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Clustering-based temporal deep neural network denoising method for event-based sensors
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作者 LI Jianing XU Jiangtao GAO Jiandong 《Optoelectronics Letters》 2025年第7期441-448,共8页
To enhance the denoising performance of event-based sensors,we introduce a clustering-based temporal deep neural network denoising method(CBTDNN).Firstly,to cluster the sensor output data and obtain the respective clu... To enhance the denoising performance of event-based sensors,we introduce a clustering-based temporal deep neural network denoising method(CBTDNN).Firstly,to cluster the sensor output data and obtain the respective cluster centers,a combination of density-based spatial clustering of applications with noise(DBSCAN)and Kmeans++is utilized.Subsequently,long short-term memory(LSTM)is employed to fit and yield optimized cluster centers with temporal information.Lastly,based on the new cluster centers and denoising ratio,a radius threshold is set,and noise points beyond this threshold are removed.The comprehensive denoising metrics F1_score of CBTDNN have achieved 0.8931,0.7735,and 0.9215 on the traffic sequences dataset,pedestrian detection dataset,and turntable dataset,respectively.And these metrics demonstrate improvements of 49.90%,33.07%,19.31%,and 22.97%compared to four contrastive algorithms,namely nearest neighbor(NNb),nearest neighbor with polarity(NNp),Autoencoder,and multilayer perceptron denoising filter(MLPF).These results demonstrate that the proposed method enhances the denoising performance of event-based sensors. 展开更多
关键词 cluster centers denoising kmeans cluster centersa temporal deep neural network clusterING event based sensors dbscan
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Multi-Order Neighborhood Fusion Based Multi-View Deep Subspace Clustering
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作者 Kai Zhou Yanan Bai +1 位作者 Yongli Hu Boyue Wang 《Computers, Materials & Continua》 2025年第3期3873-3890,共18页
Existing multi-view deep subspace clustering methods aim to learn a unified representation from multi-view data,while the learned representation is difficult to maintain the underlying structure hidden in the origin s... Existing multi-view deep subspace clustering methods aim to learn a unified representation from multi-view data,while the learned representation is difficult to maintain the underlying structure hidden in the origin samples,especially the high-order neighbor relationship between samples.To overcome the above challenges,this paper proposes a novel multi-order neighborhood fusion based multi-view deep subspace clustering model.We creatively integrate the multi-order proximity graph structures of different views into the self-expressive layer by a multi-order neighborhood fusion module.By this design,the multi-order Laplacian matrix supervises the learning of the view-consistent self-representation affinity matrix;then,we can obtain an optimal global affinity matrix where each connected node belongs to one cluster.In addition,the discriminative constraint between views is designed to further improve the clustering performance.A range of experiments on six public datasets demonstrates that the method performs better than other advanced multi-view clustering methods.The code is available at https://github.com/songzuolong/MNF-MDSC(accessed on 25 December 2024). 展开更多
关键词 Multi-view subspace clustering subspace clustering deep clustering multi-order graph structure
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Symplectic symmetry approach to clustering in atomic nuclei:the case of ^(24)Mg
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作者 H G Ganev 《Communications in Theoretical Physics》 2025年第5期118-130,共13页
Symplectic symmetry approach to clustering(SSAC)in atomic nuclei,recently proposed,is modified and further developed in more detail.It is firstly applied to the light two-cluster^(20)Ne+αsystem of^(24)Mg,the latter e... Symplectic symmetry approach to clustering(SSAC)in atomic nuclei,recently proposed,is modified and further developed in more detail.It is firstly applied to the light two-cluster^(20)Ne+αsystem of^(24)Mg,the latter exhibiting well developed low-energy K^(π)=0_(1)^(+),k^(π)=2_(1)^(+) and π^(π)=0_(1)^(-) rotational bands in its spectrum.A simple algebraic Hamiltonian,consisting of dynamical symmetry,residual and vertical mixing parts is used to describe these three lowest rotational bands of positive and negative parity in^(24)Mg.A good description of the excitation energies is obtained by considering only the SU(3)cluster states restricted to the stretched many-particle Hilbert subspace,built on the leading Pauli allowed SU(3)multiplet for the positive-and negative-parity states,respectively.The coupling to the higher cluster-model configurations allows us to describe the known low-lying experimentally observed B(E2)transition probabilities within and between the cluster states of the three bands under consideration without the use of an effective charge. 展开更多
