Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sint...Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.展开更多
In order to improve the Power Quality(PQ)of traction power supply system and reduce the power rating and operation cost of compensator,a Static VAR Compensator(SVC)integrated Railway Power Conditioner(RPC)is presented...In order to improve the Power Quality(PQ)of traction power supply system and reduce the power rating and operation cost of compensator,a Static VAR Compensator(SVC)integrated Railway Power Conditioner(RPC)is presented in this paper.RPC is a widely used device in the AC electrified railway systems to enhance the PQ indices of the main network.The next generation of this equipment is Active Power Quality Compensator(APQC).The major concern of these compensators is their high kVA rating.In this paper,a hybrid technique is proposed to solve aforementioned problems.A combination of SVC as an auxiliary device is employed together with the main compensators,i.e.,RPC and APQC that leads on to the reduction of power rating of the main compensators.The use of proposed scheme will cause to reduce significantly the initial investment cost of compensation system.The main compensators are only utilized to balance active powers of two adjacent feeder sections and suppress harmonic currents.The SVCs are used to compensate reactive power and suppress the third and fifth harmonic currents.In this paper firstly,the PQ compensation procedure in AC electrified railway is analyzed step by step.Then,the control strategies for SVC and the main compensators are presented.Finally,a simulation is fulfilled using Matlab/Simulink software to verify the effectiveness and validity of the proposed scheme and compensation strategy and also demonstrate that this technique could compensate all PQ problems.展开更多
Ca_(3-x)(PO_(4))_(2):xTb^(3+)(0.2≤x≤0.4),Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.35 A^(+)(A=Li,Na,K),and Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),yLi^(+)(0.35≤y≤0.455)phosphors were prepared by solid-state reaction.All the p...Ca_(3-x)(PO_(4))_(2):xTb^(3+)(0.2≤x≤0.4),Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.35 A^(+)(A=Li,Na,K),and Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),yLi^(+)(0.35≤y≤0.455)phosphors were prepared by solid-state reaction.All the prepared phosphors formed a rhombohedral unit cell with the R3c space group.To improve the photoluminescence(PL)properties of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor,monovalent charge compensators such as Li^(+),NA^(+),and K^(+)were added to the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.The charge compensators acted as fluxes,so they improved the crystallinity.The excitation and emission properties were significantly improved through the incorporation of charge compensators.In particular,among the charge compensators,Li^(+)ion substantially enhanced the emission intensity and color purity.Furthermore,considering the evaporation of Li_(2)CO_(3)during the annealing process,we optimized the concentration of Li^(+)charge compensator to enhance its PL performance.Impressively,the green emission intensity of the Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.385 Li^(+)phosphor was 260%higher than that of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.We believe that the effect of charge compensators on the PL properties and the optimum concentration of Li^(+)cha rge compensator are useful for the design of phosphors in light-emitting diodes.展开更多
Presents a systematic design method of reduced order dynamical compensator via the parametric representations of eigenstructure assignment for linear system, which provides maximum degree of freedom, and can be easily...Presents a systematic design method of reduced order dynamical compensator via the parametric representations of eigenstructure assignment for linear system, which provides maximum degree of freedom, and can be easily used for the design of a linear system with unknown inputs under some conditions. Even when these conditions are not satisfied, the lower order dynamical compensator can also be designed under some relaxed conditions. Some examples illustrate that the method is neat, simple and effective.展开更多
Chirped fibre Bragg gratings （CFBGs） are required to be concatenated to compensate the fibre dispersion in the dense wavelength-division multiplexing （DWDM） systems. When the channel spacing is small, the performa...Chirped fibre Bragg gratings （CFBGs） are required to be concatenated to compensate the fibre dispersion in the dense wavelength-division multiplexing （DWDM） systems. When the channel spacing is small, the performance of CFBGs is degraded, which restricts the usage of fibre gratings. The origin of the interactions between the gratings is analysed and methods of suppressing the interactions are also proposed.展开更多
A parameter that allows an evaluation of power quality transmitted, or distributed, between energy source and the final user is electric system power factor. Among other aspects, a bigger power factor, close to unit v...A parameter that allows an evaluation of power quality transmitted, or distributed, between energy source and the final user is electric system power factor. Among other aspects, a bigger power factor, close to unit value, relieves operational conditions of lines and cables, besides, it improves feeder＇s voltage behavior. Due to load variation along the day, the dynamic compensation of power factor allows maintaining this parameter close to the ideal. This paper brings a study about a reactive dynamic compensator based on the voltage control in a capacitive element, varying the reactive energy in accordance with the system demand, everything from the energy efficiency point of view. In distribution systems, the losses due to this variable compensation can be lower than in other compensation methods and also the voltage presents a better behavior, justifying its application.展开更多
With large-scale use of kinds of motors, oilfield drilling electrical system always accompanied by serious power quality problem, including reactive current, harmonics current and grid voltage distortion, which would ...With large-scale use of kinds of motors, oilfield drilling electrical system always accompanied by serious power quality problem, including reactive current, harmonics current and grid voltage distortion, which would greatly threaten the safety and proper working of the whole system. This paper focuses on a power quality improvement project to solve these problems. A hybrid compensating scheme, including an active compensator and a passive compensator, is carried out. Because of the specificity of oilfield drilling electrical system, compensators are redesigned against features of this application background. And then the current detection point arrangement of this hybrid system is also taken into consideration to build the whole system much more effective and reliable. Now the improvement project is already implemented in application field, and the power quality of the system is greatly improved.展开更多
