We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic ligh...We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic lightemitting diode(OLED)materials.By utilizing electronic structure,frontier molecular orbitals,minimum single-line absorption,triplet excited states,and emission spectral data derived from the density functional theory,the usefulness of these Ir(Ⅲ)complexes,including(piq)_(2)Ir(acac),(piq)_(2)Ir(tmd),(piq)_(2)Ir(tpip),(fpiq)_(2)Ir(acac),(fpiq)_(2)Ir(tmd),and(fpiq)_(2)Ir(tpip),in OLEDs was examined,where piq=1-phenylisoquinoline,fpiq=1-(4-fluorophenyl)isoquinoline,acac=(3Z)-4-hydroxypent-3-en-2-one,tmd=(4Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one,and tpip=tetraphenylimido-diphosphonate.These complexes all have low-efficiency roll-off properties,especially(fpiq)_(2)Ir(tpip).Some researchers have successfully synthesized complexes extremely similar to(piq)_(2)Ir(acac)through the Suzuki-Miyaura coupling reaction.展开更多
In this paper,we establish characterizations of α-Bloch functions and little α-Bloch functions on the unit ball as well as the unit polydisk of C^(m),which generalize and improve results of Aulaskari-Lappan,Minda,Au...In this paper,we establish characterizations of α-Bloch functions and little α-Bloch functions on the unit ball as well as the unit polydisk of C^(m),which generalize and improve results of Aulaskari-Lappan,Minda,Aulaskari-Wulan,and Wu.Some examples are also given to complement our theory.展开更多
The authors regret that an error occurred during the preparation of their article:One of the official databases,which was used for functional trait collections,contained an incorrect term–'chametophytes'–for...The authors regret that an error occurred during the preparation of their article:One of the official databases,which was used for functional trait collections,contained an incorrect term–'chametophytes'–for the life form category'chamaephytes'.Unfortunately,this incorrect term was used throughout the article following the nomenclature of this official database:in one instance in the main text,in Fig.3 and its caption,in Fig.5,and in two instances in the supplementary material.展开更多
For non-stationary complex dynamic systems,a standardized algorithm is developed to compute time correlation functions,addressing the limitations of traditional methods reliant on the stationary assumption.The propose...For non-stationary complex dynamic systems,a standardized algorithm is developed to compute time correlation functions,addressing the limitations of traditional methods reliant on the stationary assumption.The proposed algorithm integrates two-point and multi-point time correlation functions into a unified framework.Further,it is verified by a practical application in complex financial systems,demonstrating its potential in various complex dynamic systems.展开更多
In this paper,we consider the truncated multiplicity finite range set problem of meromorphic functions on some complex disc.By using the value distribution theory of meromorphic functions,we establish a second main th...In this paper,we consider the truncated multiplicity finite range set problem of meromorphic functions on some complex disc.By using the value distribution theory of meromorphic functions,we establish a second main theorem for meromorphic functions with finite growth index which share meromorphic functions(may not be small functions).As its application,we also extend the result of a finite range set with truncated multiplicity.展开更多
In this paper, we investigate one kind of complex-valued systems with an impulsive control field, where the complex-valued system is governed by the Schrödinger equation, which is used for quantum systems, etc. W...In this paper, we investigate one kind of complex-valued systems with an impulsive control field, where the complex-valued system is governed by the Schrödinger equation, which is used for quantum systems, etc. We study the convergence of the complex-valued system with impulsive control fields by one Lyapunov function based on the state distance and the invariant principle of impulsive systems. We propose new results for the mentioned complex-valued systems in the form of sufficient conditions and also present one numerical simulation to illustrate the effectiveness of the proposed control method.展开更多
In this paper,the class of starlike functions of complex order γ(γ∈ℂ−{0})is extended from the case on unit disk U=(z∈C:|z|<1)to the case on the unit ball B in a complex Banach space or the unit polydisk U^(n) i...In this paper,the class of starlike functions of complex order γ(γ∈ℂ−{0})is extended from the case on unit disk U=(z∈C:|z|<1)to the case on the unit ball B in a complex Banach space or the unit polydisk U^(n) in C^(n).Let g be a convex function in U. We mainly establish the sharp bounds of all terms of homogeneous polynomial expansions for a subclass of g-parametric starlike mappings of complex order γ on B (resp.U^(n))when the mappings f are k-fold symmetric, k ∈ N. Our results partly solve the Bieberbach conjecture in several complex variables and generalize some prior works.展开更多
