Titanium alloys are composed ofαandβphases and are classified as nearα,dual-phaseα+β,andβtypes.This study attempts to derive their general composition formulas within the cluster-plus-glue-atom model by interpre...Titanium alloys are composed ofαandβphases and are classified as nearα,dual-phaseα+β,andβtypes.This study attempts to derive their general composition formulas within the cluster-plus-glue-atom model by interpreting Ti-6A1-4V and other popular dual-phaseα+βTi alloy s with well-established chemical compositions.Our model identifiedαmolecule-like structural unit that covers onlyαnearest-neighbor cluster along withαfew next-neighbor glue atoms,which can be represented as"[cluster](glue atoms)x".The structural units of theαandβphases in Ti-6Al-4V,α-[Al-Ti_(12)](AlTi_(2)),andβ-[Al-Ti_(14)](V2Ti),were derived first and were in an unusual unit ratio of about 2.33:1.To obtain an alloy composition formula that satisfied this unit ratio,the two clusters were treated as hard spheres of different radii and packed according to the clusterplusglueatom model.Our calculations determined that the Ti-6A1-4V alloy unit is composed of 12α-[Al-Ti_(12)](AlTi_(2))and 5β-[Al-Ti_(14)](V2Ti)units(Ti-6.05A1-3.94V wt.%),with the fractional volume of theβphase being 32.5 vol.%,which is in agreement with experimental data.Finally,we describe how the chemical formulas of theαand p phases explain the high temperature near-a alloys(such as Ti-1100,[Al-(Ti_(0.97)Zr_(0.03))_(12)](Al_(0.67)Si_(0.12)Sn_(0.18)Mo_(0.03))_(1.01)Ti_(1.99))and high-strengthβ-Ti alloys(such as Ti-5553,[Al-Ti_(14)](Al_(0.24)Fe_(0.03)Cr_(0.20)-Mo_(0.18)V0.35)_(2.45)Ti_(0.55)),respectively.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2016YFB1100103)the Science Research Project of Liaoning Province Education Department(Grant No.JDL2019023)+1 种基金the Natural Science Foundation of Liaoning Province(Grant No.2020-BS-208)the Open Project of Key Laboratory of Materials Modification by Laser,Ion and Electron Beams(Grant No.KF2006)。
文摘Titanium alloys are composed ofαandβphases and are classified as nearα,dual-phaseα+β,andβtypes.This study attempts to derive their general composition formulas within the cluster-plus-glue-atom model by interpreting Ti-6A1-4V and other popular dual-phaseα+βTi alloy s with well-established chemical compositions.Our model identifiedαmolecule-like structural unit that covers onlyαnearest-neighbor cluster along withαfew next-neighbor glue atoms,which can be represented as"[cluster](glue atoms)x".The structural units of theαandβphases in Ti-6Al-4V,α-[Al-Ti_(12)](AlTi_(2)),andβ-[Al-Ti_(14)](V2Ti),were derived first and were in an unusual unit ratio of about 2.33:1.To obtain an alloy composition formula that satisfied this unit ratio,the two clusters were treated as hard spheres of different radii and packed according to the clusterplusglueatom model.Our calculations determined that the Ti-6A1-4V alloy unit is composed of 12α-[Al-Ti_(12)](AlTi_(2))and 5β-[Al-Ti_(14)](V2Ti)units(Ti-6.05A1-3.94V wt.%),with the fractional volume of theβphase being 32.5 vol.%,which is in agreement with experimental data.Finally,we describe how the chemical formulas of theαand p phases explain the high temperature near-a alloys(such as Ti-1100,[Al-(Ti_(0.97)Zr_(0.03))_(12)](Al_(0.67)Si_(0.12)Sn_(0.18)Mo_(0.03))_(1.01)Ti_(1.99))and high-strengthβ-Ti alloys(such as Ti-5553,[Al-Ti_(14)](Al_(0.24)Fe_(0.03)Cr_(0.20)-Mo_(0.18)V0.35)_(2.45)Ti_(0.55)),respectively.
