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Research on Reactivities of Mo Cluster. A Selective Substitution Reaction of the Bridging (dtp) Ligand and Structure of Tetranuclear Molybdenum Cluster Compound [Mo_4S_4(μ-O_2CC_6H_5)_2(dtp)_4]
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作者 庄鸿辉 吴鼎铭 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1995年第4期245-249,共5页
The cluster compound [Mo4S4 (μ-O2CC6H5)2(dtp)4] (dtp = S2P (OEt)2)was obtained by the ligand substitution reaction of tetranuclear molybdenum cluster [Mo4S4(μ-dtp)2(dtp)4] in the mixed solvent of acetone, ethanol an... The cluster compound [Mo4S4 (μ-O2CC6H5)2(dtp)4] (dtp = S2P (OEt)2)was obtained by the ligand substitution reaction of tetranuclear molybdenum cluster [Mo4S4(μ-dtp)2(dtp)4] in the mixed solvent of acetone, ethanol and water in the presence of C6H5CO2Na. It is monoclinic and crystallizesin space group C2/c, Mr =1495. 09, a=12. 175 (5) , b=22. 01 (1) , c=20.875(9) ,β=99. 04(4)°; V=5570(5) ; Z=4; Dc= 1. 78g/cm3;μ(MoKα) = 14. 52 cm-1; F(000) =2984. Final R factor is 0. 066. The result reveals that the [Mo4S4] cluster core and t-(dtp)1ligands are retained and onlyμ-bridged (dtp)1- ligands are substituted by (C6H5CO2)1in the substitution reaction, thus producing the title cluster compound,the structure of which contains two species of bidentate ligand. 展开更多
关键词 substitution reaction Mo cluster crystal structure
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Interscale analysis of sediment clusters amid turbulence 被引量:1
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作者 Wai Hong Ronald Chan Ahmed Elnahhas +3 位作者 Hanul Hwang Lucy J.Brown Andrew J.Banko S.Balachandar 《Acta Mechanica Sinica》 2026年第1期73-80,共8页
Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections... Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections to the classical turbulent energy cascade and its mass cascade counterpart running in parallel.In particular,the formation and dynamics of sediment and larvae clusters are of interest to coral larvae settlement in coastal regions and particularly the resilience of green-gray coastal protection solutions.Analogous cluster behavior is relevant to cloud microphysics and precipitation initiation,radiation transport and light transmission through colloids and suspensions,heat and mass transfer in particle-laden flows,and viral and pollutant transmission.Following a comparison between various clustering techniques,we adopt a density-based cluster identification algorithm based on its simplicity and efficiency,where particles are clustered based on the number of neighboring particles in their individual spheres of influence.We establish parallels with lattice-based percolation theory,as evident in the power-law scaling of the cluster size distribution near the percolation threshold.The degree of discontinuity of the phase transition associated with this percolation threshold is observed to broaden with larger Stokes numbers and thereby large-scale clustering.The sensitivity of our findings to the employed clustering algorithm is discussed.A novel cluster tracking algorithm is deployed to determine the interscale transfer rate along the particle-number phase-space dimension via accounting of cluster breakup and merger events,extending previous work on the bubble breakup cascade beneath surface breaking waves.Our findings shed light on the interaction between particle clusters and their carrier turbulent flows,with an eye toward transport models incorporating cluster characteristics and dynamics. 展开更多
关键词 Particle-laden flows Particle-laden turbulence Sediment transport Computational fluid dynamics Multiphase turbulence Particle clustering Percolation theory
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Ligand-directed construction of cobalt-oxo cluster-based organic frameworks:Structural modulation,semiconductor,and antiferromagnetic properties
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作者 SHI Jinlian LIU Xiaoru XU Zhongxuan 《无机化学学报》 北大核心 2026年第1期45-54,共10页
Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully construct... Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24. 展开更多
关键词 semi-rigid carboxylic acid ligands three-dimensional framework tetranuclear cobalt-oxo cluster semiconductor material antiferromagnetic magnetism
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Progress in clustering algorithms for astronomical spectra over a decade
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作者 Jianing Tian Haifeng Yang +4 位作者 Jianghui Cai Yuqing Yang Xiangru Li Zhenping Yi Lili Wang 《Astronomical Techniques and Instruments》 2026年第1期10-25,共16页