Stability criteria for the complex-valued impulsive system are applied widely in many fields, such as quantum systems, which have been studied in recent decades. In this paper, I investigate the Lyapunov control of fi...Stability criteria for the complex-valued impulsive system are applied widely in many fields, such as quantum systems, which have been studied in recent decades. In this paper, I investigate the Lyapunov control of finite dimensional complex-valued systems with impulsive control fields, where the studied complex-valued systems are governed by the Schrödinger equation and can be used in quantum systems. By one Lyapunov function based on state error and the invariant principle of impulsive systems, I study the convergence of complex-valued systems with impulsive control fields and propose new results for the mentioned complex-valued systems in the form of sufficient conditions. A numerical simulation to validate the proposed control method is provided.展开更多
Quantum density functional theory （DFT） results are reported for the building block [LaL^1（NO3）] of La complex [LaL^1（NO3）]NO3·5H2O （L^1 = （CH3）2CHCH2CH（NCHC4H3O）COO^-）. The structure was optimized an...Quantum density functional theory （DFT） results are reported for the building block [LaL^1（NO3）] of La complex [LaL^1（NO3）]NO3·5H2O （L^1 = （CH3）2CHCH2CH（NCHC4H3O）COO^-）. The structure was optimized and the calculation results show that the lanthanum ion is coordinated by one nitrogen atom and three oxygen atoms of L^1 and two oxygen atoms of nitrate ion. The bond length of La-N is 0.2637 nm and the average length of La-O is 0.2526 nm, which are consistent with the literatures. In addition, the stabilities, electronic structural characteristics and IR spectra of the complex have been analyzed, which describe the coordination of lanthanum ion with other atoms in detail.展开更多
Using energy analysis,the quantifying evaluation and study method on production, living and ecology functions and their sustainability of rural settlement ecosystem in mountain area is established with these energy in...Using energy analysis,the quantifying evaluation and study method on production, living and ecology functions and their sustainability of rural settlement ecosystem in mountain area is established with these energy index such as export of labor and products, export of water resource, internal energy reserve, energy consumption for human living, net energy of ecosystem function and net internal reserve. Taking rural settlement Raosi Village in Hengduan Mountains as a case study, and on the basis of the synthetic research into the ecological process of the complex ecosystem, the study shows that energy costs of production, human living and ecology functions are separately taking 1.36%, 13.59% and 85. 05% of the gross ecosystem functions, and the exertions of production and human living functions are close to a high-point state on the present using level of energy in the settlement. The study also shows that the most important function of a rural settlement in mountain area is its ecological rather productive function.展开更多
It is necessary to develop burn-resistant and thermal barrier complex functional coatings on the titanium alloys surface due to the poor high temperature performance for titanium materials and the problem of“titanium...It is necessary to develop burn-resistant and thermal barrier complex functional coatings on the titanium alloys surface due to the poor high temperature performance for titanium materials and the problem of“titanium fire”which is easily happened.MTU Aero Engines GmbH has developed a complex functional coating which has great performance of burn resistant and sealing,the coatings has already been applied on compressor blades and casing for aero-engines and showed great performance.In this study,the complex functional coating which is composed of an electro-spark deposited amorphous Ti40Zr25Ni3 burn-resistant layer and a high-energy plasma spraying prepared YSZ thermal barrier layer was prepared on titanium alloys surface.Then the heat insulation ability,burn resistant performance and the bonding strength were investigated.The experimental results showed that the interface between the coating and the matrix was typical metallurgical bonded,and the average bonding strength was 36.335 MPa;when the temperature of the flame on the one side of the specimen reached 600℃,the average insulated temperature of the coating samples was 70.67℃;when the flame temperature was 350℃,the titanium samples without the complex functional coatings were burned,while the samples with the coating showed great performance of burn resistant even when the temperature was 750℃.This indicates that the new functional coating has good heat-insulating and burn-resistant performance.展开更多
