In order to investigate the joint torque-based Cartesian impedance control strategies and the influence of compensations for friction, an experimental study on the identification of friction parameters, friction compe...In order to investigate the joint torque-based Cartesian impedance control strategies and the influence of compensations for friction, an experimental study on the identification of friction parameters, friction compensation and the Cartesian impedance control are developed for the harmonic drive robot, by using the sensors available in the joint itself. Different from the conventional Cartesian impedance control schemes which are mostly based on the robot end force/torque information, five joint torque-based Cartesian impedance control schemes are considered, including the force-based schemes in Cartesian/joint space, the position-based schemes in Cartesian/joint space and the stiffness control. Four of them are verified by corresponding experiments with/without friction compensations. By comparison, it is found that the force-based impedance control strategy is more suitable than the position-based one for the robot based on joint torque feedback and the friction has even a positive effect on Cartesian impedance control stability.展开更多
The values of non-marketable forest products have largely been ignored, which made the conservation of the natural resources increasingly more economically difficult. Based on the previous studies, compensation subsid...The values of non-marketable forest products have largely been ignored, which made the conservation of the natural resources increasingly more economically difficult. Based on the previous studies, compensation subsidy for the values of non-marketable forest products was computed with a method of compensation coefficient that combines the Engel Coefficient and Logistic Curve. The method was applied in Changbai Mountain area. The total value of the compensation subsidy in 1999 was supposed to 637.93 Yuan·hm-2, of which 70% would be paid directly to the local stakeholders and is much higher than the compensation subsidy previously computed (75Yuan·hm-2·year-1). It is currently impossible for the central government to bear all the costs and investment of natural forest protection. A practical solution is that the local government should invest in forest and put the compensation subsidy into the current revenue.展开更多
In recent years, the frequent occurrences of marine oil spills have already become one of the major reasons threatening the marine ecological safety of China. In the event of oil spill, oth-er than taking the necessar...In recent years, the frequent occurrences of marine oil spills have already become one of the major reasons threatening the marine ecological safety of China. In the event of oil spill, oth-er than taking the necessary emergent measures aiming specifically at the damage to the marine ecology and environment, using legal means to assure that the damage liabilities are borne by the respon-sible persons to protect the national interests are also very neces-sary. This paper advances five recommendations regarding the development of a system for ecological legal compensations from the standpoint of the current status of legislation and execution of the laws on compensation of oil spill polluting marine ecosystem. These five recommendations include: determination of the status of juristic action in marine ecological and environmental compen-sations in accordance with the laws, determination of plaintiff of marine ecological and environmental compensations in accordance with the laws, determination of the four basic principles in the le-gal actions of marine ecological and environmental compensations in accordance with the laws, determination of assessment technical standard of marine ecological and environmental damages in ac-cordance with the laws, and determination of the scope of marine ecological and environmental compensations in accordance with the laws.展开更多
Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects a...Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects arise from changes in urban environmental factors,such as near-surface air temperatures,precipitation,urban heat island(UHI)intensity,and population density(POP).The respective contributions ofω_(d) andω_(i) to vegetation net primary productivity(NPP)under various phases of urbanization are not well quantified.Using multisource remote-sensing data from 1990 to 2020,we analyzed the spatiotemporal variation in urban expansion and the effect thatω_(d) andω_(i) had on NPP in the megalopolis of Beijing,China,over 5-year intervals.During this period,Beijing underwent significant planar expansion rates of about 58.9 km^(2)/yr.Annual mean loss of NPP byω_(d) was estimated to be about 77.1 g C/(m^(2)·yr)during the 1990-2020 period,while annual mean improvement to NPP byω_(i) amounted to an increase of 28.9 g C/(m^(2)·yr).The NPP losses were partially offset by NPP improvements in the order of 18.6%-69.3%.The impact of forcing variables on NPP varied spatially.Air temperature,precipitation,UHI,POP,and ISI explained about 13.8%,23.2%,23.7%,14.7%,and 24.6%of the spatial variation in NPP.The impact of air temperature on NPP was related to available moisture,negatively affecting NPP in regions with water deficits.Our findings demonstrate the dual impact of urbanization on vegetation and underscore the necessity for spatially adaptive ecological management strategies in regions experiencing rapid urban growth.展开更多
Achieving multi-electron reaction at high operation voltage is the key to increase the energy density of Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode.However,the motivated V^(4+)/V^(5+)redox usually shows inferior reversibilit...Achieving multi-electron reaction at high operation voltage is the key to increase the energy density of Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode.However,the motivated V^(4+)/V^(5+)redox usually shows inferior reversibility and causes serious volume changes.Herein,this article proposes a local electronic interaction mechanism which achieves highly reversible multi-electron reaction of NVP.Particularly,Al-Sn co-doped and carbon coated NVP(Na_(3)Al_(0.1)Sn_(0.1)V_(1.8)(PO_(4))_(3)@C,abbreviated as NASVP@C-2)was prepared by sol-gel method.The doped-Al can activate the redox of V^(4+)/V^(5+)and generate the"pinning effect"to stabilize the crystal structure,and the Sn acts as localized electronic reservoir for charge compensation of V redox.The localized electronic interaction mechanism between Sn and V is revealed by multi ex-situ characterizations.Kinetics tests and density functional theory(DFT)calculations suggest that the Al-Sn co-doping enhances the electronic conductivity and reduces the Na^(+)diffusion barrier in NVP.An extremely low volumetric variation(1.07%)is detected in NASVP@C-2 during cycling.As a result,the highly reversible multielectron(2.53)reaction is achieved in NASVP@C-2,which releases a high capacity of 147.6 mAh g^(-1) at1 C and exhibits exceptional cycle stability and rate capability.This work provides a new strategy to design high energy density and durable NASICON cathode.展开更多
In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused...In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused byαparticle ionizing radiation was proposed,and the effects of dead-pixel compensation algorithms were compared and analyzed under different parameter conditions.The experimental results show thatαparticle response signal has highest accuracy at 9 dB gain,with an obvious“target-ring”distribution.With increasing cumulative dose,the CMOS APS pedestal tends to saturation while dead pixels continue increasing.Though some pixel damage recovers through natural annealing,the dead-to-noise ratio increases with irradiation time,reaching 32.54%after 72 h.A hierarchical clustering dead-pixel detection method is proposed,categorizing pixels into two types:those within and outside the response event.A classification compensation strategy combining mean and majority filtering is proposed.This compensation algorithm can address dead-pixel interference without affectingαparticle radiation response data.When iterated multiple times and with integration time exceeding 6.31 ms,the number of dead pixels can be effectively reduced.展开更多
