The hydrogen abstraction reaction F+CH3OH has two possible reaction pathways: HF+CH3O and HF+CH2OH. Despite the absence of intrinsic barriers for both channels, the former has a branching ratio comparable to the latte...The hydrogen abstraction reaction F+CH3OH has two possible reaction pathways: HF+CH3O and HF+CH2OH. Despite the absence of intrinsic barriers for both channels, the former has a branching ratio comparable to the latter, which is far from the statistical limit of 0.25 (one out of four available H atoms). Furthermore, the measured branching ratio of the two abstraction channels spans a large range and is not quantitatively reproduced by previous theoretical predictions based on the transition-state theory with the stationary point information calculated at the levels of MФller-Plesset perturbation theory and G2. This work reports a theoretical investigation on the kinetics and the associated branching ratio of the two competing channels of the title reaction using a quasi-classical trajectory approach on an accurate full-dimensional potential energy surface (PES) fitted by the permutation invariant polynomial-neural network approach to ca. 1.21x10^5 points calculated at the explicitly correlated (F12a) version of coupled cluster singles doubles and perturbative triples (CCSD(T)) level with the aug-cc-pVDZ basis set. The calculated room temperature rate coeffcient and branching ratio of the HF+CH3O channel are in good agreement with the available experimental data. Furthermore, our theory predicts that rate coeffcients have a slightly negative temperature dependence, consistent with barrierless nature of the reaction.展开更多
To investigate the evolution of load-bearing characteristics of pre-stressed beams throughout their service life and to provide a basis for accurately assessing the actual working state of damaged pre-stressed concret...To investigate the evolution of load-bearing characteristics of pre-stressed beams throughout their service life and to provide a basis for accurately assessing the actual working state of damaged pre-stressed concrete T-beams,destructive tests were conducted on full-scale pre-stressed concrete beams.Based on the measurement and ana-lysis of beam deflection,strain,and crack development under various loading levels during the research tests,combined with the verification coefficient indicators specified in the codes,the verification coefficients of bridges at different stages of damage can be examined.The results indicate that the T-beams experience complete,incom-plete linear,and non-linear stages during the destructive test process.In the complete linear elastic stage,both the deflection and bottom strain verification coefficients comply with the specifications,indicating a good structural load-bearing capacity no longer adheres to the code’s requirements.In the non-linear stage,both coefficients exhi-bit a sharp increase,resulting in a further decrease in the structure’s load-bearing capacity.According to the pro-visions of the current code,the beam can be in the incomplete linear stage when both values fall within the code’s specified range.The strain verification coefficient sourced from the compression zone at the bottom of theflange is not recommended for assessing the bridge’s load-bearing capacity.展开更多
The utilization of nuclear power will persist as a prominent energy source in the foreseeable future.However,it presents substantial challenges concerning waste disposal and the potential emission of untreated radioac...The utilization of nuclear power will persist as a prominent energy source in the foreseeable future.However,it presents substantial challenges concerning waste disposal and the potential emission of untreated radioactive substances,such as radioactive 129I and 131I.The transportation of radioactive iodine poses a significant threat to both the environment and human health.Nevertheless,effectively,rapidly removing iodine ion from water using porous adsorbents remains a crucial challenge.In this work,three kinds of multiple sites porous organic polymers(POPs,POP-1,POP-2,and POP-3)have been developed using a monomer pre-modification strategy for highly efficient and fast I_(3) absorption from water.It is found that the POPs exhibited exceptional performance in terms of I3 adsorption,achieving a top-performing adsorption capacity of 5.25 g g^(-1) and the fastest average adsorption rate(K_(80%)=4.25 g g^(-1) h^(-1))with POP-1.Moreover,POP-1 exhibited exceptional capacity for the removal of I3 fromflowing aqueous solutions,with 95%removal efficiency observed even at 0.0005 mol L^(-1).Such results indicate that this material has the potential to be utilized for the emergency preparation of potable water in areas contaminated with radioactive iodine.The adsorption process can be effectively characterized by the Freundlich model and the pseudo-second-order model.The exceptional I_(3) absorption capacity is primarily attributed to the incorporation of a substantial number of active adsorption sites,including bromine,carbonyl,and amide groups.展开更多
Monocrystalline Cu exhibits excellent electrical and signal-transmission properties due to its absence of grain boundaries,making it a critical material for the production of micro-machinery and micro-components;howev...Monocrystalline Cu exhibits excellent electrical and signal-transmission properties due to its absence of grain boundaries,making it a critical material for the production of micro-machinery and micro-components;however,achieving ultrahigh precision and ultralow damage machining of functional devices using traditional techniques such as grinding and polishing is extremely challenging.Consequently,nanocutting has emerged as an efficient means to fabricate monocrystalline materials with complex surface characteristics and high surface integrity.Nevertheless,the macroscopic cutting theory of metal materials cannot be applied to nanocutting.Accordingly,in this paper,both simulations and experiments were conducted to examine the chip deformation mechanisms of monocrystalline Cu.First,large-scale molecular dynamics(MD)simulations were conducted to gain a comprehensive understanding of the deformation behavior during nanocutting.This included examining the influencing factors and the variation patterns of the chip deformation coefficient,cutting force,and minimum cutting thickness.Subsequently,nanocutting experiments were performed using a specially designed nanocutting platform with high-resolution online observation by scanning electron microscopy.The experimental results served to verify the accuracy and reliability of theMDmodeling,as they exhibited excellent consistency with the simulated results.Although this work considered monocrystalline Cu,it is believed that the elucidated chip deformation mechanisms could also be applied to other face-centered-cubic metals.These results are of great value for advancing the understanding of the mechanisms of ultraprecision cutting.展开更多