Complex tibial plateau fractures can seriously affect quality of life and physical and mental health of patients.The anatomical relationship between the proximal tibial bone and soft tissue is complex,resulting in dif...Complex tibial plateau fractures can seriously affect quality of life and physical and mental health of patients.The anatomical relationship between the proximal tibial bone and soft tissue is complex,resulting in different types of tibial plateau fractures.Violent trauma can lead to displaced fracture,serious soft tissue injury,and potentially,dislocation of the knee joint.Therefore,tibial plateau fractures are extremely unstable.AIM To assess the use of locking compression plate(LCP)+T-type steel plate for postoperative weight bearing and functional recovery of complex tibial plateau fractures.METHODS Ninety-seven patients with complex tibial plateau fractures who underwent surgery at our hospital were selected for retrospective study.Forty-nine patients had been treated with LCP+T-type steel plate limited internal fixation(study group),and 48 patients with bilateral ordinary steel plate support(control group).The operation process index,postoperative rehabilitation related index,Rasmussen score of the knee joint,tibial plateau varus angle(TPA),tibial plateau retroversion angle(PA),and surgical complications of the two groups were compared.RESULTS The operation time and intraoperative bone graft volume in the study group were lower than those in the control group(P<0.05).There were no significant differences in surgical bleeding,anterior external incision length,postoperative drainage,hospital stay duration,and fracture healing time between the groups(P>0.05).There was no significant difference in the TPA and PA angle between the groups immediately and 18 mo after surgery(P>0.05).At 12 mo after surgery,the Rasmussen scale score was higher in the study group than in the control group(P<0.05).There was no significant difference in the Rasmussen scale score at 18 mo after surgery,and the radiology score at 12 and 18 mo after surgery,between the two groups(P>0.05).The postoperative complication rate in the study group(3.77%)was lower than that in the control group(15.09%;P<0.05).CONCLUSION LCP+T-type steel plate internal fixation has advantages in terms of minimizing trauma and enabling early postoperative functional exercise,promoting functional recovery and lower limb weight-bearing,and reducing postoperative complications.展开更多
In this article, we mainly develop the foundation of a new function theory of several complex variables with values in a complex Clifford algebra defined on some subdomains of C^n＋l, so-called complex holomorphic Cli...In this article, we mainly develop the foundation of a new function theory of several complex variables with values in a complex Clifford algebra defined on some subdomains of C^n＋l, so-called complex holomorphic Cliffordian functions. We define the complex holomorphic Cliffordian functions, study polynomial and singular solutions of the equation D△^mf= 0, obtain the integral representation formula for the complex holo-morphic Cliffordian functions with values in a complex Clifford algebra defined on some submanifolds of C^n＋1, deduce the Taylor expansion and the Laurent expansion for them and prove an invariance under an action of Lie group for them.展开更多
Fluorescent mesoporous silica nanoparticles functionalized with carboxyl group(Znq-CMSCOOH) were successfully synthesized by in situ formation route of 8-hydroxyquinolinate zinc complexes in channels of mesoporous sil...Fluorescent mesoporous silica nanoparticles functionalized with carboxyl group(Znq-CMSCOOH) were successfully synthesized by in situ formation route of 8-hydroxyquinolinate zinc complexes in channels of mesoporous silica nanoparticles and post-grafting of carboxyl group on the surface. Moreover,the particle size and structural properties of Znq-CMS-COOH were characterized by transmission electron microscopy(TEM),field emission scanning electron microscopy(FE-SEM),dynamic light scattering(DLS),Fourier transform infrared spectroscopy(FT-IR),UV-vis spectrometer, fluorescence spectrometer and nitrogen adsorption-desorption measurements. The obtained results suggest that the Znq-CMS-COOH presents the uniform spherical shape with the mean diameter of about 85 nm and the obvious wormhole arrangement mesoporous. In addition, the Znq-CMS-COOH possesses green fluorescence with the emission peaks at 495 nm. So the Znq-CMS-COOH, which is beneficial to further modification and tracing, might be a great potential carrier for applying in drug delivery system in the future.展开更多
