The geological background of the Subei basin is that of small relief subsidence, low geothermal gradient, multi-sedimentary hiatuses, intense reconstruction of the basin, frequent magmatic activity, and a unique combi...The geological background of the Subei basin is that of small relief subsidence, low geothermal gradient, multi-sedimentary hiatuses, intense reconstruction of the basin, frequent magmatic activity, and a unique combination of source rock and reservoir. This geological background resulted in characteristics such as many small fault blocks, multiple oil-bearing formations, scattered oil distribution, mini- to small-sized reservoirs, and difficulties in exploration. Aimed at such characteristics, an effective exploration strategy was adopted, and the oil reserves, production and economic benefits of the Jiangsu oilfield were significantly increased. This exploration strategy included understanding the hydrocarbon generation mechanism of source rocks, progressive evaluation of oil resources, comprehensive research on the faulted systems, the distribution of oil reservoirs and their controlling factors. The techniques used included integration of acquisition, processing and interpretation with 3-D seismics as the core technology, trap description and evaluation, directional drilling and cluster drilling, integration of cuttings logging, gas chromatographic logging and geochemical logging, and integration of early reservoir description and progressive exploration and development. This strategy could be guidance for other complex fault blocks.展开更多
In the present investigation, the novel copper Schiff base complex was synthesized and its catalytic activity was evaluated for the ring-opening polymerization （ROP） of lactide and block polymerization of poly（lact...In the present investigation, the novel copper Schiff base complex was synthesized and its catalytic activity was evaluated for the ring-opening polymerization （ROP） of lactide and block polymerization of poly（lactide） with po/y（ethylene glycol）methyl ether,展开更多
In the middle and second half of oilfield development,further exploration and development of petroleum reservoirs in complex fault blocks are major tasks.Based on the characteristics of fully developed farewell faults...In the middle and second half of oilfield development,further exploration and development of petroleum reservoirs in complex fault blocks are major tasks.Based on the characteristics of fully developed farewell faults in the Wenweigu oil field and the data from 3D earthquakes,RFT,HDT and other techniques,farewell faults and their distribution were identified.Conformation of the fault blocks has been provided and the precision of describing the farewell faults improved.Research technology of farewell faults has applied these methods in this region.展开更多
The solid form of drugs plays a central role in optimizing the physicochemical properties of drugs,and new solid forms will provide more options to achieve the desirable pharmaceutical profiles of drugs.Recently,certa...The solid form of drugs plays a central role in optimizing the physicochemical properties of drugs,and new solid forms will provide more options to achieve the desirable pharmaceutical profiles of drugs.Recently,certain drugs have been found to form crystalline inclusion complexes（ICs） with multiple types of linear polymers,representing a new subcategory of pharmaceutical solids.In this study,we used diflunisal（DIF） as the model drug host and extended the vip of drug/polymer ICs from homopolymers to block copolymers of poly（ethylene glycol）（PEG） and poly（s-caprolactone）（PCL）.The block length in the vip copolymers showed a significant influence on the formation,thermal stability and dissolution behavior of the DIF ICs.Though the PEG block could hardly be included alone,it could indeed be included in the DIF ICs when the PCL block was long enough.The increase of the PCL block length produced IC crystals with improved thermal stability.The dissolution profiles of DIF/block copolymer ICs exhibited gradually decreased aqueous solubility and dissolution rate with the increasing PCL block length.These results demonstrate the possibility of using drug/polymer ICs to modulate the desired pharmaceutical profiles of drugs in a predictable and controllable manner.展开更多
