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Performance Prediction Based Workload Scheduling in Co-Located Cluster
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作者 Dongyang Ou Yongjian Ren Congfeng Jiang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第5期2043-2067,共25页
Cloud service providers generally co-locate online services and batch jobs onto the same computer cluster,where the resources can be pooled in order to maximize data center resource utilization.Due to resource competi... Cloud service providers generally co-locate online services and batch jobs onto the same computer cluster,where the resources can be pooled in order to maximize data center resource utilization.Due to resource competition between batch jobs and online services,co-location frequently impairs the performance of online services.This study presents a quality of service(QoS)prediction-based schedulingmodel(QPSM)for co-locatedworkloads.The performance prediction of QPSM consists of two parts:the prediction of an online service’s QoS anomaly based on XGBoost and the prediction of the completion time of an offline batch job based on randomforest.On-line service QoS anomaly prediction is used to evaluate the influence of batch jobmix on on-line service performance,and batch job completion time prediction is utilized to reduce the total waiting time of batch jobs.When the same number of batch jobs are scheduled in experiments using typical test sets such as CloudSuite,the scheduling time required by QPSM is reduced by about 6 h on average compared with the first-come,first-served strategy and by about 11 h compared with the random scheduling strategy.Compared with the non-co-located situation,QPSM can improve CPU resource utilization by 12.15% and memory resource utilization by 5.7% on average.Experiments show that the QPSM scheduling strategy proposed in this study can effectively guarantee the quality of online services and further improve cluster resource utilization. 展开更多
关键词 co-located cluster workload scheduling online service batch jobs data center
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Ligand-directed construction of cobalt-oxo cluster-based organic frameworks:Structural modulation,semiconductor,and antiferromagnetic properties
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作者 SHI Jinlian LIU Xiaoru XU Zhongxuan 《无机化学学报》 北大核心 2026年第1期45-54,共10页
Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully construct... Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24. 展开更多
关键词 semi-rigid carboxylic acid ligands three-dimensional framework tetranuclear cobalt-oxo cluster semiconductor material antiferromagnetic magnetism
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Equivalent Modeling with Passive Filter Parameter Clustering for Photovoltaic Power Stations Based on a Particle Swarm Optimization K-Means Algorithm
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作者 Binjiang Hu Yihua Zhu +3 位作者 Liang Tu Zun Ma Xian Meng Kewei Xu 《Energy Engineering》 2026年第1期431-459,共29页
This paper proposes an equivalent modeling method for photovoltaic(PV)power stations via a particle swarm optimization(PSO)K-means clustering(KMC)algorithm with passive filter parameter clustering to address the compl... This paper proposes an equivalent modeling method for photovoltaic(PV)power stations via a particle swarm optimization(PSO)K-means clustering(KMC)algorithm with passive filter parameter clustering to address the complexities,simulation time cost and convergence problems of detailed PV power station models.First,the amplitude–frequency curves of different filter parameters are analyzed.Based on the results,a grouping parameter set for characterizing the external filter characteristics is established.These parameters are further defined as clustering parameters.A single PV inverter model is then established as a prerequisite foundation.The proposed equivalent method combines the global search capability of PSO with the rapid convergence of KMC,effectively overcoming the tendency of KMC to become trapped in local optima.This approach enhances both clustering accuracy and numerical stability when determining equivalence for PV inverter units.Using the proposed clustering method,both a detailed PV power station model and an equivalent model are developed and compared.Simulation and hardwarein-loop(HIL)results based on the equivalent model verify that the equivalent method accurately represents the dynamic characteristics of PVpower stations and adapts well to different operating conditions.The proposed equivalent modeling method provides an effective analysis tool for future renewable energy integration research. 展开更多