Hard carbon(HC)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial Coulombic efficiency(ICE)and cycling stability.Cathode compensation agent is a favorable strategy t...Hard carbon(HC)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial Coulombic efficiency(ICE)and cycling stability.Cathode compensation agent is a favorable strategy to make up for the loss of active sodium ions consumed byHCanode.Yet it lacks agent that effectively decomposes to increase the active sodium ions as well as regulate carbon defects for decreasing the irreversible sodium ions consumption.Here,we propose 1,2-dihydroxybenzene Na salt(NaDB)as a cathode compensation agent with high specific capacity(347.9 mAh g^(-1)),lower desodiation potential(2.4–2.8 V)and high utilization(99%).Meanwhile,its byproduct could functionalize HC with more C=O groups and promote its reversible capacity.Consequently,the presodiation hard carbon(pHC)anode exhibits highly reversible capacity of 204.7 mAh g^(-1) with 98%retention at 5 C rate over 1000 cycles.Moreover,with 5 wt%NaDB initially coated on the Na3V2(PO4)3(NVP)cathode,the capacity retention of NVP + NaDB|HC cell could increase from 22%to 89%after 1000 cycles at 1 C rate.This work provides a new avenue to improve reversible capacity and cycling performance of SIBs through designing functional cathode compensation agent.展开更多
A complex geological environment with faults can be encountered in the process of coal mining.Fault activation can cause instantaneous structure slipping,releasing a significant amount of elastic strain energy during ...A complex geological environment with faults can be encountered in the process of coal mining.Fault activation can cause instantaneous structure slipping,releasing a significant amount of elastic strain energy during underground coal mining.This would trigger strong rockburst disasters.To understand the occurrence of fault-slip induced rockbursts,we developed a physical model test system for fault-slip induced rockbursts in coal mine drifts.The boundary energy storage(BES)loading apparatus and bottom rapid retraction(BRR)apparatus are designed to realize energy compensation and continuous boundary stress transfer of the surrounding rocks for instantaneous fault slip,as well as to provide space for the potential fault slip.Taking the typical fault-slip induced rockburst in the Xinjulong Coal Mine,China,as the background,we conducted a model test using the test system.The deformation and stress in the rock surrounding the drift and the support unit force during fault slip are analyzed.The deformation and failure characteristics and dynamic responses of drifts under fault-slip induced rockbursts are obtained.The test results illustrate the rationality and effectiveness of the test system.Finally,corresponding recommendations and prospects are proposed based on our findings.展开更多
The hot deformation behavior of the premium GH4738 alloy was investigated in the temperature range of 1313 to 1353 K at strain rates of 0.01 to 1 s^(−1)using the hot compression test.To accurately predict flow stress,...The hot deformation behavior of the premium GH4738 alloy was investigated in the temperature range of 1313 to 1353 K at strain rates of 0.01 to 1 s^(−1)using the hot compression test.To accurately predict flow stress,three novel strain compensation constitutive equations were developed and rigorously assessed.The results indicate that the power function model(correlation coefficients r=0.98544)demonstrates greater prediction accuracy compared to other functions,with a calculated average activation energy of 507.968 kJ mol−1.Additionally,electron backscattered diffraction technology and transmission electron microscopy were used to analyze the evolution of the alloy microstructure during dynamic recrystallization under different deformation conditions.The results show that under high-temperature and large deformation conditions,the dislocation density and the degree of grain rotation increase,which promotes the formation and growth of new recrystallized grains,so that recrystallization is completed when the deformation amount reaches 30%.Besides,the increase in the temperature not only enhances the thermal activation mechanism,but also improves the grain size uniformity and texture consistency.Meanwhile,the carbide inhibits grain overgrowth by pinning grain boundaries,maintaining a fine and uniform grain structure of the alloy,and thereby improving the plasticity of the material.展开更多
Unconventional magnetism,including altermagnetism and unconventional compensated magnetism,characterized by its duality of real-space antiferromagnetic alignment and momentum-space spin splitting,has garnered widespre...Unconventional magnetism,including altermagnetism and unconventional compensated magnetism,characterized by its duality of real-space antiferromagnetic alignment and momentum-space spin splitting,has garnered widespread attention.While altermagnetism has been extensively studied,research on unconventional compensated magnetism remains very rare.In particular,unconventional compensated magnetic materials are only theoretically predicted and have not yet been synthesized experimentally.In this study,based on symmetry analysis and frst-principles electronic structure calculations,we predict that LaMn_(2)SbO_(6)is an unconventional compensated magnetic semiconductor.Given that the Mn ions at opposite spin lattice cannot be connected by any symmetry,the spin splitting in LaMn_(2)SbO_(6)is isotropic.More importantly,LaMn_(2)SbO_(6)has already been synthesized experimentally,and its magnetic structure has been confrmed by neutron scattering experiments.Therefore,LaMn_(2)SbO_(6)serves as an excellent material platform for investigating the novel physical properties of unconventional compensated magnetic materials.展开更多
The design of normal decentralized dynamic compensators for the internal properness and stability of singular decentralized control systems is investigated, and an effective sequential design approach is presented.
