Three new metal complexes derived from Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ） with 2-aminobenzohydrazide （ABH） were synthesized and characterized by elemental analyses, IR, ^1H-NMR, ES-MS and transmission electron microsco...Three new metal complexes derived from Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ） with 2-aminobenzohydrazide （ABH） were synthesized and characterized by elemental analyses, IR, ^1H-NMR, ES-MS and transmission electron microscopy （TEM）. The morphology and the particle size were determined by TEM. The results showed that the ligand acted as neutral bi-dentate coordinating to the metal ions through the carbonyl oxygen and amidic amino nitrogen. The aromatic amine group remained inert towards coordination. The optical band gap was measured and found to be 3.3, 3.5 and 4.3 eV for Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ）, respectively. The optical band gap values indicated a semi-conducting nature of the investigated complexes. The anti-inflammatory and analgesic activities of the tested compounds were determined and compared with standard meloxicam.展开更多
Axial flux hysteresis motor (AFHM) is self-starting synchronous motor that uses the hysteresis characteristics of magnetic materials. It is known that the magnetic characteristics of hysteresis motor could be easily a...Axial flux hysteresis motor (AFHM) is self-starting synchronous motor that uses the hysteresis characteristics of magnetic materials. It is known that the magnetic characteristics of hysteresis motor could be easily affected by air gap and structure dimensions variation. Air gap length plays an important role in flux distribution in hysteresis ring and influences the output torque, terminal current, efficiency and even optimal value of other structural parameters of AFHM. Regarding this issue, in this study effect of air gap variation on performance characteristics of an axial flux hysteresis motor and effect of air gap length on hysteresis ring thickness and stator winding turns is investigated. Effect of air gap length on electrical circuit model is perused. Finally, simulation of AFHM in order to extract the output values of motor and sensitivity analysis on air gap variation is done using 3D-Finite Element Model. Hysteresis loop in the shape of an inclined ellipse is adopted. This study can help designers in design approach of such motors.展开更多
Terbium-picrate triethylene glycol（EO3-Tb-Pic） complex was prepared in thin film and single layer device structure of ITO/EO3-Tb-Pic/Al, using spin coating technique. The UV-Vis absorption spectroscopy analysis was ...Terbium-picrate triethylene glycol（EO3-Tb-Pic） complex was prepared in thin film and single layer device structure of ITO/EO3-Tb-Pic/Al, using spin coating technique. The UV-Vis absorption spectroscopy analysis was performed to evaluate the electronic molecular transition of the complex. The optical band gap, Eg estimated from the Tauc model revealed that EO3-Tb-Pic thin film exhibited a direct transition with Eg of 2.70 eV. The electronic parameters of the ITO/EO3-Tb-Pic/Al device such as the ideality factor n, barrier height Φb, saturation current Io, and series resistance Rs, were extracted from the conventional lnI-V, Cheung＇s functions and Norde＇s method. It was found that the evaluated parameters calculated from Norde＇s and Cheung＇s methods were consistent with those calculated from the conventional I-V method. In the double logarithmic I-V plot, three distinct regions based on the slope were identified, and the conduction mechanisms were discussed and explained. The mobility, μ value was estimated from SCLC region as 2.58×10^–7 cm2/（V·s）. This newly obtained lanthanide complex may be potentially utilized in electronic devices.展开更多
文摘Three new metal complexes derived from Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ） with 2-aminobenzohydrazide （ABH） were synthesized and characterized by elemental analyses, IR, ^1H-NMR, ES-MS and transmission electron microscopy （TEM）. The morphology and the particle size were determined by TEM. The results showed that the ligand acted as neutral bi-dentate coordinating to the metal ions through the carbonyl oxygen and amidic amino nitrogen. The aromatic amine group remained inert towards coordination. The optical band gap was measured and found to be 3.3, 3.5 and 4.3 eV for Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ）, respectively. The optical band gap values indicated a semi-conducting nature of the investigated complexes. The anti-inflammatory and analgesic activities of the tested compounds were determined and compared with standard meloxicam.
文摘Axial flux hysteresis motor (AFHM) is self-starting synchronous motor that uses the hysteresis characteristics of magnetic materials. It is known that the magnetic characteristics of hysteresis motor could be easily affected by air gap and structure dimensions variation. Air gap length plays an important role in flux distribution in hysteresis ring and influences the output torque, terminal current, efficiency and even optimal value of other structural parameters of AFHM. Regarding this issue, in this study effect of air gap variation on performance characteristics of an axial flux hysteresis motor and effect of air gap length on hysteresis ring thickness and stator winding turns is investigated. Effect of air gap length on electrical circuit model is perused. Finally, simulation of AFHM in order to extract the output values of motor and sensitivity analysis on air gap variation is done using 3D-Finite Element Model. Hysteresis loop in the shape of an inclined ellipse is adopted. This study can help designers in design approach of such motors.
基金Project supported by University Malaya and Ministry of Higher Education Malaysia under grant(KPT 1059-2012)Science Fund(SF019-2013)Fundamental Research Grant Scheme(FP033-2013B)
文摘Terbium-picrate triethylene glycol（EO3-Tb-Pic） complex was prepared in thin film and single layer device structure of ITO/EO3-Tb-Pic/Al, using spin coating technique. The UV-Vis absorption spectroscopy analysis was performed to evaluate the electronic molecular transition of the complex. The optical band gap, Eg estimated from the Tauc model revealed that EO3-Tb-Pic thin film exhibited a direct transition with Eg of 2.70 eV. The electronic parameters of the ITO/EO3-Tb-Pic/Al device such as the ideality factor n, barrier height Φb, saturation current Io, and series resistance Rs, were extracted from the conventional lnI-V, Cheung＇s functions and Norde＇s method. It was found that the evaluated parameters calculated from Norde＇s and Cheung＇s methods were consistent with those calculated from the conventional I-V method. In the double logarithmic I-V plot, three distinct regions based on the slope were identified, and the conduction mechanisms were discussed and explained. The mobility, μ value was estimated from SCLC region as 2.58×10^–7 cm2/（V·s）. This newly obtained lanthanide complex may be potentially utilized in electronic devices.
