The scale effect on shear strength of rock joints is well-documented.However,whether scale effects are negative,positive,or even exist or not is still controversial.Joint roughness significantly influences the shear s...The scale effect on shear strength of rock joints is well-documented.However,whether scale effects are negative,positive,or even exist or not is still controversial.Joint roughness significantly influences the shear strength of rock joints.Compared to the shear tests,using the joint roughness coefficient(JRC)and its roughness parameters offers a more convenient method for describing the scale effect on shear strength.However,it is crucial to understand that the scale effect mechanisms of JRC are distinct from those of shear strength.Therefore,this paper aims to clarify these distinct mechanisms.By digitally extracting roughness parameters from granite samples,it is found that the scale effect of roughness parameters mainly comes from the sampling methods and the geometric characteristics of parameters.Furthermore,a full data sampling method considering heterogeneity is proposed to obtain more representative roughness parameters.To reveal the scale effect mechanisms of shear strength,Gaussian filtering is firstly used to separate the waviness and unevenness components of roughness,facilitating a deeper understanding of the geometric characteristics of roughness.It is suggested that the wavelength of the waviness component can reflect the scale effect on shear strength.Secondly,numerical simulations of ideal artificial joint models are conducted to validate that the wavelength of the waviness component serves as the dividing point between positive and negative scale effects.The mechanical mechanisms of positive and negative scale effects are also interpreted.Finally,these mechanisms successfully elucidate the occurrence patterns of the scale effect on natural joint profiles.展开更多
Although traditional gamma-gamma density(GGD)logging technology is widely utilized,its potential environmental risks have prompted the development of more environmentally friendly neutron-gamma density(NGD)logging tec...Although traditional gamma-gamma density(GGD)logging technology is widely utilized,its potential environmental risks have prompted the development of more environmentally friendly neutron-gamma density(NGD)logging technology.However,NGD measurements are influenced by both neutron and gamma radiations.In the logging environment,variations in the formation composition indicate different elemental compositions,which affect the neutron-gamma reaction cross-sections and gamma generation.Compared to traditional gamma sources such as Cs-137,these changes significantly affect the generation and transport of neutron-induced inelastic gamma rays and hinder accurate measurements.To address this,a novel method is proposed that incorporates the mass attenuation coefficient function to account for the effects of various lithologies and pore contents on gamma-ray attenuation,thereby achieving more accurate density measurements by clarifying the transport processes of inelastic gamma rays with varying energies and spatial distributions in varied logging environments.The proposed method avoids the complex correction of neutron transport and is verified through Monte Carlo simulations for its applicability across various lithologies and pore contents,demonstrating absolute density errors that are less than 0.02 g/cm^(3)in clean formations and indicating good accuracy.This study clarifies the NGD mechanism and provides theoretical guidance for the application of NGD logging methods.Further studies will be conducted on extreme environmental conditions and tool calibration.展开更多
This study was conducted to establish a simple convenient method for calculating crop coefficient, and provide a certain basis for the research of the empirical formula for calculating crop coefficient with plant heig...This study was conducted to establish a simple convenient method for calculating crop coefficient, and provide a certain basis for the research of the empirical formula for calculating crop coefficient with plant height which could be measured conveniently with regional differences, especially for the establishment of accurate irrigation schedule of potato in Yunnan. By the field experiment on potato under the condition of drip irrigation, it was found that the models of plant height with corrected FAO-56-recommended K and measured K were a quartic polynomial and a cubic polynomial, respectively, and the polynomial of potato plant height with measured crop coefficient was simpler with higher degree of fitting; and the differences between the period with the highest change rate of potato plant height and the periods with the greatest FAO-56-recommended K and measured K exhibited a differences of 3 d. In conclusion： In the future study of simple or empirical formula calculation of crop coefficient, plant height should be considered as a main dependent variable in that the calculation result would be closer to the measured crop coefficient with the problem of regional difference existing in the FAO method solved and the formula might be simpler; and the irrigation time of potato should be 3 d earlier than the irrigation time determined according to the corrected FAO-56-recommended crop coefficient, especially in the key water requirement stages of potato.展开更多
Tire slip angle has a great influence on peak values of both logitudinal and lateral adhesion coefficients as well as optimal slip ratios. Regression equations based on the experi- mental data from several countries...Tire slip angle has a great influence on peak values of both logitudinal and lateral adhesion coefficients as well as optimal slip ratios. Regression equations based on the experi- mental data from several countries are given to describe their dependencies. The peak value of longitudiinal adhesion coefficient has a linear relationship with tire slip angle, but peak value of lateral has a complicated relationship; the optimal slip ratio of longitudinal has an exponent function relationship, the optimal slip ratio of lateral almost has nothinng to do with tire slipangle.展开更多