The Hydro-Viscous Drive(HVD)speed regulating system finds extensive application in air transport transmission systems to regulate the stepless speed or conduct overload protection.However,its intrinsic hysteretic beha...The Hydro-Viscous Drive(HVD)speed regulating system finds extensive application in air transport transmission systems to regulate the stepless speed or conduct overload protection.However,its intrinsic hysteretic behaviors,such as the asymmetric hysteretic and dead zone,could introduce inaccuracy and delay in control applications,posing challenges to system regulation.This paper investigates a Nonlinear Hysteresis Compensation Control(NHCC)that consists of two parts to control the HVD output speed by operating the valve under different engine operating conditions.In the first part,the Inverse Hysteresis Compensator(IHC)based on major loop data is introduced for the asymmetric hysteresis characterization and compensation of the HVD speed control system of the power generation and distribution,which aims to reduce the hysteresis and dead zone effect and expand the effective input range.In the second part,the Active Disturbance Rejection Controller(ADRC)is employed to mitigate the hysteresis effects of the compensated system and remove the steady-state error,which allows real-time compensation of the estimated perturbations as state feedback to achieve the required performance.An experimental laboratory station has been fabricated to evaluate the proposed method.The test results show that the NHCC method can regulate the fan speed to the desired value(45 r/min at steady state)and broaden the effective input range to the full range under different engine conditions.Besides,the proposed control method can reduce the non-linearity of the input and output curves(from 18%to 4%)and compensate for the asymmetric hysteresis(from 38%to 5%).展开更多
Two-dimensional(2D)fully compensated collinear magnetic materials ofer signifcant advantages for spintronic applications,including robustness against magnetic feld perturbations,no stray felds,and ultrafast dynamics.A...Two-dimensional(2D)fully compensated collinear magnetic materials ofer signifcant advantages for spintronic applications,including robustness against magnetic feld perturbations,no stray felds,and ultrafast dynamics.Among these materials,fully compensated ferrimagnets are particularly promising due to their unique characteristics such as the magneto-optical efect,completely spin-polarized currents,and the anomalous Hall efect.We performed a structural search on 2D unconventional stoichiometric Cr-I crystals using a global optimization algorithm.The most stable CrI-P21/m monolayer is a fully compensated ferrimagnetic semiconductor with a band gap of 1.57 eV and a high magnetic transition temperature of 592 K.The spontaneous spin splitting in CrI-P21/m originates from the inequivalent local coordination environments of Cr^(1)and Cr^(2)ions,yielding a mismatch in their 3d orbitals splitting.Notably,carrier doping at a concentration of 0.01 electrons or holes per atom enables reversible spin polarization,generating a fully spin-polarized current in CrI-P21/m.This performance makes it a highly promising candidate for spintronic devices.Our fndings not only provide a structural paradigm for discovering fully compensated ferrimagnets but also open a new avenue for designing zero-moment magnetic materials with intrinsic spin splitting.展开更多
In this paper,we investigate the method of compensating LTS SQUID Gradiometer Systems data.By matching the attitude changes of the pod in fl ight to the anomalies of the magnetic measurement data,we find that the yaw ...In this paper,we investigate the method of compensating LTS SQUID Gradiometer Systems data.By matching the attitude changes of the pod in fl ight to the anomalies of the magnetic measurement data,we find that the yaw attitude changes most dramatically and corresponds best to the magnetic data anomaly interval.Based on this finding,we solved the compensation model using least squares fitting and Huber's parametric fitting.By comparison,we found that the Huber parametric fit not only eliminates the interference introduced by attitude changes but also retains richer anomaly source information and therefore obtains a higher signal-to-noise ratio.The experimental results show that the quality of the magnetometry data obtained by using the compensation method proposed in this paper has been significantly improved,and the mean value of its improvement ratio can reach 118.93.展开更多
To address the issue of disturbance compensation deviation in linear active disturbance rejection control(LADRC),a linear active disturbance rejection control method with reference to the integral chain model(LADRC-R)...To address the issue of disturbance compensation deviation in linear active disturbance rejection control(LADRC),a linear active disturbance rejection control method with reference to the integral chain model(LADRC-R)is proposed.By constructing an ideal control reference model,a dynamic correlation between output deviation and uncompensated disturbances is established,and a dual-loop compensation mechanism is designed.Based on theoretical analysis and frequency-domain characteristics of typical first/second-order systems,this method maintains the parameter-tuning advantages of LADRC while reducing disturbance effects by 50%and introducing no phase lag during low-frequency disturbance suppression.Simulations on second-order systems verify its robustness under parameter perturbations,gain mismatch,and complex disturbances,and an optimized design scheme for the deviation compensator is proposed to suppress discontinuous measurement noise interference.Finally,the engineering effectiveness of this method in precision motion control is validated on an electromagnetic suspension platform,providing a new approach to improving the control performance of LADRC in environments with uncertain disturbances.展开更多