High-temperature thin-film strain sensors are advanced technological devices for monitoring stress and strain in extreme environments,but the coupling of temperature and strain at high temperature is a challenge for t...High-temperature thin-film strain sensors are advanced technological devices for monitoring stress and strain in extreme environments,but the coupling of temperature and strain at high temperature is a challenge for their use.Here,this issue is addressed by creating a composite ink that combines Pb_(2)Ru_(2)O_(6) and TiB_(2) using polysilazane(PSZ)as a binder.After direct writing and annealing the PSZ/Pb_(2)Ru_(2)O_(6)/TiB_(2) film at 800℃ in air,the resulting thin film exhibits a low temperature coefficient of resistance(TCR)of only 281 ppm/℃ over a wide temperature range from 100℃ to 700℃,while also demonstrating high sensitivity with a gauge factor approaching 19.8.This exceptional performance is attributed to the intrinsic properties of Pb_(2)Ru_(2)O_(6),which has positive TCR at high temperature,and TiB2,which has negative TCR at high temperature.Combining these materials reduces the overall TCR of the film.Tests showed that the PSZ/Pb_(2)Ru_(2)O_(6)/TiB_(2) film maintains stable strain responses and significant signal output even under varying temperature.These findings provide valuable insights for developing high-temperature strain sensors with low TCR and high sensitivity,highlighting their potential for applications in high-temperature strain measurements.展开更多
This study analyzed and compared variations of the sulcus and otolith outlines of three geographic stocks(Huanghe(Yellow)River estuary(HHE),Jiaozhou Bay(JZB),and Changjiang(Yangtze)River estuary(CJE))of white croaker ...This study analyzed and compared variations of the sulcus and otolith outlines of three geographic stocks(Huanghe(Yellow)River estuary(HHE),Jiaozhou Bay(JZB),and Changjiang(Yangtze)River estuary(CJE))of white croaker Pennahia argentata in northern Chinese coastal waters.The sulcus and otolith outline analyses via elliptical Fourier transform(EFT,i.e.,outline analysis)achieved an overall classifi cation rate of 80.4%and 87.2%,respectively.Based on a combination of sulcus and otolith shape indices(SIs)and two derivative ratios,a moderate discriminatory effi ciency of 64.7%was obtained.The results indicate that sulcus outline analysis could be used alone to discriminate white croaker stocks,and that both sulcus and otolith outline analyses discriminated the fi sh stocks at a higher classifi cation rate than the shape indices.The sulcus outline analysis provided complementary information to the whole otolith outline analysis for stock discrimination.Both the sulcus and otolith outline analyses effi ciently discriminated between the most geographically separated CJE and HHE stocks,indicating that they could be considered discrete stocks for fi shery management.展开更多
The current research on gear system dynamics mainly utilizes linear spring damping model to calculate the contact force between gears. However, this linear model cannot correctly describe the energy transfer process o...The current research on gear system dynamics mainly utilizes linear spring damping model to calculate the contact force between gears. However, this linear model cannot correctly describe the energy transfer process of collision that often occurs in gear system. Focus on the contact-impact events, this paper proposes an improved gear contact force model for dynamic analysis in helical gear transmission system. In this model, a new factor associated with hysteresis damping is developed for contact-impact state, whereas the traditional linear damping factor is utilized for normal meshing state. For determining the selection strategy of these two damping factors, the fundamental contact mechanics of contact-impact event a ected by supporting forces are analyzed. During this analysis, an e ect factor is proposed for evaluating the influence of supporting forces on collision. Meanwhile, a new restitution of coe cient is deduced for calculating hysteresis damping factor, which suitable for both separation and non-separation states at the end of collision. In addition, the time-varying meshing sti ness(TVMS) is obtained based on the potential energy approach and the slice theory. Finally, a dynamic analysis of a helical gear system is carried out to better understand the contact force model proposed in this paper. The analysis results show that the contribution of supporting forces to the dynamic response of contact-impact event within gear pair is important. The supporting forces and dissipative energy are the main reasons for gear system to enter a steady contact state from repeated contact-impact state. This research proposes an improved contact force model which distinguishes meshing and collision states in gear system.展开更多
In aluminum-copper alloy, the segregation has a severe bad effect on the alloying degree, strength and corrosion resistance. A deeper understanding of element segregation behavior will have a great signif icance on th...In aluminum-copper alloy, the segregation has a severe bad effect on the alloying degree, strength and corrosion resistance. A deeper understanding of element segregation behavior will have a great signif icance on the prevention of segregation. In the study, the element segregation behavior of ZL205 A aluminum-copper alloy was investigated by examining isothermally solidifi ed samples using scanning electron microscopy and energy dispersive spectroscopy. The calculated results of segregation coeffi cients show that Cu and Mn are negative segregation elements; while Ti, V and Zr are positive segregation elements. The sequence of element segregation degree from the greatest to the least in ZL205 A alloy is Cu, Mn, V, Ti, Zr and Al. The density of residual liquid is expected to increase with a decrease in the quenching temperature ranging from 630 ℃ to 550 ℃. The calculated results conf irm that the quenching temperature has an insignif icant effect on the liquid density; and the variation of density is mainly due to element segregation. Consequently, segregations of Al, Cu and Mn lead to an increase in density, but Ti, V and Zr present the opposite effect. The contribution of each element to the variation of the liquid density was analyzed. The sequence of contributions of alloying elements to the variation of total liquid density is Cu>Al>Mn>V>Ti>Zr.展开更多
Coal seams have a pronounced bedding structure with developed cracks and exhibit signifi cant anisotropy.However,few studies have examined the frequency dispersion properties of channel waves in anisotropic coal seams...Coal seams have a pronounced bedding structure with developed cracks and exhibit signifi cant anisotropy.However,few studies have examined the frequency dispersion properties of channel waves in anisotropic coal seams.In this study,numerical solutions are calculated using the generalized reflection–transmission coefficient method for the dispersion curves of Love channel waves in vertical transversely isotropic(VTI)and horizontal transversely isotropic(HTI)medium models.Moreover,the frequency dispersion characteristics of Love channel waves in several typical transversely isotropic models are analyzed.We fi nd that the dispersion curves for isotropic and VTI media diff er signifi cantly.In addition,the phase and Airy-phase velocities in VTI media are higher than those in isotropic media.Thus,neglecting this difference in practical channel wave detection will result in large detection errors.The dispersion curves for the isotropic and HTI media do not differ signifi cantly,and the Airy-phase velocities of various modes are similar.The group-velocity curve for a coal seam model containing a dirt band is found to be extremely irregular.The fundamental-mode Airy phase is not pronounced,but the fi rst-mode Airy phase can be clearly observed.Hence,fi rst-mode channel waves are suitable for detecting dirt bands.展开更多
