Methacrylate-based monolithic column was prepared in fused-silica capillary (80 ′ 0.32 mm i.d.) by in situ polymerizetion reaction using glycidyl methacrylate as monomer;ethylene dimethacrylate as crosslinker;1-propa...Methacrylate-based monolithic column was prepared in fused-silica capillary (80 ′ 0.32 mm i.d.) by in situ polymerizetion reaction using glycidyl methacrylate as monomer;ethylene dimethacrylate as crosslinker;1-propanol, 1,4-butanediol, and water as porogenic solvents. The monolith matrix was modified with trimethylamine to create strong anion exchanger via ring opening reaction of epoxy groups. The morphology of the monolithic column was studied by using Scanning Electron Microscope (SEM). This column had good mechanical stability and permeability. The effects of various mobile phases for separation of inorganic anions were investigated. Iodate, bromate, nitrite, bromide, and nitrate were separated within 11 min using100 mMpotassium chloride as mobile phase and detected at 210 nm. This method showed good precision of retention time, acceptable linearity and good sensitivity. Under the optimum condition, the RSD of the retention time was in the range of 1.09%-1.75% (n = 6). The calibration curve showed linear relationships between the peak area and the concentration. The limits of detection (LOD) and the limits of quantitation (LOQ) were between 0.08-0.18 mM and 0.26-0.61 mM, respectively. This method was applied to the determination of inorganic anions in tap water and ground water samples.展开更多
Biochar is a soil amendment for increasing soil quality and decreasing nutrient leaching. However, there is little information on the impact of biochar-based fertilizer(BF) on soil nutrient leaching in agricultural so...Biochar is a soil amendment for increasing soil quality and decreasing nutrient leaching. However, there is little information on the impact of biochar-based fertilizer(BF) on soil nutrient leaching in agricultural soils. We conducted a soil column leaching experiment to study the effects of BF on the leaching of total nitrogen(TN), total phosphorus, and total potassium(TK) in tobacco soils. The distribution characteristics of NH_4^+-N, available P, and available K in soil profiles were analyzed after the application of BF. Biochar was prepared by pyrolysis of fluecured tobacco stems. It was applied at four levels, 0%, 3%,9%, and 15%(w/w), respectively, to the compound fertilizer. Compared with the control, the leaching loss of soil TN decreased by 8.36%, 6.72%, and 6.45%, and the loss of soil TK decreased by 9.18%, 9.31% and 11.82% in the 3%,9%, and 15% BF treatments, respectively. However, BF had no significant effect on the P leaching due to the low movement of P in the soil profile. In addition, the BF addition increased the immobilization of NH_4^+-N, available P, and available K in the soil profile. These results indicate that addition of BF to a tobacco-planting soil reduced nutrient leaching, and suggest that BF could be an effective method of applying biochar to agriculture fields.展开更多
In order to apply the performance-based seismic design, an engineer must first find out whether the column is expected to fail in shear before or after flexural yielding. According to column failure characteristics an...In order to apply the performance-based seismic design, an engineer must first find out whether the column is expected to fail in shear before or after flexural yielding. According to column failure characteristics and failure mode of reinforced concrete column, the UW-PEER structure performance database was discussed and analyzed. In order to investigate the relevance of failure mode and factors such as longitudinal reinforcement ratio, transverse reinforcement ratio, hoop spacing to depth ratio, aspect ratio, shearing resistance demand to shear capacity ratio and axial load ratio, Fisher's discriminant analysis(FDA) of the above factors was carried out. A discriminant function was developed to identify column failure mode. Results show that three factors, i.e., Vp /Vn, hoop spacing to depth ratio and aspect ratio have important influence on the failure mode. The failure mode has less to do with longitudinal reinforcement ratio, transverse reinforcement ratio and axial load ratio. Through using these three factors and the model proposed, over 85.6% of the original grouped cases were correctly classified. The value of coefficient of Vp /Vn is the largest, which means that discriminant equation is most sensitive to the shearing resistance demand to shear capacity ratio.展开更多
Since most current seismic capacity evaluations of reinforced concrete （RC） frame structures are implemented by either static pushover analysis （PA） or dynamic time history analysis, with diverse settings of the p...Since most current seismic capacity evaluations of reinforced concrete （RC） frame structures are implemented by either static pushover analysis （PA） or dynamic time history analysis, with diverse settings of the plastic hinges （PHs） on such main structural components as columns, beams and walls, the complex behavior of shear failure at beam-column joints （BCJs） during major earthquakes is commonly neglected. This study proposes new nonlinear PA procedures that consider shear failure at BCJs and seek to assess the actual damage to RC structures. Based on the specifications of FEMA-356, a simplified joint model composed of two nonlinear cross struts placed diagonally over the location of the plastic hinge is established, allowing a sophisticated PA to be performed. To verify the validity of this method, the analytical results for the capacity curves and the failure mechanism derived from three different full-size RC frames are compared with the experimental measurements. By considering shear failure at BCJs, the proposed nonlinear analytical procedures can be used to estimate the structural behavior of RC frames, including seismic capacity and the progressive failure sequence of joints, in a precise and effective manner.展开更多
文摘Methacrylate-based monolithic column was prepared in fused-silica capillary (80 ′ 0.32 mm i.d.) by in situ polymerizetion reaction using glycidyl methacrylate as monomer;ethylene dimethacrylate as crosslinker;1-propanol, 1,4-butanediol, and water as porogenic solvents. The monolith matrix was modified with trimethylamine to create strong anion exchanger via ring opening reaction of epoxy groups. The morphology of the monolithic column was studied by using Scanning Electron Microscope (SEM). This column had good mechanical stability and permeability. The effects of various mobile phases for separation of inorganic anions were investigated. Iodate, bromate, nitrite, bromide, and nitrate were separated within 11 min using100 mMpotassium chloride as mobile phase and detected at 210 nm. This method showed good precision of retention time, acceptable linearity and good sensitivity. Under the optimum condition, the RSD of the retention time was in the range of 1.09%-1.75% (n = 6). The calibration curve showed linear relationships between the peak area and the concentration. The limits of detection (LOD) and the limits of quantitation (LOQ) were between 0.08-0.18 mM and 0.26-0.61 mM, respectively. This method was applied to the determination of inorganic anions in tap water and ground water samples.