As large-scale astronomical surveys,such as the Sloan Digital Sky Survey(SDSS)and the Large Sky Area Multi-Object Fiber Spectroscopic Telescope(LAMOST),generate increasingly complex datasets,clustering algorithms have... As large-scale astronomical surveys,such as the Sloan Digital Sky Survey(SDSS)and the Large Sky Area Multi-Object Fiber Spectroscopic Telescope(LAMOST),generate increasingly complex datasets,clustering algorithms have become vital for identifying patterns and classifying celestial objects.This paper systematically investigates the application of five main categories of clustering techniques-partition-based,density-based,model-based,hierarchical,and“others”-across a range of astronomical research over the past decade.This review focuses on the six key application areas of stellar classification,galaxy structure analysis,detection of galactic and interstellar features,highenergy astrophysics,exoplanet studies,and anomaly detection.This paper provides an in-depth analysis of the performance and results of each method,considering their respective suitabilities for different data types.Additionally,it presents clustering algorithm selection strategies based on the characteristics of the spectroscopic data being analyzed.We highlight challenges such as handling large datasets,the need for more efficient computational tools,and the lack of labeled data.We also underscore the potential of unsupervised and semi-supervised clustering approaches to overcome these challenges,offering insight into their practical applications,performance,and results in astronomical research. 展开更多
关键词 clusterING Stellar types Astronomical techniques CLASSIFICATION GALAXIES
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Evolution Characteristics and Driving Mechanism of‘Bottom-up’and‘Top-down’Endogenous Automobile Industry Clusters:A Comparative Study in Taizhou and Wuhu,China
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作者 JIANG Haining ZHANG Jun +1 位作者 CHEN Jiaqi JIN Xingxing 《Chinese Geographical Science》 2026年第1期34-49,共16页
Bottom-up and top-down endogenous automobile clusters exhibit distinct evolutionary traits and driving mechanisms,yet their comparative analysis remains understudied.Therefore,using Taizhou automobile industry cluster... Bottom-up and top-down endogenous automobile clusters exhibit distinct evolutionary traits and driving mechanisms,yet their comparative analysis remains understudied.Therefore,using Taizhou automobile industry cluster(TAIC)and Wuhu automobile industry cluster(WAIC)as cases,using historical statistical data and field interview data from the 1980s to 2023,combined with qualitative research methods of thematic and diachronic analysis,and quantitative research methods of social network analysis,we compare both endogenous automobile clusters’evolutionary traits and driving mechanisms.The results confirm both clusters undergo multi-scale spatial reconfiguration,organizational complexification,and intelligent networking technological transformation,yet diverge fundamentally:TAIC evolves through market-driven progressive expansion,transitioning from single to dual-core structures via private enterprise networking,with innovation following market-integrated logic and institutional thickness built on demand-driven evolution.Conversely,WAIC follows planned expansion,maintaining state-led hierarchical single-core stability through policy-driven breakthrough innovation and supply-dominated institutional construction-though both ultimately require formal-informal system synergy.Their coevolution is driven by dynamic interactions of path dependence(weakening influence),learning-innovation(strengthening influence),and relationship selection(inverted U-shaped trajectory),with divergent development paths rooted in TAIC’s grassroots self-organization genes versus WAIC’s top-level design genes,amplified by core enterprises’strategic disparities.The research findings can not only provide decision-making support for China’s industrial upgrading,but also contribute China’s insights to global economic governance. 展开更多
关键词 endogenous automobile industrial clusters evolutionary characteristics driving mechanism Taizhou Wuhu China
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Growing Together——Villages in Zhejiang form clusters for common development
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作者 LIU TING 《ChinAfrica》 2026年第2期22-24,共3页
Villager Pan Chunlin is witnessing a boom in his homestay business.More and more visitors are coming to his village,Yucun Village in Anji County,Huzhou City,Zhejiang Province.