We analyzed the infrared 0R）-near infrared （NIR） 2D correlation spectra of drugs perturbed by temperature. By identification of functional groups by IR spectrum and by the correlation analysis of IR-NIR spectrum, w...We analyzed the infrared 0R）-near infrared （NIR） 2D correlation spectra of drugs perturbed by temperature. By identification of functional groups by IR spectrum and by the correlation analysis of IR-NIR spectrum, we identified the characteristic spectral bands that were closely related to the structure of a drug substance of interest. These characteristic spectral bands were relatively less interfered by other ingredients for analysis by the NIR correlation coefficient method. With these characteristic spectral bands, the accuracy of screening illegally added Sildenafil citrate, Tadalafil and Metforrnin hydrochloride in Chinese patent drugs and healthcare products reached about 90%, which met the requirements of rapid screening.展开更多
The objective of this study was to reconstruct light extinction coefficients （b ext ） according to chemical composition components of particulate matter up to 2.5 μm in size （PM 2.5 ）. PM 2.5 samples were collect...The objective of this study was to reconstruct light extinction coefficients （b ext ） according to chemical composition components of particulate matter up to 2.5 μm in size （PM 2.5 ）. PM 2.5 samples were collected at the monitoring station of the South China of Institute of Environmental Science （SCIES, Guangzhou, China） during January 2010, and the online absorbing and scattering coefficients were obtained using an aethalometer and a nephelometer. The measured values of light absorption coefficient by particle （b ap ） and light scattering coefficient by particle （b sp ） significantly correlated （R 2 0.95） with values of b ap and b sp that were reconstructed using the Interagency Monitoring of Protected Visual Environments （IMPROVE） formula when RH was 70%. The measured b ext had a good correlation （R 2 0.83） with the calculated b ext under ambient RH conditions. The result of source apportionment of b ext showed that ammonium sulfate [（NH 4 ） 2 SO 4 ] was the largest contributor （35.0%） to b ext , followed by ammonium nitrate （NH 4 NO 3 , 22.9%）, organic matter （16.1%）, elemental carbon （11.8%）, sea salt （4.7%）, and nitrogen dioxide （NO 2 , 9.6%）. To improve visibility in Guangzhou, the effective control of secondary particles like sulfates, nitrates, and ammonia should be given more attention in urban environmental management.展开更多
Climate change will have important implications in water shore regions,such as Huang-Huai-Hai（3H） plain,where expected warmer and drier conditions might augment crop water demand.Sensitivity analysis is important in...Climate change will have important implications in water shore regions,such as Huang-Huai-Hai（3H） plain,where expected warmer and drier conditions might augment crop water demand.Sensitivity analysis is important in understanding the relative importance of climatic variables to the variation in reference evapotranspiration（ET 0）.In this study,the 51-yr ET 0 during winter wheat and summer maize growing season were calculated from a data set of daily climate variables in 40 meteorological stations.Sensitivity maps for key climate variables were estimated according to Kriging method and the spatial pattern of sensitivity coefficients for these key variables was plotted.In addition,the slopes of the linear regression lines for sensitivity coefficients were obtained.Results showed that ET 0 during winter wheat growing season accounted for the largest proportion of annual ET 0,due to its long phenological days,while ET 0 was detected to decrease significantly with the magnitude of 0.5 mm yr-1in summer maize growing season.Solar radiation is considered to be the most sensitive and primarily controlling variable for negative trend in ET 0 for summer maize season,and higher sensitive coefficient value of ET 0 to solar radiation and temperature were detected in east part and southwest part of 3H plain respectively.Relative humidity was demonstrated as the most sensitive factor for ET 0 in winter wheat growing season and declining relativity humidity also primarily controlled a negative trend in ET 0,furthermore the sensitivity coefficient to relative humidity increased from west to southeast.The eight sensitivity centrals were all found located in Shandong Province.These ET 0 along with its sensitivity maps under winter wheat-summer maize rotation system can be applied to predict the agricultural water demand and will assist water resources planning and management for this region.展开更多
By means of a logarithm law for the velocity profile, a corrected formula of bed resistance coefficient, which involves many factors such as gradient of still water depth, variation of surface elevation, flow directio...By means of a logarithm law for the velocity profile, a corrected formula of bed resistance coefficient, which involves many factors such as gradient of still water depth, variation of surface elevation, flow direction, and so on, is derived from the 3D governing equations of tidal current by averaging over the whole water depth. Theoretical analysis and application have shown that the 2D plane tidal current numerical model would be more reasonable and could be applied to steep bottom topography when the corrected bed resistance coefficient is used, therefore the results of reproduction simulation and engineering calculation would be more scientific and reasonable.展开更多
In this paper,the formulas of elasto-hydrodynamic traction coefficients of three Chinese aviation lubricating oils,4109,4106 and 4050,were obtained by a great number of elastohydrodynamic traction tests.The nonlinear ...In this paper,the formulas of elasto-hydrodynamic traction coefficients of three Chinese aviation lubricating oils,4109,4106 and 4050,were obtained by a great number of elastohydrodynamic traction tests.The nonlinear dynamics differential equations of high-speed angular contact ball bearing were built on the basis of dynamic theory of rolling bearings and solved by Gear Stiff（GSTIFF） integer algorithm with variable step.The impact of lubricant traction coefficient on cage＇s dynamic characteristics in high-speed angular contact ball bearing was investigated,and Poincare map was used to analyze the impact of three types of aviation lubricating oils on the dynamic response of cage＇s mass center.And then,the period of dynamic response of cage＇s mass center and the slip ratio of cage were used to assess the stability of cage under various working conditions.The results of this paper provide the theoretical basis for the selection and application of aviation lubricating oil.展开更多
