A new method,named the complete liquid-phase technology,has been applied to prepare catalysts for methanol synthesis.Its main innovative thought lies in preparing slurry catalysts directly from raw solution.Activity t...A new method,named the complete liquid-phase technology,has been applied to prepare catalysts for methanol synthesis.Its main innovative thought lies in preparing slurry catalysts directly from raw solution.Activity tests indicate that the CuZnAl slurry catalyst prepared by the new method can efficiently catalyze conversion of syngas to ethanol in a slurry reactor,while CO conversion reaches 35.9%and ethanol selectivity is more than 20%,with a total alcohol selectivity of more than 87%.No deactivation was found during the 192 h reaction.展开更多
Cu-Zn-Al slurry catalysts were prepared using a complete liquid-phase preparation technology under different heat treatment atmospheres.The catalysts were characterized using X-ray diffraction,X-ray photoelectron spec...Cu-Zn-Al slurry catalysts were prepared using a complete liquid-phase preparation technology under different heat treatment atmospheres.The catalysts were characterized using X-ray diffraction,X-ray photoelectron spectroscope,and N2 adsorption-desorption.Their application in the single-step synthesis of dimethyl ether from syngas was also investigated.The results indicate that the type of heat treatment atmosphere has an influence on the Cu species and the Cu0/Cu＋ ratio on the catalyst surface.Moreover,the final Cu/Zn ratio on the catalyst surface is mainly dependent on the composition and reaction environment of the catalyst and less on the type of heat treatment atmosphere.The prepared catalysts can suppress sintering of active sites at high temperatures,and the type of heat treatment atmosphere mainly affects the capability of the catalyst for methanol synthesis.The catalysts perform best using N2 as the heat treatment atmosphere.展开更多
Technological developments that specifically address automation,compliance with environmental regulations,and hazard avoidance have accelerated more quickly than other drilling and completion technologies in the Unite...Technological developments that specifically address automation,compliance with environmental regulations,and hazard avoidance have accelerated more quickly than other drilling and completion technologies in the United States.This brief article provides a review of areas experiencing some of the most dramatic advances,while describing the need and addressing the solutions as they are now,and how they can be developed in the future.One aspect that all the new technologies have in common is an enhanced use of data analytics and in many cases,cloud-based solutions.A challenge that all have is a need to be able to quickly accommodate rapidly evolving requirements for emissions detection,hazard monitoring,and a reduced carbon footprint.Many solutions to the challenges require the ability to repurpose existing databases and use them for new purposes.展开更多
Cobetia marina is a model proteobacteria in researches on marine biofouling. Its taxonomic nomenclature has been revised many times over the past few decades. To better understand the role of the surface-associated li...Cobetia marina is a model proteobacteria in researches on marine biofouling. Its taxonomic nomenclature has been revised many times over the past few decades. To better understand the role of the surface-associated lifestyle of C. marina and the phylogeny of the family Halomonadaceae, we sequenced the entire genome of C. marina JCM 21022T using single molecule real-time sequencing technology （SMRT） and performed comparative genomics and phylogenomics analyses. The circular chromosome was 4 176 300 bp with an average GC content of 62.44% and contained 3 611 predicted coding sequences, 72 tRNA genes, and 21 rRNA genes. The C. marina JCM 2102U genome contained a set of crucial genes involved in surface colonization processes. The comparative genome analysis indicated the significant differences between C. marina JCM 21022T and Cobetia amphilecti KMM 296 （formerly named C. marina KMM 296） resulted from sequence insertions or deletions and chromosomal recombination. Despite these differences, pan and core genome analysis showed similar gene functions between the two strains. The phylogenomic study of the family Halomonadaceae is relationships were well resolved among every genera Cobetia, Kushneria, Zymobacter, and Halotalea. reported here for the first time. We found that the tested, including Chromohalobacter, Halomonas,展开更多