关键词 Huzhou city Zhejiang province VILLAGES VISITORS Yucun village clusterS common development homestay business
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The five major textile and apparel industry clusters in Xinjiang have achieved an output value exceeding 220 billion yuan
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作者 Qiu Shuchen 《China Textile》 2026年第1期34-35,共2页
In the Tianshan region,a complete textile industry chain has been established,covering the entire process from cotton cultivation and chemical fiber production,through spinning,weaving,dyeing,and finishing,and further... In the Tianshan region,a complete textile industry chain has been established,covering the entire process from cotton cultivation and chemical fiber production,through spinning,weaving,dyeing,and finishing,and further extending to apparel,home textiles,and industrial textiles.In November 2025,the first list of five characteristic textile and apparel industry clusters in Xinjiang was officially announced,marking a new stage in the clustering of Xinjiang's textile and apparel industry.Data shows that the total output value of Xinjiang's cotton and textile and apparel industry chain has exceeded 220 billion yuan.With the nation's largest cotton production,a complete industrial chain system,and strong synergistic effects,Xinjiang has become a leading and highly competitive textile industry hub in China. 展开更多
关键词 clustering XINJIANG cotton production apparel industry chemical fiber industrial chain textile industry output value
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Single-atom collaboration with cluster for accelerated nitrate electroreduction:Synergy revelation via machine learning and DFT calculations
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作者 Ruochen Zhu Haoyu Wang +4 位作者 Kongke Tang Xinyuan Yang Xiuxian Zhao Jiayuan Yu Riming Hu 《Journal of Energy Chemistry》 2026年第1期842-851,I0019,共11页
Exploring high-performance electrocatalysts for the nitrate reduction reaction(NO_(3)RR)is crucial for environmental nitrate removal and ammonia synthesis.Single-atom collaboration with cluster can provide sufficient ... Exploring high-performance electrocatalysts for the nitrate reduction reaction(NO_(3)RR)is crucial for environmental nitrate removal and ammonia synthesis.Single-atom collaboration with cluster can provide sufficient active sites for catalysts to promote NO_(3)RR,yet the unclear synergistic effect between the two hinders their rational design.Herein,a series of Ir_(3)clusters and metal single atoms co-embedded in graphitic carbon nitride(g-CN)catalysts(Ir_(3)M1)were constructed,and the synergistic effects of Ir_(3)clusters and M1 single atoms on the NO_(3)RR catalytic mechanism and activity were systematically explored using density functional theory(DFT)calculations combined with machine learning.Comprehensive evaluations of structural stability and catalytic activity demonstrate that the synergy between single atoms and clusters effectively balances the adsorption energies of key intermediates,yielding exceptional catalytic performance(the limiting potential of Ir_(3)Ti_(1)can reach−0.22 V).Machine learning models further clarify the synergistic mechanism,where the geometric configurations of clusters serve as critical features for modulating the catalytic activity of single-atom sites,whereas the electronic structures of single atoms directly govern the reactivity of cluster sites.This DFT-machine learning approach provides theoretical guidelines for catalyst design and a predictive framework for efficient NO_(3)RR electrocatalysts. 展开更多
关键词 Nitrate reduction reaction Density functional theory Single-atom catalysts cluster Machine learning
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Social Network and Value Chain Integration:Unraveling the Formation and Evolution of Meizhou Pomelo Industry Cluster in China
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作者 YANG Ren LIN Yuancheng ZHANG Xin 《Chinese Geographical Science》 2026年第2期239-255,共17页
The shift toward specialized and large-scale agricultural production has spurred the emergence of agricultural clusters as key forces of rural vitalization and sustainable development.This paper explored the formation... The shift toward specialized and large-scale agricultural production has spurred the emergence of agricultural clusters as key forces of rural vitalization and sustainable development.This paper explored the formation and evolution of Meizhou pomelo industry cluster in China,focusing on its role in restructuring rural socio-economic systems and integrating the whole value chains.Based on a case study employing qualitative methods such as in-depth interviews and participatory observation,the agricultural cluster evolution of Meizhou pomelo was categorized into three key phases of initial decentralization,self-organized scaling,and reorganized