Poly(ethylene glycol)-poly(lactic acid)block copolymer(PEG-PLA)is one of the most widely used biomedical polymers in clinical drug delivery owing to its biocompatibility and biodegradability.However,endowing PEG-PLA m...Poly(ethylene glycol)-poly(lactic acid)block copolymer(PEG-PLA)is one of the most widely used biomedical polymers in clinical drug delivery owing to its biocompatibility and biodegradability.However,endowing PEG-PLA micelles with high drug loading,self-assembly stability and fast intracellular drug release is still challenging.Redox-responsive diblock copolymers(MPEG-SS-PMLA)of poly(ethylene glycol)and phenyl-functionalized poly(lactic acid)with disulfide bond as the linker are synthesized to prepare PLA-based micelles that demonstrate excellent colloidal stability and high Ru loading.Notably,MPEGSS-PMLA achieved a remarkably high Ru loading efficiency of 84.3%due to the existence of strongπ-πstacking between phenyl and Ru complex.MPEG-SS-PMLA exhibited good colloidal stability in physiological condition but quickly destabilized by reductive tumor microenvironment.Interestingly,about 74%of Ru complex was released under 10 mmol/L GSH concentration.Ru-loaded MEPG-SS-PMLA showed efficient delivery and release of Ru complex into MCF-7 cancer cells,achieving enhanced in vitro and in vivo antitumor activity of photodynamic therapy.This feasible functionalization method of MPEG-PLA has appeared to be a clinically viable platform for controlled delivery therapeutic agents and enhanced phototherapy.展开更多
We investigate the problem of function projective synchronization （FPS） in drive–response dynamical networks with non-identical nodes. An adaptive controller is proposed for the FPS of complex dynamical networks wi...We investigate the problem of function projective synchronization （FPS） in drive–response dynamical networks with non-identical nodes. An adaptive controller is proposed for the FPS of complex dynamical networks with uncertain parameters and disturbance. Not only are the unknown parameters of the networks estimated by the adaptive laws obtained from the Lyapunov stability theory and Taylor expansions, but the unknown bounded disturbances are also simultaneously conquered by the proposed control. Finally, a numerical simulation is provided to illustrate the feasibility and effectiveness of the obtained result.展开更多
This paper deals with the modified function projective synchronization problem for general complex networks with multiple proportional delays. With the existence of multiple proportional delays, an effective hybrid fe...This paper deals with the modified function projective synchronization problem for general complex networks with multiple proportional delays. With the existence of multiple proportional delays, an effective hybrid feedback control is designed to attain modified function projective synchronization of networks. Numerical example is provided to show the effectiveness of our result.展开更多
The title compound of isonicotinato lead（Ⅱ） [Pb（C5H4NCOO）2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead（Ⅱ） ion adopts 4-coordinate geometry. Atomic charge dist...The title compound of isonicotinato lead（Ⅱ） [Pb（C5H4NCOO）2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead（Ⅱ） ion adopts 4-coordinate geometry. Atomic charge distributions indicate that during forming the title compound, each isonicotinic acid ion transfers -0.452 e to lead（Ⅱ） ion. The electronic spectra calculations show that there exist two absorption bands and the electronic transitions are mainly derived from the contribution of intraligand π→π^＊ transition and ligand-to-metal charge transfer （LMCT） transition. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between property and temperature have also been obtained. The calculation of the second order optical nonlinearity was carried out, and the molecular hyperpolarizability was 3.62365^＊10^-30 esu.展开更多
Grandi’s paradox, which was posed for a real function of the form <span style="white-space:nowrap;">1/(1+ x), has been resolved and extended to complex valued functions. Resolution of this approximate...Grandi’s paradox, which was posed for a real function of the form <span style="white-space:nowrap;">1/(1+ x), has been resolved and extended to complex valued functions. Resolution of this approximately three-hundred-year-old paradox is accomplished by the use of a consistent truncation approach that can be applied to all the series expansions of Grandi-type functions. Furthermore, a new technique for improving the convergence characteristics of power series with alternating signs is introduced. The technique works by successively averaging a series at different orders of truncation. A sound theoretical justification of the successive averaging method is demonstrated by two different series expansions of the function <span style="white-space:nowrap;">1/(1+ e<sup>x </sup>) . Grandi-type complex valued functions such as <span style="white-space:nowrap;">1/(i + x) are expressed as consistently-truncated and convergence-improved forms and Fagnano’s formula is established from the series expansions of these functions. A Grandi-type general complex valued function <img src="Edit_f4efd7cd-6853-4ca4-b4dc-00f0b798c277.png" width="80" height="24" alt="" /> is introduced and expanded to a consistently truncated and successively averaged series. Finally, an unorthodox application of the successive averaging method to polynomials is presented.展开更多