This study aims to explore how the Wei River Basin can enhance the efficiency of horizontal ecological compensation to promote high-quality and sustainable development in the Yellow River Basin.To achieve this,a four-...This study aims to explore how the Wei River Basin can enhance the efficiency of horizontal ecological compensation to promote high-quality and sustainable development in the Yellow River Basin.To achieve this,a four-stage DEA(Data Envelopment Analysis)method was employed to evaluate the efficiency of ecological compensation in six prefecture-level cities within the Wei River Basin from 2001 to 2022.In addition,the K-prototype clustering analysis method was integrated to assess the regional differences in ECE(ecological compensation efficiency).The findings indicate:(1)the ecological compensation efficiency in the upstream areas of the Wei River Basin is significantly higher than in the downstream regions;(2)the influence of factors such as the proportion of the tertiary industry,population density and residents’disposable income on the efficiency of ecological compensation is significant;(3)after excluding environmental factors,the overall ecological compensation efficiency showed a significant improvement.Based on these insights,it is recommended that the provinces of Shaanxi and Gansu further establish a robust compensation fund operation mechanism,build a cross-regional ecological compensation upstream-downstream coordination system,and strengthen inter-basin economic cooperation mechanisms to promote dual-driven development through technological advancement and scale benefits,thereby advancing ecological protection and sustainable development in the Wei River Basin.展开更多
In an ultraprecision turning process for small-diameter optical aspheric workpieces,tool-profile errors induce mid-frequency errors in the workpiece profile,limiting further improvements in precision.In this study,an ...In an ultraprecision turning process for small-diameter optical aspheric workpieces,tool-profile errors induce mid-frequency errors in the workpiece profile,limiting further improvements in precision.In this study,an XZB three-axis linkage ultraprecision machining method is proposed,and the effects of tool-center errors are analyzed.To address residual errors in Z-direction profile-error compensation,a workpiece normal-profile-error compensation method is proposed.After XZB three-axis linkage turning and compensation,the workpiece profile error(PV)reaches 0.086μm,surpassing the precision of XZ two-axis machining,and mid-frequency errors are reduced.Compared with Z-direction profile-error compensation,which results in a profile error of 0.092μm,normal-profile-error compensation reduces PV to 0.047μm,considerably improving aspheric accuracy.Experimental results demonstrate that XZB three-axis linkage machining significantly improves the aspheric workpiece profile,enhancing both its accuracy and surface quality.This method reduces mid-frequency errors,and the subsequent application of normal-profile-error compensation further refines the profile,achieving higher overall accuracy.展开更多
In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm ...In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm co-design framework:the T-type three-level bidirectional converter(100 kHz switching frequency)based on silicon carbide(SiC)MOSFET is deeply integrated with fuzzy model predictive control(Fuzzy-MPC).At the hardware level,the switching trajectory and resonance suppression circuit(attenuation resonance peak 18 dB)are optimized,and the total loss is reduced by 23%compared with the traditional silicon-based IGBT.At the algorithm level,the adaptive parameter update mechanism and multi-objective rolling optimization are adopted,and the 5 ms level dynamic power allocation is realized by relying on edge computing.Experiments on 800 V DC microgrid(including 600 kW photovoltaic and 150 A·h energy storage)built based on MATLAB/Simulink hardware-in-the-loop(HIL)platform show that the system shortens the battery charging time from 42 to 28 min(the charging speed is increased by 33%).Through the 78%valley power utilization rate,the power purchase cost of high-priced power grids was significantly reduced,and the levelized electricity price decreased by 10.3%;Under the irradiation fluctuation,the renewable energy consumption rate increases by 10.1%,and the DC bus voltage fluctuation is stable within±10 V when the load step is±30%.The co-design provides an economically feasible and dynamically robust solution for the efficient integration of PV-ESG-EV in the smart grid.展开更多
The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestratio...The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestration in grasslands remains unclear.Based on panel data from prefecture-level cities in the Yellow River Basin(YRB)from 2000 to 2020,this study explored the effects of the GECP on grassland carbon sequestration in the YRB and its heterogeneity using a time-varying difference-in-differences(TV-DID)model.Subsequently,we predicted changes in carbon sequestration in grasslands under the influence of the GECP from 2021 to 2040 using a simulation.The main conclusions are as follows:First,the implementation of the GECP promoted carbon sequestration in grasslands.This conclusion was validated after conducting a series of robustness tests.Moreover,the effects of the GECP were heterogeneous across different geographical locations,highway densities,and grassland areas.Finally,the simulation results indicated that over the next 20 years,grassland carbon sequestration will generally increase but exhibit cyclical changes.The government should align the principles and objectives of the GECP with local geographic conditions,resource availability,and socio-economic development.It must formulate and implement tailored policies that maximize the ecological protection benefits of the GECP and promote carbon sequestration in the grasslands of the YRB.展开更多
O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe ...O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe structural collapse and performance degradation.Herein,a series of high valence tantalum(Ta^(5+))doped Na(Ni_(0.4)Fe_(0.2)Mn_(0.4))_(1−x)Ta_(x)O_(2)(x=0/0.0025/0.005/0.01)secondary spherical particles are firstly developed,where Ta^(5+)doping enables the refined primary grain with a tightly stacked rod-like morphology.Comprehensive structural analysis via Neutron powder diffraction(NPD)and Synchrotron radiation X-ray diffraction(SXRD)reveals an expanded NaO_(2)slab and a reduction in Na site vacancy.The potential charge compensation mechanism is further illustrated by X-ray absorption spectroscopy(XAS)and X-ray photoelectron spectroscopy(XPS),unveiling a partial reduction from Ni^(3+)to Ni^(2+)with Ta^(5+)doping.In situ X-ray diffraction(in situ XRD)suggests that the decorated sample undergoes a volume change as low as 0.8%,in contrast with the pristine one(1.5%).Thus,the optimized sample with x=0.005 retains an enhanced capacity retention up to 70.4%at 1 C after 300 cycles in half-cell and delivers a high energy density of 251 Wh kg^(-1)(0.1 C)and with a good capacity retention of 81.0%at 1 C after 200 cycles in full-cell.Our findings provide new insights into the mechanism of high valence Ta^(5+)doping in stabilizing layered oxides cathode materials for SIBs.展开更多