关键词 symplectic symmetry approach to clustering algebraic cluster model microscopic cluster model
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Suzaku Observation of Merging Clusters A222 and A223
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作者 Yanling Chen Wei Cui +2 位作者 Aurora Simionescu Rui Huang Dan Hu 《Research in Astronomy and Astrophysics》 2025年第6期110-119,共10页
Previous X-ray and optical studies of the galaxy cluster pair A222/223 suggested the possible presence of a=lamentary structure connecting the two clusters,a result that appears to be supported by subsequent weak-lens... Previous X-ray and optical studies of the galaxy cluster pair A222/223 suggested the possible presence of a=lamentary structure connecting the two clusters,a result that appears to be supported by subsequent weak-lensing analyses.This=lament has been reported to host a primordial warm-hot intergalactic medium,which existed prior to being heated by the interactions of the clusters.In this study,we made an attempt to examine the reported emission feature with data from an archival Suzaku observation,taking advantage of its low detector background.Because the emission is expected to be very weak,we=rst carefully examined all potential sources of“contamination,”and then modeled the residual emission.Due to large uncertainties,unfortunately,our results can neither con=rm the presence of the reported emission feature nor rule it out.We discuss the sources of uncertainties. 展开更多
关键词 GALAXIES clusterS intracluster medium-X-rays GALAXIES clusters-(cosmology:)large-scale structure of universe
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A novel method for clustering cellular data to improve classification
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作者 Diek W.Wheeler Giorgio A.Ascoli 《Neural Regeneration Research》 SCIE CAS 2025年第9期2697-2705,共9页
Many fields,such as neuroscience,are experiencing the vast prolife ration of cellular data,underscoring the need fo r organizing and interpreting large datasets.A popular approach partitions data into manageable subse... Many fields,such as neuroscience,are experiencing the vast prolife ration of cellular data,underscoring the need fo r organizing and interpreting large datasets.A popular approach partitions data into manageable subsets via hierarchical clustering,but objective methods to determine the appropriate classification granularity are missing.We recently introduced a technique to systematically identify when to stop subdividing clusters based on the fundamental principle that cells must differ more between than within clusters.Here we present the corresponding protocol to classify cellular datasets by combining datadriven unsupervised hierarchical clustering with statistical testing.These general-purpose functions are applicable to any cellular dataset that can be organized as two-dimensional matrices of numerical values,including molecula r,physiological,and anatomical datasets.We demonstrate the protocol using cellular data from the Janelia MouseLight project to chara cterize morphological aspects of neurons. 展开更多
关键词 cellular data clustering dendrogram data classification Levene's one-tailed statistical test unsupervised hierarchical clustering
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Historical Lesson: Environmental and Human Impacts of Cluster Bomb Use by the United States during the Second Indochina War
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作者 Kenneth R. Olson 《Open Journal of Soil Science》 2025年第1期1-21,共21页
The legacy of United States cluster munition use in Laos and Cambodia during the Second Indochina War is residual bomblets that unexpectedly detonate years later, killing and injuring children, farmers, and other civi... The legacy of United States cluster munition use in Laos and Cambodia during the Second Indochina War is residual bomblets that unexpectedly detonate years later, killing and injuring children, farmers, and other civilians. Cluster munitions release dozens of smaller bomblets that rain deadly ammunition on troops, armored tanks, and vegetation, effectively striking broad sections of war zone landscapes in one launch. While many bomblets detonate immediately, others fail to detonate and can lie dormant on the ground for years. The primary objectives of this study were to document the long-term consequences and impacts of the US Air Force bombing of Laos and Cambodia during the Second Indochina War (1959 to 1973). The historical lessons learned by United States should be shared with Russia and Ukraine governments and military. These countries need to discontinue the use of cluster bombs to prevent additional people living along the Russia-Ukraine border from having to live and die with the consequences of unexploded ordnance, including cluster bombs, for the next century. 展开更多