Precise quantifi cation of climate-growth relationships can make a major contribution to scientifi c forest management.However,whether diff erences in the response of growth to climate at diff erent altitudes remains ...Precise quantifi cation of climate-growth relationships can make a major contribution to scientifi c forest management.However,whether diff erences in the response of growth to climate at diff erent altitudes remains unclear.To answer this,264 trees of Larix kaempferi from 88 plots,representing diff erent altitudinal ranges(1000-2100 m)and tree classes were sampled and used to develop tree-ring chronologies.Tree-ring growth(TRG)was either positively(dominant)or negatively(intermediate and suppressed)correlated with climate in diff erent tree classes at diff erent altitudes.TRG was strongly correlated with growing season at low altitudes,but was less sensitive to climate at middle altitudes.It was mainly limited by precipitation and was highly sensitive to climate at low altitudes.Climate-growth relationships at high altitudes were opposite compared to those at low altitudes.TRG of dominant trees was more sensitive to climate change compared to intermediate and suppressed trees.Climate factors(annual temperatures;moisture,the number of frost-free days)had diff erent eff ects on tree-ring growth of diff erent tree classes along altitudinal gradients.It was concluded that the increase in summer temperatures decreased water availability,resulting in a signifi cant decline in growth rates after 2005 at lower altitudes.L.kaempferi is suitable for planting in middle altitudes and dominant trees were the best sampling choice for accurately assessing climate-growth relationships.展开更多
We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 104...We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.展开更多
NH_(2)-UIO66(NU)is a promising photocatalyst for the reduction of Cr(VI)to low-toxic Cr(III)driven by visible light under ambient conditions.However,the main limitation in this process is the ineffi cient ligand to me...NH_(2)-UIO66(NU)is a promising photocatalyst for the reduction of Cr(VI)to low-toxic Cr(III)driven by visible light under ambient conditions.However,the main limitation in this process is the ineffi cient ligand to metal charge transfer(LMCT)of photo-excited electrons,which is caused by inherent energy gap(ΔE_(LMCT)).This study synthesized the defective NU(NUXH,where X is the molar equivalent of the modulator)with reducedΔE_(LMCT)through linkers removal via acid treatment.The electronic structure of NUX-H was systematically investigated,and the results indicated that the structural defects in NUX-H strongly altered the environment of the Zr atoms.Furthermore,they substantially lowered the energy of the unoccupied d orbitals(LUMO),which was benefi cial to effi cient LMCT,resulting in an improved photocatalytic activity of NUX-H toward high-concentration(100 mg/L)Cr(VI)reduction.Compared to NU with defect-free structure,the reducing rate of Cr(VI)was increased by 47 times.This work introduced an alternative strategy in terms of designing effi cient photocatalysts for reducing Cr(VI)under ambient conditions.展开更多
A numerical solution based on the Steffensen stable point iterative method is proposed to resolve the transcendental frequency equation of a stay cable-damper system. The frequency equation, which considers clamped su...A numerical solution based on the Steffensen stable point iterative method is proposed to resolve the transcendental frequency equation of a stay cable-damper system. The frequency equation, which considers clamped supports and fl exural rigidity of the cable, is intended to investigate the infl uence of the parameters of the cable damper system on its dynamic characteristics. Two factors involved in the design and construction phases, the damping coeffi cient induced by external dampers and the cable tension, are the focus of this study. Their impact on modal frequencies and damping ratios in these two phases of cable-damper systems are investigated by resolving the equation with the proposed solution. It is shown that the damping coeffi cient and cable tension exert more noticeable effects on the modal damping ratios than on the modal frequencies of stay cable-damper systems, and the two factors can serve as design variables in the design phase and as adjustment factors in the construction phase. On the basis of the results, a roadmap for system-level optimal design of stay cable-damper systems that can achieve global optimal vibration suppression for the entire bridge is proposed and discussed.展开更多
The paper attempts to analyze full load characteristics of over 500 combustion engines. Using statistical tools, the author determined the value of the coe cient of flexibility. Engine flexibility is the capability of...The paper attempts to analyze full load characteristics of over 500 combustion engines. Using statistical tools, the author determined the value of the coe cient of flexibility. Engine flexibility is the capability of the engine to adapt to varying loads. Importantly, in the investigations, the author took into account the parameters calculated in the course of the investigations on a chassis dynamometer, i.e., actual, not taken from technical specifications of brand new vehicles. Di erent stages of operating wear allow a better characterization of the population. Subsequent utilization of the results in tractive calculations is more reliable. The engines were divided into in six groups, depending on the type of fuel system: fuel injected gasoline and turbocharged gasoline, spark ignition LPG, naturally aspirated diesel and turbocharged diesel. However, engines running on alternative fuels are characterized with a greater flexibility than the fuel injected base engines. Conformity of flexibility of fuel injected and LPG IV generation engines have been observed,which confirms the appropriateness of engine adaptation to alternative fueling. Gasoline engine supercharging allowed a reduction of the maximum engine speed of the maximum torque, which extends the range of analyzable speeds for flexibility and consequently, the flexibility as such.展开更多