3 degrees of freedom(DOF)exterior ballistic computer models are used in fragment studies to calculate individual trajectories of each fragment based on drag coefficient and the projected(presented)area in the directio...3 degrees of freedom(DOF)exterior ballistic computer models are used in fragment studies to calculate individual trajectories of each fragment based on drag coefficient and the projected(presented)area in the direction of velocity of center of mass.The expectation of a randomly distributed projected area is commonly used for fragments that tumble(random rotation)during flight.We forecast a model where the expected drag coefficient is dependent of shape and Mach number.Rotation or tumbling only affects the expected projected area.Models of projected areas during tumbling and rotation are presented.An examination of the data by Mc Cleskey(1988)indicates that the volume of the fragment to the power of2/3 is a better parameter to characterize the drag coefficient of the fragments than the maximum projected area.Hydrocode simulations are used to verify results and to study projected area and drag coefficient of fragments.展开更多
Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The UR...Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The URCS was analyzed based on an acoustic transmission model for the multi-layered structure.The longitudinal velocity in the coatings was calculated from the experimental URCS,and the attenuation coefficient expression was deduced by comparing the experimental and numerical fitting amplitude spectral lines.The longitudinal velocity of as-sprayed Cr2O3 coating is 2 002 m/s,and increases to 2 099 and 2 148 m/s after being irradiated by HIPIB with 1 and 5 shots.Correspondingly,the factor A changes from 0.046 to 0.026 and 0.020 and n from 1.702 to 1.658 and 1.649 in the attenuation coefficient expression of α=Af n.It is observed that the surface morphology of Cr2O3 coatings changes from rough and porous to smooth and uniform with the increase of shot number,which accords with the ultrasonic analyses reasonably.The URCS seems to provide a convenient and nondestructive method to characterize surface modification of the plasma sprayed coatings.展开更多
New descriptors were constructed and structures of some oxygen-containing organic compounds were parameterized. The multiple linear regression（MLR） and partial least squares regression（PLS） methods were employed t...New descriptors were constructed and structures of some oxygen-containing organic compounds were parameterized. The multiple linear regression（MLR） and partial least squares regression（PLS） methods were employed to build two relationship models between the structures and octanol/water partition coefficients（LogP） of the compounds. The modeling correlation coefficients（R） were 0.976 and 0.922, and the ＂leave one out＂ cross validation correlation coefficients（R（CV）） were 0.973 and 0.909, respectively. The results showed that the structural descriptors could well characterize the molecular structures of the compounds; the stability and predictive power of the models were good.展开更多
This letter presents a theoretical model of the normal （head-on） collisions between two soft spheres for predicting the experimental characteristic of the coefficient of restitution dependent on impact velocity. Aft...This letter presents a theoretical model of the normal （head-on） collisions between two soft spheres for predicting the experimental characteristic of the coefficient of restitution dependent on impact velocity. After the contact force law between the contacted spheres during a collision is phenomenologically formulated in terms of the compression or overlap displacement under considera- tion of an elastic-plastic loading and a plastic unloading subprocesses, the coefficient of restitution is gained by the dynamic equation of the contact process once an initial impact velocity is input. It is found that the theoretical predictions of the coefficient of restitution varying with the impact velocity are well in agreement with the existing experimental characteristics which are fitted by the explicit formula.展开更多
BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sin...BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sintering technique. The temperature dependence of resistivity shows that the phase transition of the PTC thermistor ceramic occurs at the Curie temperature, Tc = 155℃, which is higher than that of BaTiO3 （≤ 130 ℃）. Analysis of ac impedance data using complex impedance spectroscopy gives the alternate current （AC） resistance of the PTCR ceramic. By additional use of the complex electric modulus formalism to analyse the same data, the inhomogeneous nature of the ceramic may be unveiled. The impedance spectra reveal that the grain resistance of the BB-BT sample is slightly influenced by the increase of temperature, indicating that the increase in overall resistivity is entirely due to a grain-boundary effect. Based on the dependence of the extent to which the peaks of the imaginary part of electric modulus and impedance are matched on frequency, the conduction mechanism is also discussed for a BB-BT ceramic system.展开更多
In a gas circuit breaker,metal vapor resulting from electrode erosion is injected into the arc plasma.The arc then burns in a mixture of SF;and electrode vapor,which has properties significantly different from those o...In a gas circuit breaker,metal vapor resulting from electrode erosion is injected into the arc plasma.The arc then burns in a mixture of SF;and electrode vapor,which has properties significantly different from those of pure SF;.Thermodynamic properties and transport coefficients of thermal plasmas formed in SF;-copper vapor mixtures change as a function of temperature and pressure.The property that is mostly affected by the presence of copper is electrical conductivity,which is important in magnetohydrodynamic（MHD） analysis.In this study,the transport coefficients of SF;in the presence of 10 percent copper are considered as the basis of MHD simulation.Comparisons are made between the results during arc formation for pure SF;and SF;-Cu mixture in a medium voltage（MV） circuit breaker.According to the transport coefficients influenced by the SF;-Cu mixture,the distribution of the electric potential, temperature,electromagnetic force density and current density of the arc column are presented and discussed.Also,the arc stability and pinch effect near current zero with 3-D simulation are investigated,which is advantageous to improving the efficiency of arc plasma simulation.展开更多