关键词 Photovoltaic power station multi-machine equivalentmodeling particle swarmoptimization K-means clustering algorithm
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Cu cluster@UiO-66团簇负载型催化剂促进光催化CO_(2)加氢反应 被引量:2
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作者 王秀林 岐少鹏 +6 位作者 周昆 邓希 姚辉超 戴若云 张雨晴 伍思达 聂锁府 《分子催化(中英文)》 北大核心 2025年第2期111-119,I0001,共10页
针对高活性Cu基团簇(Cu cluster)催化剂的稳定性问题,利用MOFs材料独特的结构限域作用,将Cu团簇锚定在UiO-66中,构建了Cu cluster@UiO-66复合材料,改善了催化剂的稳定性和催化活性.在该复合结构中,UiO-66不仅可作为吸光单元捕获太阳光... 针对高活性Cu基团簇(Cu cluster)催化剂的稳定性问题,利用MOFs材料独特的结构限域作用,将Cu团簇锚定在UiO-66中,构建了Cu cluster@UiO-66复合材料,改善了催化剂的稳定性和催化活性.在该复合结构中,UiO-66不仅可作为吸光单元捕获太阳光形成光生载流子,而且UiO-66的多孔结构可以有效稳定Cu团簇,保证其微观尺度上的高度分散和结构稳定.研究发现,在光催化反应过程中,UiO-66的光生电子可快速转移至Cu团簇,进而以Cu团簇作为催化活性位点驱动CO_(2)还原反应.得益于复合材料中高效的电荷转移和稳定的团簇活性位点结构,光催化CO_(2)加氢反应活性明显增强.本研究为合成MOFs负载型团簇材料提供了新的思路. 展开更多
关键词 复合结构 UiO-66 铜纳米簇 光催化CO_(2)还原
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Research on D2D Co-localization Algorithm Based on Clustering Filtering 被引量:1
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作者 Jiawen Zhang Fuxing Yang +2 位作者 Zhongliang Deng Xiao Fu Jiazhi Han 《China Communications》 SCIE CSCD 2020年第8期121-132,共12页
Nowadays, most positioning systems carry out locational calculation based on the accurate location information of some devices in the network. However there is a deviation in the locational information of the part of ... Nowadays, most positioning systems carry out locational calculation based on the accurate location information of some devices in the network. However there is a deviation in the locational information of the part of the device, we need to reduce it in order to obtain higher positioning accuracy. In this paper, we proposed a new centralized D2D(Device-to-Device) co-location algorithm. This algorithm uses DBSACN(Density-Based Spatial Clustering of Applications with Noise) clustering to reduce the deviation of device location information. Numerical results show that the positioning accuracy of the centralized D2D co-localization algorithm is improved by 62.7% compared with the SPAWN algorithm, which positioning performance superior to the traditional co-localization algorithm. 展开更多
关键词 co-locATION D2D clusterING DBSACN
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Three co-located resistance genes confer resistance to leaf rust and stripe rust in wheat variety Borlaug 100 被引量:3
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作者 Bowei Ye Ravi P.Singh +6 位作者 Chan Yuan Demei Liu Mandeep S.Randhawa Julio Huerta-Espino Sridhar Bhavani Evans Lagudah Caixia Lan 《The Crop Journal》 SCIE CSCD 2022年第2期490-497,共8页
Leaf rust(LR) and stripe rust(YR) are important diseases in wheat producing areas worldwide and cause severe yield losses under favorable environmental conditions when susceptible varieties are grown. We determined th... Leaf rust(LR) and stripe rust(YR) are important diseases in wheat producing areas worldwide and cause severe yield losses under favorable environmental conditions when susceptible varieties are grown. We determined the genetic basis of resistance to LR and YR in variety Borlaug 100 by developing and phenotyping a population of 198 F6 recombinant inbred lines derived from a cross with the susceptible parent Apav#1. LR and YR phenotyping were conducted for 4 and 3 seasons, respectively, at CIMMYT research stations in Mexico under artificial epidemics. Mendelian segregation analyses indicated that 3–5 LR and 2 YR genes conferred resistance in Borlaug 100. Lr46/Yr29(1 BL), Yr17(2 AS) and Yr30(3 BS) were present in the resistant parent and segregated in the RIL population based on characterization by molecular markers linked to these genes. When present alone, Lr46/Yr29 caused average 13% and 16% reductions in LR and YR severities, respectively, in RILs. Similarly, Yr17 and Yr30 reduced YR severities by 57% and 11%, respectively. The Yr30 and the Yr17 translocation were also associated with 27% and 14% reductions, respectively, in LR severity, indicating that the 3 BS and 2 AS chromosomal regions likely carry new slow rusting LR resistance genes, temporarily designated as Lr B1 and Lr B2, respectively. Additive effects of Yr30*Yr17, Yr29*Yr17 and Yr29*Yr30 on YR and LR were significant and reduced YR severities by 56%,55%, and 45%, respectively, and LR severities by 34%, 40%, and 45%, respectively. Furthermore, interaction between the three genes was also significant, with mean reductions of 70% for YR and 54% for LR severities. Borlaug 100, or any one of the 21 lines with variable agronomic traits but carrying all three colocated resistance loci, can be used as resistance sources in wheat breeding programs. 展开更多