基金supported by the National Natural Science Foundation of China (Nos. 41773144 U1612441+5 种基金 41503080)the Key Technologies R&D Project in Agriculture of Guizhou province (Nos. NY [2013] 3019 NY [2015] 3001-1)the Major S&T Special Project of Guizhou province (No. [2014] 6015-21)the Opening Fund of the State Key Laboratory of Environmental Geochemistry (SKLEG2018905)Innovative Plan of Guizhou province and the Science and Technology Project of Guizhou Tobacco Company (201614)
文摘Biochar is a soil amendment for increasing soil quality and decreasing nutrient leaching. However, there is little information on the impact of biochar-based fertilizer(BF) on soil nutrient leaching in agricultural soils. We conducted a soil column leaching experiment to study the effects of BF on the leaching of total nitrogen(TN), total phosphorus, and total potassium(TK) in tobacco soils. The distribution characteristics of NH_4^+-N, available P, and available K in soil profiles were analyzed after the application of BF. Biochar was prepared by pyrolysis of fluecured tobacco stems. It was applied at four levels, 0%, 3%,9%, and 15%(w/w), respectively, to the compound fertilizer. Compared with the control, the leaching loss of soil TN decreased by 8.36%, 6.72%, and 6.45%, and the loss of soil TK decreased by 9.18%, 9.31% and 11.82% in the 3%,9%, and 15% BF treatments, respectively. However, BF had no significant effect on the P leaching due to the low movement of P in the soil profile. In addition, the BF addition increased the immobilization of NH_4^+-N, available P, and available K in the soil profile. These results indicate that addition of BF to a tobacco-planting soil reduced nutrient leaching, and suggest that BF could be an effective method of applying biochar to agriculture fields.
基金Project(2011ZA05) supported by the State Key Laboratory’s Autonomous Project of Subtropical Building Science in South China University of Technology
文摘In order to apply the performance-based seismic design, an engineer must first find out whether the column is expected to fail in shear before or after flexural yielding. According to column failure characteristics and failure mode of reinforced concrete column, the UW-PEER structure performance database was discussed and analyzed. In order to investigate the relevance of failure mode and factors such as longitudinal reinforcement ratio, transverse reinforcement ratio, hoop spacing to depth ratio, aspect ratio, shearing resistance demand to shear capacity ratio and axial load ratio, Fisher's discriminant analysis(FDA) of the above factors was carried out. A discriminant function was developed to identify column failure mode. Results show that three factors, i.e., Vp /Vn, hoop spacing to depth ratio and aspect ratio have important influence on the failure mode. The failure mode has less to do with longitudinal reinforcement ratio, transverse reinforcement ratio and axial load ratio. Through using these three factors and the model proposed, over 85.6% of the original grouped cases were correctly classified. The value of coefficient of Vp /Vn is the largest, which means that discriminant equation is most sensitive to the shearing resistance demand to shear capacity ratio.
文摘Since most current seismic capacity evaluations of reinforced concrete （RC） frame structures are implemented by either static pushover analysis （PA） or dynamic time history analysis, with diverse settings of the plastic hinges （PHs） on such main structural components as columns, beams and walls, the complex behavior of shear failure at beam-column joints （BCJs） during major earthquakes is commonly neglected. This study proposes new nonlinear PA procedures that consider shear failure at BCJs and seek to assess the actual damage to RC structures. Based on the specifications of FEMA-356, a simplified joint model composed of two nonlinear cross struts placed diagonally over the location of the plastic hinge is established, allowing a sophisticated PA to be performed. To verify the validity of this method, the analytical results for the capacity curves and the failure mechanism derived from three different full-size RC frames are compared with the experimental measurements. By considering shear failure at BCJs, the proposed nonlinear analytical procedures can be used to estimate the structural behavior of RC frames, including seismic capacity and the progressive failure sequence of joints, in a precise and effective manner.
