Superalloys feature multi-elements and complex elemental ranges,which makes the proper composition selection difficult.In fact,more strict composition standards generally apply in practical productions.The objective o...Superalloys feature multi-elements and complex elemental ranges,which makes the proper composition selection difficult.In fact,more strict composition standards generally apply in practical productions.The objective of this paper is to understand and eventually to renew the composition standard via example of the most common grade Inconel 718.We have recently shown that t he alloy chemistry originates from a nearest-neighbor cluster[center-shell]plus a few next-neighbor glue atoms,or expressed in cluster for-mula[center-shell](glue atoms).By grouping the elements into Ni=(Ni,Co,Cu,Fe),Cr=(Cr,Mn,Si,Mo),and Nb=(Nb,Al,Ti),it is found that the reported alloys fall within a narrow composition zone Ni_(11.0-13.0)-Cr_(3.5-4.5)-Nb_(1) confined by cluster formulas of 16 and 18 atoms.This composition zone is also expressed in terms of 288-atom supercluster formulas,Ni_(198-208)-Cr_(63-72)-Nb_(16-18),which leads to coordi-nated elemental variations in wt.%:69.0≤Ni+Co+Cu+Fe≤72.7;19.8≤Cr+Mn+1.7 Si+0.6 Mo≤22.8;8.7≤Nb+3.2 Al+1.9 Ti≤9.8.Within this composition zone,Ni_(206)-Cr_(65.5)-Nb_(16.5) is further pinpointed and validated by our own experiments to possess the optimal match of strength and plasticity both at room and at 923 K.展开更多
A Ti-5.4Al-6.4Zr-6.2Sn-0.4Mo-1.6W-0.4Nb-3.2Ta-0.5Si alloy is designed following cluster formula approach that achieves a strength level of 1 GPa at 600℃in the as-cast state,superior to any existing high-temperature T...A Ti-5.4Al-6.4Zr-6.2Sn-0.4Mo-1.6W-0.4Nb-3.2Ta-0.5Si alloy is designed following cluster formula approach that achieves a strength level of 1 GPa at 600℃in the as-cast state,superior to any existing high-temperature Ti alloys.Its composition is formulated by 17 basic units,α-{[Al-Ti12](AlTi2)}12+β-{[Al-Ti_(12)Zr_(2)](Mo_(0.125)Nb_(0.125)Ta_(0.5)W_(0.25)Sn_(1.5)Si_(0.5))}_(5),each unit covering a nearest-neighbor cluster plus a few next-neighbor glue atoms.This design is on the basis of the composition formula of Ti65 alloy,with an enhancedβstability via more Zr,Mo,Nb,Ta,W,Sn,and Si co-alloying.Upon copper-mold pour casting,this alloy shows a good microstructure stability.In tensile testing below at 650℃,itsαplates thickness is nearly at the same level of 0.2μm,which is much smaller than 0.7-0.8μm of Ti65 at the same condition.The changes in volume fraction ofβphase are increased by 86%,much less than by 105%in Ti65.Its room-temperature strength reaches the ultra-high-strength level,with an ultimate tensile strength of 1328 MPa and a yield strength of 1117 MPa,with a moderate elongation of 3.8%.At 600℃,its ultimate tensile strength of 1017 MPa and yield strength of 936 MPa are superior to those of any existing high-temperature Ti alloys,with an elongation of 7.2%.At 650℃,its ultimate tensile strength of 848 MPa still maintains a high level.展开更多
The multi-component composition characteristics of high-temperature near-α Ti alloys were investigated in the present work by means of a cluster formula approach. The uniform cluster formula [CN12 cluster](glue atom)...The multi-component composition characteristics of high-temperature near-α Ti alloys were investigated in the present work by means of a cluster formula approach. The uniform cluster formula [CN12 cluster](glue atom)3 for the hexagonal close-packed α solid solution was first obtained based on the Friedel oscillation theory, with a total atom number in the formula of Z = 16. Then it was analyzed that the Z values in the cluster composition formulas of typical near-α Ti alloys are within the range of Z = 16.0016.30, being perfectly consistent with the ideal Z = 16. Based on it, a series of new alloys with Z = 16 and with Nb/Ta substitution for Mo in Ti1100 alloy were designed, suction-cast into φ 6 mm rods, and then heat-treated with solid solution and aging. It was found that the alloy with co-addition of Mo, Ta and Nb has a high strength and good ductility at both room and high temperatures. More importantly, the additions of Nb and Ta can contribute to the formation of continuous and compact Al2O3 scales, resulting in an obvious improvement of oxidation resistances at both 923 K and 1073 K. The effects of Mo, Ta and Nb on the oxidation behaviors of the designed alloys at 1073 K were further discussed.展开更多
针对Leach(low energy adaptive clustering hierarchy)协议在大规模网络中存在着数据传输效率不高和网络生命周期短的问题,提出了一种LEACH-CM-NGO优化算法。该方法通过在簇头选取阶段优化簇头数在所有节点中占比,引进能量密度因子和...针对Leach(low energy adaptive clustering hierarchy)协议在大规模网络中存在着数据传输效率不高和网络生命周期短的问题,提出了一种LEACH-CM-NGO优化算法。该方法通过在簇头选取阶段优化簇头数在所有节点中占比,引进能量密度因子和能耗因子改进阈值公式优化簇头分布,并在数据传输阶段,由原本的单跳传输改为多跳方式传输数据,引入基于立方映射方法,自适应权重策略和柯西变异的北方苍鹰优化算法改进簇头间数据传输路径,以提高网络的能效和数据传输效率。仿真结果表明,所提出的方法在减少能耗的同时,显著延长了网络的生命周期并提高了数据传输的成功率。展开更多
基金supported by the Key Discipline and Major Project of Dalian Science and Technology Innovation Foun-dation(No.2020JJ25CY004).