关键词 co-located resistance loci Common wheat Gene interaction Puccinia triticina Puccinia striiformis Triticum aestivum
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Adaptive resource management for multi-target tracking in co-located MIMO radar based on time-space joint allocation 被引量:2
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作者 SU Yang CHENG Ting +2 位作者 HE Zishu LI Xi LU Yanxi 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2020年第5期916-927,共12页
Compared with the traditional phased array radar, the co-located multiple-input multiple-output(MIMO) radar is able to transmit orthogonal waveforms to form different illuminating modes, providing a larger freedom deg... Compared with the traditional phased array radar, the co-located multiple-input multiple-output(MIMO) radar is able to transmit orthogonal waveforms to form different illuminating modes, providing a larger freedom degree in radar resource management. In order to implement the effective resource management for the co-located MIMO radar in multi-target tracking,this paper proposes a resource management optimization model,where the system resource consumption and the tracking accuracy requirements are considered comprehensively. An adaptive resource management algorithm for the co-located MIMO radar is obtained based on the proposed model, where the sub-array number, sampling period, transmitting energy, beam direction and working mode are adaptively controlled to realize the time-space resource joint allocation. Simulation results demonstrate the superiority of the proposed algorithm. Furthermore, the co-located MIMO radar using the proposed algorithm can satisfy the predetermined tracking accuracy requirements with less comprehensive cost compared with the phased array radar. 展开更多
关键词 co-located multiple-input multiple-output(MIMO)radar adaptive resource management multi-target tracking sub-array division time-space joint allocation
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Mathematical model for computing precise local tie vectors for CMONOC co-located GNSS/VLBI/SLR stations 被引量:1
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作者 Shen Yunzhong You Xinzhao +4 位作者 Wang Jiexian Wu Bin Chen Junping Ma Xiaping Gong Xiuqiang 《Geodesy and Geodynamics》 2015年第1期1-6,共6页
The seven co-located sites of the Crustal Movement Observation Network of China(CMONOC) in Shanghai, Wuhan, Kunming, Beijing, Xi'an, Changchun, and Urumqi are equipped with Global Navigation Satellite System(GNSS... The seven co-located sites of the Crustal Movement Observation Network of China(CMONOC) in Shanghai, Wuhan, Kunming, Beijing, Xi'an, Changchun, and Urumqi are equipped with Global Navigation Satellite System(GNSS), very long baseline interferometry(VLBI), and satellite laser ranging(SLR) equipment. Co-location surveying of these sites was performed in 2012 and the accuracies of the solved tie vectors are approximately 5 mm.This paper proposes a mathematical model that handles the least squares adjustment of the 3D control network and calculates the tie vectors in one step, using all the available constraints in the adjustment. Using the new mathematical model, local tie vectors can be more precisely determined and their covariance more reasonably estimated. 展开更多
关键词 co-located site Tie vector(TV) Reference point Global Navigation satellite system(GNSS) Very long baseline interferometry(VLBI)
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Virtual fire drill system supporting co-located collaboration 被引量:1
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作者 Yuan WEI Dongdong GUAN +5 位作者 Qiuchen WANG Xiangxian LI Yulong BIAN Pu QIN Yanning XU Chenglei YANG 《Virtual Reality & Intelligent Hardware》 2019年第3期290-302,共13页