In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along...In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along the primary delivery feeder from the external network.Besides,the giant induction electro-motors as the working horse of industries requires remarkable amounts of reactive power for electro-mechanical energy conversions.To reduce power losses and operating costs of the MG as well as to improve the voltage quality,this study aims at providing an insightful model for optimal placement and sizing of reactive power compensation capacitors in an industrial MG.In the presented model,the objective function considers voltage profile and network power factor improvement at the MG connection point.Also,it realizes power flow equations within which all operational security constraints are considered.Various reactive power compensation strategies including distributed group compensation,centralized compensation at the main substation,and distributed compensation along the primary delivery feeder are scrutinized.A real industrial MG,say as Urmia Petrochemical plant,is considered in numerical validations.The obtained results in each scenario are discussed in depth.As seen,the best performance is obtained when the optimal location and sizing of capacitors are simultaneously determined at the main buses of the industrial plants,at the main substation of the MG,and alongside the primary delivery feeder.In this way,74.81%improvement in power losses reduction,1.3%lower active power import from the main grid,23.5%improvement in power factor,and 37.5%improvement in network voltage deviation summation are seen in this case compared to the base case.展开更多
Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely...Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely low cross sections.Key challenges include significant energy loss as ions penetrate the target material,limiting measurements to thin target layers.To overcome these obstacles,we propose a novel method,the in-target energy loss compensating(eLOC)method,specifically designed for gas targets,which utilizes a gas-filled magnetic field and accelerating electric fields to compensate for ion energy loss in the target.Simulations show that this approach significantly enhances the effective target thickness by over 140 times in the case of the“Holy Grail”reaction with an inverse-kinematics setup.This eLOC method may provide a powerful new tool for obtaining critical data in nuclear astrophysics,thereby advancing our understanding of stellar nucleosynthesis and the origins of elements in the universe,as well as benefiting other related fields such as isotope production.展开更多
With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challe...With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challenge of improving the frequency regulation performance of a thermal-storage primary frequency regulation system while reducing its associated losses,this paper proposes a multi-dimensional cooperative optimization strategy for the control parameters of a combined thermal-storage system,considering regulation losses.First,the frequency regulation losses of various components within the thermal power unit are quantified,and a calculation method for energy storage regulation loss is proposed,based on Depth of Discharge(DOD)and C-rate.Second,a thermal-storage cooperative control method based on series compensation is developed to improve the system’s frequency regulation performance.Third,targeting system regulation loss cost and regulation output,and considering constraints on output overshoot and system parameters,an improved Particle Swarm Optimization(PSO)algorithm is employed to tune the parameters of the low-pass filter and the series compensator,thereby reducing regulation losses while enhancing performance.Finally,simulation results demonstrate that the total loss cost of the proposed control strategy is comparable to that of a system with only thermal power participation.However,the thermal power loss cost is reduced by 42.16%compared to the thermal-only case,while simultaneously improving system frequency stability.Thus,the proposed strategy effectively balances system frequency stability and economic efficiency.展开更多
The origin of the catalytic power of enzymes with a meta-stable native state,e.g.molten globular state,is an unsolved challenging issue in biochemistry.To help understand the possible differences between this special ...The origin of the catalytic power of enzymes with a meta-stable native state,e.g.molten globular state,is an unsolved challenging issue in biochemistry.To help understand the possible differences between this special class of enzymes and the typical ones,we report here computer simulations of the catalysis of both the well-folded wild-type and the molten globular mutant of chorismate mutase.Using the ab initio quantum mechanical/molecular mechanical minimum free-energy path method,we determined the height of reaction barriers that are in good agreement with experimental measurements.Enzyme-substrate interactions were analyzed in detail to identify factors contributing to catalysis.Computed angular order parameters of backbone N–H bonds and side-chain methyl groups suggested site-specific,non-uniform rigidity changes of the enzymes during catalysis.The change of conformational entropy from the ground state to the transition state revealed distinctly contrasting entropy/enthalpy compensations in the dimeric wild-type enzyme and its molten globular monomeric variant.A unique catalytic strategy was suggested for enzymes that are natively molten globules:some may possess large conformational flexibility to provide strong electrostatic interactions to stabilize the transition state of the substrate and compensate for the entropy loss in the transition state.The equilibrium conformational dynamics in the reactant state were analyzed to quantify their contributions to the structural transitions enzymes needed to reach the transition states.The results suggest that large-scale conformational dynamics make important catalytic contributions to sampling conformational regions in favor of binding the transition state of substrate.展开更多
Hard carbon(HC)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial Coulombic efficiency(ICE)and cycling stability.Cathode compensation agent is a favorable strategy t...Hard carbon(HC)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial Coulombic efficiency(ICE)and cycling stability.Cathode compensation agent is a favorable strategy to make up for the loss of active sodium ions consumed byHCanode.Yet it lacks agent that effectively decomposes to increase the active sodium ions as well as regulate carbon defects for decreasing the irreversible sodium ions consumption.Here,we propose 1,2-dihydroxybenzene Na salt(NaDB)as a cathode compensation agent with high specific capacity(347.9 mAh g^(-1)),lower desodiation potential(2.4–2.8 V)and high utilization(99%).Meanwhile,its byproduct could functionalize HC with more C=O groups and promote its reversible capacity.Consequently,the presodiation hard carbon(pHC)anode exhibits highly reversible capacity of 204.7 mAh g^(-1) with 98%retention at 5 C rate over 1000 cycles.Moreover,with 5 wt%NaDB initially coated on the Na3V2(PO4)3(NVP)cathode,the capacity retention of NVP + NaDB|HC cell could increase from 22%to 89%after 1000 cycles at 1 C rate.This work provides a new avenue to improve reversible capacity and cycling performance of SIBs through designing functional cathode compensation agent.展开更多