Recent research challenges in the wireless communication include the usage of diversity and efficient coding to improve data transmission quality and spectral efficiency. Space diversity uses multiple transmitting and...Recent research challenges in the wireless communication include the usage of diversity and efficient coding to improve data transmission quality and spectral efficiency. Space diversity uses multiple transmitting and/or receiving antennas to create independent fading channels without penalty in bandwidth efficiency. Space-time block coding is an encoding scheme for communication over Rayleigh fading channels using multiple transmitting antennas. Space-time block codes from complex orthogonal designs exist only for two transmitting antennas. This paper generalizes a new complex orthogonal space-time block code for four transmitting antennas, whose decoding complexity is very low. Simulations show that the generalized complex orthogonal space-time block code has low bit error rate, full rate and possibly large diversity.展开更多
Paleoproterozoic potassic granitoids in the southern Sushui Complex from the Zhongtiao Mountains yielded SHRIMP zircon U-Pb ages of 1968-1944 Ma. Lithologically, the potassic granitoid series consists chiefly of monzo...Paleoproterozoic potassic granitoids in the southern Sushui Complex from the Zhongtiao Mountains yielded SHRIMP zircon U-Pb ages of 1968-1944 Ma. Lithologically, the potassic granitoid series consists chiefly of monzodiorite, quartz monzonite and syenogranite. Their trace elements and Sm-Nd isotope characteristics indicate that they were derived from partial melting of Archean TTG rocks in an overthickened continental crust. Petrogenesis of this potassic granitoid series implies a collisional environment within the Trans-North China Orogen in the Paleoproterozoic, which supports a tectonic model of Eastern and Western Continental Blocks being amalgamated in the Paleoproterozoic.展开更多
In combination with methyllithium,a 2,6-bis(amino)phenol zinc complex 1 was used in the ring-opening polymerization ofδ-valerolactone in the absence or presence of benzyl alcohol and showed high efficiency,mainly pro...In combination with methyllithium,a 2,6-bis(amino)phenol zinc complex 1 was used in the ring-opening polymerization ofδ-valerolactone in the absence or presence of benzyl alcohol and showed high efficiency,mainly producing cyclic and linear polyvalerolactones,respectively.On the basis of homopolymerization,the ring-opening copolymerization ofε-caprolactone andδ-valerolactone was investigated.The P(CL-co-VL)random copolymers,PCL-b-PVL and PVL-b-PCL diblock copolymers,were prepared by varying the feeding strategy(premixing or sequential feeding).The copolymer composition was adjusted by varying the feeding ratio of two monomers.The structure and thermal properties of obtained polymers were characterized by GPC,1 H-NMR,13 C-NMR,MALDI-TOF mass spectroscopy,and DSC,respectively.展开更多
The evaluation of wide QRS complex tachycardias (WCT)remains a common dilemma for clinicians.Numerous algorithms exist to aid in arriving at the correct diagnosis.Unfortunately,these algorithms are difficult to rememb...The evaluation of wide QRS complex tachycardias (WCT)remains a common dilemma for clinicians.Numerous algorithms exist to aid in arriving at the correct diagnosis.Unfortunately,these algorithms are difficult to remember,and overreliance on them may prevent cardiologists from understanding the mechanisms underlying these arrhythmias.One distinct subcategory of WCTs are those that present with a"typical"or"classic" left bundle branch block pattern.These tachycardias may be supraventricular or ventricular in origin and arise from functional or fixed aberrancy,bystander or participating atriofascicular pre-excitation,and bundle branch reentry.This review will describe these arrhythmias,illustrate their mechanisms,and discuss their clinical features and treatment strategies.展开更多
L-lactide（LLA） homopolymerization and copolymerization with ε-caprolactone（CL） in toluene initiated by tetrahydrosalen-supported yttrium borohydride complex were systematically investigated. A possible mechanism ...L-lactide（LLA） homopolymerization and copolymerization with ε-caprolactone（CL） in toluene initiated by tetrahydrosalen-supported yttrium borohydride complex were systematically investigated. A possible mechanism of LLA homopolymerization was proposed according to the 1H-NMR result. In addition, PCL-b-PLLA copolymers were synthesized by sequential addition of monomers and their structure was characterized by GPC, 1H-NMR and 13C-NMR.展开更多