The contact resistance between the armature and rails is an important indicator of the contact characteristics in electromagnetic launches.As the contact resistance depends not only on the contact state but also on th...The contact resistance between the armature and rails is an important indicator of the contact characteristics in electromagnetic launches.As the contact resistance depends not only on the contact state but also on the contact stress and temperature,there are some limitations in analyzing the contact characteristics using only the contact resistance.In this paper,the contact characteristics of the augmented railgun are analyzed by the combination of contact resistance and sliding friction coefficient.Firstly,the theoretical calculation model of the contact resistance and friction coefficient of the augmented electromagnetic railgun is established.Then the contact resistance and friction coefficient are calculated by the measured values of the muzzle voltage,rail current and armature displacement.Finally,the contact characteristics are analyzed according to the features of the waveforms of the contact resistance and the friction coefficient,and the analysis conclusions are verified by experimental rail images.The results showed that:the aluminum melt film gradually formed on the contact surface reduces the contact resistance and the friction coefficient;the wear and erosion of the armature cause deterioration of the contact state;after the transition,the reliability of the sliding contact between the armature and rails decreases,resulting in an increase in contact resistance.展开更多
The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this ...The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this paper,the influence of structural parameters of the turbocharger floating bearing on its dynamic characteristic coefficientsis systematically investigated based on the theories of hydrodynamic lubrication and tribology.The influence of clearance ratio on eccentricity and the influence of internal to external radius ratios,and Sommerfeld number were analyzed.A new formula of responding characteristics of the oil film force caused by the displacement or velocity disturbance was deduced near an equilibrium in the steady state.Applying the newly developed formula,the dynamic characteristic was studied for floating bearings.Regularity for change of oil film stiffness and damping was analyzed with the structural parameters of floating bearing such as radius ratios and eccentricity.It has been found that the clearance ratio increases with eccentricity when the radius ratio is unchanged.The eccentricity decreases with the internal to external radius ratio of floating rings when the clearance ratio is constant.The absolute value of total principal stiffness and total main damping decrease with the clearance ratio and radius ratio of floating rings when the total cross damping is stable.The results and findings in this paper can contribute to nonlinear dynamics designs of turbocharger rotor-bearing systems.展开更多
Exact calculations of the static earth pressure from a thick alluvium require accurate/Co values. These calculations influence the sinking cost and the safety of the freezing method. The static earth pressure coeffici...Exact calculations of the static earth pressure from a thick alluvium require accurate/Co values. These calculations influence the sinking cost and the safety of the freezing method. The static earth pressure coefficient （K0） of thick and deep soil was analyzed using laboratory tests. The results show that the static earth pressure coefficient of thick and deep soils is nonlinear and different from that of superficial soils. The constant of superficial soils is usually invariant and the total stress or incremental stress definitions used in traditional geo-meehanics give the same value. The influence of load increments when calculating for superficial soil is ignored. The difference in values of K0 for thick alluvium defimed by the total stress or the incremental stress methods is over 10%. The effects of the thick alluvium on K0 should be considered during the design of frozen shaft projects. Such things as the frozen shaft thickness and the excavated section height should be chosen to assure the rationality of the design and to avoid potential faults and accidents.展开更多
Interdiffusion coefficients at 950℃ and 1050℃ are calculated by Wagner analysis method as a function of composition of β-NiAI phase. The β-NiAI phase is formed by pack cementation on surface of superalloy. Results...Interdiffusion coefficients at 950℃ and 1050℃ are calculated by Wagner analysis method as a function of composition of β-NiAI phase. The β-NiAI phase is formed by pack cementation on surface of superalloy. Results of the calculation show that interdiffusion coefficients in β-NiAI phase strongly depend on the compositions and vary over several orders of magnitude. Compared with the interdiffusion coefficients in the stoichiometric β-NiAI phase, the interdiffusion coefficients in β-NiAI phase formed on superalloy is obviously small, probably due to the composition, complicated microstructure and precipitates. However, it could be seen clearly that the shapes of the diffusivity curves are very similar to each other. The similarity of the diffusion curves and the difference between interdiffusion coefficients imply that the compositions, microstructures and precipitates of superalloy have a distinctly adverse effect on the interdiffusion of Ni and Al atoms during aluminization, but do not change the essential characteristics of β-NiAI phase.展开更多
基金funded by the National Natural Science Foundation Projects(Grant Nos.41772287 and 42277132)the Key R&D Project of Zhejiang Province(Grant No.2021C03159).