Accurate determination of the optical properties of biological tissues enables quantitative understanding of light propagation in these tissues for optical diagnosis and treatment applications.The absorption(μa)and s...Accurate determination of the optical properties of biological tissues enables quantitative understanding of light propagation in these tissues for optical diagnosis and treatment applications.The absorption(μa)and scattering(μs)coe±cients of biological tissues are inversely analyzed from their diffuse re°ectance(R)and total transmittance(T),which are measured using a double integrating spheres(DIS)system.The inversion algorithms,for example,inverse adding doubling method and inverse Monte Carlo method,are sensitive to noise signals during the DIS measurements,resulting in reduced accuracy during determination.In this study,we propose an arti ficial neural network(ANN)to estimateμa andμs at a target wavelength from the R and T spectra measured via the DIS to reduce noise in the optical properties.Approximate models of the optical properties and Monte Carlo calculations that simulated the DIS measurements were used to generate spectral datasets comprisingμa,μs,R and T.Measurement noise signals were added to R and T,and the ANN model was then trained using the noise-added datasets.Numerical results showed that the trained ANN model reduced the effects of noise inμa andμs estimation.Experimental veri fication indicated noise-reduced estimation from the R and T values measured by the DIS with a small number of scans on average,resulting in measurement time reduction.The results demonstrated the noise robustness of the proposed ANN-based method for optical properties determination and will contribute to shorter DIS measurement times,thus reducing changes in the optical properties due to desiccation of the samples.展开更多
Community renewal in the new era of transformation has entered the stage of stock planning,and user demand for high-quality urban life is becoming more and more urgent.This study constructed a community renewal method...Community renewal in the new era of transformation has entered the stage of stock planning,and user demand for high-quality urban life is becoming more and more urgent.This study constructed a community renewal method that considers user satisfaction and its differences.Through the community survey data,we analyzed the satisfaction and differences of user needs,found out key problems and focus groups,and proposed improvement strategies.Taking the Anju Dongcheng Community in Handan City as an example,the overall satisfaction of user groups,the satisfaction of users of different ages and their differences were analyzed.It is concluded that the main problems were the health and environmental problem,in which the focus of dog keeping were young and old people,and the focus of garbage classification problem were young and middle-aged people.Finally,the corresponding renewal strategies and designs were put forward to improve the quality of community living environment.展开更多
The CO_(2)effl ux of branches and leaves plays an important role in ecosystem carbon balance.Using a carbon fl ux system,the effl ux of Larix gmelinii var.principisrupprechtii(Dahurian larch)was investigated in 27 yea...The CO_(2)effl ux of branches and leaves plays an important role in ecosystem carbon balance.Using a carbon fl ux system,the effl ux of Larix gmelinii var.principisrupprechtii(Dahurian larch)was investigated in 27 years(immature),31 years(near-mature),and 47 years(mature)stands at diurnal,seasonal,and spatial scales(direction and height)as well as its connection with environmental factors from May to October 2020.Diurnal variation in effl ux was a single peak,and the maximum occurring between 14:00 and 16:00.Seasonal variation also exhibited a single peak,with the maximum in late July and the minimum in early October.From May to September,effl ux on the south side was the largest among the three stands,and mean values on the south side of 27 year-old,31 year-old,and 47 year-old trees were 0.50,0.97 and 1.05μmol·m^(–2)·s^(–1),respectively.The minimum occurred on the north side.Except for the maximum in July and September in the 27 year-old stand in the middle of the canopy,the maximum effl ux in the upper canopy,and the means in the 27 year-old,31 year-old,and 47 year-old stands were 0.49,0.96 and 1.04μmol·m^(-2)·s^(-1),respectively;the minimum occurred in the lower canopy.Temperatures and relative humidity infl uenced seasonal variations in effl ux.Seasonal variation in temperature sensitivity coeffi cient(Q 10)was opposite that of temperature,increasing with decreasing temperature.At the spatial scale,maximum Q 10 occurred in the mid canopy.With the effl ux and temperature data in diff erent locations,it is possible to better estimate effl ux variations in each stand.展开更多
Wireless Sensor Networks(WSN)have revolutionized the processes involved in industrial communication.However,the most important challenge faced by WSN sensors is the presence of limited energy.Multiple research inves-t...Wireless Sensor Networks(WSN)have revolutionized the processes involved in industrial communication.However,the most important challenge faced by WSN sensors is the presence of limited energy.Multiple research inves-tigations have been conducted so far on how to prolong the energy in WSN.This phenomenon is a result of inability of the network to have battery powered-sensor terminal.Energy-efficient routing on packetflow is a parallel phenomenon to delay nature,whereas the primary energy gets wasted as a result of WSN holes.Energy holes are present in the vicinity of sink and it is an important efficient-routing protocol for WSNs.In order to solve the issues discussed above,an energy-efficient routing protocol is proposed in this study named as Adaptive Route Decision Sink Relocation Protocol using Cluster Head Chain Cycling approach(ARDSR-CHC2H).The proposed method aims at improved communica-tion at sink-inviting routes.At this point,Cluster Head Node(CHN)is selected,since it consumes low energy and permits one node to communicate with others in two groups.The main purpose of the proposed model is to reduce energy con-sumption and define new interchange technology.A comparison of simulation results demonstrates that the proposed algorithm achieved low cluster creation time,better network error and high Packet Delivery Rate with less network failure.展开更多
基金supported by the National Natural Science Foundation of China (No.21573027 to Jun Li)the US Department of Energy (DE-SC0015997 to Hua Guo)
文摘The hydrogen abstraction reaction F+CH3OH has two possible reaction pathways: HF+CH3O and HF+CH2OH. Despite the absence of intrinsic barriers for both channels, the former has a branching ratio comparable to the latter, which is far from the statistical limit of 0.25 (one out of four available H atoms). Furthermore, the measured branching ratio of the two abstraction channels spans a large range and is not quantitatively reproduced by previous theoretical predictions based on the transition-state theory with the stationary point information calculated at the levels of MФller-Plesset perturbation theory and G2. This work reports a theoretical investigation on the kinetics and the associated branching ratio of the two competing channels of the title reaction using a quasi-classical trajectory approach on an accurate full-dimensional potential energy surface (PES) fitted by the permutation invariant polynomial-neural network approach to ca. 1.21x10^5 points calculated at the explicitly correlated (F12a) version of coupled cluster singles doubles and perturbative triples (CCSD(T)) level with the aug-cc-pVDZ basis set. The calculated room temperature rate coeffcient and branching ratio of the HF+CH3O channel are in good agreement with the available experimental data. Furthermore, our theory predicts that rate coeffcients have a slightly negative temperature dependence, consistent with barrierless nature of the reaction.