As a new form of industry proposed in the context of the rural revitalization strategy,the pastoral complex has sprung up under the support of various policies.However,there are also various problems in the developmen...As a new form of industry proposed in the context of the rural revitalization strategy,the pastoral complex has sprung up under the support of various policies.However,there are also various problems in the development of pastoral complex.The functional positioning of pastoral complex is not proper and there is serious homogeneous problem.These greatly restrict the development of pastoral complex.This study,taking the rural revitalization strategy as the background,analyzed the functional positioning of pastoral complex from production,ecology,and living.Besides,taking Pavlo Eco Valley in Gaoan City of Jiangxi Province as an example,it studied its functional positioning and came up with pertinent recommendations for its further development.展开更多
文摘We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic lightemitting diode(OLED)materials.By utilizing electronic structure,frontier molecular orbitals,minimum single-line absorption,triplet excited states,and emission spectral data derived from the density functional theory,the usefulness of these Ir(Ⅲ)complexes,including(piq)_(2)Ir(acac),(piq)_(2)Ir(tmd),(piq)_(2)Ir(tpip),(fpiq)_(2)Ir(acac),(fpiq)_(2)Ir(tmd),and(fpiq)_(2)Ir(tpip),in OLEDs was examined,where piq=1-phenylisoquinoline,fpiq=1-(4-fluorophenyl)isoquinoline,acac=(3Z)-4-hydroxypent-3-en-2-one,tmd=(4Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one,and tpip=tetraphenylimido-diphosphonate.These complexes all have low-efficiency roll-off properties,especially(fpiq)_(2)Ir(tpip).Some researchers have successfully synthesized complexes extremely similar to(piq)_(2)Ir(acac)through the Suzuki-Miyaura coupling reaction.
基金Supported by Natural Science Research Project for Colleges and Universities of Anhui Province(Grant No.2022AH050329)Yunnan Provincial Department of Education Fund(Grant No.2025J0376).
文摘In this paper,we establish characterizations of α-Bloch functions and little α-Bloch functions on the unit ball as well as the unit polydisk of C^(m),which generalize and improve results of Aulaskari-Lappan,Minda,Aulaskari-Wulan,and Wu.Some examples are also given to complement our theory.
文摘The authors regret that an error occurred during the preparation of their article:One of the official databases,which was used for functional trait collections,contained an incorrect term–'chametophytes'–for the life form category'chamaephytes'.Unfortunately,this incorrect term was used throughout the article following the nomenclature of this official database:in one instance in the main text,in Fig.3 and its caption,in Fig.5,and in two instances in the supplementary material.
基金Project supported by the Postdoctoral Fellowship Program of China Postdoctoral Science Foundation(Grant No.GZC20231050)the National Natural Science Foundation of China(Grant Nos.12175193 and 11905183)the 13th Five-year plan for Education Science Funding of Guangdong Province(Grant No.2021GXJK349)。
文摘For non-stationary complex dynamic systems,a standardized algorithm is developed to compute time correlation functions,addressing the limitations of traditional methods reliant on the stationary assumption.The proposed algorithm integrates two-point and multi-point time correlation functions into a unified framework.Further,it is verified by a practical application in complex financial systems,demonstrating its potential in various complex dynamic systems.
基金Supported by National Natural Science Foundation of China(12061041)Jiangxi Provincial Natural Science Foundation(20232BAB201003).
文摘In this paper,we consider the truncated multiplicity finite range set problem of meromorphic functions on some complex disc.By using the value distribution theory of meromorphic functions,we establish a second main theorem for meromorphic functions with finite growth index which share meromorphic functions(may not be small functions).As its application,we also extend the result of a finite range set with truncated multiplicity.
文摘In this paper, we investigate one kind of complex-valued systems with an impulsive control field, where the complex-valued system is governed by the Schrödinger equation, which is used for quantum systems, etc. We study the convergence of the complex-valued system with impulsive control fields by one Lyapunov function based on the state distance and the invariant principle of impulsive systems. We propose new results for the mentioned complex-valued systems in the form of sufficient conditions and also present one numerical simulation to illustrate the effectiveness of the proposed control method.