clustering.Geographical proximity and industrial agglomeration constitute the physical foundation,while vertical/horizontal linkages,technologic-al innovation,and policy support enhance competitiveness.Special mechanisms emerge through localized social networks,farmer co-operatives’activation,and cross-regional market expansion.The cluster’s impact is manifested in the shift from extensive to standard-ized and modernized production,diversified and flexible livelihood of farmers,and the integration of agriculture with industry and ser-vices.The development of the whole value chain based on agricultural cluster represents a critical pathway for achieving agricultural modernization,encompassing both internal and external value chain optimization.Through quality assurance systems,product diversi-fication strategies,operational efficiency improvements,and brand enhancement,these clusters amplify product value propositions and market competitiveness.This systemic approach facilitates supply-demand coordination,enables resource synergies,and optimizes eco-nomic returns across the horizontal and vertical value chain.This paper argues that agricultural clusters serve as strategic catalysts for sustainable rural development by reconstructing local production systems,fostering innovation ecosystems,and aligning agricultural modernization.It contributes to debates on rural vitalization by demonstrating how agricultural clustering can reconfigure rural areas as hubs of ecological modernization,rather than mere urban peripheries. 展开更多
关键词 agricultural cluster sustainable rural development agricultural systems social network whole value chain China
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Grey Wolf Optimizer for Cluster-Based Routing in Wireless Sensor Networks:A Methodological Survey
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作者 Mohammad Shokouhifar Fakhrosadat Fanian +4 位作者 Mehdi Hosseinzadeh Aseel Smerat Kamal M.Othman Abdulfattah Noorwali Esam Y.O.Zafar 《Computer Modeling in Engineering & Sciences》 2026年第1期191-255,共65页
Wireless Sensor Networks(WSNs)have become foundational in numerous real-world applications,ranging from environmental monitoring and industrial automation to healthcare systems and smart city development.As these netw... Wireless Sensor Networks(WSNs)have become foundational in numerous real-world applications,ranging from environmental monitoring and industrial automation to healthcare systems and smart city development.As these networks continue to grow in scale and complexity,the need for energy-efficient,scalable,and robust communication protocols becomes more critical than ever.Metaheuristic algorithms have shown significant promise in addressing these challenges,offering flexible and effective solutions for optimizing WSN performance.Among them,the Grey Wolf Optimizer(GWO)algorithm has attracted growing attention due to its simplicity,fast convergence,and strong global search capabilities.Accordingly,this survey provides an in-depth review of the applications of GWO and its variants for clustering,multi-hop routing,and hybrid cluster-based routing in WSNs.We categorize and analyze the existing GWO-based approaches across these key network optimization tasks,discussing the different problem formulations,decision variables,objective functions,and performance metrics used.In doing so,we examine standard GWO,multi-objective GWO,and hybrid GWO models that incorporate other computational intelligence techniques.Each method is evaluated based on how effectively it addresses the core constraints of WSNs,including energy consumption,communication overhead,and network lifetime.Finally,this survey outlines existing gaps in the literature and proposes potential future research directions aimed at enhancing the effectiveness and real-world applicability of GWO-based techniques for WSN clustering and routing.Our goal is to provide researchers and practitioners with a clear,structured understanding of the current state of GWO in WSNs and inspire further innovation in this evolving field. 展开更多
关键词 Wireless sensor networks data transmission energy efficiency LIFETIME clusterING ROUTING optimization metaheuristic algorithms grey wolf optimizer
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Multipoint Deformation Prediction Model Based on Clustering Partition of Extra High-Arch Dams
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作者 Bin Ou Haoquan Chi +3 位作者 Xu’an Qian Shuyan Fu Zhirui Miao Dingzhu Zhao 《Computer Modeling in Engineering & Sciences》 2026年第1期546-576,共31页