文摘The scale effect on shear strength of rock joints is well-documented.However,whether scale effects are negative,positive,or even exist or not is still controversial.Joint roughness significantly influences the shear strength of rock joints.Compared to the shear tests,using the joint roughness coefficient(JRC)and its roughness parameters offers a more convenient method for describing the scale effect on shear strength.However,it is crucial to understand that the scale effect mechanisms of JRC are distinct from those of shear strength.Therefore,this paper aims to clarify these distinct mechanisms.By digitally extracting roughness parameters from granite samples,it is found that the scale effect of roughness parameters mainly comes from the sampling methods and the geometric characteristics of parameters.Furthermore,a full data sampling method considering heterogeneity is proposed to obtain more representative roughness parameters.To reveal the scale effect mechanisms of shear strength,Gaussian filtering is firstly used to separate the waviness and unevenness components of roughness,facilitating a deeper understanding of the geometric characteristics of roughness.It is suggested that the wavelength of the waviness component can reflect the scale effect on shear strength.Secondly,numerical simulations of ideal artificial joint models are conducted to validate that the wavelength of the waviness component serves as the dividing point between positive and negative scale effects.The mechanical mechanisms of positive and negative scale effects are also interpreted.Finally,these mechanisms successfully elucidate the occurrence patterns of the scale effect on natural joint profiles.
基金supported by the National Natural Science Foundation of China(U23B20151 and 52171253).
文摘Although traditional gamma-gamma density(GGD)logging technology is widely utilized,its potential environmental risks have prompted the development of more environmentally friendly neutron-gamma density(NGD)logging technology.However,NGD measurements are influenced by both neutron and gamma radiations.In the logging environment,variations in the formation composition indicate different elemental compositions,which affect the neutron-gamma reaction cross-sections and gamma generation.Compared to traditional gamma sources such as Cs-137,these changes significantly affect the generation and transport of neutron-induced inelastic gamma rays and hinder accurate measurements.To address this,a novel method is proposed that incorporates the mass attenuation coefficient function to account for the effects of various lithologies and pore contents on gamma-ray attenuation,thereby achieving more accurate density measurements by clarifying the transport processes of inelastic gamma rays with varying energies and spatial distributions in varied logging environments.The proposed method avoids the complex correction of neutron transport and is verified through Monte Carlo simulations for its applicability across various lithologies and pore contents,demonstrating absolute density errors that are less than 0.02 g/cm^(3)in clean formations and indicating good accuracy.This study clarifies the NGD mechanism and provides theoretical guidance for the application of NGD logging methods.Further studies will be conducted on extreme environmental conditions and tool calibration.
基金Supported by the Scientific Research Project of Yunnan Agricultural University(A3007680)the Fund for Scientific Research of Department of Education+1 种基金Yunnan(2014y1902014y193)~~
文摘This study was conducted to establish a simple convenient method for calculating crop coefficient, and provide a certain basis for the research of the empirical formula for calculating crop coefficient with plant height which could be measured conveniently with regional differences, especially for the establishment of accurate irrigation schedule of potato in Yunnan. By the field experiment on potato under the condition of drip irrigation, it was found that the models of plant height with corrected FAO-56-recommended K and measured K were a quartic polynomial and a cubic polynomial, respectively, and the polynomial of potato plant height with measured crop coefficient was simpler with higher degree of fitting; and the differences between the period with the highest change rate of potato plant height and the periods with the greatest FAO-56-recommended K and measured K exhibited a differences of 3 d. In conclusion： In the future study of simple or empirical formula calculation of crop coefficient, plant height should be considered as a main dependent variable in that the calculation result would be closer to the measured crop coefficient with the problem of regional difference existing in the FAO method solved and the formula might be simpler; and the irrigation time of potato should be 3 d earlier than the irrigation time determined according to the corrected FAO-56-recommended crop coefficient, especially in the key water requirement stages of potato.
文摘Tire slip angle has a great influence on peak values of both logitudinal and lateral adhesion coefficients as well as optimal slip ratios. Regression equations based on the experi- mental data from several countries are given to describe their dependencies. The peak value of longitudiinal adhesion coefficient has a linear relationship with tire slip angle, but peak value of lateral has a complicated relationship; the optimal slip ratio of longitudinal has an exponent function relationship, the optimal slip ratio of lateral almost has nothinng to do with tire slipangle.