关键词 cluster Munitions ORDNANCE BOMBS Laos cluster Bomblets US Air Force Air America UXO
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Classification of forest vegetation with the application of iterative reallocation and model-based clustering
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作者 Naghmeh Pakgohar Javad Eshaghi Rad +4 位作者 Hossein Gholami Ahmad Alijanpour David W.Roberts Attila Lengyel Enrico Feoli 《Journal of Forestry Research》 2025年第5期103-112,共10页
Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study comp... Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study compares the performance of practical iterative reallocation algorithms with model-based clustering algorithms.The data is from forest vegetation in Virginia(United States),the Hyrcanian Forest(Asia),and European beech forests.Practical iterative reallocation algorithms were applied as non-hierarchical methods and Finite Gaussian mixture modeling was used as a model-based clustering method.Due to limitations on dimensionality in model-based clustering,principal coordinates analysis was employed to reduce the dataset’s dimensions.A log transformation was applied to achieve a normal distribution for the pseudo-species data before calculating the Bray-Curtis dissimilarity.The findings indicate that the reallocation of misclassified objects based on silhouette width(OPTSIL)with Flexible-β(-0.25)had the highest mean among the tested clustering algorithms with Silhouette width 1(REMOS1)with Flexible-β(-0.25)second.However,model-based clustering performed poorly.Based on these results,it is recommended using OPTSIL with Flexible-β(-0.25)and REMOS1 with Flexible-β(-0.25)for forest vegetation classification instead of model-based clustering particularly for heterogeneous datasets common in forest vegetation community data. 展开更多
关键词 CLASSIFICATION Heuristic clustering Finite mixture Forest ecosystems Model-based clustering
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Characterization and clustering of rock discontinuity sets:A review
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作者 Changle Pu Jiewei Zhan +1 位作者 Wen Zhang Jianbing Peng 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第2期1240-1262,共23页
The characterization and clustering of rock discontinuity sets are a crucial and challenging task in rock mechanics and geotechnical engineering.Over the past few decades,the clustering of discontinuity sets has under... The characterization and clustering of rock discontinuity sets are a crucial and challenging task in rock mechanics and geotechnical engineering.Over the past few decades,the clustering of discontinuity sets has undergone rapid and remarkable development.However,there is no relevant literature summarizing these achievements,and this paper attempts to elaborate on the current status and prospects in this field.Specifically,this review aims to discuss the development process of clustering methods for discontinuity sets and the state-of-the-art relevant algorithms.First,we introduce the importance of discontinuity clustering analysis and follow the comprehensive characterization approaches of discontinuity data.A bibliometric analysis is subsequently conducted to clarify the current status and development characteristics of the clustering of discontinuity sets.The methods for the clustering analysis of rock discontinuities are reviewed in terms of single-and multi-parameter clustering methods.Single-parameter methods can be classified into empirical judgment methods,dynamic clustering methods,relative static clustering methods,and static clustering methods,reflecting the continuous optimization and improvement of clustering algorithms.Moreover,this paper compares the current mainstream of single-parameter clustering methods with multi-parameter clustering methods.It is emphasized that the current single-parameter clustering methods have reached their performance limits,with little room for improvement,and that there is a need to extend the study of multi-parameter clustering methods.Finally,several suggestions are offered for future research on the clustering of discontinuity sets. 展开更多
