Accurate reconstructed series are crucial for studying the differences in regional hydroclimatic variations in Europe over the past millennium.Using hierarchical clustering analysis and stepwise regression methods,we ...Accurate reconstructed series are crucial for studying the differences in regional hydroclimatic variations in Europe over the past millennium.Using hierarchical clustering analysis and stepwise regression methods,we reconstructed yearly time series of the summer standardized precipitation evapotranspiration index(SPEl)for six European regions over the past millennium.Our analysis also revealed prominent regional hydroclimatic differences in multidecadal signals over the past 500 years.For instance,in the 1500s-1570s(from the beginning of the 1500s to the end of the 1570s),drying trends were observed in northern and southeastern Europe,whereas southwestern Europe experienced a wetting trend.Moreover,drying trends were observed in northern and central Europe in the 1640s-1670s.Additionally,wetting trends were observed in western and central Europe during the 1830s-1850s,with drying trends in northern and southeastern Europe.Notably,the hydroclimatic variations in most European regions showed drying trends in the 1920s-1950s,especially in southern Europe.By utilizing large amounts of tree-ring samples and directly comparing regional hydroclimatic variations,our reconstructions provide a consistent and comprehensive dataset for further analysis.The reconstructed dataset is available at https://doi.org/10.57760/sciencedb.07215.展开更多
Recently, because of the importance of research into environmental change and thanks to the overlap of some branches of sciences, there has been great advance in dendrochronology. The response of ring-width growth to ...Recently, because of the importance of research into environmental change and thanks to the overlap of some branches of sciences, there has been great advance in dendrochronology. The response of ring-width growth to variation of ecological en- vironment system has become one of the major projects in earth science and ecology.展开更多
Cenozoic trachytes are characteristic of some active volcanic fields in China.In particular,the origin and mechanisms of the evolution of trachytes from the Tianchi(Changbaishan)volcano(TV,China/North Korea)are poorly...Cenozoic trachytes are characteristic of some active volcanic fields in China.In particular,the origin and mechanisms of the evolution of trachytes from the Tianchi(Changbaishan)volcano(TV,China/North Korea)are poorly known.Here,we present new geochronological,geochemical and isotopic data on two trachytic suites outcropping on the northern and southern upper slopes of TV.Detailed zircon laser ablation-multicollector-inductively coupled plasma-mass spectrometry(LA-MC-ICP-MS)U-Pb dating,Rb-Sr isochron dating of plagioclase and hornblende,^(40)Ar/^(39)Ar chronology with mineral chemistry,whole-rock element and Sr-Nd-Pb isotope data are used to explore their origins and evolutionary mechanisms during the late Middle Pleistocene.Our data indicate that the trachytes mainly consist of sanidine,orthoclase and plagioclase,with minor albite,quartz and hornblende.They formed at 0.353-0.346 Ma(lava flow from the northern slope)and 0.383-0.311 Ma(lava flow from the southern slope),respectively.The TV trachytes are characterized by high K_(2)O/Na_(2)O and AR values,with low A/CNK and Mg~#values.They are enriched in rare earth elements(REEs;except Eu),depleted in Sr and Ba,crystallizing at 742-858℃.The TV trachytes have high(^(87)Sr/^(86)Sr)_i values(0.70776-0.71195),positiveε_(Nd)(t)values(0.61-2.93)and radiogenic^(206)Pb/^(204)Pb values(17.515-17.806).These values are similar to those of the Pleistocene and Holocene TV trachytes.Geochemical data indicate that they were formed by fractional crystallization from a basaltic melt and assimilated upper crust material.The trace element pattern of the studied trachytes is consistent with an evolution from basaltic melts representative of an enriched mantle source.The vent from which the trachytic magma was erupted probably collapsed inside the caldera during the TV'Millennium'eruption(ME)in 946 AD.The contemporaneous emission of basaltic and trachytic magma during the Middle-Late Pleistocene suggests the coexistence of fissural basaltic volcanism and central-type trachytic volcanism,the latter of which was associated with a magma chamber in the upper crust during the TV cone-construction stage.展开更多