文摘To investigate the evolution of load-bearing characteristics of pre-stressed beams throughout their service life and to provide a basis for accurately assessing the actual working state of damaged pre-stressed concrete T-beams,destructive tests were conducted on full-scale pre-stressed concrete beams.Based on the measurement and ana-lysis of beam deflection,strain,and crack development under various loading levels during the research tests,combined with the verification coefficient indicators specified in the codes,the verification coefficients of bridges at different stages of damage can be examined.The results indicate that the T-beams experience complete,incom-plete linear,and non-linear stages during the destructive test process.In the complete linear elastic stage,both the deflection and bottom strain verification coefficients comply with the specifications,indicating a good structural load-bearing capacity no longer adheres to the code’s requirements.In the non-linear stage,both coefficients exhi-bit a sharp increase,resulting in a further decrease in the structure’s load-bearing capacity.According to the pro-visions of the current code,the beam can be in the incomplete linear stage when both values fall within the code’s specified range.The strain verification coefficient sourced from the compression zone at the bottom of theflange is not recommended for assessing the bridge’s load-bearing capacity.
基金support from the National Natural Science Foundation of China(No.22273016,22273017,22233006)Plan for Henan Province University Science and Technology Innovation Team(No.25IRTSTHN002)+1 种基金Young Backbone Teacher Training Program of Henan Province(2023GGJS036)the 111 project(No.D17007).
文摘The utilization of nuclear power will persist as a prominent energy source in the foreseeable future.However,it presents substantial challenges concerning waste disposal and the potential emission of untreated radioactive substances,such as radioactive 129I and 131I.The transportation of radioactive iodine poses a significant threat to both the environment and human health.Nevertheless,effectively,rapidly removing iodine ion from water using porous adsorbents remains a crucial challenge.In this work,three kinds of multiple sites porous organic polymers(POPs,POP-1,POP-2,and POP-3)have been developed using a monomer pre-modification strategy for highly efficient and fast I_(3) absorption from water.It is found that the POPs exhibited exceptional performance in terms of I3 adsorption,achieving a top-performing adsorption capacity of 5.25 g g^(-1) and the fastest average adsorption rate(K_(80%)=4.25 g g^(-1) h^(-1))with POP-1.Moreover,POP-1 exhibited exceptional capacity for the removal of I3 fromflowing aqueous solutions,with 95%removal efficiency observed even at 0.0005 mol L^(-1).Such results indicate that this material has the potential to be utilized for the emergency preparation of potable water in areas contaminated with radioactive iodine.The adsorption process can be effectively characterized by the Freundlich model and the pseudo-second-order model.The exceptional I_(3) absorption capacity is primarily attributed to the incorporation of a substantial number of active adsorption sites,including bromine,carbonyl,and amide groups.
基金support of the National Natural Science Foundation of China(Grant No.51805371)the Innovation and Entrepreneurship Training Program of Tianjin University of Commerce(Grant No.202310069067).
文摘Monocrystalline Cu exhibits excellent electrical and signal-transmission properties due to its absence of grain boundaries,making it a critical material for the production of micro-machinery and micro-components;however,achieving ultrahigh precision and ultralow damage machining of functional devices using traditional techniques such as grinding and polishing is extremely challenging.Consequently,nanocutting has emerged as an efficient means to fabricate monocrystalline materials with complex surface characteristics and high surface integrity.Nevertheless,the macroscopic cutting theory of metal materials cannot be applied to nanocutting.Accordingly,in this paper,both simulations and experiments were conducted to examine the chip deformation mechanisms of monocrystalline Cu.First,large-scale molecular dynamics(MD)simulations were conducted to gain a comprehensive understanding of the deformation behavior during nanocutting.This included examining the influencing factors and the variation patterns of the chip deformation coefficient,cutting force,and minimum cutting thickness.Subsequently,nanocutting experiments were performed using a specially designed nanocutting platform with high-resolution online observation by scanning electron microscopy.The experimental results served to verify the accuracy and reliability of theMDmodeling,as they exhibited excellent consistency with the simulated results.Although this work considered monocrystalline Cu,it is believed that the elucidated chip deformation mechanisms could also be applied to other face-centered-cubic metals.These results are of great value for advancing the understanding of the mechanisms of ultraprecision cutting.
基金the National Key Research and Development Program of China(Grant No.2021YFB2012100)the Major Science and Technology Projects in Fujian Province(Grant No.2023HZ021005)+1 种基金the Open Project Program of Fujian Key Laboratory of Special Intelligent Equipment Measurement and Control(Grant No.FJIES2023KF06)the Industry-University-Research Co-operation Fund of the Eighth Research Institute of China Aerospace Science and Technology Corporation(Grant No.SAST2023-061).