基金National Key Technology R & D Program-On-site Rapid Identification of Drug Research Project (Grant No. 2008BAI55B06)
文摘We analyzed the infrared 0R）-near infrared （NIR） 2D correlation spectra of drugs perturbed by temperature. By identification of functional groups by IR spectrum and by the correlation analysis of IR-NIR spectrum, we identified the characteristic spectral bands that were closely related to the structure of a drug substance of interest. These characteristic spectral bands were relatively less interfered by other ingredients for analysis by the NIR correlation coefficient method. With these characteristic spectral bands, the accuracy of screening illegally added Sildenafil citrate, Tadalafil and Metforrnin hydrochloride in Chinese patent drugs and healthcare products reached about 90%, which met the requirements of rapid screening.
基金supported by the Special Scientific Research Funds for Environment Protection Commonweal Section (Grant Nos 200809143 and 201009001)Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No IAP09320)
文摘The objective of this study was to reconstruct light extinction coefficients （b ext ） according to chemical composition components of particulate matter up to 2.5 μm in size （PM 2.5 ）. PM 2.5 samples were collected at the monitoring station of the South China of Institute of Environmental Science （SCIES, Guangzhou, China） during January 2010, and the online absorbing and scattering coefficients were obtained using an aethalometer and a nephelometer. The measured values of light absorption coefficient by particle （b ap ） and light scattering coefficient by particle （b sp ） significantly correlated （R 2 0.95） with values of b ap and b sp that were reconstructed using the Interagency Monitoring of Protected Visual Environments （IMPROVE） formula when RH was 70%. The measured b ext had a good correlation （R 2 0.83） with the calculated b ext under ambient RH conditions. The result of source apportionment of b ext showed that ammonium sulfate [（NH 4 ） 2 SO 4 ] was the largest contributor （35.0%） to b ext , followed by ammonium nitrate （NH 4 NO 3 , 22.9%）, organic matter （16.1%）, elemental carbon （11.8%）, sea salt （4.7%）, and nitrogen dioxide （NO 2 , 9.6%）. To improve visibility in Guangzhou, the effective control of secondary particles like sulfates, nitrates, and ammonia should be given more attention in urban environmental management.
基金supported by the Key Technologies R&D Program of China during the 12th Five-Year Plan period(2012BAD09B01)the National 973 Program of China(2012CB955904)the Project of Food Security and Climate Change in the Asia-Pacific Region:Evaluating Mismatch between Crop Development and Water Availability and Project of National Non-profit Institute Fund,China-Australia(BSRF201206)
文摘Climate change will have important implications in water shore regions,such as Huang-Huai-Hai（3H） plain,where expected warmer and drier conditions might augment crop water demand.Sensitivity analysis is important in understanding the relative importance of climatic variables to the variation in reference evapotranspiration（ET 0）.In this study,the 51-yr ET 0 during winter wheat and summer maize growing season were calculated from a data set of daily climate variables in 40 meteorological stations.Sensitivity maps for key climate variables were estimated according to Kriging method and the spatial pattern of sensitivity coefficients for these key variables was plotted.In addition,the slopes of the linear regression lines for sensitivity coefficients were obtained.Results showed that ET 0 during winter wheat growing season accounted for the largest proportion of annual ET 0,due to its long phenological days,while ET 0 was detected to decrease significantly with the magnitude of 0.5 mm yr-1in summer maize growing season.Solar radiation is considered to be the most sensitive and primarily controlling variable for negative trend in ET 0 for summer maize season,and higher sensitive coefficient value of ET 0 to solar radiation and temperature were detected in east part and southwest part of 3H plain respectively.Relative humidity was demonstrated as the most sensitive factor for ET 0 in winter wheat growing season and declining relativity humidity also primarily controlled a negative trend in ET 0,furthermore the sensitivity coefficient to relative humidity increased from west to southeast.The eight sensitivity centrals were all found located in Shandong Province.These ET 0 along with its sensitivity maps under winter wheat-summer maize rotation system can be applied to predict the agricultural water demand and will assist water resources planning and management for this region.
基金National Natural Science Foundation of China(Grant No.49971064)
文摘By means of a logarithm law for the velocity profile, a corrected formula of bed resistance coefficient, which involves many factors such as gradient of still water depth, variation of surface elevation, flow direction, and so on, is derived from the 3D governing equations of tidal current by averaging over the whole water depth. Theoretical analysis and application have shown that the 2D plane tidal current numerical model would be more reasonable and could be applied to steep bottom topography when the corrected bed resistance coefficient is used, therefore the results of reproduction simulation and engineering calculation would be more scientific and reasonable.