The Ning-Wu Basin is an important part of the Middle-Lower Yangtze River Metallogenic Belt in eastern China.It contains well-preserved Mesozoic volcanic sequences that document significant geodynamic evolution.However...The Ning-Wu Basin is an important part of the Middle-Lower Yangtze River Metallogenic Belt in eastern China.It contains well-preserved Mesozoic volcanic sequences that document significant geodynamic evolution.However,uncertainties surrounding the ages of eruptions and the temporal relationships between the four main volcanic cycles—the Longwangshan,Dawangshan,Gushan and Niangniangshan formations—have hindered our understanding of magmatic pulsation and its connection to iron mineralisation.Here,high-precision LA-ICP-MS zircon U-Pb dating of four fresh volcanic samples(one per formation)reveals weighted mean ages of 132.3±1.0 Ma(Longwangshan;MSWD=1.3),130.4±1.6 Ma(Dawangshan;MSWD=1.3),128.1±1.9 Ma(Gushan;MSWD=2.0)and 127.2±1.1 Ma(Niangniangshan;MSWD=0.23).These dates constrain volcanic activity to the Early Cretaceous Valanginian-Hauterivian interval and show a systematic trend of increasingly younger ages spanning~8 Ma(133-125 Ma).This magmatism can be subdivided into three phases:initiation(133-132 Ma),peak activity(132-130 Ma)and cessation(128-125 Ma).The episodic volcanism correlates with the accelerating rollback of the Pacific subduction zone,which drives crustal melting and asthenospheric upwelling.Notably,these cycles supplied the thermal energy,fluids and iron-rich melts that were essential for the formation of porphyritic iron deposits in the basin.By establishing a highresolution chronostratigraphic framework,this study sheds light on the spatiotemporal evolution of the Ning-Wu Basin,elucidating the coupling between crust-mantle dynamics,volcanic cyclicity and ore-forming processes across eastern China’s metallogenic belt.展开更多
The Tong’an-Baishuidong mining district(TBMD),located in the eastern section of the Jiangnan Orogen,is a newly discovered granite-type lithium mining district.Thisstudy presents new monazite U-Pb chronological,whole-...The Tong’an-Baishuidong mining district(TBMD),located in the eastern section of the Jiangnan Orogen,is a newly discovered granite-type lithium mining district.Thisstudy presents new monazite U-Pb chronological,whole-rock geochemical,and Nd-Pb isotopic data to reveal the petrogenesis and geodynamic setting of the Wutang granites in the TBMD.The monazite U-Pb age of 145.8±1.0 Ma indicates that the granites were emplaced at the end of the Late Jurassic.Whole-rock geochemical results demonstrate that the Wutang granites are enriched in SiO_(2)(72.80-73.40 wt%)but depleted in CaO(0.44-0.90 wt%)and MgO+TiO_(2)+TFeO(1.79-2.05 wt%).These granites exhibit negative Eu anomalies(δEu=0.3−0.4)and high aluminum saturation indexes(A/CNK=1.2−1.6),differentiation indexes(DI=90-92),and Rb/Sr ratios(4.7-8.1).They also have moderate Ba contents(239-278 ppm)and low Sr contents(52.7-82.0 ppm)as well as low Nb/Ta(2.2-5.3)and Zr/Hf(21.3-31.5)ratios.All these indicate that they are highly fractionated granites.Additionally,these granites contain 5-10 wt%muscovite but no hornblende,with calculated corundum contents of 2.3-5.5 wt%.They have low high-field strength element(HFSE)contents(Zr+Nb+Ce+Y=182-202 ppm)and zircon saturation temperatures(700-770℃),with Th and Y negatively linked with Rb.These petrographic and geochemi-cal features further reveal that the Wutang granites belong to highly fractionated S-type granites.TheεNd(t)values of these granites range from−9.03 to−8.23,corresponding to two-stage model ages(T DM2)of 1488-1553 Ma.The initial Pb isotope ratios are:(206 Pb/^(204)Pb)i=18.38-18.55,(^(207)Pb/^(204)Pb)i=15.67-15.68,and(^(208)Pb/^(204)Pb)i=38.62-38.67.These Nd-Pb isotopic results demonstrate that the parental magma originated from the partial melting of ancient crustal materials.In the meantime,the TBMD in the eastern section of the Jiangnan Orogen was in a compression-extension transitional setting associated with the episodic subduction of the Paleo-Pacific Plate.展开更多
Paleo-dune deposits have been widely used as a proxy indicator of past dune ac- tivity, which is further used to reconstruct paleoclimates. However, recent studies have criti- cally examined the reproducibility of dun...Paleo-dune deposits have been widely used as a proxy indicator of past dune ac- tivity, which is further used to reconstruct paleoclimates. However, recent studies have criti- cally examined the reproducibility of dune chronologies and the complexity of paleo-dune deposits as paleoenvironmental records. This paper addresses questions on the paleoenvi- ronmental implications of dune chronostratigraphies that have been raised by those reviews, in the specific case of crescentic dunes, using a case study from the Mu Us dune field, north-central China. The processes of turn-over and stabilization of relatively small crescentic dunes are first investigated by observational evidence. In combination with the