A complex geological environment with faults can be encountered in the process of coal mining.Fault activation can cause instantaneous structure slipping,releasing a significant amount of elastic strain energy during ...A complex geological environment with faults can be encountered in the process of coal mining.Fault activation can cause instantaneous structure slipping,releasing a significant amount of elastic strain energy during underground coal mining.This would trigger strong rockburst disasters.To understand the occurrence of fault-slip induced rockbursts,we developed a physical model test system for fault-slip induced rockbursts in coal mine drifts.The boundary energy storage(BES)loading apparatus and bottom rapid retraction(BRR)apparatus are designed to realize energy compensation and continuous boundary stress transfer of the surrounding rocks for instantaneous fault slip,as well as to provide space for the potential fault slip.Taking the typical fault-slip induced rockburst in the Xinjulong Coal Mine,China,as the background,we conducted a model test using the test system.The deformation and stress in the rock surrounding the drift and the support unit force during fault slip are analyzed.The deformation and failure characteristics and dynamic responses of drifts under fault-slip induced rockbursts are obtained.The test results illustrate the rationality and effectiveness of the test system.Finally,corresponding recommendations and prospects are proposed based on our findings.展开更多
Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sint...Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.展开更多
Electromagnetic interference(EMI)shielding materials with adaptive strain capability have broad applications in wearable electronic devices.However,as an important candidate,compressible conductive foam generally suff...Electromagnetic interference(EMI)shielding materials with adaptive strain capability have broad applications in wearable electronic devices.However,as an important candidate,compressible conductive foam generally suffers from a reduction in EMI shielding performance during compression,which limits its application.Here,a compressible conductive aerogel with a unique conductive compensation effect is designed to solve this problem.CuS microspheres with metal-like conductivity serve as conductive compensation sites,and are chemically embedded in the skeletons of lamellar-structured carboxymethylcellulose(CMC)/MXene aerogel through Cu–S−Ti−C chemical bonds.The incorporation of CuS induces circularly-distributed interfacial polarization to enhance the attenuation of EM waves.More importantly,these CuS microspheres act as interlayer bridges to connect the upper and lower MXene/CMC layers during compression,thereby establishing numerous conductive compensation paths to offset the negative effect of thickness reduction on shielding performance.The optimized CMC/MXene/CuS aerogel shows stable EMI shielding performance during compression,and maintains a high shielding effectiveness of∼32.31 dB with increasing compressive strain.In addition,this composite aerogel exhibits good thermal insulation and sound absorption performances,achieving triple shielding functions against EM waves,heat and sound.展开更多
The complex working environment of distribution networks tends to cause impermanent single-phase-to-ground(SPG)fault,and high-temperature ground fault arc is prone to endanger lives and power equipment,resulting in la...The complex working environment of distribution networks tends to cause impermanent single-phase-to-ground(SPG)fault,and high-temperature ground fault arc is prone to endanger lives and power equipment,resulting in large-scale power outages and fire accidents.Thus,fault arc should be extinguished in time.Meanwhile,stable operation conditions of distribution networks and reliable load power supply should be guaranteed to provide high-quality customer service.This paper proposes an active mitigation strategy for SPG fault,and provide active and reactive power compensation at the same time by utilizing an improved flexible power electronic equipment(FPEE)with dc-link sources.These controls are decoupled from each other,so utilization of FPEE is maximized as much as possible.When a SPG fault occurs in distribution networks,FPEE can output,simultaneously,active power,reactive power,and SPG fault compensation current by controlling output current on the d,q,0 coordinate system,respectively.During normal operation of distribution networks,the FPEE can be used as a virtual synchronous generator to compensate load power and its fluctuation.The proposed simultaneous multi-function can also be applied in other cases.Simulation cases are implemented to verify principles and practicability.展开更多
基金The National Natural Science Foundation of China(No.60675045)the National High Technology Research and Development Program of China (863Program) (No.2006AA04Z255)
文摘In order to investigate the joint torque-based Cartesian impedance control strategies and the influence of compensations for friction, an experimental study on the identification of friction parameters, friction compensation and the Cartesian impedance control are developed for the harmonic drive robot, by using the sensors available in the joint itself. Different from the conventional Cartesian impedance control schemes which are mostly based on the robot end force/torque information, five joint torque-based Cartesian impedance control schemes are considered, including the force-based schemes in Cartesian/joint space, the position-based schemes in Cartesian/joint space and the stiffness control. Four of them are verified by corresponding experiments with/without friction compensations. By comparison, it is found that the force-based impedance control strategy is more suitable than the position-based one for the robot based on joint torque feedback and the friction has even a positive effect on Cartesian impedance control stability.
文摘The values of non-marketable forest products have largely been ignored, which made the conservation of the natural resources increasingly more economically difficult. Based on the previous studies, compensation subsidy for the values of non-marketable forest products was computed with a method of compensation coefficient that combines the Engel Coefficient and Logistic Curve. The method was applied in Changbai Mountain area. The total value of the compensation subsidy in 1999 was supposed to 637.93 Yuan·hm-2, of which 70% would be paid directly to the local stakeholders and is much higher than the compensation subsidy previously computed (75Yuan·hm-2·year-1). It is currently impossible for the central government to bear all the costs and investment of natural forest protection. A practical solution is that the local government should invest in forest and put the compensation subsidy into the current revenue.
基金funded by the "Study of Legal Mechanism of Compensation Demanded by the State and International Practices in Marine Ecological Damages (Grant No.2008GXS5B100) in the Programme of national Soft Sciences Research Projects
文摘In recent years, the frequent occurrences of marine oil spills have already become one of the major reasons threatening the marine ecological safety of China. In the event of oil spill, oth-er than taking the necessary emergent measures aiming specifically at the damage to the marine ecology and environment, using legal means to assure that the damage liabilities are borne by the respon-sible persons to protect the national interests are also very neces-sary. This paper advances five recommendations regarding the development of a system for ecological legal compensations from the standpoint of the current status of legislation and execution of the laws on compensation of oil spill polluting marine ecosystem. These five recommendations include: determination of the status of juristic action in marine ecological and environmental compen-sations in accordance with the laws, determination of plaintiff of marine ecological and environmental compensations in accordance with the laws, determination of the four basic principles in the le-gal actions of marine ecological and environmental compensations in accordance with the laws, determination of assessment technical standard of marine ecological and environmental damages in ac-cordance with the laws, and determination of the scope of marine ecological and environmental compensations in accordance with the laws.
基金supported by the National Key Research and Develop-ment Program of China(No.2020YFA0608100)the National Nat-ural Science Foundation of China(Nos.32071842 and 32101588).