Chemical oxygen demand(COD)is an important criterion for detecting the emission of pollutants and judging the quality of water.This paper improves the absorption spectrum compensation model for COD and turbidity mixed...Chemical oxygen demand(COD)is an important criterion for detecting the emission of pollutants and judging the quality of water.This paper improves the absorption spectrum compensation model for COD and turbidity mixed solution in the dual-wavelength spectral method based on the Lambert-Beer law additive principle.It compensates for the influence of turbidity on the absorption coefficient of the COD solution at 355 nm by the absorption spectrum coefficient of the mixed solution at 623 nm.This paper establishes a linear relationship model between the absorbance difference of the mixed solution at 355 nm and 623 nm and COD.The experimental determination coefficient R2 of the model is 0.98335,with a relative error of 3.5%and an average error of 0.7 mg/L.The design of the model is simple and easy to systematize,which is of strong significance for practical application.展开更多
The information exchange among satellites is crucial for the implementation of cluster satellite cooperative missions.However,achieving fast perception,rapid networking,and highprecision time synchronization among nod...The information exchange among satellites is crucial for the implementation of cluster satellite cooperative missions.However,achieving fast perception,rapid networking,and highprecision time synchronization among nodes without the support of the Global Navigation Satellite System(GNSS)and other prior information remains a formidable challenge to real-time wireless networks design.Therefore,a self-organizing network methodology based on multi-agent negotiation is proposed,which autonomously determines the master node through collaborative negotiation and competitive elections.On this basis,a real-time network protocol design is carried out and a high-precision time synchronization method with motion compensation is proposed.Simulation results demonstrate that the proposed method enables rapid networking with the capability of selfdiscovery,self-organization,and self-healing.For a cluster of 8 satellites,the networking time and the reorganization time are less than 4 s.The time synchronization accuracy exceeds 10-10s with motion compensation,demonstrating excellent real-time performance and stability.The research presented in this paper provides a valuable reference for the design and application of spacebased self-organizing networks for satellite cluster.展开更多
Absorption compensation is a process involving the exponential amplification of reflection amplitudes.This process amplifies the seismic signal and noise,thereby substantially reducing the signal-tonoise ratio of seis...Absorption compensation is a process involving the exponential amplification of reflection amplitudes.This process amplifies the seismic signal and noise,thereby substantially reducing the signal-tonoise ratio of seismic data.Therefore,this paper proposes a multichannel inversion absorption compensation method based on structure tensor regularization.First,the structure tensor is utilized to extract the spatial inclination of seismic signals,and the spatial prediction filter is designed along the inclination direction.The spatial prediction filter is then introduced into the regularization condition of multichannel inversion absorption compensation,and the absorption compensation is realized under the framework of multichannel inversion theory.The spatial predictability of seismic signals is also introduced into the objective function of absorption compensation inversion.Thus,the inversion system can effectively suppress the noise amplification effect during absorption compensation and improve the recovery accuracy of high-frequency signals.Synthetic and field data tests are conducted to demonstrate the accuracy and effectiveness of the proposed method.展开更多
This study aimed to identify and compensate for the geometric errors of the double swiveling axes in a five-axis computer numerical control(CNC)machining center.Hence,a three-dimensional coordinate calculation algorit...This study aimed to identify and compensate for the geometric errors of the double swiveling axes in a five-axis computer numerical control(CNC)machining center.Hence,a three-dimensional coordinate calculation algorithm for a measured point with additional rotational rigid body motion constraints is proposed.The motion constraints of the rotational rigid body were analyzed,and a mathematical model of the measured point algorithm in the swiveling axes was established.The Levenberg-Marquard method was used to solve the nonlinear superstatically determined equations.The spatial coordinate error was used to separate the spatial deviation of the measured point.An identification model of the position-independent and position-dependent geometric errors was established.The three-dimensional coordinate-solving algorithm of the measured point in the swiveling axis and geometric error identification method based on the Monte Carlo method were analyzed numerically.Geometric error measurement and cutting experiments were performed on a VMC25100U five-axis machining center,which integrated two swiveling axes.Geometric errors of the A-and B-axes were identified and measured experimentally.The angular positioning errors before and after compensation were measured using a laser interferometer,which verified the effectiveness of the proposed algorithm.A cutting experiment of a round table part was performed.The shape and position accuracy of the processed part before and after compensation were detected using a coordinate measuring machine.It verified that the geometric error of the swiveling axis was effectively compensated by the algorithm proposed herein.展开更多
基金financially supported by the National Natural Science Foundation of China(52102206)the Natural Science Foundation of Beijing Municipality-Shunyi Innovation Collaborative Joint Fund(L247018)+2 种基金the Natural Science Foundation of Beijing Municipality(2254076 and 2252024)the Central Guidance on Local Science and Technology Development Fund of Hebei Province(246Z4412G)the Fundamental Research Funds for the Central Universities(2025MS022,North China Electric Power University)。
文摘Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.