The solid forms of drugs play a central role in controlling their physicochemical properties and consequently the bioavailability. Multiple types of drug solid forms have been developed to achieve the desirable pharma...The solid forms of drugs play a central role in controlling their physicochemical properties and consequently the bioavailability. Multiple types of drug solid forms have been developed to achieve the desirable pharmaceutical profiles, but new solid forms will provide more options for the solid-state property optimization and hence are highly desirable. This review focuses on a new pharmaceutical solid form, drug-polymer inclusion complexes （ICs）, and summarizes their structural features, structure- property relationships, as well as potential pharmaceutical applications展开更多
This study shows that the intrusive rocks distributed in the Aoyiqieke-Tamuqi area on the southern margin of the Tarim Block are composed of gabbro, diorite, granodiorite and granite, which constitute regionally a nea...This study shows that the intrusive rocks distributed in the Aoyiqieke-Tamuqi area on the southern margin of the Tarim Block are composed of gabbro, diorite, granodiorite and granite, which constitute regionally a nearly EW-trending tectono-magmatic belt. Petrochemically the diorite, granodiorite and granite belong to the calc-alkaline, high-K series, with Na 2O/K 2O ratios varying between 0.83 and 2.63. M/F ratios in the diorite are within the range of 0.44- 0.70 and those of the granodiorite (granite) are 0.45- 0.87. Petrochemistry data show that the intrusive complexes are of the I type and their ΣREE is slightly variable, within the range of 178.31- 229.01×10 -6. The LREE/HREE ratios of the diorite and granite are 3.78- 5.13 and 6.69- 7.66, respectively. The plutons usually show moderate negative Eu anomalies with δEu values ranging from 0.53 to 0.82, showing almost no difference among different rocks. The (La/Yb) N values of diorite and granite are 12.39- 14.86 and 22.07- 26.03, respectively. The diorite and granite possess very similar REE distribution patterns, indicating that they were both derived from the same source. As for their trace element ratios, the diorite has higher Nb/Ta ratios than the granite, which are 15.73- 17.16 and 12.03- 15.01, respectively. It can be seen that the Nb/Ta ratios of the diorite are much closer to the average mantle ( 17.5). Their Zr/Hf ratios are very close to each other, within the range of 29-34. Th/Y ratios in the diorite are 0.42- 0.80 (all less than unity) while those of the granite are 1.02- 2.04. Some difference is also noticed in Ti/V between the diorite and the granite ( 52.6- 54.2 for the former and 52.6- 54.2 for the latter). As compared with ocean ridge granites, both diorite and granite are characterized by remarkable LILE enrichment, as well as by moderate negative Ba and postive Ce anomalies. The contents of Nb and Ta in the diorite and granite are equivalent to those of the ocean ridge granites, but the contents of Zr, Hf, Sm, Y, and Yb are all lower than those of the ocean ridge granites, indicating that these granites are similar to the island-arc granites of Chile. From their geochemical characteristics, it is considered that the intrusive rocks in the area studied were formed in an island-arc environment at the continental margin.展开更多
The charnockites of Marandahalli, Dharmapuri District, Tamil Nadu India, form a part of the southern granulitic terrain in the Salem Block (SB). The charnockites are medium to coarse grained, inequigranular, with porp...The charnockites of Marandahalli, Dharmapuri District, Tamil Nadu India, form a part of the southern granulitic terrain in the Salem Block (SB). The charnockites are medium to coarse grained, inequigranular, with porphyroblastic and granophyric textures. They are composed of plagioclase feldspars (49 - 66 vol.%), K-feldspar (1 - 5 vol.%) and quartz (21 - 34 vol.%). The mafic minerals include pyroxene (2 - 7 vol.%) and biotite (1 - 12 vol.%). The accessory minerals include magnetite and apatite. Orthopyroxene compositions (MgO 16 - 22 wt.