文摘Urbanization alters vegetation productivity by both direct(ωd)and indirect(ω_(i))effects.The direct effect is from the change of vegetated area indicated by impervious surface intensity(ISI),while indirect effects arise from changes in urban environmental factors,such as near-surface air temperatures,precipitation,urban heat island(UHI)intensity,and population density(POP).The respective contributions ofω_(d) andω_(i) to vegetation net primary productivity(NPP)under various phases of urbanization are not well quantified.Using multisource remote-sensing data from 1990 to 2020,we analyzed the spatiotemporal variation in urban expansion and the effect thatω_(d) andω_(i) had on NPP in the megalopolis of Beijing,China,over 5-year intervals.During this period,Beijing underwent significant planar expansion rates of about 58.9 km^(2)/yr.Annual mean loss of NPP byω_(d) was estimated to be about 77.1 g C/(m^(2)·yr)during the 1990-2020 period,while annual mean improvement to NPP byω_(i) amounted to an increase of 28.9 g C/(m^(2)·yr).The NPP losses were partially offset by NPP improvements in the order of 18.6%-69.3%.The impact of forcing variables on NPP varied spatially.Air temperature,precipitation,UHI,POP,and ISI explained about 13.8%,23.2%,23.7%,14.7%,and 24.6%of the spatial variation in NPP.The impact of air temperature on NPP was related to available moisture,negatively affecting NPP in regions with water deficits.Our findings demonstrate the dual impact of urbanization on vegetation and underscore the necessity for spatially adaptive ecological management strategies in regions experiencing rapid urban growth.
基金financially supported by the National Natural Science Foundation of China(52462030,52464034,52364038,12464049 and 52474330)Outstanding Youth Funding program of Hunan Province(No.2023JJ10033)+5 种基金Excellent Youth Foundation of Hunan Provincial Education Department(No.23B0527,23B0528)the Natural Science Foundation of Hunan Province(No.2024JJ7399,No.2024JJ7398)Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Provincethe Hunan Provincial Undergraduate Innovation Training Program General Project(Grant No.S202410531041,No.S202310531052)the Postgraduate Research Innovation Program of Jishou University([2024]11-82)the Postgraduate Graduate Research Project of Jishou University(2023-53)。
文摘Achieving multi-electron reaction at high operation voltage is the key to increase the energy density of Na_(3)V_(2)(PO_(4))_(3)(NVP)cathode.However,the motivated V^(4+)/V^(5+)redox usually shows inferior reversibility and causes serious volume changes.Herein,this article proposes a local electronic interaction mechanism which achieves highly reversible multi-electron reaction of NVP.Particularly,Al-Sn co-doped and carbon coated NVP(Na_(3)Al_(0.1)Sn_(0.1)V_(1.8)(PO_(4))_(3)@C,abbreviated as NASVP@C-2)was prepared by sol-gel method.The doped-Al can activate the redox of V^(4+)/V^(5+)and generate the"pinning effect"to stabilize the crystal structure,and the Sn acts as localized electronic reservoir for charge compensation of V redox.The localized electronic interaction mechanism between Sn and V is revealed by multi ex-situ characterizations.Kinetics tests and density functional theory(DFT)calculations suggest that the Al-Sn co-doping enhances the electronic conductivity and reduces the Na^(+)diffusion barrier in NVP.An extremely low volumetric variation(1.07%)is detected in NASVP@C-2 during cycling.As a result,the highly reversible multielectron(2.53)reaction is achieved in NASVP@C-2,which releases a high capacity of 147.6 mAh g^(-1) at1 C and exhibits exceptional cycle stability and rate capability.This work provides a new strategy to design high energy density and durable NASICON cathode.
基金supported by the National Natural Science Foundation of China(No.11905102)Hunan Provincial Postgraduate Research and Innovation Project(No.QL20230234)。
文摘In this study,the mechanism and characteristics of the responseαparticles and the damage caused by them in CMOS active pixel(APS)sensors were investigated.A detection and compensation algorithm for dead pixels caused byαparticle ionizing radiation was proposed,and the effects of dead-pixel compensation algorithms were compared and analyzed under different parameter conditions.The experimental results show thatαparticle response signal has highest accuracy at 9 dB gain,with an obvious“target-ring”distribution.With increasing cumulative dose,the CMOS APS pedestal tends to saturation while dead pixels continue increasing.Though some pixel damage recovers through natural annealing,the dead-to-noise ratio increases with irradiation time,reaching 32.54%after 72 h.A hierarchical clustering dead-pixel detection method is proposed,categorizing pixels into two types:those within and outside the response event.A classification compensation strategy combining mean and majority filtering is proposed.This compensation algorithm can address dead-pixel interference without affectingαparticle radiation response data.When iterated multiple times and with integration time exceeding 6.31 ms,the number of dead pixels can be effectively reduced.
基金funded by the Gansu Soft Science Planning Project(Grant No.25JRZA170).
文摘This study aims to explore how the Wei River Basin can enhance the efficiency of horizontal ecological compensation to promote high-quality and sustainable development in the Yellow River Basin.To achieve this,a four-stage DEA(Data Envelopment Analysis)method was employed to evaluate the efficiency of ecological compensation in six prefecture-level cities within the Wei River Basin from 2001 to 2022.In addition,the K-prototype clustering analysis method was integrated to assess the regional differences in ECE(ecological compensation efficiency).The findings indicate:(1)the ecological compensation efficiency in the upstream areas of the Wei River Basin is significantly higher than in the downstream regions;(2)the influence of factors such as the proportion of the tertiary industry,population density and residents’disposable income on the efficiency of ecological compensation is significant;(3)after excluding environmental factors,the overall ecological compensation efficiency showed a significant improvement.Based on these insights,it is recommended that the provinces of Shaanxi and Gansu further establish a robust compensation fund operation mechanism,build a cross-regional ecological compensation upstream-downstream coordination system,and strengthen inter-basin economic cooperation mechanisms to promote dual-driven development through technological advancement and scale benefits,thereby advancing ecological protection and sustainable development in the Wei River Basin.
基金supported by the National Natural Science Foundation of China(Grant No.52130503)the Science and Technology Innovation Program of Hunan Province(Grants Nos.2023RC1046 and 2023GK2008)+2 种基金the Hunan Provincial Science and Technology Department(Grant No.2021JC0005)the Postgraduate Scientific Research Innovation Project of Hunan Province(Grant No.QL20220088)the Shenzhen Undertakes Major National Science and Technology Projects(Grant No.CJGJZD20220517142406015).