文摘In order to improve the Power Quality(PQ)of traction power supply system and reduce the power rating and operation cost of compensator,a Static VAR Compensator(SVC)integrated Railway Power Conditioner(RPC)is presented in this paper.RPC is a widely used device in the AC electrified railway systems to enhance the PQ indices of the main network.The next generation of this equipment is Active Power Quality Compensator(APQC).The major concern of these compensators is their high kVA rating.In this paper,a hybrid technique is proposed to solve aforementioned problems.A combination of SVC as an auxiliary device is employed together with the main compensators,i.e.,RPC and APQC that leads on to the reduction of power rating of the main compensators.The use of proposed scheme will cause to reduce significantly the initial investment cost of compensation system.The main compensators are only utilized to balance active powers of two adjacent feeder sections and suppress harmonic currents.The SVCs are used to compensate reactive power and suppress the third and fifth harmonic currents.In this paper firstly,the PQ compensation procedure in AC electrified railway is analyzed step by step.Then,the control strategies for SVC and the main compensators are presented.Finally,a simulation is fulfilled using Matlab/Simulink software to verify the effectiveness and validity of the proposed scheme and compensation strategy and also demonstrate that this technique could compensate all PQ problems.
基金financially supported by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant funded by the Korea government Ministry of Trade,Industry&Energy(No.20184030202260)。
文摘Ca_(3-x)(PO_(4))_(2):xTb^(3+)(0.2≤x≤0.4),Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.35 A^(+)(A=Li,Na,K),and Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),yLi^(+)(0.35≤y≤0.455)phosphors were prepared by solid-state reaction.All the prepared phosphors formed a rhombohedral unit cell with the R3c space group.To improve the photoluminescence(PL)properties of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor,monovalent charge compensators such as Li^(+),NA^(+),and K^(+)were added to the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.The charge compensators acted as fluxes,so they improved the crystallinity.The excitation and emission properties were significantly improved through the incorporation of charge compensators.In particular,among the charge compensators,Li^(+)ion substantially enhanced the emission intensity and color purity.Furthermore,considering the evaporation of Li_(2)CO_(3)during the annealing process,we optimized the concentration of Li^(+)charge compensator to enhance its PL performance.Impressively,the green emission intensity of the Ca_(2.3)(PO_(4))_(2):0.35 Tb^(3+),0.385 Li^(+)phosphor was 260%higher than that of the Ca_(2.65)(PO_(4))_(2):0.35 Tb^(3+)phosphor.We believe that the effect of charge compensators on the PL properties and the optimum concentration of Li^(+)cha rge compensator are useful for the design of phosphors in light-emitting diodes.
文摘Presents a systematic design method of reduced order dynamical compensator via the parametric representations of eigenstructure assignment for linear system, which provides maximum degree of freedom, and can be easily used for the design of a linear system with unknown inputs under some conditions. Even when these conditions are not satisfied, the lower order dynamical compensator can also be designed under some relaxed conditions. Some examples illustrate that the method is neat, simple and effective.
文摘Chirped fibre Bragg gratings （CFBGs） are required to be concatenated to compensate the fibre dispersion in the dense wavelength-division multiplexing （DWDM） systems. When the channel spacing is small, the performance of CFBGs is degraded, which restricts the usage of fibre gratings. The origin of the interactions between the gratings is analysed and methods of suppressing the interactions are also proposed.
文摘A parameter that allows an evaluation of power quality transmitted, or distributed, between energy source and the final user is electric system power factor. Among other aspects, a bigger power factor, close to unit value, relieves operational conditions of lines and cables, besides, it improves feeder＇s voltage behavior. Due to load variation along the day, the dynamic compensation of power factor allows maintaining this parameter close to the ideal. This paper brings a study about a reactive dynamic compensator based on the voltage control in a capacitive element, varying the reactive energy in accordance with the system demand, everything from the energy efficiency point of view. In distribution systems, the losses due to this variable compensation can be lower than in other compensation methods and also the voltage presents a better behavior, justifying its application.
文摘With large-scale use of kinds of motors, oilfield drilling electrical system always accompanied by serious power quality problem, including reactive current, harmonics current and grid voltage distortion, which would greatly threaten the safety and proper working of the whole system. This paper focuses on a power quality improvement project to solve these problems. A hybrid compensating scheme, including an active compensator and a passive compensator, is carried out. Because of the specificity of oilfield drilling electrical system, compensators are redesigned against features of this application background. And then the current detection point arrangement of this hybrid system is also taken into consideration to build the whole system much more effective and reliable. Now the improvement project is already implemented in application field, and the power quality of the system is greatly improved.