%) fall within the hypersthene series (En55.03Fs43.57Wo1.4) and yield peak metamorphic temperatures of 800˚C - 1000˚C. Biotites show K2O, MgO, FeO, TiO2, and Al2O3 concentrations consistent with magmatic formation, and Ti-in-biotite thermometry suggests temperatures of ~740˚C - 800˚C. Plagioclase compositions (An26-33) plot in the oligoclase field, while K-feldspar (Or93-99) plots in the orthoclase/microcline field. A ternary feldspar geothermometer indicates a retrograde temperature of 2 (65 - 68 wt.%), Na2O > K2O, high CaO (3 - 5 wt.%), MgO (2.5 - 4 wt.%) and Fe2O3 (2 - 6 wt.%). The concentration of V, Rb and Ni, and LREE-rich and HREE-depleted patterns of the rocks indicate low degree of partial melting.展开更多
文摘The geological background of the Subei basin is that of small relief subsidence, low geothermal gradient, multi-sedimentary hiatuses, intense reconstruction of the basin, frequent magmatic activity, and a unique combination of source rock and reservoir. This geological background resulted in characteristics such as many small fault blocks, multiple oil-bearing formations, scattered oil distribution, mini- to small-sized reservoirs, and difficulties in exploration. Aimed at such characteristics, an effective exploration strategy was adopted, and the oil reserves, production and economic benefits of the Jiangsu oilfield were significantly increased. This exploration strategy included understanding the hydrocarbon generation mechanism of source rocks, progressive evaluation of oil resources, comprehensive research on the faulted systems, the distribution of oil reservoirs and their controlling factors. The techniques used included integration of acquisition, processing and interpretation with 3-D seismics as the core technology, trap description and evaluation, directional drilling and cluster drilling, integration of cuttings logging, gas chromatographic logging and geochemical logging, and integration of early reservoir description and progressive exploration and development. This strategy could be guidance for other complex fault blocks.
文摘In the present investigation, the novel copper Schiff base complex was synthesized and its catalytic activity was evaluated for the ring-opening polymerization （ROP） of lactide and block polymerization of poly（lactide） with po/y（ethylene glycol）methyl ether,
文摘In the middle and second half of oilfield development,further exploration and development of petroleum reservoirs in complex fault blocks are major tasks.Based on the characteristics of fully developed farewell faults in the Wenweigu oil field and the data from 3D earthquakes,RFT,HDT and other techniques,farewell faults and their distribution were identified.Conformation of the fault blocks has been provided and the precision of describing the farewell faults improved.Research technology of farewell faults has applied these methods in this region.
基金financially supported by the National Natural Science Foundation of China(Nos.21434008,21374054)National Basic Research Program of China(973 Program,No.2014CB932202)
文摘The solid form of drugs plays a central role in optimizing the physicochemical properties of drugs,and new solid forms will provide more options to achieve the desirable pharmaceutical profiles of drugs.Recently,certain drugs have been found to form crystalline inclusion complexes（ICs） with multiple types of linear polymers,representing a new subcategory of pharmaceutical solids.In this study,we used diflunisal（DIF） as the model drug host and extended the vip of drug/polymer ICs from homopolymers to block copolymers of poly（ethylene glycol）（PEG） and poly（s-caprolactone）（PCL）.The block length in the vip copolymers showed a significant influence on the formation,thermal stability and dissolution behavior of the DIF ICs.Though the PEG block could hardly be included alone,it could indeed be included in the DIF ICs when the PCL block was long enough.The increase of the PCL block length produced IC crystals with improved thermal stability.The dissolution profiles of DIF/block copolymer ICs exhibited gradually decreased aqueous solubility and dissolution rate with the increasing PCL block length.These results demonstrate the possibility of using drug/polymer ICs to modulate the desired pharmaceutical profiles of drugs in a predictable and controllable manner.