文摘In an ultraprecision turning process for small-diameter optical aspheric workpieces,tool-profile errors induce mid-frequency errors in the workpiece profile,limiting further improvements in precision.In this study,an XZB three-axis linkage ultraprecision machining method is proposed,and the effects of tool-center errors are analyzed.To address residual errors in Z-direction profile-error compensation,a workpiece normal-profile-error compensation method is proposed.After XZB three-axis linkage turning and compensation,the workpiece profile error(PV)reaches 0.086μm,surpassing the precision of XZ two-axis machining,and mid-frequency errors are reduced.Compared with Z-direction profile-error compensation,which results in a profile error of 0.092μm,normal-profile-error compensation reduces PV to 0.047μm,considerably improving aspheric accuracy.Experimental results demonstrate that XZB three-axis linkage machining significantly improves the aspheric workpiece profile,enhancing both its accuracy and surface quality.This method reduces mid-frequency errors,and the subsequent application of normal-profile-error compensation further refines the profile,achieving higher overall accuracy.
基金Jiangsu Provincial College Student Innovation and Entrepreneurship Program(Grant No.SJCX25_2184)—“Multi-energy Complementary Optimization and Vehicle-Storage Bidirectional Interaction Technology Driven by Novel 5E Framework”(Principal Investigator:Yuan-Yuan ShiFunding Agency:Jiangsu Provincial Education Department)+3 种基金Huaian Natural Science Research Project(Grant No.HAB2024046)—“Optimal Control of Flexible Cold-Heat-Power Integrated System with Source-Grid-Load-Storage Coordination”(Principal Investigator:Jie JiFunding Agency:Huaian Science and Technology Bureau)Huaiyin Institute of TechnologyUniversity-funded Project(GrantNo.HGYK202511)—“Data-driven CooperativeOptimization Dispatch for Source-Grid-Load Systems”(Principal Investigator:Chu-Tong ZhangFunding Agency:Huaiyin Institute of Technology).
文摘In order to solve the problems of slow dynamic response and difficult multi-source coordination of solar electric vehicle charging stations under intermittent renewable energy,this paper proposes a hardware-algorithm co-design framework:the T-type three-level bidirectional converter(100 kHz switching frequency)based on silicon carbide(SiC)MOSFET is deeply integrated with fuzzy model predictive control(Fuzzy-MPC).At the hardware level,the switching trajectory and resonance suppression circuit(attenuation resonance peak 18 dB)are optimized,and the total loss is reduced by 23%compared with the traditional silicon-based IGBT.At the algorithm level,the adaptive parameter update mechanism and multi-objective rolling optimization are adopted,and the 5 ms level dynamic power allocation is realized by relying on edge computing.Experiments on 800 V DC microgrid(including 600 kW photovoltaic and 150 A·h energy storage)built based on MATLAB/Simulink hardware-in-the-loop(HIL)platform show that the system shortens the battery charging time from 42 to 28 min(the charging speed is increased by 33%).Through the 78%valley power utilization rate,the power purchase cost of high-priced power grids was significantly reduced,and the levelized electricity price decreased by 10.3%;Under the irradiation fluctuation,the renewable energy consumption rate increases by 10.1%,and the DC bus voltage fluctuation is stable within±10 V when the load step is±30%.The co-design provides an economically feasible and dynamically robust solution for the efficient integration of PV-ESG-EV in the smart grid.
基金supported by the National Natural Science Foundation of China[Grant No.71773091]the Graduate Student Science and Technology Innovation Program of College of Economics and Management[Grant No.JGYJSCXXM202308].
文摘The Grassland Ecological Compensation Policy(GECP)is a large-scale project that has been investing in China since 2011.Despite the significant investment and long duration of the GECP,its impact on carbon sequestration in grasslands remains unclear.Based on panel data from prefecture-level cities in the Yellow River Basin(YRB)from 2000 to 2020,this study explored the effects of the GECP on grassland carbon sequestration in the YRB and its heterogeneity using a time-varying difference-in-differences(TV-DID)model.Subsequently,we predicted changes in carbon sequestration in grasslands under the influence of the GECP from 2021 to 2040 using a simulation.The main conclusions are as follows:First,the implementation of the GECP promoted carbon sequestration in grasslands.This conclusion was validated after conducting a series of robustness tests.Moreover,the effects of the GECP were heterogeneous across different geographical locations,highway densities,and grassland areas.Finally,the simulation results indicated that over the next 20 years,grassland carbon sequestration will generally increase but exhibit cyclical changes.The government should align the principles and objectives of the GECP with local geographic conditions,resource availability,and socio-economic development.It must formulate and implement tailored policies that maximize the ecological protection benefits of the GECP and promote carbon sequestration in the grasslands of the YRB.
基金supported by the National Natural Science Foundation of China (52402298, 52172224, 52202228, 22479112)the Science and Technology Correspondent Project of Tianjin(24YDTPJC00240)+3 种基金Science Research Project of Hebei Education Department (BJK2022011)Central Funds Guiding the Local Science and Technology Development of Hebei Province (236Z4404G)the Beijing Tianjin Hebei Basic Research Cooperation Special Project(E2024202273)Tianjin Sci.&Tech. Program (22YFYSHZ00220)
文摘O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe structural collapse and performance degradation.Herein,a series of high valence tantalum(Ta^(5+))doped Na(Ni_(0.4)Fe_(0.2)Mn_(0.4))_(1−x)Ta_(x)O_(2)(x=0/0.0025/0.005/0.01)secondary spherical particles are firstly developed,where Ta^(5+)doping enables the refined primary grain with a tightly stacked rod-like morphology.Comprehensive structural analysis via Neutron powder diffraction(NPD)and Synchrotron radiation X-ray diffraction(SXRD)reveals an expanded NaO_(2)slab and a reduction in Na site vacancy.The potential charge compensation mechanism is further illustrated by X-ray absorption spectroscopy(XAS)and X-ray photoelectron spectroscopy(XPS),unveiling a partial reduction from Ni^(3+)to Ni^(2+)with Ta^(5+)doping.In situ X-ray diffraction(in situ XRD)suggests that the decorated sample undergoes a volume change as low as 0.8%,in contrast with the pristine one(1.5%).Thus,the optimized sample with x=0.005 retains an enhanced capacity retention up to 70.4%at 1 C after 300 cycles in half-cell and delivers a high energy density of 251 Wh kg^(-1)(0.1 C)and with a good capacity retention of 81.0%at 1 C after 200 cycles in full-cell.Our findings provide new insights into the mechanism of high valence Ta^(5+)doping in stabilizing layered oxides cathode materials for SIBs.