Background Due to the restriction of display mode,in most of the virtual reality systems with multiple people in the same physical space,the program renders the scene based on the position and perspective of the one u... Background Due to the restriction of display mode,in most of the virtual reality systems with multiple people in the same physical space,the program renders the scene based on the position and perspective of the one user,so that other users just see the same scene,resulting in vision disorder.Methods To improve experience of multi-user co-located collaboration,in this study,we propose a fire drill system supporting co-located collaboration,in which three co-located users can collaborate to complete the virtual firefighting mission.Firstly,with multi-view stereoscopic projective display technology and ultra wideband(UWB)technology,co-located users can roam independently and watch virtual scenes through the correct perspective view based on their own position by wearing dedicated shutter glasses,thus carrying out different virtual tasks,which improves the flexibility of co-located collaboration.Secondly,we design simulated firefighting water-gun using the micro-electromechanical system sensor,through which users can interact with virtual environment,and thus provide a better interactive experience.Finally,we develop a workbench including a holographic display module and multi touch operation module for virtual scene assembly and virtual environment control.Results The controller can use the workbench to adjust the virtual layout in real time,and control the virtual task process to increase the flexibility and playability of system.Conclusions Our work can be employed in a wide range of related virtual reality applications. 展开更多
关键词 Virtual reality co-located collaboration Multi-view display Ultra wideband Simulated firefighting water-gun
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基于Context量化和空间co-location模式的熵编码在基因组压缩中的应用
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作者 陈慧 王丽珍 《中国科技信息》 2025年第13期135-137,共3页
1背景随着大数据和云计算等信息处理技术日趋应用广泛,熵编码日益普遍,它是以信息的概率分布特性作为编码的依据,是一种无失真的信源压缩和一种无损的压缩编码。然而在实际应用中,这些条件概率分布事先并不知道,需要通过估计得到。对条... 1背景随着大数据和云计算等信息处理技术日趋应用广泛,熵编码日益普遍,它是以信息的概率分布特性作为编码的依据,是一种无失真的信源压缩和一种无损的压缩编码。然而在实际应用中,这些条件概率分布事先并不知道,需要通过估计得到。对条件概率分布进行估计的过程称为Context建模。已有一些现成的基因组序列压缩工具可供使用,但这些工具并不针对特定基因组序列。因此,基于Context建模熵编码技术的生物基因组序列研究仍具有重要的理论意义。 展开更多
关键词 Context建模 空间co-location模式 熵编码 基因组压缩
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Multi-View Picture Fuzzy Clustering:A Novel Method for Partitioning Multi-View Relational Data 被引量:1
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作者 Pham Huy Thong Hoang Thi Canh +2 位作者 Luong Thi Hong Lan Nguyen Tuan Huy Nguyen Long Giang 《Computers, Materials & Continua》 2025年第6期5461-5485,共25页
Multi-view clustering is a critical research area in computer science aimed at effectively extracting meaningful patterns from complex,high-dimensional data that single-view methods cannot capture.Traditional fuzzy cl... Multi-view clustering is a critical research area in computer science aimed at effectively extracting meaningful patterns from complex,high-dimensional data that single-view methods cannot capture.Traditional fuzzy clustering techniques,such as Fuzzy C-Means(FCM),face significant challenges in handling uncertainty and the dependencies between different views.To overcome these limitations,we introduce a new multi-view fuzzy clustering approach that integrates picture fuzzy sets with a dual-anchor graph method for multi-view data,aiming to enhance clustering accuracy and robustness,termed Multi-view Picture Fuzzy Clustering(MPFC).In particular,the picture fuzzy set theory extends the capability to represent uncertainty by modeling three membership levels:membership degrees,neutral degrees,and refusal degrees.This allows for a more flexible representation of uncertain and conflicting data than traditional fuzzy models.Meanwhile,dual-anchor graphs exploit the similarity relationships between data points and integrate information across views.This combination improves stability,scalability,and robustness when handling noisy and heterogeneous data.Experimental results on several benchmark datasets demonstrate significant improvements in clustering accuracy and efficiency,outperforming traditional methods.Specifically,the MPFC algorithm demonstrates outstanding clustering performance on a variety of datasets,attaining a Purity(PUR)score of 0.6440 and an Accuracy(ACC)score of 0.6213 for the 3 Sources dataset,underscoring its robustness and efficiency.The proposed approach significantly contributes to fields such as pattern recognition,multi-view relational data analysis,and large-scale clustering problems.Future work will focus on extending the method for semi-supervised multi-view clustering,aiming to enhance adaptability,scalability,and performance in real-world applications. 展开更多
关键词 Multi-view clustering picture fuzzy sets dual anchor graph fuzzy clustering multi-view relational data