Deformation prediction for extra-high arch dams is highly important for ensuring their safe operation.To address the challenges of complex monitoring data,the uneven spatial distribution of deformation,and the constru... Deformation prediction for extra-high arch dams is highly important for ensuring their safe operation.To address the challenges of complex monitoring data,the uneven spatial distribution of deformation,and the construction and optimization of a prediction model for deformation prediction,a multipoint ultrahigh arch dam deformation prediction model,namely,the CEEMDAN-KPCA-GSWOA-KELM,which is based on a clustering partition,is pro-posed.First,the monitoring data are preprocessed via variational mode decomposition(VMD)and wavelet denoising(WT),which effectively filters out noise and improves the signal-to-noise ratio of the data,providing high-quality input data for subsequent prediction models.Second,scientific cluster partitioning is performed via the K-means++algorithm to precisely capture the spatial distribution characteristics of extra-high arch dams and ensure the consistency of deformation trends at measurement points within each partition.Finally,CEEMDAN is used to separate monitoring data,predict and analyze each component,combine the KPCA(Kernel Principal Component Analysis)and the KELM(Kernel Extreme Learning Machine)optimized by the GSWOA(Global Search Whale Optimization Algorithm),integrate the predictions of each component via reconstruction methods,and precisely predict the overall trend of ultrahigh arch dam deformation.An extra high arch dam project is taken as an example and validated via a comparative analysis of multiple models.The results show that the multipoint deformation prediction model in this paper can combine data from different measurement points,achieve a comprehensive,precise prediction of the deformation situation of extra high arch dams,and provide strong technical support for safe operation. 展开更多
关键词 Extra high arch dams deformation prediction data noise reduction spatial distribution clustering partition
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Visual field prediction using K-means clustering in patients with primary open angle glaucoma
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作者 Junyoung Lee Jihun Kim +5 位作者 Hwayoung Kim Sangwoo Moon EunAh Kim Sanghun Jeong Hojin Yang Jiwoong Lee 《International Journal of Ophthalmology(English edition)》 2026年第1期63-68,共6页
AIM:To evaluate long-term visual field(VF)prediction using K-means clustering in patients with primary open angle glaucoma(POAG).METHODS:Patients who underwent 24-2 VF tests≥10 were included in this study.Using 52 to... AIM:To evaluate long-term visual field(VF)prediction using K-means clustering in patients with primary open angle glaucoma(POAG).METHODS:Patients who underwent 24-2 VF tests≥10 were included in this study.Using 52 total deviation values(TDVs)from the first 10 VF tests of the training dataset,VF points were clustered into several regions using the hierarchical ordered partitioning and collapsing hybrid(HOPACH)and K-means clustering.Based on the clustering results,a linear regression analysis was applied to each clustered region of the testing dataset to predict the TDVs of the 10th VF test.Three to nine VF tests were used to predict the 10th VF test,and the prediction errors(root mean square error,RMSE)of each clustering method and pointwise linear regression(PLR)were compared.RESULTS:The training group consisted of 228 patients(mean age,54.20±14.38y;123 males and 105 females),and the testing group included 81 patients(mean age,54.88±15.22y;43 males and 38 females).All subjects were diagnosed with POAG.Fifty-two VF points were clustered into 11 and nine regions using HOPACH and K-means clustering,respectively.K-means clustering had a lower prediction error than PLR when n=1:3 and 1:4(both P≤0.003).The prediction errors of K-means clustering were lower than those of HOPACH in all sections(n=1:4 to 1:9;all P≤0.011),except for n=1:3(P=0.680).PLR outperformed K-means clustering only when n=1:8 and 1:9(both P≤0.020).CONCLUSION:K-means clustering can predict longterm VF test results more accurately in patients with POAG with limited VF data. 展开更多
关键词 K-means clustering hierarchical ordered partitioning and collapsing hybrid pointwise linear regression visual field prediction
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Cu cluster@UiO-66团簇负载型催化剂促进光催化CO_(2)加氢反应 被引量:2
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作者 王秀林 岐少鹏 +6 位作者 周昆 邓希 姚辉超 戴若云 张雨晴 伍思达 聂锁府 《分子催化(中英文)》 北大核心 2025年第2期111-119,I0001,共10页
针对高活性Cu基团簇(Cu cluster)催化剂的稳定性问题,利用MOFs材料独特的结构限域作用,将Cu团簇锚定在UiO-66中,构建了Cu cluster@UiO-66复合材料,改善了催化剂的稳定性和催化活性.在该复合结构中,UiO-66不仅可作为吸光单元捕获太阳光... 针对高活性Cu基团簇(Cu cluster)催化剂的稳定性问题,利用MOFs材料独特的结构限域作用,将Cu团簇锚定在UiO-66中,构建了Cu cluster@UiO-66复合材料,改善了催化剂的稳定性和催化活性.在该复合结构中,UiO-66不仅可作为吸光单元捕获太阳光形成光生载流子,而且UiO-66的多孔结构可以有效稳定Cu团簇,保证其微观尺度上的高度分散和结构稳定.研究发现,在光催化反应过程中,UiO-66的光生电子可快速转移至Cu团簇,进而以Cu团簇作为催化活性位点驱动CO_(2)还原反应.得益于复合材料中高效的电荷转移和稳定的团簇活性位点结构,光催化CO_(2)加氢反应活性明显增强.本研究为合成MOFs负载型团簇材料提供了新的思路. 展开更多
关键词 复合结构 UiO-66 铜纳米簇 光催化CO_(2)还原
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Technical progress and application of global carbon dioxide capture,utilization and storage cluster 被引量:2