文摘In real industrial microgrids(MGs),the length of the primary delivery feeder to the connection point of the main substation is sometimes long.This reduces the power factor and increases reactive power absorption along the primary delivery feeder from the external network.Besides,the giant induction electro-motors as the working horse of industries requires remarkable amounts of reactive power for electro-mechanical energy conversions.To reduce power losses and operating costs of the MG as well as to improve the voltage quality,this study aims at providing an insightful model for optimal placement and sizing of reactive power compensation capacitors in an industrial MG.In the presented model,the objective function considers voltage profile and network power factor improvement at the MG connection point.Also,it realizes power flow equations within which all operational security constraints are considered.Various reactive power compensation strategies including distributed group compensation,centralized compensation at the main substation,and distributed compensation along the primary delivery feeder are scrutinized.A real industrial MG,say as Urmia Petrochemical plant,is considered in numerical validations.The obtained results in each scenario are discussed in depth.As seen,the best performance is obtained when the optimal location and sizing of capacitors are simultaneously determined at the main buses of the industrial plants,at the main substation of the MG,and alongside the primary delivery feeder.In this way,74.81%improvement in power losses reduction,1.3%lower active power import from the main grid,23.5%improvement in power factor,and 37.5%improvement in network voltage deviation summation are seen in this case compared to the base case.
基金supported by the the National Key R&D Program of China (Grant Nos.2023YFA1606900 and 2022YFA1602301)the National Natural Science Foundation of China (Grant Nos.12235003,12435010,and 12147101)+3 种基金the Guangdong Major Project of Basic and Applied Basic Research (Grant No.2020B0301030008)the STCSM (Grant No.23590780100)the Natural Science Foundation of Shanghai (Grant No.23JC1400200)the China Postdoctoral Science Foundation (Grant No.2024M760483)。
文摘Measuring cross sections of nuclear reactions,such as the so-called“Holy Grail”reaction,^(12)C(σ,γ)^(16)O,is essential for understanding stellar nucleosynthesis but presents significant challenges due to extremely low cross sections.Key challenges include significant energy loss as ions penetrate the target material,limiting measurements to thin target layers.To overcome these obstacles,we propose a novel method,the in-target energy loss compensating(eLOC)method,specifically designed for gas targets,which utilizes a gas-filled magnetic field and accelerating electric fields to compensate for ion energy loss in the target.Simulations show that this approach significantly enhances the effective target thickness by over 140 times in the case of the“Holy Grail”reaction with an inverse-kinematics setup.This eLOC method may provide a powerful new tool for obtaining critical data in nuclear astrophysics,thereby advancing our understanding of stellar nucleosynthesis and the origins of elements in the universe,as well as benefiting other related fields such as isotope production.
基金supported by the Science and Technology Development Project of Jilin Province(Project No.YDZJ202301ZYTS284).
文摘With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challenge of improving the frequency regulation performance of a thermal-storage primary frequency regulation system while reducing its associated losses,this paper proposes a multi-dimensional cooperative optimization strategy for the control parameters of a combined thermal-storage system,considering regulation losses.First,the frequency regulation losses of various components within the thermal power unit are quantified,and a calculation method for energy storage regulation loss is proposed,based on Depth of Discharge(DOD)and C-rate.Second,a thermal-storage cooperative control method based on series compensation is developed to improve the system’s frequency regulation performance.Third,targeting system regulation loss cost and regulation output,and considering constraints on output overshoot and system parameters,an improved Particle Swarm Optimization(PSO)algorithm is employed to tune the parameters of the low-pass filter and the series compensator,thereby reducing regulation losses while enhancing performance.Finally,simulation results demonstrate that the total loss cost of the proposed control strategy is comparable to that of a system with only thermal power participation.However,the thermal power loss cost is reduced by 42.16%compared to the thermal-only case,while simultaneously improving system frequency stability.Thus,the proposed strategy effectively balances system frequency stability and economic efficiency.
基金support from HKU seed funding for basic research and Hong Kong General Research Fund is greatly appreciatedThe high-perfor-mance computing facility at the University of Hong Kong provided computing resources for this work
文摘The origin of the catalytic power of enzymes with a meta-stable native state,e.g.molten globular state,is an unsolved challenging issue in biochemistry.To help understand the possible differences between this special class of enzymes and the typical ones,we report here computer simulations of the catalysis of both the well-folded wild-type and the molten globular mutant of chorismate mutase.Using the ab initio quantum mechanical/molecular mechanical minimum free-energy path method,we determined the height of reaction barriers that are in good agreement with experimental measurements.Enzyme-substrate interactions were analyzed in detail to identify factors contributing to catalysis.Computed angular order parameters of backbone N–H bonds and side-chain methyl groups suggested site-specific,non-uniform rigidity changes of the enzymes during catalysis.The change of conformational entropy from the ground state to the transition state revealed distinctly contrasting entropy/enthalpy compensations in the dimeric wild-type enzyme and its molten globular monomeric variant.A unique catalytic strategy was suggested for enzymes that are natively molten globules:some may possess large conformational flexibility to provide strong electrostatic interactions to stabilize the transition state of the substrate and compensate for the entropy loss in the transition state.The equilibrium conformational dynamics in the reactant state were analyzed to quantify their contributions to the structural transitions enzymes needed to reach the transition states.The results suggest that large-scale conformational dynamics make important catalytic contributions to sampling conformational regions in favor of binding the transition state of substrate.
基金supported by National Natural Science Foundation of China(No.22278308 and 22109114)Open Foundation of Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering(Grant number:JDSX2022023).