The exploration and development of oil and gas resources in the Sichuan Basin is shifting to the deeper strata.The deep and ultra-deep wells in deep carbonate gas reservoirs are faced with many difficulties,such as mu...The exploration and development of oil and gas resources in the Sichuan Basin is shifting to the deeper strata.The deep and ultra-deep wells in deep carbonate gas reservoirs are faced with many difficulties,such as multiple pressure systems,poor drillability,ultra-high pressure,ultra-high temperature and high sulfur content,which bring great challenges to drilling and completion engineering.In order to ensure the smooth exploration and development of deep carbonate oil and gas resources in the Sichuan Basin,the overall concept of combiningfield practice and technological research is followed.During the 13th Five-Year Plan,a batch of ultra-deep wells(well depth about 8000 m)have been drilled fast and safely(such as Well SYX133 in the Shuangyushi structure),and great progresses have been achieved in the experimental research of the support technologies in drilling and completion of deep and ultra-deep wells.And the achievements are as follows.First,the optimization of non-standard well structure,combined with the application of precisely managed pressure drilling technology and under-pressure plugging technology,lays a foundation for the optimized fast drilling and the safe reaching of geological targets.Second,a high-efficiency customized PDC drill bit is comprehensively optimized,popularized and applied,which effectively improves the average rate of penetration(ROP)in difficult-to-drill formations.Third,the development and application of drillingfluids(e.g.being resistant to high temperature of 200 C and anti-composite brine)and active under-pressure plugging technology effectively reduces downhole complexities while drilling the complex for-mations,such as high temperature and high pressure brine and circulation loss.Fourth,when precisely managed pressure drilling and precisely managed pressure cementing methods are applied in the strata with a narrow density window,multiple pressure systems and pressure sensitivity,the average drilling and completionfluid loss is reduced by more than 90%,and the complexity treatment time is cut down by more than 85%,and the cementing quality pass rate is increased by more than 20%.Fifth,the integrated application of ROP improvement technologies and tools(e.g.air drilling)results in a great reduction of drilling cycle and cost.It is concluded that the experimental research achievements provide basic support for the fast development of natural gas resources in the Anyue Gas Field,Sichuan Basin,and the great discovery of the Permian and Devonian natural gas resources in the northwestern Sichuan Basin.What's more,in order to adapt to the development of the deep natural gas(over 9000 m)in the Sichuan Basin during the 14th Five-Year Plan,it is necessary to speed up researches on drilling and completion tech-nologies in nine aspects,e.g.high-temperature downhole tools and workingfluid.展开更多
The Yuanba Gasfield is a large gasfield discovered by Sinopec in the Sichuan Basin in recent years,and another main exploration area for natural gas reserves and production increase after the Puguang Gasfield.The ultr...The Yuanba Gasfield is a large gasfield discovered by Sinopec in the Sichuan Basin in recent years,and another main exploration area for natural gas reserves and production increase after the Puguang Gasfield.The ultra-deep sour gas reservoir in the Yuanba Gasfield is characterized by complicated geologic structure,deep reservoirs and complex drilled formation,especially in the continental deep strata which are highly abrasive with low ROP(rate of penetration)and long drilling period.After many years of drilling practice and technical research,the following six key drilling and completion technologies for this type reservoir are established by introducing new tools and technologies,developing specialized drill bits and optimizing drilling design.They are:casing program optimization technology for ROP increasing and safe well completion;gas drilling technology for shallow continental strata and high-efficiency drilling technology for deep high-abrasion continental strata;drillingfluid support technologies of gaseliquid conversion,ultra-deep highly-deviated wells and horizontal-well lubrication and drag reduction,hole stability control and sour gas contamination prevention;well cementing technologies for gas medium,deep-well long cementing intervals and ultra-high pressure small space;horizontal-well trajectory control technologies for measuring instrument,downhole motor opti-mization and bottom hole assembly design;and liner completion modes and completion string optimization technologies suitable for this gas reservoir.Field application shows that these key technologies are contributive to ROP increase and efficiency improvement of 7000 m deep horizontal wells and to significant operational cycle shortening.展开更多