关键词 Discontinuity clustering clustering algorithms Discontinuity characterization Orientation analysis Rock mass
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A Clustering Model Based on Density Peak Clustering and the Sparrow Search Algorithm for VANETs
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作者 Chaoliang Wang Qi Fu Zhaohui Li 《Computers, Materials & Continua》 2025年第8期3707-3729,共23页
Cluster-basedmodels have numerous application scenarios in vehicular ad-hoc networks(VANETs)and can greatly help improve the communication performance of VANETs.However,the frequent movement of vehicles can often lead... Cluster-basedmodels have numerous application scenarios in vehicular ad-hoc networks(VANETs)and can greatly help improve the communication performance of VANETs.However,the frequent movement of vehicles can often lead to changes in the network topology,thereby reducing cluster stability in urban scenarios.To address this issue,we propose a clustering model based on the density peak clustering(DPC)method and sparrow search algorithm(SSA),named SDPC.First,the model constructs a fitness function based on the parameters obtained from the DPC method and deploys the SSA for iterative optimization to select cluster heads(CHs).Then,the vehicles that have not been selected as CHs are assigned to appropriate clusters by comprehensively considering the distance parameter and link-reliability parameter.Finally,cluster maintenance strategies are considered to tackle the changes in the clusters’organizational structure.To verify the performance of the model,we conducted a simulation on a real-world scenario for multiple metrics related to clusters’stability.The results show that compared with the APROVE and the GAPC,SDPC showed clear performance advantages,indicating that SDPC can effectively ensure VANETs’cluster stability in urban scenarios. 展开更多
关键词 VANETS cluster density peak clustering sparrow search algorithm
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Multi-View Picture Fuzzy Clustering:A Novel Method for Partitioning Multi-View Relational Data
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作者 Pham Huy Thong Hoang Thi Canh +2 位作者 Luong Thi Hong Lan Nguyen Tuan Huy Nguyen Long Giang 《Computers, Materials & Continua》 2025年第6期5461-5485,共25页
Multi-view clustering is a critical research area in computer science aimed at effectively extracting meaningful patterns from complex,high-dimensional data that single-view methods cannot capture.Traditional fuzzy cl... Multi-view clustering is a critical research area in computer science aimed at effectively extracting meaningful patterns from complex,high-dimensional data that single-view methods cannot capture.Traditional fuzzy clustering techniques,such as Fuzzy C-Means(FCM),face significant challenges in handling uncertainty and the dependencies between different views.To overcome these limitations,we introduce a new multi-view fuzzy clustering approach that integrates picture fuzzy sets with a dual-anchor graph method for multi-view data,aiming to enhance clustering accuracy and robustness,termed Multi-view Picture Fuzzy Clustering(MPFC).In particular,the picture fuzzy set theory extends the capability to represent uncertainty by modeling three membership levels:membership degrees,neutral degrees,and refusal degrees.This allows for a more flexible representation of uncertain and conflicting data than traditional fuzzy models.Meanwhile,dual-anchor graphs exploit the similarity relationships between data points and integrate information across views.This combination improves stability,scalability,and robustness when handling noisy and heterogeneous data.Experimental results on several benchmark datasets demonstrate significant improvements in clustering accuracy and efficiency,outperforming traditional methods.Specifically,the MPFC algorithm demonstrates outstanding clustering performance on a variety of datasets,attaining a Purity(PUR)score of 0.6440 and an Accuracy(ACC)score of 0.6213 for the 3 Sources dataset,underscoring its robustness and efficiency.The proposed approach significantly contributes to fields such as pattern recognition,multi-view relational data analysis,and large-scale clustering problems.Future work will focus on extending the method for semi-supervised multi-view clustering,aiming to enhance adaptability,scalability,and performance in real-world applications. 展开更多
关键词 Multi-view clustering picture fuzzy sets dual anchor graph fuzzy clustering multi-view relational data
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Generalized Energy-Based Fragmentation DLPNO-CCSD(T)Approach at Complete Basis Set Limit and Its Application to Benzene Clusters