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FedCPS:A Dual Optimization Model for Federated Learning Based on Clustering and Personalization Strategy 被引量:1
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作者 Zhen Yang Yifan Liu +2 位作者 Fan Feng Yi Liu Zhenpeng Liu 《Computers, Materials & Continua》 2025年第4期357-380,共24页
Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients a... Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients and the server.However,the presence of data heterogeneity can lead to inefficient model training and even reduce the final model’s accuracy and generalization capability.Meanwhile,data scarcity can result in suboptimal cluster distributions for few-shot clients in centralized clustering tasks,and standalone personalization tasks may cause severe overfitting issues.To address these limitations,we introduce a federated learning dual optimization model based on clustering and personalization strategy(FedCPS).FedCPS adopts a decentralized approach,where clients identify their cluster membership locally without relying on a centralized clustering algorithm.Building on this,FedCPS introduces personalized training tasks locally,adding a regularization term to control deviations between local and cluster models.This improves the generalization ability of the final model while mitigating overfitting.The use of weight-sharing techniques also reduces the computational cost of central machines.Experimental results on MNIST,FMNIST,CIFAR10,and CIFAR100 datasets demonstrate that our method achieves better personalization effects compared to other personalized federated learning methods,with an average test accuracy improvement of 0.81%–2.96%.Meanwhile,we adjusted the proportion of few-shot clients to evaluate the impact on accuracy across different methods.The experiments show that FedCPS reduces accuracy by only 0.2%–3.7%,compared to 2.1%–10%for existing methods.Our method demonstrates its advantages across diverse data environments. 展开更多
关键词 Federated learning cluster PERSONALIZATION OVERFITTING
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A novel method for clustering cellular data to improve classification
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作者 Diek W.Wheeler Giorgio A.Ascoli 《Neural Regeneration Research》 SCIE CAS 2025年第9期2697-2705,共9页
Many fields,such as neuroscience,are experiencing the vast prolife ration of cellular data,underscoring the need fo r organizing and interpreting large datasets.A popular approach partitions data into manageable subse... Many fields,such as neuroscience,are experiencing the vast prolife ration of cellular data,underscoring the need fo r organizing and interpreting large datasets.A popular approach partitions data into manageable subsets via hierarchical clustering,but objective methods to determine the appropriate classification granularity are missing.We recently introduced a technique to systematically identify when to stop subdividing clusters based on the fundamental principle that cells must differ more between than within clusters.Here we present the corresponding protocol to classify cellular datasets by combining datadriven unsupervised hierarchical clustering with statistical testing.These general-purpose functions are applicable to any cellular dataset that can be organized as two-dimensional matrices of numerical values,including molecula r,physiological,and anatomical datasets.We demonstrate the protocol using cellular data from the Janelia MouseLight project to chara cterize morphological aspects of neurons. 展开更多
关键词 cellular data clustering dendrogram data classification Levene's one-tailed statistical test unsupervised hierarchical clustering
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Mechanistic insights into cluster strengthening and grain refinement toughening in fully oxidized AgMgNi alloys 被引量:1
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作者 Haicheng Zhu Bingrui Liu +9 位作者 Shaohong Liu Limin Zhou Hao Cui Manmen Liu Li Chen Ming Wen Haigang Dong Feng Liu Song Li Liang Zuo 《Journal of Materials Science & Technology》 2025年第20期252-263,共12页
