin complexes on Titanium surfaces TiO Fn SMC
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One Novel Mn(Ⅱ)Complex with 1-Substituted-1H-1,2,3-triazole-4-carboxylic Acid:Crystal Structure,Fluorescence and Hirshfeld Surface Analysis 被引量:3
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作者 赵红 朱毓卿 冯超 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第1期66-72,共7页
The crystal structure of one novel Mn(II) complex, [Mn(pmta)_3]_2[Mn(H_2O)_6]·4H_2O(1), is reported(Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid). In the title compound, the asymmetric ... The crystal structure of one novel Mn(II) complex, [Mn(pmta)_3]_2[Mn(H_2O)_6]·4H_2O(1), is reported(Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid). In the title compound, the asymmetric unit consists of a [Mn(pmta_)3]ˉ anion, half [Mn(H_2O)_6]^(2+) counter cation and two lattice H_2O molecules, and the intra- and intermolecular hydrogen bonds connect the complex into a supramolecular structure. The liquid-state fluorescence spectra of complex 1 have been determined. Hirshfeld surface analysis was also studied. The main intermolecular interactions in the complex are O···H and H···H contacts. 展开更多
关键词 Mn(Ⅱ) complex crystal structure supramolecular structure Hirshfeld surface
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THE MECHANISM OF SURFACE METALLIZATION OF POLYVINYL ALCOHOL COMPLEX METAL CHELATE FILMS
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作者 Ding Sheng YU Shi Zhi CHEN Shu Ke JIAO 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第9期831-832,共2页
A novel method for preparing metalllzed film has been studied.The reduction process and properties of the poly(vinyl alcohol)(PVA)were probed by several analytic means.According to the etudies,a mechanism for the poly... A novel method for preparing metalllzed film has been studied.The reduction process and properties of the poly(vinyl alcohol)(PVA)were probed by several analytic means.According to the etudies,a mechanism for the polymer surface reduction metallization was proposed and proved. 展开更多
关键词 CU CI THE MECHANISM OF surface METALLIZATION OF POLYVINYL ALCOHOL complex METAL CHELATE FILMS PVA
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Research on Extraction Method of Surface Information Based on Multi-Feature Combination Such as Fractal Texture 被引量:1
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作者 Zhen Chen Yiyang Zheng 《Journal of Geoscience and Environment Protection》 2023年第10期50-66,共17页
Because of the developed economy and lush vegetation in southern China, the following obstacles or difficulties exist in remote sensing land surface classification: 1) Diverse surface composition types;2) Undulating t... Because of the developed economy and lush vegetation in southern China, the following obstacles or difficulties exist in remote sensing land surface classification: 1) Diverse surface composition types;2) Undulating terrains;3) Small fragmented land;4) Indistinguishable shadows of surface objects. It is our top priority to clarify how to use the concept of big data (Data mining technology) and various new technologies and methods to make complex surface remote sensing information extraction technology develop in the direction of automation, refinement and intelligence. In order to achieve the above research objectives, the paper takes the Gaofen-2 satellite data produced in China as the data source, and takes the complex surface remote sensing information extraction technology as the research object, and intelligently analyzes the remote sensing information of complex surface on the basis of completing the data collection and preprocessing. The specific extraction methods are as follows: 1) extraction research on fractal texture features of Brownian motion;2) extraction research on color features;3) extraction research on vegetation index;4) research on vectors and corresponding classification. In this paper, fractal texture features, color features, vegetation features and spectral features of remote sensing images are combined to form a combination feature vector, which improves the dimension of features, and the feature vector improves the difference of remote sensing features, and it is more conducive to the classification of remote sensing features, and thus it improves the classification accuracy of remote sensing images. It is suitable for remote sensing information extraction of complex surface in southern China. This method can be extended to complex surface area in the future. 展开更多
关键词 complex surface Remote Sensing Information Extraction Remote Sensing Land Classification Transfer Learning Brownian Motion Fractal Texture
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Natural brown coal as an adsorbent for manganese removal from groundwater:A mechanistic and operational evaluation
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作者 Obiri-Nyarko F Darko DA +2 位作者 Quansah JO Asare SV Karikari AY 《Journal of Groundwater Science and Engineering》 2025年第4期371-385,共15页
