A series of new pentanary inorganic supramolecular sulfides(A_(3)X)[MB_(12)(MS_(4))_(3)](A=K,Cs;X=Cl,Br,I;M=Ga,In,Gd)have been synthesized using high-temperature solid-state reactions.They crystallize in the noncentro...A series of new pentanary inorganic supramolecular sulfides(A_(3)X)[MB_(12)(MS_(4))_(3)](A=K,Cs;X=Cl,Br,I;M=Ga,In,Gd)have been synthesized using high-temperature solid-state reactions.They crystallize in the noncentrosymmetric hexagonal space group P6_(3)22.展开更多
基金the financial support from the Natural Science Foundation of China(21673203 and 21771159)the Higher Education Science Foundation of Jiangsu Province(15KJB150031)the Natural Science Foundation of Yangzhou(YZ2016122),the Qing Lan Project and the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘A series of new pentanary inorganic supramolecular sulfides(A_(3)X)[MB_(12)(MS_(4))_(3)](A=K,Cs;X=Cl,Br,I;M=Ga,In,Gd)have been synthesized using high-temperature solid-state reactions.They crystallize in the noncentrosymmetric hexagonal space group P6_(3)22.