analysis of a simplified sand preservation model and stratigraphic records, the effect of dune morphody- namics on sand preservation is demonstrated. It is especially evident that thick, nearly in- stantaneously deposited sand units record dune stabilization near the very end of a dune activity episode, while thin sand units may signal the preservation of sand deposited earlier in episodes of activity. Interpreting the distribution of luminescence ages that indicate sand deposition over time is not as simple as assumed in some previous work. Low frequency of sand ages could indicate an interval of either dune field stabilization or extensive dune activity but poor sand preservation. A peak of sand age frequency likely represents a shift in dune field activity towards stabilization, not a peak of active dune extent, especially if it partially overlaps with an independently identified interval of stabilization (e.g. one recorded by pa- leosols). The nature and magnitude of these biases in the distribution of sand ages over time are strongly affected by the magnitude of net sand accumulation, which is in turn related to sand supply, transport capacity and sand availability, and ultimately climate change. Rela- tively short dune stabilization and turn-over time (101 to 102 yrs) indicate that dune geomor- phic processes can quickly respond to short-term disturbance, but the chronology of that response must be interpreted in light of how those processes influence age distributions.展开更多
Based on geological, chronological, geochemical and Nd isotopic studies of the high-grade basement of the Qilian terrane, the authors have drawn the following main conclusions: (1) the high-grade basement of the Qilia...Based on geological, chronological, geochemical and Nd isotopic studies of the high-grade basement of the Qilian terrane, the authors have drawn the following main conclusions: (1) the high-grade basement of the Qilian terrane consists mainly of meta-argillo-arenaceous rocks and granites and its bulk part was formed in the period of 0.8–1.0 Ga (the Jinningian period); (2) most of the meta-argillo-arenaceous rocks and granitic rocks have strong negative Eu and Ba anomalies (Eu/Eu*= 0.47–0.71 and Ba/Ba*=0.16–0.64), with fDM and ENd (1.0 Ga) ranging from 1.87 to 2.26 Ga and from ?8.54 to ?4.06 respectively, showing relatively high maturity; and (3) the Jinningian granitic rocks are a typical product of continent-continent collision, being probably related to the formation of the supercontinent Rodinia. These studies, combined with the study of high-grade basement rocks near the Qilian terrane, suggest that before the Jinningian period, the Qilian-Qaidam northern-margin terrane and Dunhuang-Alxa terrane were separated from each other, belonging to different plate systems of the North China craton and Yangtze platform respectively. The Qilian orogenic belt was the same as or similar to the Qiling orogenic belt in terms of the geological evolution history at least before the Jinningian period.展开更多
The calculation of a maximum depositional age(MDA)from a detrital zircon sample can provide insight into a variety of geological problems.However,the impact of sample size and calculation method on the accuracy of a r...The calculation of a maximum depositional age(MDA)from a detrital zircon sample can provide insight into a variety of geological problems.However,the impact of sample size and calculation method on the accuracy of a resulting MDA has not been evaluated.We use large populations of synthetic zircon dates(N≈25,000)to analyze the impact of varying sample size(n),measurement uncertainty,and the abundance of neardepositional-age zircons on the accuracy and uncertainty of 9 commonly used MDA calculation methods.Furthermore,a new method,the youngest statistical population is tested.For each method,500 samples of n synthetic dates were drawn from the parent population and MDAs were calculated.The mean and standard deviation of each method ove r the 500 trials at each n-value(50-1000,in increments of 50)were compa red to the known depositional age of the synthetic population and used to compare the methods quantitatively in two simulation scenarios.The first simulation scenario varied the proportion of near-depositional-age grains in the synthetic population.The second scenario varied the uncertainty of the dates used to calculate the MDAs.Increasing sample size initially decreased the mean residual error and standard deviation calculated by each method.At higher n-values(>~300 grains),calculated MDAs changed more slowly and the mean resid ual error increased or decreased depending on the method used.Increasing the p roportion of near-depositional-age grains and lowering measurement uncertainty