The pursuit of Ag-based alloys with both high strength and toughness has posed a longstanding chal-lenge.In this study,we investigated the cluster strengthening and grain refinement toughening mecha-nisms in fully oxi... The pursuit of Ag-based alloys with both high strength and toughness has posed a longstanding chal-lenge.In this study,we investigated the cluster strengthening and grain refinement toughening mecha-nisms in fully oxidized AgMgNi alloys,which were internally oxidized at 800℃ for 8 h under an oxy-gen atmosphere.We found that Mg-O clusters contributed to the hardening(138 HV)and strengthening(376.9 MPa)of the AgMg alloy through solid solution strengthening effects,albeit at the expense of duc-tility.To address this limitation,we introduced Ni nanoparticles into the AgMg alloy,resulting in signifi-cant grain refinement within its microstructure.Specifically,the grain size decreased from 67.2μm in the oxidized AgMg alloy to below 6.0μm in the oxidized AgMgNi alloy containing 0.3 wt%Ni.Consequently,the toughness increased significantly,rising from toughness value of 2177.9 MJ m^(-3) in the oxidized AgMg alloy to 6186.1 MJ m^(-3) in the oxidized AgMgNi alloy,representing a remarkable 2.8-fold enhancement.Furthermore,the internally oxidized AgMgNi alloy attained a strength of up to 387.6 MPa,comparable to that of the internally oxidized AgMg alloy,thereby demonstrating the successful realization of concurrent strengthening and toughening.These results collectively offer a novel approach for the design of high-performance alloys through the synergistic combination of cluster strengthening and grain refinement toughening. 展开更多
关键词 Ag-based alloys Mg-O cluster Grain refining Internal oxidation HARDENING
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Heteronuclear lanthanide titanium-oxygen cluster luminescence thermometer with adjustable operating range and sensitivity 被引量:1
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作者 Ting-Ting Li Jin-Zhe Liu +8 位作者 Shao-Jiang Zheng Feng Jiang Jin-Yu Liu Wei-Nan Dong Yu Zhang Shao-Ping Zheng Ya-Nan Li Zhen-Nan Wu Xue Bai 《Rare Metals》 2025年第4期2438-2449,共12页
Given customizable crystal structure and intriguing optical properties,lanthanide titanium-oxygen clusters(LTOCs)with atomic-level accuracy have gained a lot of interest.In this study,we prepared[Ln_(9)Ti_(2)(μ4-O)(... Given customizable crystal structure and intriguing optical properties,lanthanide titanium-oxygen clusters(LTOCs)with atomic-level accuracy have gained a lot of interest.In this study,we prepared[Ln_(9)Ti_(2)(μ4-O)(μ3-OH)_(14)(acac)_(17)(CH_(3)O)_(2)(CH_(3)OH)_(3)](Ln=Tb_(x)Eu_(9−x)(x=0,4,6,7,8,9),Hacac=acetylacetone),Tb^(3+)and Eu^(3+)co-doped LTOCs,to modify the optical properties for the luminescence thermometer.In detail,the serial LTOCs display dual characteristic emission peaks of ^(5)D_(4)→^(7)F_(5) for Tb^(3+)and^(5)D_(0)→^(7)F_(2) for Eu^(3+)at 548 and 616 nm,respectively,under 330 nm excitation.Effective energy transfer(ET)between Tb^(3+)ions and Eu^(3+)ions was revealed in terms of both emission spectra and luminescence lifetime.The ^(5)D_(0)→^(7)F_(2) emission intensity of Eu^(3+)ions at 616 nm is maximally enhanced(by a factor of 11.2)with a change in the relative molar ratio of Tb^(3+)to Eu^(3+),along with a change in the ET efficiency of Tb^(3+)→Eu^(3+).In addition,the luminescent color changes from red,orange,yellow,to green.This precise control of the ET process between rare-earth ions allows{Tb_(6)Eu_(3)Ti_(2)}to reach a maximum relative sensitivity of 1.241 K^(−1) at 355 K,which is an enhancement of up to 4.6-fold with respect to the previously reported homonuclear emission,holding great potential in the optical thermometers. 展开更多
关键词 Lanthanide titanium-oxygen clusters Energy transfer Color-changing luminescence Optical thermometer
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Exploring core symptoms and symptom clusters among patients with neuromyelitis optica spectrum disorder: A network analysis 被引量:1
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作者 Hao Liang Jiehan Chen +4 位作者 Lixin Wang Zhuyun Liu Haoyou Xu Min Zhao Xiaopei Zhang 《International Journal of Nursing Sciences》 2025年第2期152-160,共9页
Objectives To identify core symptoms and symptom clusters in patients with neuromyelitis optica spectrum disorder(NMOSD)by network analysis.Methods From October 10 to 30,2023,140 patients with NMOSD were selected to p... Objectives To identify core symptoms and symptom clusters in patients with neuromyelitis optica spectrum disorder(NMOSD)by network analysis.Methods From October 10 to 30,2023,140 patients with NMOSD were selected to participate in this online questionnaire survey.The survey tools included a general information questionnaire and a self-made NMOSD symptoms scale,which included the prevalence,severity,and distress of 29 symptoms.Cluster analysis was used to identify symptom clusters,and