Focusing on the extending length restriction of the completion screen pipe resistance running into ultra-short radius horizontal well,this paper proposed technology of hydraulic drive completion tubular string running...Focusing on the extending length restriction of the completion screen pipe resistance running into ultra-short radius horizontal well,this paper proposed technology of hydraulic drive completion tubular string running into ultra-short radius horizontal well.Innovative hydraulic drive tools and string structure are designed,which are composed of guide tubing,hydraulic drive tubing and non-metallic completion screen pipe from inside to outside.A novel mechanical-hydraulic coupling model is established.Based on the wellbore structure of an ultra-short radius horizontal well for deep coalbed methane,the numerical calculations of force and hydraulic load on tubular strings were accomplished by the mechanical-hydraulic coupling model.The results show that the extending length of completion tubular string with the hydraulic drive is 17 times that of conventional completion technology under the same conditions.The multi-factor orthogonal design is adopted to analyze the numerical calculations,and the results show that the extending length of the completion tubular string is mainly affected by the completion tubular string structure and the friction coefficient between the non-metallic composite continuous screen pipe and the wellbore.Two series of hydraulic drive completion tubular string structures suitable for ultra-short radius horizontal wells under different conditions are optimized,with the extending limits of 381 m and 655 m,respectively.These researches will provide theoretical guidance for design and control of hydraulic drive non-metallic composite continuous completion screen pipe running into ultra-short radius horizontal wells.展开更多
Ultra-deep formations hold abundant oil and gas resources.As the demand for oil and gas increases with economic development,more and more efforts are putting into the exploration and development of oil and gas reservo...Ultra-deep formations hold abundant oil and gas resources.As the demand for oil and gas increases with economic development,more and more efforts are putting into the exploration and development of oil and gas reservoirs in deep formations around the world.In China,the exploration and development of deep oil and gas are pacing up,especially in ultra-deep formations in the Sichuan Basin,Tarim Basin and Ordos Basin.The reservoirs in these basins feature extremely large depth(over 7000 m),super high temperature(150°C-210°C),super high pressure(over 150 MPa),high acid gas content(H_2S and CO_2),strong heterogeneity,and multiple pressure systems,which pose a series of challenges to wellbore engineering technologies including drilling,drilling fluid,cementing,logging,and completion testing.Therefore,it is necessary to delve into core drilling and testing technologies for deep formations.展开更多
文摘A new method,named the complete liquid-phase technology,has been applied to prepare catalysts for methanol synthesis.Its main innovative thought lies in preparing slurry catalysts directly from raw solution.Activity tests indicate that the CuZnAl slurry catalyst prepared by the new method can efficiently catalyze conversion of syngas to ethanol in a slurry reactor,while CO conversion reaches 35.9%and ethanol selectivity is more than 20%,with a total alcohol selectivity of more than 87%.No deactivation was found during the 192 h reaction.
基金supported by the National Natural Science Foundation of China(No.20706039)the National Basic Research Program(973 Program) of China (No.2005CB221204)+1 种基金the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi of China in 2010the Young Scientific and the Technical Fund of Shanxi of China (No.2006021010)
文摘Cu-Zn-Al slurry catalysts were prepared using a complete liquid-phase preparation technology under different heat treatment atmospheres.The catalysts were characterized using X-ray diffraction,X-ray photoelectron spectroscope,and N2 adsorption-desorption.Their application in the single-step synthesis of dimethyl ether from syngas was also investigated.The results indicate that the type of heat treatment atmosphere has an influence on the Cu species and the Cu0/Cu＋ ratio on the catalyst surface.Moreover,the final Cu/Zn ratio on the catalyst surface is mainly dependent on the composition and reaction environment of the catalyst and less on the type of heat treatment atmosphere.The prepared catalysts can suppress sintering of active sites at high temperatures,and the type of heat treatment atmosphere mainly affects the capability of the catalyst for methanol synthesis.The catalysts perform best using N2 as the heat treatment atmosphere.