文摘Hard carbon(HC)is widely used in sodium-ion batteries(SIBs),but its performance has always been limited by lowinitial Coulombic efficiency(ICE)and cycling stability.Cathode compensation agent is a favorable strategy to make up for the loss of active sodium ions consumed byHCanode.Yet it lacks agent that effectively decomposes to increase the active sodium ions as well as regulate carbon defects for decreasing the irreversible sodium ions consumption.Here,we propose 1,2-dihydroxybenzene Na salt(NaDB)as a cathode compensation agent with high specific capacity(347.9 mAh g^(-1)),lower desodiation potential(2.4–2.8 V)and high utilization(99%).Meanwhile,its byproduct could functionalize HC with more C=O groups and promote its reversible capacity.Consequently,the presodiation hard carbon(pHC)anode exhibits highly reversible capacity of 204.7 mAh g^(-1) with 98%retention at 5 C rate over 1000 cycles.Moreover,with 5 wt%NaDB initially coated on the Na3V2(PO4)3(NVP)cathode,the capacity retention of NVP + NaDB|HC cell could increase from 22%to 89%after 1000 cycles at 1 C rate.This work provides a new avenue to improve reversible capacity and cycling performance of SIBs through designing functional cathode compensation agent.
基金support from the National Natural Science Foundation of China (Grant Nos.51927807,42077267 and 42277174).
文摘A complex geological environment with faults can be encountered in the process of coal mining.Fault activation can cause instantaneous structure slipping,releasing a significant amount of elastic strain energy during underground coal mining.This would trigger strong rockburst disasters.To understand the occurrence of fault-slip induced rockbursts,we developed a physical model test system for fault-slip induced rockbursts in coal mine drifts.The boundary energy storage(BES)loading apparatus and bottom rapid retraction(BRR)apparatus are designed to realize energy compensation and continuous boundary stress transfer of the surrounding rocks for instantaneous fault slip,as well as to provide space for the potential fault slip.Taking the typical fault-slip induced rockburst in the Xinjulong Coal Mine,China,as the background,we conducted a model test using the test system.The deformation and stress in the rock surrounding the drift and the support unit force during fault slip are analyzed.The deformation and failure characteristics and dynamic responses of drifts under fault-slip induced rockbursts are obtained.The test results illustrate the rationality and effectiveness of the test system.Finally,corresponding recommendations and prospects are proposed based on our findings.
基金financially supported by the National Natural Science Foundation of China(52102206)the Natural Science Foundation of Beijing Municipality-Shunyi Innovation Collaborative Joint Fund(L247018)+2 种基金the Natural Science Foundation of Beijing Municipality(2254076 and 2252024)the Central Guidance on Local Science and Technology Development Fund of Hebei Province(246Z4412G)the Fundamental Research Funds for the Central Universities(2025MS022,North China Electric Power University)。
文摘Composite cathodes integrating Ni-rich layered oxides and oxide solid electrolytes are essential for highenergy all-solid-state lithium-ion batteries(ASSLBs),yet interfacial degradation during high-temperature co-sintering(>600℃)remains a critical challenge.While surface passivation strategies mitigate reactions below 400℃,their effectiveness diminishes at elevated temperatures due to inability to counteract Li^(+)concentration gradients.Here,we introduce in situ lithium compensators,i.e.,LiOH/Li_(2)CO_(3),into NCM-LATP composite cathodes to dynamically replenish Li^(+)during co-sintering.These additives melt to form transient Li^(+)-rich phases that back-diffuse Li^(+)into NCM lattices,suppressing layered-to-rock salt transitions and stabilizing the interface.Quasi in situ XRD confirms retention of the layered structure at temperature up to 700℃,while electrochemical tests demonstrate a reversible capacity of 222.2 mA h g^(-1)—comparable to NCM before co-sintering—and an impressive 65.3% capacity retention improvement over100 cycles.In contrast,uncompensated cathodes exhibit severe degradation to 96.5 mA h g^(-1)due to Li depletion and resistive Li-Ti-O interphases.This strategy integrates sacrificial chemistry with scalable powder-mixing workflows,achieving a 93.4% reduction in interfacial impedance.By addressing Li^(+)flux homogenization and structural stability,this work provides a practical pathway toward industrialscale fabrication of high-performance ASSLBs.
基金financially supported by the National Key Research and Development Program of China(No.2021YBF3501304)the National Natural Science Foundation of China(Nos.52371171,52222106,51971008,52121001)+1 种基金the Natural Science Foundation of Beijing Municipality(No.2212033)We thank the researchers at the Analysis&Testing Center of Beihang University for their assistance with testing.
文摘Electromagnetic interference(EMI)shielding materials with adaptive strain capability have broad applications in wearable electronic devices.However,as an important candidate,compressible conductive foam generally suffers from a reduction in EMI shielding performance during compression,which limits its application.Here,a compressible conductive aerogel with a unique conductive compensation effect is designed to solve this problem.CuS microspheres with metal-like conductivity serve as conductive compensation sites,and are chemically embedded in the skeletons of lamellar-structured carboxymethylcellulose(CMC)/MXene aerogel through Cu–S−Ti−C chemical bonds.The incorporation of CuS induces circularly-distributed interfacial polarization to enhance the attenuation of EM waves.More importantly,these CuS microspheres act as interlayer bridges to connect the upper and lower MXene/CMC layers during compression,thereby establishing numerous conductive compensation paths to offset the negative effect of thickness reduction on shielding performance.The optimized CMC/MXene/CuS aerogel shows stable EMI shielding performance during compression,and maintains a high shielding effectiveness of∼32.31 dB with increasing compressive strain.In addition,this composite aerogel exhibits good thermal insulation and sound absorption performances,achieving triple shielding functions against EM waves,heat and sound.
基金supported in part by the National Natural Science Foundation of China(No.51677030).
文摘The complex working environment of distribution networks tends to cause impermanent single-phase-to-ground(SPG)fault,and high-temperature ground fault arc is prone to endanger lives and power equipment,resulting in large-scale power outages and fire accidents.Thus,fault arc should be extinguished in time.Meanwhile,stable operation conditions of distribution networks and reliable load power supply should be guaranteed to provide high-quality customer service.This paper proposes an active mitigation strategy for SPG fault,and provide active and reactive power compensation at the same time by utilizing an improved flexible power electronic equipment(FPEE)with dc-link sources.These controls are decoupled from each other,so utilization of FPEE is maximized as much as possible.When a SPG fault occurs in distribution networks,FPEE can output,simultaneously,active power,reactive power,and SPG fault compensation current by controlling output current on the d,q,0 coordinate system,respectively.During normal operation of distribution networks,the FPEE can be used as a virtual synchronous generator to compensate load power and its fluctuation.The proposed simultaneous multi-function can also be applied in other cases.Simulation cases are implemented to verify principles and practicability.