network analysis was used to analyze the symptom network and node characteristics and central indicators including strength centrality(r_(s)),closeness centrality(r_(c))and betweeness centrality(r_(b))were used to identify core symptoms and symptom clusters.Results The most common symptom was pain(65.7%),followed by paraesthesia(65.0%),fatigue(65.0%),easy awakening(63.6%).Regarding the burden level of symptoms,pain was the most burdensome symptom,followed by paraesthesia,easy awakening,fatigue,and difficulty falling asleep.Six clusters were identified:somatosensory,motor,visual,and memory symptom clusters,bladder and rectum symptom clusters,sleep symptoms clusters,and neuropsychological symptom clusters.Fatigue(r_(s)=12.39,r_(b)=68.00,r_(c)=0.02)was the most central and prominent bridge symptom,and motor symptom cluster(r_(s)=2.68,r_(c)=0.10)was the most central symptom cluster among the six clusters.Conclusions Our study demonstrated the necessity of symptom management targeting fatigue,pain,and motor symptom cluster in patients with NMOSD. 展开更多
关键词 Neuromyelitis optica spectrum disorder Network analysis SYMPTOM Symptom clusters NURSING
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Technical progress and application of global carbon dioxide capture,utilization and storage cluster 被引量:1
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作者 WANG Guofeng LYU Weifeng +4 位作者 CUI Kai JI Zemin WANG Heng HE Chang HE Chunyu 《Petroleum Exploration and Development》 2025年第2期536-547,共12页
By systematically reviewing the development status of global carbon dioxide capture,utilization and storage(CCUS)cluster,and comparing domestic and international CCUS industrial models and successful experiences,this ... By systematically reviewing the development status of global carbon dioxide capture,utilization and storage(CCUS)cluster,and comparing domestic and international CCUS industrial models and successful experiences,this study explores the challenges and strategies for the scaled development of the CCUS industry of China.Globally,the CCUS industry has entered a phase of scaled and clustered development.North America has established a system of key technologies in large-scale CO_(2) capture,long-distance pipeline transmission,pipeline network optimization,and large-scale CO_(2) flooding for enhanced oil recovery(CO_(2)-EOR),with relatively mature cluster development and a gradual shift in industrial model from CO_(2)-EOR to geological storage.The CCUS industry of China has developed rapidly across all segments but remains in the early stage of cluster development,facing challenges such as absent business model,insufficient policy support,and technological gaps in core areas.China needs to improve the policy support system to boost enterprises participation across the entire industrial chain,strengthen top-level design and medium-to long-term planning to accelerate demonstration projects construction for whole-process CCUS clusters,advance for a full-chain technological system,including low-cost capture,pipeline optimization and EOR/storage integration technologies,and strengthen personnel training,strengthen discipline construction and university-enterprise research cooperation. 展开更多
关键词 CCUS industrial cluster business model policy guarantee entire industrial chain technology running cost
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Boron cluster-based TADF emitter via through-space charge transfer enabling efficient orange-red electroluminescence 被引量:1
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作者 Xiao Yu Dongyue Cui +8 位作者 Mengmeng Wang Zhaojin Wang Mengzhu Wang Deshuang Tu Vladimir Bregadze Changsheng Lu Qiang Zhao Runfeng Chen Hong Yan 《Chinese Chemical Letters》 2025年第3期232-238,共7页
Thermally activated delayed fluorescence(TADF)materials driven by a through-space charge transfer(TSCT)mechanism have garnered wide interest.However,access of TSCT-TADF molecules with longwavelength emission remains a... Thermally activated delayed fluorescence(TADF)materials driven by a through-space charge transfer(TSCT)mechanism have garnered wide interest.However,access of TSCT-TADF molecules with longwavelength emission remains a formidable challenge.In this study,we introduce a novel V-type DA-D-A’emitter,Trz-mCzCbCz,by using a carborane scaffold.This design strategically incorporates carbazole(Cz)and 2,4,6-triphenyl-1,3,5-triazine(Trz)as donor and acceptor moieties,respectively.Theoretical calculations alongside experimental validations affirm the typical TSCT-TADF