文摘Recent research challenges in the wireless communication include the usage of diversity and efficient coding to improve data transmission quality and spectral efficiency. Space diversity uses multiple transmitting and/or receiving antennas to create independent fading channels without penalty in bandwidth efficiency. Space-time block coding is an encoding scheme for communication over Rayleigh fading channels using multiple transmitting antennas. Space-time block codes from complex orthogonal designs exist only for two transmitting antennas. This paper generalizes a new complex orthogonal space-time block code for four transmitting antennas, whose decoding complexity is very low. Simulations show that the generalized complex orthogonal space-time block code has low bit error rate, full rate and possibly large diversity.
基金This study was financially supported by the National Natural Science Foundation of China （Grant Nos. 40412012035 and 40511140503）.
文摘Paleoproterozoic potassic granitoids in the southern Sushui Complex from the Zhongtiao Mountains yielded SHRIMP zircon U-Pb ages of 1968-1944 Ma. Lithologically, the potassic granitoid series consists chiefly of monzodiorite, quartz monzonite and syenogranite. Their trace elements and Sm-Nd isotope characteristics indicate that they were derived from partial melting of Archean TTG rocks in an overthickened continental crust. Petrogenesis of this potassic granitoid series implies a collisional environment within the Trans-North China Orogen in the Paleoproterozoic, which supports a tectonic model of Eastern and Western Continental Blocks being amalgamated in the Paleoproterozoic.
基金financially supported by the National Key R&D Program of China (No. 2016YFC1100801)the State Key Laboratory of Chemical Engineering (No. SKL-ChE-18D01)
文摘In combination with methyllithium,a 2,6-bis(amino)phenol zinc complex 1 was used in the ring-opening polymerization ofδ-valerolactone in the absence or presence of benzyl alcohol and showed high efficiency,mainly producing cyclic and linear polyvalerolactones,respectively.On the basis of homopolymerization,the ring-opening copolymerization ofε-caprolactone andδ-valerolactone was investigated.The P(CL-co-VL)random copolymers,PCL-b-PVL and PVL-b-PCL diblock copolymers,were prepared by varying the feeding strategy(premixing or sequential feeding).The copolymer composition was adjusted by varying the feeding ratio of two monomers.The structure and thermal properties of obtained polymers were characterized by GPC,1 H-NMR,13 C-NMR,MALDI-TOF mass spectroscopy,and DSC,respectively.
文摘The evaluation of wide QRS complex tachycardias (WCT)remains a common dilemma for clinicians.Numerous algorithms exist to aid in arriving at the correct diagnosis.Unfortunately,these algorithms are difficult to remember,and overreliance on them may prevent cardiologists from understanding the mechanisms underlying these arrhythmias.One distinct subcategory of WCTs are those that present with a"typical"or"classic" left bundle branch block pattern.These tachycardias may be supraventricular or ventricular in origin and arise from functional or fixed aberrancy,bystander or participating atriofascicular pre-excitation,and bundle branch reentry.This review will describe these arrhythmias,illustrate their mechanisms,and discuss their clinical features and treatment strategies.
基金supported by the National Natural Science Foundation of China(No.21174129)the Program for Zhejiang Leading Teams of S&T Innovation(2011R50007)
文摘L-lactide（LLA） homopolymerization and copolymerization with ε-caprolactone（CL） in toluene initiated by tetrahydrosalen-supported yttrium borohydride complex were systematically investigated. A possible mechanism of LLA homopolymerization was proposed according to the 1H-NMR result. In addition, PCL-b-PLLA copolymers were synthesized by sequential addition of monomers and their structure was characterized by GPC, 1H-NMR and 13C-NMR.