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作者 Yan Sun Benkun Hong +1 位作者 Wei Li Shuhua Li 《Chinese Journal of Chemical Physics》 2025年第3期347-355,I0061-I0105,I0109,共55页
Accurate description of noncova-lent interactions in large systems is challenging due to the require-ment of high-level electron corre-lation methods.The generalized energy-based fragmentation(GEBF)approach,in conjunc... Accurate description of noncova-lent interactions in large systems is challenging due to the require-ment of high-level electron corre-lation methods.The generalized energy-based fragmentation(GEBF)approach,in conjunc-tion with the domain-based local pair natural orbital(DLPNO)method,has been applied to assess the average binding energies(ABEs)of large benzene clus-ters,specifically(C6H6)13,at the coupled cluster singles and doubles with perturbative triples correction[CCSD(T)]level and the complete basis set(CBS)limit.Utilizing GEBF-DLPNO-CCSD(T)/CBS ABEs as benchmarks,various DFT functionals were evaluated.It was found that several functionals with empirical dispersion correction,including M06-2X-D3,B3LYP-D3(BJ),and PBE-D3(BJ),provide accurate descriptions of the ABEs for(C6H6)13 clusters.Additionally,the M06-2X-D3 functional was used to calculate the ABEs and relative stabili-ties of(C6H6)n clusters for n=11,12,13,14,and 15 revealing that the(C6H6)13 cluster ex-hibits the highest relative stability.These findings align with experimental evidence suggest-ing that n=13 is one of the magic numbers for benzene clusters(C6H6)n,with n≤30. 展开更多
关键词 Generalized energy-based fragmentation approach Coupled cluster Complete basis set limit Benzene cluster Dispersion interactions
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Dynamic Clustering Method for Underwater Wireless Sensor Networks based on Deep Reinforcement Learning
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作者 Kohyar Bolvary Zadeh Dashtestani Reza Javidan Reza Akbari 《哈尔滨工程大学学报(英文版)》 2025年第4期864-876,共13页
Underwater wireless sensor networks(UWSNs)have emerged as a new paradigm of real-time organized systems,which are utilized in a diverse array of scenarios to manage the underwater environment surrounding them.One of t... Underwater wireless sensor networks(UWSNs)have emerged as a new paradigm of real-time organized systems,which are utilized in a diverse array of scenarios to manage the underwater environment surrounding them.One of the major challenges that these systems confront is topology control via clustering,which reduces the overload of wireless communications within a network and ensures low energy consumption and good scalability.This study aimed to present a clustering technique in which the clustering process and cluster head(CH)selection are performed based on the Markov decision process and deep reinforcement learning(DRL).DRL algorithm selects the CH by maximizing the defined reward function.Subsequently,the sensed data are collected by the CHs and then sent to the autonomous underwater vehicles.In the final phase,the consumed energy by each sensor is calculated,and its residual energy is updated.Then,the autonomous underwater vehicle performs all clustering and CH selection operations.This procedure persists until the point of cessation when the sensor’s power has been reduced to such an extent that no node can become a CH.Through analysis of the findings from this investigation and their comparison with alternative frameworks,the implementation of this method can be used to control the cluster size and the number of CHs,which ultimately augments the energy usage of nodes and prolongs the lifespan of the network.Our simulation results illustrate that the suggested methodology surpasses the conventional low-energy adaptive clustering hierarchy,the distance-and energy-constrained K-means clustering scheme,and the vector-based forward protocol and is viable for deployment in an actual operational environment. 展开更多
关键词 Underwater wireless sensor network clusterING cluster head selection Deep reinforcement learning
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Reduced-width amplitude in nuclear cluster physics
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作者 De-Ye Tao Bo Zhou 《Nuclear Science and Techniques》 2025年第4期23-44,共22页