characteristics of this luminogen.Owing to the unique structural and electronic attributes of carboranes,Trz-mCzCbCz exhibits an orange-red emission,markedly diverging from the traditional blue-to-green emissions observed in classical Cz and Trz-based TADF molecules.Moreover,bright emission in aggregates was observed for Trz-mCzCbCz with absolute photoluminescence quantum yield(PLQY)of up to 88.8%.As such,we have successfully fabricated five organic light-emitting diodes(OLEDs)by utilizing Trz-mCzCbCz as the emitting layer.It is important to note that both the reverse intersystem crossing process and the TADF properties are profoundly influenced by host materials.The fabricated OLED devices reached a maximum external quantum efficiency(EQE)of 12.7%,with an emission peak at 592 nm.This represents the highest recorded efficiency for TSCT-TADF OLEDs employing carborane derivatives as emitting layers. 展开更多
关键词 Thermally activated delayed fluorescence Through-space charge transfer CARBORANE Boron clusters Organic light-emitting diodes
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Clustering optimization strategy for cooperative positioning system aided by UAV 被引量:1
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作者 Hongbo ZHAO Zeqi YIN Shan HU 《Chinese Journal of Aeronautics》 2025年第9期421-435,共15页
For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Veh... For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Vehicles(SRVs)into CP networks,which is called SRV-aided CP.However,the CP system may split into several sub-clusters that cannot be connected with each other in dense urban environments,in which the sub-clusters with few SRVs will suffer from degradation of CP performance.Since Unmanned Aerial Vehicles(UAVs)have been widely used to aid vehicular communications,we intend to utilize UAVs to assist sub-clusters in CP.In this paper,a UAV-aided CP network is constructed to fully utilize information from SRVs.First,the inter-node connection structure among the UAV and vehicles is designed to share available information from SRVs.After that,the clustering optimization strategy is proposed,in which the UAV cooperates with the high-precision sub-cluster to obtain available information from SRVs,and then broadcasts this positioning-related information to other low-precision sub-clusters.Finally,the Locally-Centralized Factor Graph Optimization(LC-FGO)algorithm is designed to fuse positioning information from cooperators.Simulation results indicate that the positioning accuracy of the CP system could be improved by fully utilizing positioning-related information from SRVs. 展开更多
关键词 clustering optimization Cooperative positioning Locally-centralized FGO Networking wireless sensors Unmanned aerial vehicles Urban degradation environments
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Historical Lesson: Environmental and Human Impacts of Cluster Bomb Use by the United States during the Second Indochina War
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作者 Kenneth R. Olson 《Open Journal of Soil Science》 2025年第1期1-21,共21页
The legacy of United States cluster munition use in Laos and Cambodia during the Second Indochina War is residual bomblets that unexpectedly detonate years later, killing and injuring children, farmers, and other civi... The legacy of United States cluster munition use in Laos and Cambodia during the Second Indochina War is residual bomblets that unexpectedly detonate years later, killing and injuring children, farmers, and other civilians. Cluster munitions release dozens of smaller bomblets that rain deadly ammunition on troops, armored tanks, and vegetation, effectively striking broad sections of war zone landscapes in one launch. While many bomblets detonate immediately, others fail to detonate and can lie dormant on the ground for years. The primary objectives of this study were to document the long-term consequences and impacts of the US Air Force bombing of Laos and Cambodia during the Second Indochina War (1959 to 1973). The historical lessons learned by United States should be shared with Russia and Ukraine governments and military. These countries need to discontinue the use of cluster bombs to prevent additional people living along the Russia-Ukraine border from having to live and die with the consequences of unexploded ordnance, including cluster bombs, for the next century. 展开更多
关键词 cluster Munitions ORDNANCE BOMBS Laos cluster Bomblets US Air Force Air America UXO
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