基金supported by National Natural Science Foundation of China(No.22278308 and 22109114)Open Foundation of Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering(Grant number:JDSX2022023).
文摘Hard carbon(HC)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial Coulombic efficiency(ICE)and cycling stability.Cathode compensation agent is a favorable strategy to make up for the loss of active sodium ions consumed byHCanode.Yet it lacks agent that effectively decomposes to increase the active sodium ions as well as regulate carbon defects for decreasing the irreversible sodium ions consumption.Here,we propose 1,2-dihydroxybenzene Na salt(NaDB)as a cathode compensation agent with high specific capacity(347.9 mAh g^(-1)),lower desodiation potential(2.4–2.8 V)and high utilization(99%).Meanwhile,its byproduct could functionalize HC with more C=O groups and promote its reversible capacity.Consequently,the presodiation hard carbon(pHC)anode exhibits highly reversible capacity of 204.7 mAh g^(-1) with 98%retention at 5 C rate over 1000 cycles.Moreover,with 5 wt%NaDB initially coated on the Na3V2(PO4)3(NVP)cathode,the capacity retention of NVP + NaDB|HC cell could increase from 22%to 89%after 1000 cycles at 1 C rate.This work provides a new avenue to improve reversible capacity and cycling performance of SIBs through designing functional cathode compensation agent.
基金support from the National Natural Science Foundation of China (Grant Nos.51927807,42077267 and 42277174).
文摘A complex geological environment with faults can be encountered in the process of coal mining.Fault activation can cause instantaneous structure slipping,releasing a significant amount of elastic strain energy during underground coal mining.This would trigger strong rockburst disasters.To understand the occurrence of fault-slip induced rockbursts,we developed a physical model test system for fault-slip induced rockbursts in coal mine drifts.The boundary energy storage(BES)loading apparatus and bottom rapid retraction(BRR)apparatus are designed to realize energy compensation and continuous boundary stress transfer of the surrounding rocks for instantaneous fault slip,as well as to provide space for the potential fault slip.Taking the typical fault-slip induced rockburst in the Xinjulong Coal Mine,China,as the background,we conducted a model test using the test system.The deformation and stress in the rock surrounding the drift and the support unit force during fault slip are analyzed.The deformation and failure characteristics and dynamic responses of drifts under fault-slip induced rockbursts are obtained.The test results illustrate the rationality and effectiveness of the test system.Finally,corresponding recommendations and prospects are proposed based on our findings.
基金supported by the National Key R&D Program of China(No.2021YFB3700403).
文摘The hot deformation behavior of the premium GH4738 alloy was investigated in the temperature range of 1313 to 1353 K at strain rates of 0.01 to 1 s^(−1)using the hot compression test.To accurately predict flow stress,three novel strain compensation constitutive equations were developed and rigorously assessed.The results indicate that the power function model(correlation coefficients r=0.98544)demonstrates greater prediction accuracy compared to other functions,with a calculated average activation energy of 507.968 kJ mol−1.Additionally,electron backscattered diffraction technology and transmission electron microscopy were used to analyze the evolution of the alloy microstructure during dynamic recrystallization under different deformation conditions.The results show that under high-temperature and large deformation conditions,the dislocation density and the degree of grain rotation increase,which promotes the formation and growth of new recrystallized grains,so that recrystallization is completed when the deformation amount reaches 30%.Besides,the increase in the temperature not only enhances the thermal activation mechanism,but also improves the grain size uniformity and texture consistency.Meanwhile,the carbide inhibits grain overgrowth by pinning grain boundaries,maintaining a fine and uniform grain structure of the alloy,and thereby improving the plasticity of the material.
基金supported by the National Natural Science Foundation of China(Grant Nos.12204533,12434009,and 62476278)the National Key R&D Program of China(Grant No.2024YFA1408601)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(Grant No.24XNKJ15)。
文摘Unconventional magnetism,including altermagnetism and unconventional compensated magnetism,characterized by its duality of real-space antiferromagnetic alignment and momentum-space spin splitting,has garnered widespread attention.While altermagnetism has been extensively studied,research on unconventional compensated magnetism remains very rare.In particular,unconventional compensated magnetic materials are only theoretically predicted and have not yet been synthesized experimentally.In this study,based on symmetry analysis and frst-principles electronic structure calculations,we predict that LaMn_(2)SbO_(6)is an unconventional compensated magnetic semiconductor.Given that the Mn ions at opposite spin lattice cannot be connected by any symmetry,the spin splitting in LaMn_(2)SbO_(6)is isotropic.More importantly,LaMn_(2)SbO_(6)has already been synthesized experimentally,and its magnetic structure has been confrmed by neutron scattering experiments.Therefore,LaMn_(2)SbO_(6)serves as an excellent material platform for investigating the novel physical properties of unconventional compensated magnetic materials.