As a cluster overlap amplitude,the reduced-width amplitude is an important physical quantity for analyzing clustering in the nucleus depending on specified channels and has been calculated and widely applied in nuclea... As a cluster overlap amplitude,the reduced-width amplitude is an important physical quantity for analyzing clustering in the nucleus depending on specified channels and has been calculated and widely applied in nuclear cluster physics.In this review,we briefly revisit the theoretical framework for calculating the reduced-width amplitude,as well as the outlines of cluster models to obtain microscopic or semi-microscopic cluster wave functions.We also introduce the recent progress related to cluster overlap amplitudes,including the implementation of cross-section estimation and extension to three-body clustering analysis.Comprehensive examples are provided to demonstrate the application of the reduced-width amplitude in analyzing clustering structures. 展开更多
关键词 Nuclear clustering Microscopic cluster model Reduced-width amplitude
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Cluster Federated Learning with Intra-Cluster Correction
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作者 Yunong Yang Long Ma +1 位作者 Liang Fan Tao Xie 《Computers, Materials & Continua》 2025年第8期3459-3476,共18页
Federated learning has emerged as an essential technique of protecting privacy since it allows clients to train models locally without explicitly exchanging sensitive data.Extensive research has been conducted on the ... Federated learning has emerged as an essential technique of protecting privacy since it allows clients to train models locally without explicitly exchanging sensitive data.Extensive research has been conducted on the issue of data heterogeneity in federated learning,but effective model training with severely imbalanced label distributions remains an unexplored area.This paper presents a novel Cluster Federated Learning Algorithm with Intra-cluster Correction(CFIC).First,CFICselects samples fromeach cluster during each round of sampling,ensuring that no single category of data dominates the model training.Second,in addition to updating local models,CFIC adjusts its own parameters based on information shared by other clusters,allowing the final cluster models to better reflect the true nature of the entire dataset.Third,CFIC refines the cluster models into a global model,ensuring that even when label distributions are extremely imbalanced,the negative effects are significantly mitigated,thereby improving the global model’s performance.We conducted extensive experiments on seven datasets and six benchmark algorithms.Theresults show that the CFIC algorithm has a higher generalization ability than the benchmark algorithms.CFIC maintains high accuracy and rapid convergence rates even in a variety of non-independent identically distributed label skew distribution settings.The findings indicate that the proposed algorithm has the potential to become a trustworthy and practical solution for privacy preservation,whichmight be applied to fields such as medical image analysis,autonomous driving technologies,and intelligent educational platforms. 展开更多
关键词 Federated learning non-IID client clustering intra-cluster correction
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Energy Efficient Clustering and Sink Mobility Protocol Using Hybrid Golden Jackal and Improved Whale Optimization Algorithm for Improving Network Longevity in WSNs
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作者 S B Lenin R Sugumar +2 位作者 J S Adeline Johnsana N Tamilarasan R Nathiya 《China Communications》 2025年第3期16-35,共20页
Reliable Cluster Head(CH)selectionbased routing protocols are necessary for increasing the packet transmission efficiency with optimal path discovery that never introduces degradation over the transmission reliability... Reliable Cluster Head(CH)selectionbased routing protocols are necessary for increasing the packet transmission efficiency with optimal path discovery that never introduces degradation over the transmission reliability.In this paper,Hybrid Golden Jackal,and Improved Whale Optimization Algorithm(HGJIWOA)is proposed as an effective and optimal routing protocol that guarantees efficient routing of data packets in the established between the CHs and the movable sink.This HGJIWOA included the phases of Dynamic Lens-Imaging Learning Strategy and Novel Update Rules for determining the reliable route essential for data packets broadcasting attained through fitness measure estimation-based CH selection.The process of CH selection achieved using Golden Jackal Optimization Algorithm(GJOA)completely depends on the factors of maintainability,consistency,trust,delay,and energy.The adopted GJOA algorithm play a dominant role in determining the optimal path of routing depending on the parameter of reduced delay and minimal distance.It further utilized Improved Whale Optimisation Algorithm(IWOA)for forwarding the data from chosen CHs to the BS via optimized route depending on the parameters of energy and distance.It also included a reliable route maintenance process that aids in deciding the selected route through which data need to be transmitted or re-routed.The simulation outcomes of the proposed HGJIWOA mechanism with different sensor nodes confirmed an improved mean throughput of 18.21%,sustained residual energy of 19.64%with minimized end-to-end delay of 21.82%,better than the competitive CH selection approaches. 展开更多