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作者 WANG Guofeng LYU Weifeng +4 位作者 CUI Kai JI Zemin WANG Heng HE Chang HE Chunyu 《Petroleum Exploration and Development》 2025年第2期536-547,共12页
By systematically reviewing the development status of global carbon dioxide capture,utilization and storage(CCUS)cluster,and comparing domestic and international CCUS industrial models and successful experiences,this ... By systematically reviewing the development status of global carbon dioxide capture,utilization and storage(CCUS)cluster,and comparing domestic and international CCUS industrial models and successful experiences,this study explores the challenges and strategies for the scaled development of the CCUS industry of China.Globally,the CCUS industry has entered a phase of scaled and clustered development.North America has established a system of key technologies in large-scale CO_(2) capture,long-distance pipeline transmission,pipeline network optimization,and large-scale CO_(2) flooding for enhanced oil recovery(CO_(2)-EOR),with relatively mature cluster development and a gradual shift in industrial model from CO_(2)-EOR to geological storage.The CCUS industry of China has developed rapidly across all segments but remains in the early stage of cluster development,facing challenges such as absent business model,insufficient policy support,and technological gaps in core areas.China needs to improve the policy support system to boost enterprises participation across the entire industrial chain,strengthen top-level design and medium-to long-term planning to accelerate demonstration projects construction for whole-process CCUS clusters,advance for a full-chain technological system,including low-cost capture,pipeline optimization and EOR/storage integration technologies,and strengthen personnel training,strengthen discipline construction and university-enterprise research cooperation. 展开更多
关键词 CCUS industrial cluster business model policy guarantee entire industrial chain technology running cost
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Multi-View Picture Fuzzy Clustering:A Novel Method for Partitioning Multi-View Relational Data 被引量:1
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作者 Pham Huy Thong Hoang Thi Canh +2 位作者 Luong Thi Hong Lan Nguyen Tuan Huy Nguyen Long Giang 《Computers, Materials & Continua》 2025年第6期5461-5485,共25页
Multi-view clustering is a critical research area in computer science aimed at effectively extracting meaningful patterns from complex,high-dimensional data that single-view methods cannot capture.Traditional fuzzy cl... Multi-view clustering is a critical research area in computer science aimed at effectively extracting meaningful patterns from complex,high-dimensional data that single-view methods cannot capture.Traditional fuzzy clustering techniques,such as Fuzzy C-Means(FCM),face significant challenges in handling uncertainty and the dependencies between different views.To overcome these limitations,we introduce a new multi-view fuzzy clustering approach that integrates picture fuzzy sets with a dual-anchor graph method for multi-view data,aiming to enhance clustering accuracy and robustness,termed Multi-view Picture Fuzzy Clustering(MPFC).In particular,the picture fuzzy set theory extends the capability to represent uncertainty by modeling three membership levels:membership degrees,neutral degrees,and refusal degrees.This allows for a more flexible representation of uncertain and conflicting data than traditional fuzzy models.Meanwhile,dual-anchor graphs exploit the similarity relationships between data points and integrate information across views.This combination improves stability,scalability,and robustness when handling noisy and heterogeneous data.Experimental results on several benchmark datasets demonstrate significant improvements in clustering accuracy and efficiency,outperforming traditional methods.Specifically,the MPFC algorithm demonstrates outstanding clustering performance on a variety of datasets,attaining a Purity(PUR)score of 0.6440 and an Accuracy(ACC)score of 0.6213 for the 3 Sources dataset,underscoring its robustness and efficiency.The proposed approach significantly contributes to fields such as pattern recognition,multi-view relational data analysis,and large-scale clustering problems.Future work will focus on extending the method for semi-supervised multi-view clustering,aiming to enhance adaptability,scalability,and performance in real-world applications. 展开更多
关键词 Multi-view clustering picture fuzzy sets dual anchor graph fuzzy clustering multi-view relational data
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FedCPS:A Dual Optimization Model for Federated Learning Based on Clustering and Personalization Strategy 被引量:1
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作者 Zhen Yang Yifan Liu +2 位作者 Fan Feng Yi Liu Zhenpeng Liu 《Computers, Materials & Continua》 2025年第4期357-380,共24页
Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients a... Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients and the server.However,the presence of data heterogeneity can lead to inefficient model training and even reduce the final model’s accuracy and generalization capability.Meanwhile,data scarcity can result in suboptimal cluster distributions for few-shot clients in centralized clustering tasks,and standalone personalization tasks may cause severe overfitting issues.To address these limitations,we introduce a federated learning dual optimization model based on clustering and personalization strategy(FedCPS).FedCPS adopts a decentralized approach,where clients identify their cluster membership locally without relying on a centralized clustering algorithm.Building on this,FedCPS introduces personalized training tasks locally,adding a regularization term to control deviations between local and cluster models.This improves the generalization ability of the final model while mitigating overfitting.The use of weight-sharing techniques also reduces the computational cost of central machines.Experimental results on MNIST,FMNIST,CIFAR10,and CIFAR100 datasets demonstrate that our method achieves better personalization effects compared to other personalized federated learning methods,with an average test accuracy improvement of 0.81%–2.96%.Meanwhile,we adjusted the proportion of few-shot clients to evaluate the impact on accuracy across different methods.The experiments show that FedCPS reduces accuracy by only 0.2%–3.7%,compared to 2.1%–10%for existing methods.Our method demonstrates its advantages across diverse data environments. 展开更多
关键词 Federated learning cluster PERSONALIZATION OVERFITTING
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Mechanistic insights into cluster strengthening and grain refinement toughening in fully oxidized AgMgNi alloys 被引量:1
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作者 Haicheng Zhu Bingrui Liu +9 位作者 Shaohong Liu Limin Zhou Hao Cui Manmen Liu Li Chen Ming Wen Haigang Dong Feng Liu Song Li Liang Zuo 《Journal of Materials Science & Technology》 2025年第20期252-263,共12页
The pursuit of Ag-based alloys with both high strength and toughness has posed a longstanding chal-lenge.In this study,we investigated the cluster strengthening and grain refinement toughening mecha-nisms in fully oxi... The pursuit of Ag-based alloys with both high strength and toughness has posed a longstanding chal-lenge.In this study,we investigated the cluster strengthening and grain refinement toughening mecha-nisms in fully oxidized AgMgNi alloys,which were internally oxidized at 800℃ for 8 h under an oxy-gen atmosphere.We found that Mg-O clusters contributed to the hardening(138 HV)and strengthening(376.9 MPa)of the AgMg alloy through solid solution strengthening effects,albeit at the expense of duc-tility.To address this limitation,we introduced Ni nanoparticles into the AgMg alloy,resulting in signifi-cant grain refinement within its microstructure.Specifically,the grain size decreased from 67.2μm in the oxidized AgMg alloy to below 6.0μm in the oxidized AgMgNi alloy containing 0.3 wt%Ni.Consequently,the toughness increased significantly,rising from toughness value of 2177.9 MJ m^(-3) in the oxidized AgMg alloy to 6186.1 MJ m^(-3) in the oxidized AgMgNi alloy,representing a remarkable 2.8-fold enhancement.Furthermore,the internally oxidized AgMgNi alloy attained a strength of up to 387.6 MPa,comparable to that of the internally oxidized AgMg alloy,thereby demonstrating the successful realization of concurrent strengthening and toughening.These results collectively offer a novel approach for the design of high-performance alloys through the synergistic combination of cluster strengthening and grain refinement toughening. 展开更多
关键词 Ag-based alloys Mg-O cluster Grain refining Internal oxidation HARDENING
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A High-quality Ellipse Detection Method for Machine Vision Based on Geometric Constraints and Hierarchical Clustering 被引量:1
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作者 Lin Zhang Xuan Liu +3 位作者 Chen Zhang Yuqing Hou Xiaowei He Sheng Tang 《Instrumentation》 2025年第3期39-52,共14页