decreased the number of measurements required for the calculated MDAs to stabilize and decreased the standard deviation in calculated MDAs of the 500 samples.Results of the two simulation scenarios show that the most successful way to increase the accuracy of a calculated M DA is by acquiring a large number of low-uncertainty measurements(300300)approach is used if the calculation of accurate MDAs are key to research goals.Other acquisition method s,such as high-to moderate-precision measurement methods(e.g.,1%-5%,2σ)acquiring low-to moderate-n datasets(50300).Additionally,they are most susceptible to producing erroneous MDAs due to contamination in the field or laboratory,or through disturbances of the youngest zircon’s U-Pb systematics(e.g.,lead loss).More conservative methods that still produce accurate MDAs and are less susceptible to contamination or lead loss include:youngest grain cluster at 1σunce rtainty(YGC 1σ),youngest grain clusterat 2σuncertainty(YGC 2σ),and youngest statistical population(YSP).The ages calculated by these methods may be more useful and appealing when fitting calculated MDAs in to pre-existing chronostratigraphic frameworks,as they are less likely to be younger than the true depositional age.From the results of our numerical models we illustrate what geologic processes(i.e.,tectonic or sedimentary)can be resolved using MDAs derived from strata of different ages.展开更多
There have been conflicting ideas about the Indosinian mineralization in E. Xinjiang, a subject that has attracted many geologists' attention over a long period. Isotopic dating shows that the Shiyingtan gold depo...There have been conflicting ideas about the Indosinian mineralization in E. Xinjiang, a subject that has attracted many geologists' attention over a long period. Isotopic dating shows that the Shiyingtan gold deposit located on the southern margin of the Turpan-Hami basin has a quartz fluid inclusion Rb-Sr isochron age of 237±9 Ma (95% conf.); the Shuangfengshan gold deposit on the southern margin of the Junggar orogenic belt has a quartz fluid inclusion Rb-Sr isochron age of 226 ±21 Ma (95% conf.); the Weiya vanadium-titanium magnetite in the E. Tianshan mountains has a mineral-whole rock Sm-Nd isochron age of 220 ±30 Ma (95% conf.); the Jinwozi and Jinwozi 210 gold deposits in the E. Tianshan mountains have quartz fluid inclusion Rb-Sr isochron ages of 228±22 Ma (95% conf.) and 230±6 Ma (95% conf.), respectively; and the Xiaobaishitouquan scheelite deposit in the E. Tianshan mountains has a quartz fluid inclusion Rb-Sr isochron age of 248±7 Ma (95% conf.). The metallogenetic ages mentioned above prove the existence of Indosinian mineralization in E. Xinjiang, and the metallogenetic event might have been related to Triassic intraplate magmatic evolution, intra-continent subduction, strike-slip shoving and ductile shearing in the studied area, representing another mineralization peak after the Late Paleozoic.展开更多
A huge thrust system, the North Lhasa Thrust (NLT), was discovered in the northern Lhasa block of the Tibetan Plateau based on geological mapping of the Damxung region and its vicinity, the Deqen-Lunpola traverse and ...A huge thrust system, the North Lhasa Thrust (NLT), was discovered in the northern Lhasa block of the Tibetan Plateau based on geological mapping of the Damxung region and its vicinity, the Deqen-Lunpola traverse and the Amdo-Bam Co profile. The NLT consists of the Dongqiao-Lunpola thrust (DLT), the west Namco thrust (WNT) and the south Damxung thrust (SDT) and ductile shear zones, ophiolite slices and folds extending in a WNW direction. Major thrust faults of the NLT seem to merge into a single deep-seated detachment of the upper-crust and totally displaced southward as far as 100-120 km. Chronological analyses with 39Ar-40Ar of plagioclase and hornblende, Rb-Sr isochron of minerals and fission-tracks of apatite from mylonite within the WNT yield ages of 174-173 Ma, 109 Ma and 44 Ma, showing 3 periods of thrusting in the north Lhasa block caused by subduction of the Tethys oceanic plate and the India-Eurasia continental collision respectively.展开更多