基金supported by the National Natural Science Foundation of China(12061035)the Research Foundation of Jiangxi Science and Technology Normal University of China(2021QNBJRC003)supported by the Graduate Innovation Fund of Jiangxi Science and Technology Normal University(YC2024-X10).
文摘In this paper,the class of starlike functions of complex order γ(γ∈ℂ−{0})is extended from the case on unit disk U=(z∈C:|z|<1)to the case on the unit ball B in a complex Banach space or the unit polydisk U^(n) in C^(n).Let g be a convex function in U. We mainly establish the sharp bounds of all terms of homogeneous polynomial expansions for a subclass of g-parametric starlike mappings of complex order γ on B (resp.U^(n))when the mappings f are k-fold symmetric, k ∈ N. Our results partly solve the Bieberbach conjecture in several complex variables and generalize some prior works.
文摘Stability criteria for the complex-valued impulsive system are applied widely in many fields, such as quantum systems, which have been studied in recent decades. In this paper, I investigate the Lyapunov control of finite dimensional complex-valued systems with impulsive control fields, where the studied complex-valued systems are governed by the Schrödinger equation and can be used in quantum systems. By one Lyapunov function based on state error and the invariant principle of impulsive systems, I study the convergence of complex-valued systems with impulsive control fields and propose new results for the mentioned complex-valued systems in the form of sufficient conditions. A numerical simulation to validate the proposed control method is provided.
基金This work was supported by the National Natural Science Foundation of China (20203011)
文摘Quantum density functional theory （DFT） results are reported for the building block [LaL^1（NO3）] of La complex [LaL^1（NO3）]NO3·5H2O （L^1 = （CH3）2CHCH2CH（NCHC4H3O）COO^-）. The structure was optimized and the calculation results show that the lanthanum ion is coordinated by one nitrogen atom and three oxygen atoms of L^1 and two oxygen atoms of nitrate ion. The bond length of La-N is 0.2637 nm and the average length of La-O is 0.2526 nm, which are consistent with the literatures. In addition, the stabilities, electronic structural characteristics and IR spectra of the complex have been analyzed, which describe the coordination of lanthanum ion with other atoms in detail.
文摘Using energy analysis,the quantifying evaluation and study method on production, living and ecology functions and their sustainability of rural settlement ecosystem in mountain area is established with these energy index such as export of labor and products, export of water resource, internal energy reserve, energy consumption for human living, net energy of ecosystem function and net internal reserve. Taking rural settlement Raosi Village in Hengduan Mountains as a case study, and on the basis of the synthetic research into the ecological process of the complex ecosystem, the study shows that energy costs of production, human living and ecology functions are separately taking 1.36%, 13.59% and 85. 05% of the gross ecosystem functions, and the exertions of production and human living functions are close to a high-point state on the present using level of energy in the settlement. The study also shows that the most important function of a rural settlement in mountain area is its ecological rather productive function.
文摘It is necessary to develop burn-resistant and thermal barrier complex functional coatings on the titanium alloys surface due to the poor high temperature performance for titanium materials and the problem of“titanium fire”which is easily happened.MTU Aero Engines GmbH has developed a complex functional coating which has great performance of burn resistant and sealing,the coatings has already been applied on compressor blades and casing for aero-engines and showed great performance.In this study,the complex functional coating which is composed of an electro-spark deposited amorphous Ti40Zr25Ni3 burn-resistant layer and a high-energy plasma spraying prepared YSZ thermal barrier layer was prepared on titanium alloys surface.Then the heat insulation ability,burn resistant performance and the bonding strength were investigated.The experimental results showed that the interface between the coating and the matrix was typical metallurgical bonded,and the average bonding strength was 36.335 MPa;when the temperature of the flame on the one side of the specimen reached 600℃,the average insulated temperature of the coating samples was 70.67℃;when the flame temperature was 350℃,the titanium samples without the complex functional coatings were burned,while the samples with the coating showed great performance of burn resistant even when the temperature was 750℃.This indicates that the new functional coating has good heat-insulating and burn-resistant performance.