文摘High-temperature thin-film strain sensors are advanced technological devices for monitoring stress and strain in extreme environments,but the coupling of temperature and strain at high temperature is a challenge for their use.Here,this issue is addressed by creating a composite ink that combines Pb_(2)Ru_(2)O_(6) and TiB_(2) using polysilazane(PSZ)as a binder.After direct writing and annealing the PSZ/Pb_(2)Ru_(2)O_(6)/TiB_(2) film at 800℃ in air,the resulting thin film exhibits a low temperature coefficient of resistance(TCR)of only 281 ppm/℃ over a wide temperature range from 100℃ to 700℃,while also demonstrating high sensitivity with a gauge factor approaching 19.8.This exceptional performance is attributed to the intrinsic properties of Pb_(2)Ru_(2)O_(6),which has positive TCR at high temperature,and TiB2,which has negative TCR at high temperature.Combining these materials reduces the overall TCR of the film.Tests showed that the PSZ/Pb_(2)Ru_(2)O_(6)/TiB_(2) film maintains stable strain responses and significant signal output even under varying temperature.These findings provide valuable insights for developing high-temperature strain sensors with low TCR and high sensitivity,highlighting their potential for applications in high-temperature strain measurements.
基金Supported by the National Natural Science Foundation of China(NSFC)under the Programs Science Fund for Creative Research Groups(Nos.40821004,41121064)。
文摘This study analyzed and compared variations of the sulcus and otolith outlines of three geographic stocks(Huanghe(Yellow)River estuary(HHE),Jiaozhou Bay(JZB),and Changjiang(Yangtze)River estuary(CJE))of white croaker Pennahia argentata in northern Chinese coastal waters.The sulcus and otolith outline analyses via elliptical Fourier transform(EFT,i.e.,outline analysis)achieved an overall classifi cation rate of 80.4%and 87.2%,respectively.Based on a combination of sulcus and otolith shape indices(SIs)and two derivative ratios,a moderate discriminatory effi ciency of 64.7%was obtained.The results indicate that sulcus outline analysis could be used alone to discriminate white croaker stocks,and that both sulcus and otolith outline analyses discriminated the fi sh stocks at a higher classifi cation rate than the shape indices.The sulcus outline analysis provided complementary information to the whole otolith outline analysis for stock discrimination.Both the sulcus and otolith outline analyses effi ciently discriminated between the most geographically separated CJE and HHE stocks,indicating that they could be considered discrete stocks for fi shery management.
基金Supported by National Natural Science Foundation of China(Grant No.51475263)
文摘The current research on gear system dynamics mainly utilizes linear spring damping model to calculate the contact force between gears. However, this linear model cannot correctly describe the energy transfer process of collision that often occurs in gear system. Focus on the contact-impact events, this paper proposes an improved gear contact force model for dynamic analysis in helical gear transmission system. In this model, a new factor associated with hysteresis damping is developed for contact-impact state, whereas the traditional linear damping factor is utilized for normal meshing state. For determining the selection strategy of these two damping factors, the fundamental contact mechanics of contact-impact event a ected by supporting forces are analyzed. During this analysis, an e ect factor is proposed for evaluating the influence of supporting forces on collision. Meanwhile, a new restitution of coe cient is deduced for calculating hysteresis damping factor, which suitable for both separation and non-separation states at the end of collision. In addition, the time-varying meshing sti ness(TVMS) is obtained based on the potential energy approach and the slice theory. Finally, a dynamic analysis of a helical gear system is carried out to better understand the contact force model proposed in this paper. The analysis results show that the contribution of supporting forces to the dynamic response of contact-impact event within gear pair is important. The supporting forces and dissipative energy are the main reasons for gear system to enter a steady contact state from repeated contact-impact state. This research proposes an improved contact force model which distinguishes meshing and collision states in gear system.
基金financially supported by the National Natural Science Foundation of China(Grant No.51375391)
文摘In aluminum-copper alloy, the segregation has a severe bad effect on the alloying degree, strength and corrosion resistance. A deeper understanding of element segregation behavior will have a great signif icance on the prevention of segregation. In the study, the element segregation behavior of ZL205 A aluminum-copper alloy was investigated by examining isothermally solidifi ed samples using scanning electron microscopy and energy dispersive spectroscopy. The calculated results of segregation coeffi cients show that Cu and Mn are negative segregation elements; while Ti, V and Zr are positive segregation elements. The sequence of element segregation degree from the greatest to the least in ZL205 A alloy is Cu, Mn, V, Ti, Zr and Al. The density of residual liquid is expected to increase with a decrease in the quenching temperature ranging from 630 ℃ to 550 ℃. The calculated results conf irm that the quenching temperature has an insignif icant effect on the liquid density; and the variation of density is mainly due to element segregation. Consequently, segregations of Al, Cu and Mn lead to an increase in density, but Ti, V and Zr present the opposite effect. The contribution of each element to the variation of the liquid density was analyzed. The sequence of contributions of alloying elements to the variation of total liquid density is Cu>Al>Mn>V>Ti>Zr.