In machine vision,elliptical targets frequently appear within the camera's region of interest(ROI).Ellipse detection is essential for shape detection and geometric measurements in machine vision.However,existing e... In machine vision,elliptical targets frequently appear within the camera's region of interest(ROI).Ellipse detection is essential for shape detection and geometric measurements in machine vision.However,existing ellipse detection algorithms often face issues such as high computational complexity,strong dependence on initial conditions,sensitivity to noise,and lack of robustness to occlusions.In this paper,we propose a fast and robust ellipse detection method to address these challenges.This method first utilizes edge gradient and curvature information to segment the curve into circular arcs.Next,based on the convexity of the arcs,it divides them into different quadrants of the ellipse,groups and fits the arcs according to multiple geometric constraints at a low computational cost.Finally,it reduces the parameter space for hierarchical clustering and then segments the complete ellipse into several sectors for verification.We compare our method across seven datasets,including five public image datasets and two from industrial camera scenes.Experimental results show that our method achieves a precision ranging from 67.1%to 98.9%,a recall ranging from 48.1%to 92.9%,and an F-measure ranging from 58.0%to 95.8%.The average execution time per image ranges from 25 ms to 192 ms,demonstrating both high accuracy and efficiency. 展开更多
关键词 ellipse detection geometric constraints hierarchical clustering camera datasets
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Exploring core symptoms and symptom clusters among patients with neuromyelitis optica spectrum disorder: A network analysis 被引量:1
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作者 Hao Liang Jiehan Chen +4 位作者 Lixin Wang Zhuyun Liu Haoyou Xu Min Zhao Xiaopei Zhang 《International Journal of Nursing Sciences》 2025年第2期152-160,共9页
Objectives To identify core symptoms and symptom clusters in patients with neuromyelitis optica spectrum disorder(NMOSD)by network analysis.Methods From October 10 to 30,2023,140 patients with NMOSD were selected to p... Objectives To identify core symptoms and symptom clusters in patients with neuromyelitis optica spectrum disorder(NMOSD)by network analysis.Methods From October 10 to 30,2023,140 patients with NMOSD were selected to participate in this online questionnaire survey.The survey tools included a general information questionnaire and a self-made NMOSD symptoms scale,which included the prevalence,severity,and distress of 29 symptoms.Cluster analysis was used to identify symptom clusters,and network analysis was used to analyze the symptom network and node characteristics and central indicators including strength centrality(r_(s)),closeness centrality(r_(c))and betweeness centrality(r_(b))were used to identify core symptoms and symptom clusters.Results The most common symptom was pain(65.7%),followed by paraesthesia(65.0%),fatigue(65.0%),easy awakening(63.6%).Regarding the burden level of symptoms,pain was the most burdensome symptom,followed by paraesthesia,easy awakening,fatigue,and difficulty falling asleep.Six clusters were identified:somatosensory,motor,visual,and memory symptom clusters,bladder and rectum symptom clusters,sleep symptoms clusters,and neuropsychological symptom clusters.Fatigue(r_(s)=12.39,r_(b)=68.00,r_(c)=0.02)was the most central and prominent bridge symptom,and motor symptom cluster(r_(s)=2.68,r_(c)=0.10)was the most central symptom cluster among the six clusters.Conclusions Our study demonstrated the necessity of symptom management targeting fatigue,pain,and motor symptom cluster in patients with NMOSD. 展开更多
关键词 Neuromyelitis optica spectrum disorder Network analysis SYMPTOM Symptom clusters NURSING
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A novel method for clustering cellular data to improve classification
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作者 Diek W.Wheeler Giorgio A.Ascoli 《Neural Regeneration Research》 SCIE CAS 2025年第9期2697-2705,共9页
Many fields,such as neuroscience,are experiencing the vast prolife ration of cellular data,underscoring the need fo r organizing and interpreting large datasets.A popular approach partitions data into manageable subse... Many fields,such as neuroscience,are experiencing the vast prolife ration of cellular data,underscoring the need fo r organizing and interpreting large datasets.A popular approach partitions data into manageable subsets via hierarchical clustering,but objective methods to determine the appropriate classification granularity are missing.We recently introduced a technique to systematically identify when to stop subdividing clusters based on the fundamental principle that cells must differ more between than within clusters.Here we present the corresponding protocol to classify cellular datasets by combining datadriven unsupervised hierarchical clustering with statistical testing.These general-purpose functions are applicable to any cellular dataset that can be organized as two-dimensional matrices of numerical values,including molecula r,physiological,and anatomical datasets.We demonstrate the protocol using cellular data from the Janelia MouseLight project to chara cterize morphological aspects of neurons. 展开更多
关键词 cellular data clustering dendrogram data classification Levene's one-tailed statistical test unsupervised hierarchical clustering
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