文摘Complex tibial plateau fractures can seriously affect quality of life and physical and mental health of patients.The anatomical relationship between the proximal tibial bone and soft tissue is complex,resulting in different types of tibial plateau fractures.Violent trauma can lead to displaced fracture,serious soft tissue injury,and potentially,dislocation of the knee joint.Therefore,tibial plateau fractures are extremely unstable.AIM To assess the use of locking compression plate(LCP)+T-type steel plate for postoperative weight bearing and functional recovery of complex tibial plateau fractures.METHODS Ninety-seven patients with complex tibial plateau fractures who underwent surgery at our hospital were selected for retrospective study.Forty-nine patients had been treated with LCP+T-type steel plate limited internal fixation(study group),and 48 patients with bilateral ordinary steel plate support(control group).The operation process index,postoperative rehabilitation related index,Rasmussen score of the knee joint,tibial plateau varus angle(TPA),tibial plateau retroversion angle(PA),and surgical complications of the two groups were compared.RESULTS The operation time and intraoperative bone graft volume in the study group were lower than those in the control group(P<0.05).There were no significant differences in surgical bleeding,anterior external incision length,postoperative drainage,hospital stay duration,and fracture healing time between the groups(P>0.05).There was no significant difference in the TPA and PA angle between the groups immediately and 18 mo after surgery(P>0.05).At 12 mo after surgery,the Rasmussen scale score was higher in the study group than in the control group(P<0.05).There was no significant difference in the Rasmussen scale score at 18 mo after surgery,and the radiology score at 12 and 18 mo after surgery,between the two groups(P>0.05).The postoperative complication rate in the study group(3.77%)was lower than that in the control group(15.09%;P<0.05).CONCLUSION LCP+T-type steel plate internal fixation has advantages in terms of minimizing trauma and enabling early postoperative functional exercise,promoting functional recovery and lower limb weight-bearing,and reducing postoperative complications.
基金Supported by NNSF of China (6087349, 10871150)863Project of China (2008AA01Z419)+1 种基金RFDP of Higher Education (20060486001)Post-Doctor Foundation ofChina (20090460316)
文摘In this article, we mainly develop the foundation of a new function theory of several complex variables with values in a complex Clifford algebra defined on some subdomains of C^n＋l, so-called complex holomorphic Cliffordian functions. We define the complex holomorphic Cliffordian functions, study polynomial and singular solutions of the equation D△^mf= 0, obtain the integral representation formula for the complex holo-morphic Cliffordian functions with values in a complex Clifford algebra defined on some submanifolds of C^n＋1, deduce the Taylor expansion and the Laurent expansion for them and prove an invariance under an action of Lie group for them.
基金Fund by the National Natural Science Foundation of China(No.8120119)
文摘Fluorescent mesoporous silica nanoparticles functionalized with carboxyl group(Znq-CMSCOOH) were successfully synthesized by in situ formation route of 8-hydroxyquinolinate zinc complexes in channels of mesoporous silica nanoparticles and post-grafting of carboxyl group on the surface. Moreover,the particle size and structural properties of Znq-CMS-COOH were characterized by transmission electron microscopy(TEM),field emission scanning electron microscopy(FE-SEM),dynamic light scattering(DLS),Fourier transform infrared spectroscopy(FT-IR),UV-vis spectrometer, fluorescence spectrometer and nitrogen adsorption-desorption measurements. The obtained results suggest that the Znq-CMS-COOH presents the uniform spherical shape with the mean diameter of about 85 nm and the obvious wormhole arrangement mesoporous. In addition, the Znq-CMS-COOH possesses green fluorescence with the emission peaks at 495 nm. So the Znq-CMS-COOH, which is beneficial to further modification and tracing, might be a great potential carrier for applying in drug delivery system in the future.