基金financially co-supported by the National Natural Science Foundation of China(No.U1404514)Henan Outstanding Person Foundation(No.144200510020) of ChinaCollaborative Innovation Center of Major Machine Manufacturing in Liaoning,China
文摘In this paper,the formulas of elasto-hydrodynamic traction coefficients of three Chinese aviation lubricating oils,4109,4106 and 4050,were obtained by a great number of elastohydrodynamic traction tests.The nonlinear dynamics differential equations of high-speed angular contact ball bearing were built on the basis of dynamic theory of rolling bearings and solved by Gear Stiff（GSTIFF） integer algorithm with variable step.The impact of lubricant traction coefficient on cage＇s dynamic characteristics in high-speed angular contact ball bearing was investigated,and Poincare map was used to analyze the impact of three types of aviation lubricating oils on the dynamic response of cage＇s mass center.And then,the period of dynamic response of cage＇s mass center and the slip ratio of cage were used to assess the stability of cage under various working conditions.The results of this paper provide the theoretical basis for the selection and application of aviation lubricating oil.
文摘3 degrees of freedom(DOF)exterior ballistic computer models are used in fragment studies to calculate individual trajectories of each fragment based on drag coefficient and the projected(presented)area in the direction of velocity of center of mass.The expectation of a randomly distributed projected area is commonly used for fragments that tumble(random rotation)during flight.We forecast a model where the expected drag coefficient is dependent of shape and Mach number.Rotation or tumbling only affects the expected projected area.Models of projected areas during tumbling and rotation are presented.An examination of the data by Mc Cleskey(1988)indicates that the volume of the fragment to the power of2/3 is a better parameter to characterize the drag coefficient of the fragments than the maximum projected area.Hydrocode simulations are used to verify results and to study projected area and drag coefficient of fragments.
基金Project(KM200710015010) supported by the Scientific Research Program of Beijing Municipal Education Commission,China
文摘Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The URCS was analyzed based on an acoustic transmission model for the multi-layered structure.The longitudinal velocity in the coatings was calculated from the experimental URCS,and the attenuation coefficient expression was deduced by comparing the experimental and numerical fitting amplitude spectral lines.The longitudinal velocity of as-sprayed Cr2O3 coating is 2 002 m/s,and increases to 2 099 and 2 148 m/s after being irradiated by HIPIB with 1 and 5 shots.Correspondingly,the factor A changes from 0.046 to 0.026 and 0.020 and n from 1.702 to 1.658 and 1.649 in the attenuation coefficient expression of α=Af n.It is observed that the surface morphology of Cr2O3 coatings changes from rough and porous to smooth and uniform with the increase of shot number,which accords with the ultrasonic analyses reasonably.The URCS seems to provide a convenient and nondestructive method to characterize surface modification of the plasma sprayed coatings.
基金supported by the Youth Foundation of Education Bureau,Sichuan Province(13ZB0003)
文摘New descriptors were constructed and structures of some oxygen-containing organic compounds were parameterized. The multiple linear regression（MLR） and partial least squares regression（PLS） methods were employed to build two relationship models between the structures and octanol/water partition coefficients（LogP） of the compounds. The modeling correlation coefficients（R） were 0.976 and 0.922, and the ＂leave one out＂ cross validation correlation coefficients（R（CV）） were 0.973 and 0.909, respectively. The results showed that the structural descriptors could well characterize the molecular structures of the compounds; the stability and predictive power of the models were good.
基金supported by the Innovation Team Fund of the National Natural Science Foundation of China(11121202)
文摘This letter presents a theoretical model of the normal （head-on） collisions between two soft spheres for predicting the experimental characteristic of the coefficient of restitution dependent on impact velocity. After the contact force law between the contacted spheres during a collision is phenomenologically formulated in terms of the compression or overlap displacement under considera- tion of an elastic-plastic loading and a plastic unloading subprocesses, the coefficient of restitution is gained by the dynamic equation of the contact process once an initial impact velocity is input. It is found that the theoretical predictions of the coefficient of restitution varying with the impact velocity are well in agreement with the existing experimental characteristics which are fitted by the explicit formula.
基金supported by the Research Funds of the Guangxi Key Laboratory of Information Materials at the School of Material Science and Engineering,China (Grant No. 0710908-07-Z)
文摘BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sintering technique. The temperature dependence of resistivity shows that the phase transition of the PTC thermistor ceramic occurs at the Curie temperature, Tc = 155℃, which is higher than that of BaTiO3 （≤ 130 ℃）. Analysis of ac impedance data using complex impedance spectroscopy gives the alternate current （AC） resistance of the PTCR ceramic. By additional use of the complex electric modulus formalism to analyse the same data, the inhomogeneous nature of the ceramic may be unveiled. The impedance spectra reveal that the grain resistance of the BB-BT sample is slightly influenced by the increase of temperature, indicating that the increase in overall resistivity is entirely due to a grain-boundary effect. Based on the dependence of the extent to which the peaks of the imaginary part of electric modulus and impedance are matched on frequency, the conduction mechanism is also discussed for a BB-BT ceramic system.