基金supported by the National Natural Science Foundation of China (No. 21434008)
文摘The solid forms of drugs play a central role in controlling their physicochemical properties and consequently the bioavailability. Multiple types of drug solid forms have been developed to achieve the desirable pharmaceutical profiles, but new solid forms will provide more options for the solid-state property optimization and hence are highly desirable. This review focuses on a new pharmaceutical solid form, drug-polymer inclusion complexes （ICs）, and summarizes their structural features, structure- property relationships, as well as potential pharmaceutical applications
文摘This study shows that the intrusive rocks distributed in the Aoyiqieke-Tamuqi area on the southern margin of the Tarim Block are composed of gabbro, diorite, granodiorite and granite, which constitute regionally a nearly EW-trending tectono-magmatic belt. Petrochemically the diorite, granodiorite and granite belong to the calc-alkaline, high-K series, with Na 2O/K 2O ratios varying between 0.83 and 2.63. M/F ratios in the diorite are within the range of 0.44- 0.70 and those of the granodiorite (granite) are 0.45- 0.87. Petrochemistry data show that the intrusive complexes are of the I type and their ΣREE is slightly variable, within the range of 178.31- 229.01×10 -6. The LREE/HREE ratios of the diorite and granite are 3.78- 5.13 and 6.69- 7.66, respectively. The plutons usually show moderate negative Eu anomalies with δEu values ranging from 0.53 to 0.82, showing almost no difference among different rocks. The (La/Yb) N values of diorite and granite are 12.39- 14.86 and 22.07- 26.03, respectively. The diorite and granite possess very similar REE distribution patterns, indicating that they were both derived from the same source. As for their trace element ratios, the diorite has higher Nb/Ta ratios than the granite, which are 15.73- 17.16 and 12.03- 15.01, respectively. It can be seen that the Nb/Ta ratios of the diorite are much closer to the average mantle ( 17.5). Their Zr/Hf ratios are very close to each other, within the range of 29-34. Th/Y ratios in the diorite are 0.42- 0.80 (all less than unity) while those of the granite are 1.02- 2.04. Some difference is also noticed in Ti/V between the diorite and the granite ( 52.6- 54.2 for the former and 52.6- 54.2 for the latter). As compared with ocean ridge granites, both diorite and granite are characterized by remarkable LILE enrichment, as well as by moderate negative Ba and postive Ce anomalies. The contents of Nb and Ta in the diorite and granite are equivalent to those of the ocean ridge granites, but the contents of Zr, Hf, Sm, Y, and Yb are all lower than those of the ocean ridge granites, indicating that these granites are similar to the island-arc granites of Chile. From their geochemical characteristics, it is considered that the intrusive rocks in the area studied were formed in an island-arc environment at the continental margin.
文摘The charnockites of Marandahalli, Dharmapuri District, Tamil Nadu India, form a part of the southern granulitic terrain in the Salem Block (SB). The charnockites are medium to coarse grained, inequigranular, with porphyroblastic and granophyric textures. They are composed of plagioclase feldspars (49 - 66 vol.%), K-feldspar (1 - 5 vol.%) and quartz (21 - 34 vol.%). The mafic minerals include pyroxene (2 - 7 vol.%) and biotite (1 - 12 vol.%). The accessory minerals include magnetite and apatite. Orthopyroxene compositions (MgO 16 - 22 wt.%) fall within the hypersthene series (En55.03Fs43.57Wo1.4) and yield peak metamorphic temperatures of 800˚C - 1000˚C. Biotites show K2O, MgO, FeO, TiO2, and Al2O3 concentrations consistent with magmatic formation, and Ti-in-biotite thermometry suggests temperatures of ~740˚C - 800˚C. Plagioclase compositions (An26-33) plot in the oligoclase field, while K-feldspar (Or93-99) plots in the orthoclase/microcline field. A ternary feldspar geothermometer indicates a retrograde temperature of 2 (65 - 68 wt.%), Na2O > K2O, high CaO (3 - 5 wt.%), MgO (2.5 - 4 wt.%) and Fe2O3 (2 - 6 wt.%). The concentration of V, Rb and Ni, and LREE-rich and HREE-depleted patterns of the rocks indicate low degree of partial melting.