基金financially supported by the National Science Foundation of China(Nos.22022803,22078046,21808028)Science and Technology Foundation of Liaoning Province(Nos.2019BS-047,2021-YGJC-17)Fundamental Research Funds for the Central Universities(No.DUT20YG131)。
文摘Poly(ethylene glycol)-poly(lactic acid)block copolymer(PEG-PLA)is one of the most widely used biomedical polymers in clinical drug delivery owing to its biocompatibility and biodegradability.However,endowing PEG-PLA micelles with high drug loading,self-assembly stability and fast intracellular drug release is still challenging.Redox-responsive diblock copolymers(MPEG-SS-PMLA)of poly(ethylene glycol)and phenyl-functionalized poly(lactic acid)with disulfide bond as the linker are synthesized to prepare PLA-based micelles that demonstrate excellent colloidal stability and high Ru loading.Notably,MPEGSS-PMLA achieved a remarkably high Ru loading efficiency of 84.3%due to the existence of strongπ-πstacking between phenyl and Ru complex.MPEG-SS-PMLA exhibited good colloidal stability in physiological condition but quickly destabilized by reductive tumor microenvironment.Interestingly,about 74%of Ru complex was released under 10 mmol/L GSH concentration.Ru-loaded MEPG-SS-PMLA showed efficient delivery and release of Ru complex into MCF-7 cancer cells,achieving enhanced in vitro and in vivo antitumor activity of photodynamic therapy.This feasible functionalization method of MPEG-PLA has appeared to be a clinically viable platform for controlled delivery therapeutic agents and enhanced phototherapy.
基金the National Natural Science Foundation of China(Grant No.70871056)the Fundamental Research Funds for the Central Universities,China(Grant No.2013B10014)
文摘We investigate the problem of function projective synchronization （FPS） in drive–response dynamical networks with non-identical nodes. An adaptive controller is proposed for the FPS of complex dynamical networks with uncertain parameters and disturbance. Not only are the unknown parameters of the networks estimated by the adaptive laws obtained from the Lyapunov stability theory and Taylor expansions, but the unknown bounded disturbances are also simultaneously conquered by the proposed control. Finally, a numerical simulation is provided to illustrate the feasibility and effectiveness of the obtained result.
文摘This paper deals with the modified function projective synchronization problem for general complex networks with multiple proportional delays. With the existence of multiple proportional delays, an effective hybrid feedback control is designed to attain modified function projective synchronization of networks. Numerical example is provided to show the effectiveness of our result.
基金This work was supported by the Natural Science Foundation of Shandong Province (No. Y2002B06)
文摘The title compound of isonicotinato lead（Ⅱ） [Pb（C5H4NCOO）2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead（Ⅱ） ion adopts 4-coordinate geometry. Atomic charge distributions indicate that during forming the title compound, each isonicotinic acid ion transfers -0.452 e to lead（Ⅱ） ion. The electronic spectra calculations show that there exist two absorption bands and the electronic transitions are mainly derived from the contribution of intraligand π→π^＊ transition and ligand-to-metal charge transfer （LMCT） transition. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between property and temperature have also been obtained. The calculation of the second order optical nonlinearity was carried out, and the molecular hyperpolarizability was 3.62365^＊10^-30 esu.
文摘Grandi’s paradox, which was posed for a real function of the form <span style="white-space:nowrap;">1/(1+ x), has been resolved and extended to complex valued functions. Resolution of this approximately three-hundred-year-old paradox is accomplished by the use of a consistent truncation approach that can be applied to all the series expansions of Grandi-type functions. Furthermore, a new technique for improving the convergence characteristics of power series with alternating signs is introduced. The technique works by successively averaging a series at different orders of truncation. A sound theoretical justification of the successive averaging method is demonstrated by two different series expansions of the function <span style="white-space:nowrap;">1/(1+ e<sup>x </sup>) . Grandi-type complex valued functions such as <span style="white-space:nowrap;">1/(i + x) are expressed as consistently-truncated and convergence-improved forms and Fagnano’s formula is established from the series expansions of these functions. A Grandi-type general complex valued function <img src="Edit_f4efd7cd-6853-4ca4-b4dc-00f0b798c277.png" width="80" height="24" alt="" /> is introduced and expanded to a consistently truncated and successively averaged series. Finally, an unorthodox application of the successive averaging method to polynomials is presented.
文摘As a new form of industry proposed in the context of the rural revitalization strategy,the pastoral complex has sprung up under the support of various policies.However,there are also various problems in the development of pastoral complex.The functional positioning of pastoral complex is not proper and there is serious homogeneous problem.These greatly restrict the development of pastoral complex.This study,taking the rural revitalization strategy as the background,analyzed the functional positioning of pastoral complex from production,ecology,and living.Besides,taking Pavlo Eco Valley in Gaoan City of Jiangxi Province as an example,it studied its functional positioning and came up with pertinent recommendations for its further development.