文摘The design of normal decentralized dynamic compensators for the internal properness and stability of singular decentralized control systems is investigated, and an effective sequential design approach is presented.
文摘The Hydro-Viscous Drive(HVD)speed regulating system finds extensive application in air transport transmission systems to regulate the stepless speed or conduct overload protection.However,its intrinsic hysteretic behaviors,such as the asymmetric hysteretic and dead zone,could introduce inaccuracy and delay in control applications,posing challenges to system regulation.This paper investigates a Nonlinear Hysteresis Compensation Control(NHCC)that consists of two parts to control the HVD output speed by operating the valve under different engine operating conditions.In the first part,the Inverse Hysteresis Compensator(IHC)based on major loop data is introduced for the asymmetric hysteresis characterization and compensation of the HVD speed control system of the power generation and distribution,which aims to reduce the hysteresis and dead zone effect and expand the effective input range.In the second part,the Active Disturbance Rejection Controller(ADRC)is employed to mitigate the hysteresis effects of the compensated system and remove the steady-state error,which allows real-time compensation of the estimated perturbations as state feedback to achieve the required performance.An experimental laboratory station has been fabricated to evaluate the proposed method.The test results show that the NHCC method can regulate the fan speed to the desired value(45 r/min at steady state)and broaden the effective input range to the full range under different engine conditions.Besides,the proposed control method can reduce the non-linearity of the input and output curves(from 18%to 4%)and compensate for the asymmetric hysteresis(from 38%to 5%).
基金supported by the Natural Science Foundation of Wenzhou Institute,University of Chinese Academy of Sciences(UCAS)(Grant No.WIUCASQD2023004)the National Natural Science Foundation of China(Grant Nos.12304006,12404265,and 12435001)+2 种基金the Natural Science Foundation of Shanghai,China(Grant No.23JC1401400)the Natural Science Foundation of Wenzhou(Grant No.L2023005)the Fundamental Research Funds for the Central Universities of East China University of Science and Technology。
文摘Two-dimensional(2D)fully compensated collinear magnetic materials ofer signifcant advantages for spintronic applications,including robustness against magnetic feld perturbations,no stray felds,and ultrafast dynamics.Among these materials,fully compensated ferrimagnets are particularly promising due to their unique characteristics such as the magneto-optical efect,completely spin-polarized currents,and the anomalous Hall efect.We performed a structural search on 2D unconventional stoichiometric Cr-I crystals using a global optimization algorithm.The most stable CrI-P21/m monolayer is a fully compensated ferrimagnetic semiconductor with a band gap of 1.57 eV and a high magnetic transition temperature of 592 K.The spontaneous spin splitting in CrI-P21/m originates from the inequivalent local coordination environments of Cr^(1)and Cr^(2)ions,yielding a mismatch in their 3d orbitals splitting.Notably,carrier doping at a concentration of 0.01 electrons or holes per atom enables reversible spin polarization,generating a fully spin-polarized current in CrI-P21/m.This performance makes it a highly promising candidate for spintronic devices.Our fndings not only provide a structural paradigm for discovering fully compensated ferrimagnets but also open a new avenue for designing zero-moment magnetic materials with intrinsic spin splitting.
基金Earth Observation and Navigation Special,Research on Low Temperature Superconducting Aeromagnetic Vector Gradient Observation Technology(2021YFB3900201)projectState Key Laboratory of Remote Sensing Science project.
文摘In this paper,we investigate the method of compensating LTS SQUID Gradiometer Systems data.By matching the attitude changes of the pod in fl ight to the anomalies of the magnetic measurement data,we find that the yaw attitude changes most dramatically and corresponds best to the magnetic data anomaly interval.Based on this finding,we solved the compensation model using least squares fitting and Huber's parametric fitting.By comparison,we found that the Huber parametric fit not only eliminates the interference introduced by attitude changes but also retains richer anomaly source information and therefore obtains a higher signal-to-noise ratio.The experimental results show that the quality of the magnetometry data obtained by using the compensation method proposed in this paper has been significantly improved,and the mean value of its improvement ratio can reach 118.93.
基金supported by the National Natural Science Foundation of China(Nos.62063009,52262050)the National Key Research and Development Program during the 14th 5-Year Plan(No.2023YFB4302100)the Major Science and Technology Research and Development Special Project in Jiangxi Province(No.20232ACE01011).
文摘To address the issue of disturbance compensation deviation in linear active disturbance rejection control(LADRC),a linear active disturbance rejection control method with reference to the integral chain model(LADRC-R)is proposed.By constructing an ideal control reference model,a dynamic correlation between output deviation and uncompensated disturbances is established,and a dual-loop compensation mechanism is designed.Based on theoretical analysis and frequency-domain characteristics of typical first/second-order systems,this method maintains the parameter-tuning advantages of LADRC while reducing disturbance effects by 50%and introducing no phase lag during low-frequency disturbance suppression.Simulations on second-order systems verify its robustness under parameter perturbations,gain mismatch,and complex disturbances,and an optimized design scheme for the deviation compensator is proposed to suppress discontinuous measurement noise interference.Finally,the engineering effectiveness of this method in precision motion control is validated on an electromagnetic suspension platform,providing a new approach to improving the control performance of LADRC in environments with uncertain disturbances.