文摘Superalloys feature multi-elements and complex elemental ranges,which makes the proper composition selection difficult.In fact,more strict composition standards generally apply in practical productions.The objective of this paper is to understand and eventually to renew the composition standard via example of the most common grade Inconel 718.We have recently shown that t he alloy chemistry originates from a nearest-neighbor cluster[center-shell]plus a few next-neighbor glue atoms,or expressed in cluster for-mula[center-shell](glue atoms).By grouping the elements into Ni=(Ni,Co,Cu,Fe),Cr=(Cr,Mn,Si,Mo),and Nb=(Nb,Al,Ti),it is found that the reported alloys fall within a narrow composition zone Ni_(11.0-13.0)-Cr_(3.5-4.5)-Nb_(1) confined by cluster formulas of 16 and 18 atoms.This composition zone is also expressed in terms of 288-atom supercluster formulas,Ni_(198-208)-Cr_(63-72)-Nb_(16-18),which leads to coordi-nated elemental variations in wt.%:69.0≤Ni+Co+Cu+Fe≤72.7;19.8≤Cr+Mn+1.7 Si+0.6 Mo≤22.8;8.7≤Nb+3.2 Al+1.9 Ti≤9.8.Within this composition zone,Ni_(206)-Cr_(65.5)-Nb_(16.5) is further pinpointed and validated by our own experiments to possess the optimal match of strength and plasticity both at room and at 923 K.
基金supported by the Natural Science Foundation of Shenyang,China(Grant No.22315605)the“Rejuvenating Liaoning Talents Plan”Project of Liaoning Province(Grant No.XLYC2203121)the Outstanding Youth Science and Technology Talent Project of Dalian(Grant No.2023RY040).
文摘A Ti-5.4Al-6.4Zr-6.2Sn-0.4Mo-1.6W-0.4Nb-3.2Ta-0.5Si alloy is designed following cluster formula approach that achieves a strength level of 1 GPa at 600℃in the as-cast state,superior to any existing high-temperature Ti alloys.Its composition is formulated by 17 basic units,α-{[Al-Ti12](AlTi2)}12+β-{[Al-Ti_(12)Zr_(2)](Mo_(0.125)Nb_(0.125)Ta_(0.5)W_(0.25)Sn_(1.5)Si_(0.5))}_(5),each unit covering a nearest-neighbor cluster plus a few next-neighbor glue atoms.This design is on the basis of the composition formula of Ti65 alloy,with an enhancedβstability via more Zr,Mo,Nb,Ta,W,Sn,and Si co-alloying.Upon copper-mold pour casting,this alloy shows a good microstructure stability.In tensile testing below at 650℃,itsαplates thickness is nearly at the same level of 0.2μm,which is much smaller than 0.7-0.8μm of Ti65 at the same condition.The changes in volume fraction ofβphase are increased by 86%,much less than by 105%in Ti65.Its room-temperature strength reaches the ultra-high-strength level,with an ultimate tensile strength of 1328 MPa and a yield strength of 1117 MPa,with a moderate elongation of 3.8%.At 600℃,its ultimate tensile strength of 1017 MPa and yield strength of 936 MPa are superior to those of any existing high-temperature Ti alloys,with an elongation of 7.2%.At 650℃,its ultimate tensile strength of 848 MPa still maintains a high level.
基金financially supported by the National Key Research and Development Plan(No.2017YFB0702400)the Science Challenge Project(No.TZ2016004)+1 种基金the National Magnetic Confinement Fusion Energy Research Project(No.2015GB121004)the Foundation of Guangxi Key Laboratory of Information Materials(No.161002-K)
文摘The multi-component composition characteristics of high-temperature near-α Ti alloys were investigated in the present work by means of a cluster formula approach. The uniform cluster formula [CN12 cluster](glue atom)3 for the hexagonal close-packed α solid solution was first obtained based on the Friedel oscillation theory, with a total atom number in the formula of Z = 16. Then it was analyzed that the Z values in the cluster composition formulas of typical near-α Ti alloys are within the range of Z = 16.0016.30, being perfectly consistent with the ideal Z = 16. Based on it, a series of new alloys with Z = 16 and with Nb/Ta substitution for Mo in Ti1100 alloy were designed, suction-cast into φ 6 mm rods, and then heat-treated with solid solution and aging. It was found that the alloy with co-addition of Mo, Ta and Nb has a high strength and good ductility at both room and high temperatures. More importantly, the additions of Nb and Ta can contribute to the formation of continuous and compact Al2O3 scales, resulting in an obvious improvement of oxidation resistances at both 923 K and 1073 K. The effects of Mo, Ta and Nb on the oxidation behaviors of the designed alloys at 1073 K were further discussed.
文摘针对Leach(low energy adaptive clustering hierarchy)协议在大规模网络中存在着数据传输效率不高和网络生命周期短的问题,提出了一种LEACH-CM-NGO优化算法。该方法通过在簇头选取阶段优化簇头数在所有节点中占比,引进能量密度因子和能耗因子改进阈值公式优化簇头分布,并在数据传输阶段,由原本的单跳传输改为多跳方式传输数据,引入基于立方映射方法,自适应权重策略和柯西变异的北方苍鹰优化算法改进簇头间数据传输路径,以提高网络的能效和数据传输效率。仿真结果表明,所提出的方法在减少能耗的同时,显著延长了网络的生命周期并提高了数据传输的成功率。