文摘In a gas circuit breaker,metal vapor resulting from electrode erosion is injected into the arc plasma.The arc then burns in a mixture of SF;and electrode vapor,which has properties significantly different from those of pure SF;.Thermodynamic properties and transport coefficients of thermal plasmas formed in SF;-copper vapor mixtures change as a function of temperature and pressure.The property that is mostly affected by the presence of copper is electrical conductivity,which is important in magnetohydrodynamic（MHD） analysis.In this study,the transport coefficients of SF;in the presence of 10 percent copper are considered as the basis of MHD simulation.Comparisons are made between the results during arc formation for pure SF;and SF;-Cu mixture in a medium voltage（MV） circuit breaker.According to the transport coefficients influenced by the SF;-Cu mixture,the distribution of the electric potential, temperature,electromagnetic force density and current density of the arc column are presented and discussed.Also,the arc stability and pinch effect near current zero with 3-D simulation are investigated,which is advantageous to improving the efficiency of arc plasma simulation.
文摘The contact resistance between the armature and rails is an important indicator of the contact characteristics in electromagnetic launches.As the contact resistance depends not only on the contact state but also on the contact stress and temperature,there are some limitations in analyzing the contact characteristics using only the contact resistance.In this paper,the contact characteristics of the augmented railgun are analyzed by the combination of contact resistance and sliding friction coefficient.Firstly,the theoretical calculation model of the contact resistance and friction coefficient of the augmented electromagnetic railgun is established.Then the contact resistance and friction coefficient are calculated by the measured values of the muzzle voltage,rail current and armature displacement.Finally,the contact characteristics are analyzed according to the features of the waveforms of the contact resistance and the friction coefficient,and the analysis conclusions are verified by experimental rail images.The results showed that:the aluminum melt film gradually formed on the contact surface reduces the contact resistance and the friction coefficient;the wear and erosion of the armature cause deterioration of the contact state;after the transition,the reliability of the sliding contact between the armature and rails decreases,resulting in an increase in contact resistance.
基金Supported by the Natural Science Foundation of Shanxi Province Project(2012011023-2)
文摘The structure parameters in an actual industrial production have a great influence on the coefficient of supercharger floating bearing dynamic characteristics,but there has been little systematic study so far.In this paper,the influence of structural parameters of the turbocharger floating bearing on its dynamic characteristic coefficientsis systematically investigated based on the theories of hydrodynamic lubrication and tribology.The influence of clearance ratio on eccentricity and the influence of internal to external radius ratios,and Sommerfeld number were analyzed.A new formula of responding characteristics of the oil film force caused by the displacement or velocity disturbance was deduced near an equilibrium in the steady state.Applying the newly developed formula,the dynamic characteristic was studied for floating bearings.Regularity for change of oil film stiffness and damping was analyzed with the structural parameters of floating bearing such as radius ratios and eccentricity.It has been found that the clearance ratio increases with eccentricity when the radius ratio is unchanged.The eccentricity decreases with the internal to external radius ratio of floating rings when the clearance ratio is constant.The absolute value of total principal stiffness and total main damping decrease with the clearance ratio and radius ratio of floating rings when the total cross damping is stable.The results and findings in this paper can contribute to nonlinear dynamics designs of turbocharger rotor-bearing systems.
基金Project BK2007040 supported by the Provincial Natural Science Foundation of Jiangsu, China
文摘Exact calculations of the static earth pressure from a thick alluvium require accurate/Co values. These calculations influence the sinking cost and the safety of the freezing method. The static earth pressure coefficient （K0） of thick and deep soil was analyzed using laboratory tests. The results show that the static earth pressure coefficient of thick and deep soils is nonlinear and different from that of superficial soils. The constant of superficial soils is usually invariant and the total stress or incremental stress definitions used in traditional geo-meehanics give the same value. The influence of load increments when calculating for superficial soil is ignored. The difference in values of K0 for thick alluvium defimed by the total stress or the incremental stress methods is over 10%. The effects of the thick alluvium on K0 should be considered during the design of frozen shaft projects. Such things as the frozen shaft thickness and the excavated section height should be chosen to assure the rationality of the design and to avoid potential faults and accidents.
文摘Interdiffusion coefficients at 950℃ and 1050℃ are calculated by Wagner analysis method as a function of composition of β-NiAI phase. The β-NiAI phase is formed by pack cementation on surface of superalloy. Results of the calculation show that interdiffusion coefficients in β-NiAI phase strongly depend on the compositions and vary over several orders of magnitude. Compared with the interdiffusion coefficients in the stoichiometric β-NiAI phase, the interdiffusion coefficients in β-NiAI phase formed on superalloy is obviously small, probably due to the composition, complicated microstructure and precipitates. However, it could be seen clearly that the shapes of the diffusivity curves are very similar to each other. The similarity of the diffusion curves and the difference between interdiffusion coefficients imply that the compositions, microstructures and precipitates of superalloy have a distinctly adverse effect on the interdiffusion of Ni and Al atoms during aluminization, but do not change the essential characteristics of β-NiAI phase.