关键词 cluster Heads(CHs) Golden Jackal Optimization Algorithm(GJOA) Improved Whale Optimization Algorithm(IWOA) unequal clustering
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Ligand-engineered octanuclear bismuth-oxo clusters with exposed active sites for enhanced CO_(2)-to-HCOOH electroreduction
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作者 Hao-Nan Zhou Lan-Yan Li +3 位作者 Hong-Bing Mo Yi-Xin Li Jun Yan Chao Liu 《Chinese Chemical Letters》 2025年第10期661-665,共5页
The atomic-level exploration of structure-property correlations poses significant challenges in establishing precise design principles for electrocatalysts targeting efficient CO_(2)conversion.This study demonstrates ... The atomic-level exploration of structure-property correlations poses significant challenges in establishing precise design principles for electrocatalysts targeting efficient CO_(2)conversion.This study demonstrates how controlled exposure of metal sites governs CO_(2)electroreduction performance through two octanuclear bismuth-oxo clusters with distinct architectures.The Bi_(8)-DMF cluster,constructed using tert–butylthiacalix[4]arene(TC4A)as the sole ligand,features two surface-exposed Bi active sites,while the dual-ligand Bi_(8)-Fc(with TC4A/ferrocene carboxylate)forms a fully encapsulated structure.Electrocatalytic tests reveal Bi_(8)-DMF achieves exceptional formate selectivity(>90%Faradaic efficiency)across a broad potential window(-0.9 V to-1.6 V vs.RHE)with 20 h stability,outperforming Bi_(8)-Fc(60%efficiency at-1.5 V).Theoretical calculations attribute Bi_(8)-DMF's superiority to exposed Bi sites that stabilize the critical*OCHO intermediate via optimized orbital interactions.This work provides crucial guidance for polynuclear catalyst design:moderate exposure of metal active sites significantly enhances CO_(2)reduction performance. 展开更多
关键词 Nanocluster Bismuth-oxo clusters CO_(2)electroreduction Formic acid Ligand engineering
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Cu cluster@UiO-66团簇负载型催化剂促进光催化CO_(2)加氢反应 被引量:2
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作者 王秀林 岐少鹏 +6 位作者 周昆 邓希 姚辉超 戴若云 张雨晴 伍思达 聂锁府 《分子催化(中英文)》 北大核心 2025年第2期111-119,I0001,共10页
针对高活性Cu基团簇(Cu cluster)催化剂的稳定性问题,利用MOFs材料独特的结构限域作用,将Cu团簇锚定在UiO-66中,构建了Cu cluster@UiO-66复合材料,改善了催化剂的稳定性和催化活性.在该复合结构中,UiO-66不仅可作为吸光单元捕获太阳光... 针对高活性Cu基团簇(Cu cluster)催化剂的稳定性问题,利用MOFs材料独特的结构限域作用,将Cu团簇锚定在UiO-66中,构建了Cu cluster@UiO-66复合材料,改善了催化剂的稳定性和催化活性.在该复合结构中,UiO-66不仅可作为吸光单元捕获太阳光形成光生载流子,而且UiO-66的多孔结构可以有效稳定Cu团簇,保证其微观尺度上的高度分散和结构稳定.研究发现,在光催化反应过程中,UiO-66的光生电子可快速转移至Cu团簇,进而以Cu团簇作为催化活性位点驱动CO_(2)还原反应.得益于复合材料中高效的电荷转移和稳定的团簇活性位点结构,光催化CO_(2)加氢反应活性明显增强.本研究为合成MOFs负载型团簇材料提供了新的思路. 展开更多
关键词 复合结构 UiO-66 铜纳米簇 光催化CO_(2)还原
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FedCPS:A Dual Optimization Model for Federated Learning Based on Clustering and Personalization Strategy 被引量:1
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作者 Zhen Yang Yifan Liu +2 位作者 Fan Feng Yi Liu Zhenpeng Liu 《Computers, Materials & Continua》 2025年第4期357-380,共24页
Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients a... Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients and the server.However,the presence of data heterogeneity can lead to inefficient model training and even reduce the final model’s accuracy and generalization capability.Meanwhile,data scarcity can result in suboptimal cluster distributions for few-shot clients in centralized clustering tasks,and standalone personalization tasks may cause severe overfitting issues.To address these limitations,we introduce a federated learning dual optimization model based on clustering and personalization strategy(FedCPS).FedCPS adopts a decentralized approach,where clients identify their cluster membership locally without relying on a centralized clustering algorithm.Building on this,FedCPS introduces personalized training tasks locally,adding a regularization term to control deviations between local and cluster models.This improves the generalization ability of the final model while mitigating overfitting.The use of weight-sharing techniques also reduces the computational cost of central machines.Experimental results on MNIST,FMNIST,CIFAR10,and CIFAR100 datasets demonstrate that our method achieves better personalization effects compared to other personalized federated learning methods,with an average test accuracy improvement of 0.81%–2.96%.Meanwhile,we adjusted the proportion of few-shot clients to evaluate the impact on accuracy across different methods.The experiments show that FedCPS reduces accuracy by only 0.2%–3.7%,compared to 2.1%–10%for existing methods.Our method demonstrates its advantages across diverse data environments. 展开更多