基金supported by the National Key R&D Program of China (No. 2018YFC0807804-3)Key R&D Program of Anhui Province (No. 1804a0802213)Scientifi c Research Foundation for the introduction talent of Anhui University of Science and Technology。
文摘Coal seams have a pronounced bedding structure with developed cracks and exhibit signifi cant anisotropy.However,few studies have examined the frequency dispersion properties of channel waves in anisotropic coal seams.In this study,numerical solutions are calculated using the generalized reflection–transmission coefficient method for the dispersion curves of Love channel waves in vertical transversely isotropic(VTI)and horizontal transversely isotropic(HTI)medium models.Moreover,the frequency dispersion characteristics of Love channel waves in several typical transversely isotropic models are analyzed.We fi nd that the dispersion curves for isotropic and VTI media diff er signifi cantly.In addition,the phase and Airy-phase velocities in VTI media are higher than those in isotropic media.Thus,neglecting this difference in practical channel wave detection will result in large detection errors.The dispersion curves for the isotropic and HTI media do not differ signifi cantly,and the Airy-phase velocities of various modes are similar.The group-velocity curve for a coal seam model containing a dirt band is found to be extremely irregular.The fundamental-mode Airy phase is not pronounced,but the fi rst-mode Airy phase can be clearly observed.Hence,fi rst-mode channel waves are suitable for detecting dirt bands.
基金funded by Fundamental Research Funds of CAF (CAFYBB2022ZA00103)National Natural Science Foundation of China (General Program)(31971652)+1 种基金National Natural Science Foundation of China (32001308)Fundamental Research Funds of CAF (CAFYBB2022ZC001)
文摘Precise quantifi cation of climate-growth relationships can make a major contribution to scientifi c forest management.However,whether diff erences in the response of growth to climate at diff erent altitudes remains unclear.To answer this,264 trees of Larix kaempferi from 88 plots,representing diff erent altitudinal ranges(1000-2100 m)and tree classes were sampled and used to develop tree-ring chronologies.Tree-ring growth(TRG)was either positively(dominant)or negatively(intermediate and suppressed)correlated with climate in diff erent tree classes at diff erent altitudes.TRG was strongly correlated with growing season at low altitudes,but was less sensitive to climate at middle altitudes.It was mainly limited by precipitation and was highly sensitive to climate at low altitudes.Climate-growth relationships at high altitudes were opposite compared to those at low altitudes.TRG of dominant trees was more sensitive to climate change compared to intermediate and suppressed trees.Climate factors(annual temperatures;moisture,the number of frost-free days)had diff erent eff ects on tree-ring growth of diff erent tree classes along altitudinal gradients.It was concluded that the increase in summer temperatures decreased water availability,resulting in a signifi cant decline in growth rates after 2005 at lower altitudes.L.kaempferi is suitable for planting in middle altitudes and dominant trees were the best sampling choice for accurately assessing climate-growth relationships.
文摘We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.
基金This work was supported by the National Key Research and Development Program of China(No.2020YFA0211000)the National Natural Science Foundation of China(Nos.21876114,21761142011,and 51572174)+3 种基金the Shanghai Government(Nos.19DZ1205102 and 19160712900)the International Joint Laboratory on Resource Chemistry(No.IJLRC)the Ministry of Education of China(No.PCSIRT_IRT_16R49)This research was also supported by The Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,the Shuguang Research Program of Shanghai Education Committee,and the Shanghai Engineering Research Center of Green Energy Chemical Engineering(No.18DZ2254200).
文摘NH_(2)-UIO66(NU)is a promising photocatalyst for the reduction of Cr(VI)to low-toxic Cr(III)driven by visible light under ambient conditions.However,the main limitation in this process is the ineffi cient ligand to metal charge transfer(LMCT)of photo-excited electrons,which is caused by inherent energy gap(ΔE_(LMCT)).This study synthesized the defective NU(NUXH,where X is the molar equivalent of the modulator)with reducedΔE_(LMCT)through linkers removal via acid treatment.The electronic structure of NUX-H was systematically investigated,and the results indicated that the structural defects in NUX-H strongly altered the environment of the Zr atoms.Furthermore,they substantially lowered the energy of the unoccupied d orbitals(LUMO),which was benefi cial to effi cient LMCT,resulting in an improved photocatalytic activity of NUX-H toward high-concentration(100 mg/L)Cr(VI)reduction.Compared to NU with defect-free structure,the reducing rate of Cr(VI)was increased by 47 times.This work introduced an alternative strategy in terms of designing effi cient photocatalysts for reducing Cr(VI)under ambient conditions.
基金Key State Laboratories Freedom Research Project under Grant No.SLDRCE09-D-01the Fundamental Research Funds for the Central Universities,the Project of National Key Technology R&D Program in the 12th Five Year Plan of China under Grant No.2012BAJ11B01+2 种基金National Natural Science Foundation of China under Grant No.50978196State Meteorological Administration Special Funds of Meteorological Industry Research under Grant No.201306102the Ministry of Education of China under Grant No.2008B090500222
文摘A numerical solution based on the Steffensen stable point iterative method is proposed to resolve the transcendental frequency equation of a stay cable-damper system. The frequency equation, which considers clamped supports and fl exural rigidity of the cable, is intended to investigate the infl uence of the parameters of the cable damper system on its dynamic characteristics. Two factors involved in the design and construction phases, the damping coeffi cient induced by external dampers and the cable tension, are the focus of this study. Their impact on modal frequencies and damping ratios in these two phases of cable-damper systems are investigated by resolving the equation with the proposed solution. It is shown that the damping coeffi cient and cable tension exert more noticeable effects on the modal damping ratios than on the modal frequencies of stay cable-damper systems, and the two factors can serve as design variables in the design phase and as adjustment factors in the construction phase. On the basis of the results, a roadmap for system-level optimal design of stay cable-damper systems that can achieve global optimal vibration suppression for the entire bridge is proposed and discussed.