文摘Technological developments that specifically address automation,compliance with environmental regulations,and hazard avoidance have accelerated more quickly than other drilling and completion technologies in the United States.This brief article provides a review of areas experiencing some of the most dramatic advances,while describing the need and addressing the solutions as they are now,and how they can be developed in the future.One aspect that all the new technologies have in common is an enhanced use of data analytics and in many cases,cloud-based solutions.A challenge that all have is a need to be able to quickly accommodate rapidly evolving requirements for emissions detection,hazard monitoring,and a reduced carbon footprint.Many solutions to the challenges require the ability to repurpose existing databases and use them for new purposes.
基金Supported by the National Natural Science Foundation of China(Nos.41006082,31372517)
文摘Cobetia marina is a model proteobacteria in researches on marine biofouling. Its taxonomic nomenclature has been revised many times over the past few decades. To better understand the role of the surface-associated lifestyle of C. marina and the phylogeny of the family Halomonadaceae, we sequenced the entire genome of C. marina JCM 21022T using single molecule real-time sequencing technology （SMRT） and performed comparative genomics and phylogenomics analyses. The circular chromosome was 4 176 300 bp with an average GC content of 62.44% and contained 3 611 predicted coding sequences, 72 tRNA genes, and 21 rRNA genes. The C. marina JCM 2102U genome contained a set of crucial genes involved in surface colonization processes. The comparative genome analysis indicated the significant differences between C. marina JCM 21022T and Cobetia amphilecti KMM 296 （formerly named C. marina KMM 296） resulted from sequence insertions or deletions and chromosomal recombination. Despite these differences, pan and core genome analysis showed similar gene functions between the two strains. The phylogenomic study of the family Halomonadaceae is relationships were well resolved among every genera Cobetia, Kushneria, Zymobacter, and Halotalea. reported here for the first time. We found that the tested, including Chromohalobacter, Halomonas,
基金supported by the National Research Council of Science and Technology Major Project“Sichuan Basin Large-scale Carbonate Cas Fiekd Development Demonstration Project”(No.:2016ZX05052).
文摘The exploration and development of oil and gas resources in the Sichuan Basin is shifting to the deeper strata.The deep and ultra-deep wells in deep carbonate gas reservoirs are faced with many difficulties,such as multiple pressure systems,poor drillability,ultra-high pressure,ultra-high temperature and high sulfur content,which bring great challenges to drilling and completion engineering.In order to ensure the smooth exploration and development of deep carbonate oil and gas resources in the Sichuan Basin,the overall concept of combiningfield practice and technological research is followed.During the 13th Five-Year Plan,a batch of ultra-deep wells(well depth about 8000 m)have been drilled fast and safely(such as Well SYX133 in the Shuangyushi structure),and great progresses have been achieved in the experimental research of the support technologies in drilling and completion of deep and ultra-deep wells.And the achievements are as follows.First,the optimization of non-standard well structure,combined with the application of precisely managed pressure drilling technology and under-pressure plugging technology,lays a foundation for the optimized fast drilling and the safe reaching of geological targets.Second,a high-efficiency customized PDC drill bit is comprehensively optimized,popularized and applied,which effectively improves the average rate of penetration(ROP)in difficult-to-drill formations.Third,the development and application of drillingfluids(e.g.being resistant to high temperature of 200 C and anti-composite brine)and active under-pressure plugging technology effectively reduces downhole complexities while drilling the complex for-mations,such as high temperature and high pressure brine and circulation loss.Fourth,when precisely managed pressure drilling and precisely managed pressure cementing methods are applied in the strata with a narrow density window,multiple pressure systems and pressure sensitivity,the average drilling and completionfluid loss is reduced by more than 90%,and the complexity treatment time is cut down by more than 85%,and the cementing quality pass rate is increased by more than 20%.Fifth,the integrated application of ROP improvement technologies and tools(e.g.air drilling)results in a great reduction of drilling cycle and cost.It is concluded that the experimental research achievements provide basic support for the fast development of natural gas resources in the Anyue Gas Field,Sichuan Basin,and the great discovery of the Permian and Devonian natural gas resources in the northwestern Sichuan Basin.What's more,in order to adapt to the development of the deep natural gas(over 9000 m)in the Sichuan Basin during the 14th Five-Year Plan,it is necessary to speed up researches on drilling and completion tech-nologies in nine aspects,e.g.high-temperature downhole tools and workingfluid.