关键词 Federated learning cluster PERSONALIZATION OVERFITTING
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Boron cluster-based TADF emitter via through-space charge transfer enabling efficient orange-red electroluminescence 被引量:1
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作者 Xiao Yu Dongyue Cui +8 位作者 Mengmeng Wang Zhaojin Wang Mengzhu Wang Deshuang Tu Vladimir Bregadze Changsheng Lu Qiang Zhao Runfeng Chen Hong Yan 《Chinese Chemical Letters》 2025年第3期232-238,共7页
Thermally activated delayed fluorescence(TADF)materials driven by a through-space charge transfer(TSCT)mechanism have garnered wide interest.However,access of TSCT-TADF molecules with longwavelength emission remains a... Thermally activated delayed fluorescence(TADF)materials driven by a through-space charge transfer(TSCT)mechanism have garnered wide interest.However,access of TSCT-TADF molecules with longwavelength emission remains a formidable challenge.In this study,we introduce a novel V-type DA-D-A’emitter,Trz-mCzCbCz,by using a carborane scaffold.This design strategically incorporates carbazole(Cz)and 2,4,6-triphenyl-1,3,5-triazine(Trz)as donor and acceptor moieties,respectively.Theoretical calculations alongside experimental validations affirm the typical TSCT-TADF characteristics of this luminogen.Owing to the unique structural and electronic attributes of carboranes,Trz-mCzCbCz exhibits an orange-red emission,markedly diverging from the traditional blue-to-green emissions observed in classical Cz and Trz-based TADF molecules.Moreover,bright emission in aggregates was observed for Trz-mCzCbCz with absolute photoluminescence quantum yield(PLQY)of up to 88.8%.As such,we have successfully fabricated five organic light-emitting diodes(OLEDs)by utilizing Trz-mCzCbCz as the emitting layer.It is important to note that both the reverse intersystem crossing process and the TADF properties are profoundly influenced by host materials.The fabricated OLED devices reached a maximum external quantum efficiency(EQE)of 12.7%,with an emission peak at 592 nm.This represents the highest recorded efficiency for TSCT-TADF OLEDs employing carborane derivatives as emitting layers. 展开更多
关键词 Thermally activated delayed fluorescence Through-space charge transfer CARBORANE Boron clusters Organic light-emitting diodes
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Clustering optimization strategy for cooperative positioning system aided by UAV 被引量:1
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作者 Hongbo ZHAO Zeqi YIN Shan HU 《Chinese Journal of Aeronautics》 2025年第9期421-435,共15页
For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Veh... For multi-vehicle networks,Cooperative Positioning(CP)technique has become a promising way to enhance vehicle positioning accuracy.Especially,the CP performance could be further improved by introducing Sensor-Rich Vehicles(SRVs)into CP networks,which is called SRV-aided CP.However,the CP system may split into several sub-clusters that cannot be connected with each other in dense urban environments,in which the sub-clusters with few SRVs will suffer from degradation of CP performance.Since Unmanned Aerial Vehicles(UAVs)have been widely used to aid vehicular communications,we intend to utilize UAVs to assist sub-clusters in CP.In this paper,a UAV-aided CP network is constructed to fully utilize information from SRVs.First,the inter-node connection structure among the UAV and vehicles is designed to share available information from SRVs.After that,the clustering optimization strategy is proposed,in which the UAV cooperates with the high-precision sub-cluster to obtain available information from SRVs,and then broadcasts this positioning-related information to other low-precision sub-clusters.Finally,the Locally-Centralized Factor Graph Optimization(LC-FGO)algorithm is designed to fuse positioning information from cooperators.Simulation results indicate that the positioning accuracy of the CP system could be improved by fully utilizing positioning-related information from SRVs. 展开更多
关键词 clustering optimization Cooperative positioning Locally-centralized FGO Networking wireless sensors Unmanned aerial vehicles Urban degradation environments
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