This study investigates the potential of natural Brown Coal(BC)as a sustainable,cost-effective adsorbent for the removal of manganese(Mn2+)from contaminated groundwater.A series of batch adsorp-tion experiments was co... This study investigates the potential of natural Brown Coal(BC)as a sustainable,cost-effective adsorbent for the removal of manganese(Mn2+)from contaminated groundwater.A series of batch adsorp-tion experiments was conducted to assess the influence of key operational parameters—such as solution pH,2+initial Mn concentration,BC dosage,temperature,and the presence of competing ions—on 2+Mn removal efficiency.The environmental compatibility and regeneration potential of BC were also evaluated to deter-mine its practical viability for repeated use.To better understand the adsorption behaviour,equilibrium and kinetic data were analysed using established isotherm and kinetic models,while thermodynamic parameters were computed to assess the spontaneity and thermal characteristics of the adsorption process.Furthermore,geochemical modelling and comprehensive BC characterization—including surface morphology,miner-alogical and elemental composition,and functional group analysis—were 2+performed to elucidate Mn speciation under varying environmental conditions and to uncover the underlying adsorption mechanisms.2+Results showed that Mn removal efficiency increased with higher pH,temperature,and BC dosage,but 2+declined at elevated initial Mn concentrations due to active site saturation.The process was spontaneous 2 and endothermic,with the Langmuir isotherm model(R=0.994)and pseudo-second-order kinetic model 2(R=0.996)providing the best fit to experimental data.Mechanistic analysis indicated that chemisorption,2+primarily through ion exchange and inner-sphere complexation,was the dominant mode of Mn uptake.3+The presence of competing cations,especially Fe and Cu2+,2+significantly hindered Mn removal due to preferential binding.Importantly,BC exhibited strong reusability,maintaining over 80%removal effi-ciency across four adsorption–desorption cycles without evidence of secondary pollutants.These findings demonstrate the potential of natural BC as an efficient,reusable,and environmentally benign material for treating manganese-contaminated groundwater. 展开更多
关键词 SORPTION surface complexation Ion exchange Geochemical modelling Heavy metals Secondary pollution
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Application of Surface Complexation Model to^(63)Ni Sorption to Selected Granitic Rocks and Minerals:Sorption at Varying pH
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作者 Fidelis Sameh Ebong Gillian Nkeudem Asoba +1 位作者 Frederick Ngolemasango Ediage Nick Evans 《Journal of Geoscience and Environment Protection》 2025年第4期269-294,共26页
The immobilisation of radionuclides in groundwater environments cannot be explained solely by the empirical models.These empirical models are not sen-sitive to the varying conditions that are found in nature.Sorption ... The immobilisation of radionuclides in groundwater environments cannot be explained solely by the empirical models.These empirical models are not sen-sitive to the varying conditions that are found in nature.Sorption has been shown to be very sensitive to pH,Eh and ionic strength of the solution in which the radionuclides are found.Batch sorption experiments at different ionic strengths were conducted and LogK constants for the sorption processes were determined.JChess Geochemical code was used to compare experimentally and predicted Log K constants obtained from surface complexation reactions with different granitic rock samples.For pH dependent sorption,1×10^(-5) mol·dm^(-3) solutions of NiCl_(2) were prepared,and the pH was adjusted from 4 to 11,with intervals of 0.6 to 0.8 on the pH scale using NaOH(aq)and HCl(aq).Different concentrations of pH adjusting solutions were made from very weak to very strong acid or base.Sample separation was performed and counting was performed for Ni using the scintillation counter.Packard TRI-CARB 2750 TR/LL Liquid Scintillation Counter:Used for Ni sorption studies,counting from 0 to 67 keV to 2σ.Results showed varying sorption properties from one granitic mineral to the other.There was no effect of ionic strength on the sorp-tion of Ni to Muscovite Mica(MM).Varying pH sorption isotherms for Ni sorption to Orthoclase Feldspar,showed experimental data and modelled matched for monodentate and bi dentate sorption using the same experimental conditions,modelling done assuming mono and bidentate complex formation.The following conclusions can be made after studying varying pH sorption profiles of selected granitic rocks and mineral in different NaCl concentrations,using different models.Ni sorption is suppressed in the presence of NaCl,due to competition for the sorption sites. 展开更多
关键词 surface complexation SORPTION Granitic Materials
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