基金financed from the funding allocated for science by the Ministry of Science and Higher Education–Poland
文摘The paper attempts to analyze full load characteristics of over 500 combustion engines. Using statistical tools, the author determined the value of the coe cient of flexibility. Engine flexibility is the capability of the engine to adapt to varying loads. Importantly, in the investigations, the author took into account the parameters calculated in the course of the investigations on a chassis dynamometer, i.e., actual, not taken from technical specifications of brand new vehicles. Di erent stages of operating wear allow a better characterization of the population. Subsequent utilization of the results in tractive calculations is more reliable. The engines were divided into in six groups, depending on the type of fuel system: fuel injected gasoline and turbocharged gasoline, spark ignition LPG, naturally aspirated diesel and turbocharged diesel. However, engines running on alternative fuels are characterized with a greater flexibility than the fuel injected base engines. Conformity of flexibility of fuel injected and LPG IV generation engines have been observed,which confirms the appropriateness of engine adaptation to alternative fueling. Gasoline engine supercharging allowed a reduction of the maximum engine speed of the maximum torque, which extends the range of analyzable speeds for flexibility and consequently, the flexibility as such.
基金supported by the Japan Society for the Promotion of Science KAKENHI(Grant numbers:20H04549 and 19K12822)the Japan Science and Technology Agency ACT–X(Grant Number:JPMJAX21K7).
文摘Accurate determination of the optical properties of biological tissues enables quantitative understanding of light propagation in these tissues for optical diagnosis and treatment applications.The absorption(μa)and scattering(μs)coe±cients of biological tissues are inversely analyzed from their diffuse re°ectance(R)and total transmittance(T),which are measured using a double integrating spheres(DIS)system.The inversion algorithms,for example,inverse adding doubling method and inverse Monte Carlo method,are sensitive to noise signals during the DIS measurements,resulting in reduced accuracy during determination.In this study,we propose an arti ficial neural network(ANN)to estimateμa andμs at a target wavelength from the R and T spectra measured via the DIS to reduce noise in the optical properties.Approximate models of the optical properties and Monte Carlo calculations that simulated the DIS measurements were used to generate spectral datasets comprisingμa,μs,R and T.Measurement noise signals were added to R and T,and the ANN model was then trained using the noise-added datasets.Numerical results showed that the trained ANN model reduced the effects of noise inμa andμs estimation.Experimental veri fication indicated noise-reduced estimation from the R and T values measured by the DIS with a small number of scans on average,resulting in measurement time reduction.The results demonstrated the noise robustness of the proposed ANN-based method for optical properties determination and will contribute to shorter DIS measurement times,thus reducing changes in the optical properties due to desiccation of the samples.
基金Sponsored by Social Science Fund Project of Hebei Province(HB19S039)Training Project of School of Architecture and Art,Hebei University of Engineering(2020-KJZD-001).
文摘Community renewal in the new era of transformation has entered the stage of stock planning,and user demand for high-quality urban life is becoming more and more urgent.This study constructed a community renewal method that considers user satisfaction and its differences.Through the community survey data,we analyzed the satisfaction and differences of user needs,found out key problems and focus groups,and proposed improvement strategies.Taking the Anju Dongcheng Community in Handan City as an example,the overall satisfaction of user groups,the satisfaction of users of different ages and their differences were analyzed.It is concluded that the main problems were the health and environmental problem,in which the focus of dog keeping were young and old people,and the focus of garbage classification problem were young and middle-aged people.Finally,the corresponding renewal strategies and designs were put forward to improve the quality of community living environment.
基金supported by the National Natural Science Foundation of China(No.31870387),China Scholarship Council.
文摘The CO_(2)effl ux of branches and leaves plays an important role in ecosystem carbon balance.Using a carbon fl ux system,the effl ux of Larix gmelinii var.principisrupprechtii(Dahurian larch)was investigated in 27 years(immature),31 years(near-mature),and 47 years(mature)stands at diurnal,seasonal,and spatial scales(direction and height)as well as its connection with environmental factors from May to October 2020.Diurnal variation in effl ux was a single peak,and the maximum occurring between 14:00 and 16:00.Seasonal variation also exhibited a single peak,with the maximum in late July and the minimum in early October.From May to September,effl ux on the south side was the largest among the three stands,and mean values on the south side of 27 year-old,31 year-old,and 47 year-old trees were 0.50,0.97 and 1.05μmol·m^(–2)·s^(–1),respectively.The minimum occurred on the north side.Except for the maximum in July and September in the 27 year-old stand in the middle of the canopy,the maximum effl ux in the upper canopy,and the means in the 27 year-old,31 year-old,and 47 year-old stands were 0.49,0.96 and 1.04μmol·m^(-2)·s^(-1),respectively;the minimum occurred in the lower canopy.Temperatures and relative humidity infl uenced seasonal variations in effl ux.Seasonal variation in temperature sensitivity coeffi cient(Q 10)was opposite that of temperature,increasing with decreasing temperature.At the spatial scale,maximum Q 10 occurred in the mid canopy.With the effl ux and temperature data in diff erent locations,it is possible to better estimate effl ux variations in each stand.
文摘Wireless Sensor Networks(WSN)have revolutionized the processes involved in industrial communication.However,the most important challenge faced by WSN sensors is the presence of limited energy.Multiple research inves-tigations have been conducted so far on how to prolong the energy in WSN.This phenomenon is a result of inability of the network to have battery powered-sensor terminal.Energy-efficient routing on packetflow is a parallel phenomenon to delay nature,whereas the primary energy gets wasted as a result of WSN holes.Energy holes are present in the vicinity of sink and it is an important efficient-routing protocol for WSNs.In order to solve the issues discussed above,an energy-efficient routing protocol is proposed in this study named as Adaptive Route Decision Sink Relocation Protocol using Cluster Head Chain Cycling approach(ARDSR-CHC2H).The proposed method aims at improved communica-tion at sink-inviting routes.At this point,Cluster Head Node(CHN)is selected,since it consumes low energy and permits one node to communicate with others in two groups.The main purpose of the proposed model is to reduce energy con-sumption and define new interchange technology.A comparison of simulation results demonstrates that the proposed algorithm achieved low cluster creation time,better network error and high Packet Delivery Rate with less network failure.