基金supported by the Youth Project of National Natural Science Foundation of China(No.61505145)the Tianjin Science and Technology Commissioner Project(No.20YDTPJC02010)+1 种基金the Tianjin Municipal Education Commission(No.2021KJ003)the Tianjin Zhonghuan Tianjia Electronics Company(No.HX20193)。
文摘Chemical oxygen demand(COD)is an important criterion for detecting the emission of pollutants and judging the quality of water.This paper improves the absorption spectrum compensation model for COD and turbidity mixed solution in the dual-wavelength spectral method based on the Lambert-Beer law additive principle.It compensates for the influence of turbidity on the absorption coefficient of the COD solution at 355 nm by the absorption spectrum coefficient of the mixed solution at 623 nm.This paper establishes a linear relationship model between the absorbance difference of the mixed solution at 355 nm and 623 nm and COD.The experimental determination coefficient R2 of the model is 0.98335,with a relative error of 3.5%and an average error of 0.7 mg/L.The design of the model is simple and easy to systematize,which is of strong significance for practical application.
基金supported by the National Natural Science Foundation of China(No.62401597)the Natural Science Foundation of Hunan Province,China(No.2024JJ6469)the Scientific Research Project of National University of Defense Technology,China(No.ZK22-02)。
文摘The information exchange among satellites is crucial for the implementation of cluster satellite cooperative missions.However,achieving fast perception,rapid networking,and highprecision time synchronization among nodes without the support of the Global Navigation Satellite System(GNSS)and other prior information remains a formidable challenge to real-time wireless networks design.Therefore,a self-organizing network methodology based on multi-agent negotiation is proposed,which autonomously determines the master node through collaborative negotiation and competitive elections.On this basis,a real-time network protocol design is carried out and a high-precision time synchronization method with motion compensation is proposed.Simulation results demonstrate that the proposed method enables rapid networking with the capability of selfdiscovery,self-organization,and self-healing.For a cluster of 8 satellites,the networking time and the reorganization time are less than 4 s.The time synchronization accuracy exceeds 10-10s with motion compensation,demonstrating excellent real-time performance and stability.The research presented in this paper provides a valuable reference for the design and application of spacebased self-organizing networks for satellite cluster.
基金funded by the National Key R&D Program of China(Grant no.2018YFA0702504)the Sinopec research project(P22162).
文摘Absorption compensation is a process involving the exponential amplification of reflection amplitudes.This process amplifies the seismic signal and noise,thereby substantially reducing the signal-tonoise ratio of seismic data.Therefore,this paper proposes a multichannel inversion absorption compensation method based on structure tensor regularization.First,the structure tensor is utilized to extract the spatial inclination of seismic signals,and the spatial prediction filter is designed along the inclination direction.The spatial prediction filter is then introduced into the regularization condition of multichannel inversion absorption compensation,and the absorption compensation is realized under the framework of multichannel inversion theory.The spatial predictability of seismic signals is also introduced into the objective function of absorption compensation inversion.Thus,the inversion system can effectively suppress the noise amplification effect during absorption compensation and improve the recovery accuracy of high-frequency signals.Synthetic and field data tests are conducted to demonstrate the accuracy and effectiveness of the proposed method.
基金Supported by Shanxi Provincial Natural Science Foundation(Grant No.2021JM010)The Youth Innovation Team of Shaanxi Universities.
文摘This study aimed to identify and compensate for the geometric errors of the double swiveling axes in a five-axis computer numerical control(CNC)machining center.Hence,a three-dimensional coordinate calculation algorithm for a measured point with additional rotational rigid body motion constraints is proposed.The motion constraints of the rotational rigid body were analyzed,and a mathematical model of the measured point algorithm in the swiveling axes was established.The Levenberg-Marquard method was used to solve the nonlinear superstatically determined equations.The spatial coordinate error was used to separate the spatial deviation of the measured point.An identification model of the position-independent and position-dependent geometric errors was established.The three-dimensional coordinate-solving algorithm of the measured point in the swiveling axis and geometric error identification method based on the Monte Carlo method were analyzed numerically.Geometric error measurement and cutting experiments were performed on a VMC25100U five-axis machining center,which integrated two swiveling axes.Geometric errors of the A-and B-axes were identified and measured experimentally.The angular positioning errors before and after compensation were measured using a laser interferometer,which verified the effectiveness of the proposed algorithm.A cutting experiment of a round table part was performed.The shape and position accuracy of the processed part before and after compensation were detected using a coordinate measuring machine.It verified that the geometric error of the swiveling axis was effectively compensated by the algorithm proposed herein.