文摘The Yuanba Gasfield is a large gasfield discovered by Sinopec in the Sichuan Basin in recent years,and another main exploration area for natural gas reserves and production increase after the Puguang Gasfield.The ultra-deep sour gas reservoir in the Yuanba Gasfield is characterized by complicated geologic structure,deep reservoirs and complex drilled formation,especially in the continental deep strata which are highly abrasive with low ROP(rate of penetration)and long drilling period.After many years of drilling practice and technical research,the following six key drilling and completion technologies for this type reservoir are established by introducing new tools and technologies,developing specialized drill bits and optimizing drilling design.They are:casing program optimization technology for ROP increasing and safe well completion;gas drilling technology for shallow continental strata and high-efficiency drilling technology for deep high-abrasion continental strata;drillingfluid support technologies of gaseliquid conversion,ultra-deep highly-deviated wells and horizontal-well lubrication and drag reduction,hole stability control and sour gas contamination prevention;well cementing technologies for gas medium,deep-well long cementing intervals and ultra-high pressure small space;horizontal-well trajectory control technologies for measuring instrument,downhole motor opti-mization and bottom hole assembly design;and liner completion modes and completion string optimization technologies suitable for this gas reservoir.Field application shows that these key technologies are contributive to ROP increase and efficiency improvement of 7000 m deep horizontal wells and to significant operational cycle shortening.
基金Supported by the Innovative Research Group Project of China National Natural Science Foundation(51821092)Key Project of China National Natural Science Foundation(U1762214).
文摘Focusing on the extending length restriction of the completion screen pipe resistance running into ultra-short radius horizontal well,this paper proposed technology of hydraulic drive completion tubular string running into ultra-short radius horizontal well.Innovative hydraulic drive tools and string structure are designed,which are composed of guide tubing,hydraulic drive tubing and non-metallic completion screen pipe from inside to outside.A novel mechanical-hydraulic coupling model is established.Based on the wellbore structure of an ultra-short radius horizontal well for deep coalbed methane,the numerical calculations of force and hydraulic load on tubular strings were accomplished by the mechanical-hydraulic coupling model.The results show that the extending length of completion tubular string with the hydraulic drive is 17 times that of conventional completion technology under the same conditions.The multi-factor orthogonal design is adopted to analyze the numerical calculations,and the results show that the extending length of the completion tubular string is mainly affected by the completion tubular string structure and the friction coefficient between the non-metallic composite continuous screen pipe and the wellbore.Two series of hydraulic drive completion tubular string structures suitable for ultra-short radius horizontal wells under different conditions are optimized,with the extending limits of 381 m and 655 m,respectively.These researches will provide theoretical guidance for design and control of hydraulic drive non-metallic composite continuous completion screen pipe running into ultra-short radius horizontal wells.
文摘Ultra-deep formations hold abundant oil and gas resources.As the demand for oil and gas increases with economic development,more and more efforts are putting into the exploration and development of oil and gas reservoirs in deep formations around the world.In China,the exploration and development of deep oil and gas are pacing up,especially in ultra-deep formations in the Sichuan Basin,Tarim Basin and Ordos Basin.The reservoirs in these basins feature extremely large depth(over 7000 m),super high temperature(150°C-210°C),super high pressure(over 150 MPa),high acid gas content(H_2S and CO_2),strong heterogeneity,and multiple pressure systems,which pose a series of challenges to wellbore engineering technologies including drilling,drilling fluid,cementing,logging,and completion testing.Therefore,it is necessary to delve into core drilling and testing technologies for deep formations.