The high-Mg diorites, widely occurring in western Shandong, have important implications in the study of the relationship between the Mesozoic magmatism and the nature of the lithosphere and its thinning period in the ...The high-Mg diorites, widely occurring in western Shandong, have important implications in the study of the relationship between the Mesozoic magmatism and the nature of the lithosphere and its thinning period in the eastern North China craton (NCC). The Tietonggou and Jinling intrusions are typically representatives. LA-ICP-MS zircon U-Pb dating, major and trace element and Sr-Nd isotopic compositions of the Mesozoic intrusive rocks from western Shandong, eastern China, were analyzed. The weighted mean 106^pb/ 238^U ages from LA-ICP-MS zircon U-Pb dating results for early norite-diorite, late pyroxene-diorite from the Tietonggou intrusion and biotite-diorite from the Jinling intrusion are (131.4±4.9) Ma(n=15), (134. 5±2.3) Ma(n=13), and (132.8±4. 2) Ma(n=12), respectively, implying that they were formed in the Early Cretaceous. The weighted mean 207^pb/ 204^Pb ages for round zircons from late pyroxene-diorite in the Tietonggou intrusion is ( 2 513 ± 54) Ma( n= 8), suggesting that the basement of the North China craton should exist in the research area. The high-Mg diorites are characterized by enrichment in MgO, Na20, and light rare earth elements (LREE), and they are poor in heavy rare earth elements (HREE) and high field strength elements (HFSE), being similar to adakite. The existence of the mantle peridotite xenoliths with a high-Mg feature for these intrusive rocks implies that their primary magma should be derived from the upper mantle. However, Sr-Nd isotopic composi- tions (Is: 0.704 75--0.707 15;ENd (130 Ma) values: --3.95 to -- 13.30), depletion in HFSE, and the occurrence of Archean inherited zircons suggest that crustal materials could be involved in the derivation of the primary magma. The compositional difference between the diorites from the Tietonggou and Jinling intrusions could be attributed to those of magma sources and degrees of partial melting. The Early Cretaceous high-Mg diorites are considered to have been formed by the mixed melting of the delaminated lithosphere (lithospheric mantle + crust) and asthenosphere, based on their geochemistry, the mantlederived xenoliths, and the Early Mesozoic lithospheric evolutionary history of the eastern North China craton.展开更多
The Xuhe mafic rocks, located in Ziyang county of Shaanxi Province, are dominated by diabase-porphyrite, gabbro-diabase, diabase, and pyroxene diorite. Primitive mantle-normalized multi-element patterns show that, the...The Xuhe mafic rocks, located in Ziyang county of Shaanxi Province, are dominated by diabase-porphyrite, gabbro-diabase, diabase, and pyroxene diorite. Primitive mantle-normalized multi-element patterns show that, the Xuhe marie rocks are enriched in large ion lithophile elements (LITE), such as Ba and Pb, depleted in K and Sr for basic rocks, and are depleted in Sr, P and Ti for pyroxene diorite. Chondrite-normalized REE patterns display LREE enrichment (LaN/YbN = 9.34- 13.99) and have normalized patterns for trace element and REE similar to that of typical OIB. Detailed SIMS zircon U-Pb dating yields emplacement ages of 438.4 ± 3.1 Ma for Xuhe mafic rocks. The relatively low MgO (basic rock: 3.11-7.21 wt%; pyroxene diorite: 0.89-1.21 wt% ) and Mg# (0.20- 0.49) for Xuhe mafic rocks suggest that they were possibly originated from an extremely evolved magma. The rising parental mafic magmas underwent pyroxene and plagioclase fractionation. Crustal contamination of pyroxene diorite before emplacement occurred at a higher crustal level compared to other lithology in Xuhe mafic rocks. The degree of partial melt was low (5%-10%) and in garnetspinel transition facies. Sr-Nd isotope of pyroxene diorite and enrichment mantle characteristics for Xuhe mafic rocks suggest that mafic rocks in the North Daba Mountains were derived from a mixture of HIMU, EMII and small amount of EMI components. Furthermore, this study discusses mantle geodynamic significance of Xuhe mafic rocks in the Silurian, which indicates subduction and uplift of magma caused back-arc extension.展开更多
The Qinling-Dabie-Sulu high-pressure and ultra-high pressure metamorphic belt wasformed by subduction and collision between the North China and Yangtze plates. The study ofthe eclogite belt is very important in unders...The Qinling-Dabie-Sulu high-pressure and ultra-high pressure metamorphic belt wasformed by subduction and collision between the North China and Yangtze plates. The study ofthe eclogite belt is very important in understanding the evolution of the Qinling Dabie orogen. Inthe present paper the geology, petrology, minerology and chronology of the eclogites in the Dabieand Sulu areas are described. The principal conclusions of this work are as follows: (1) Based up-on the field occurrence and the P-T conditions of the eclogites, two types of eclogite can be dis-tinguished: Type 1—the low-temperature and high-pressure eclogite in the mid-late Proterozoicmetamorphic series, and Type 2—the ultra-high pressure eclogite in the late Archaean to earlyProterozoic metamorphic complex. In the Dabie area, the ultra-high-pressure eclogite,high-pressure eclogite and epidote-blueschist units are nearly parallel to each other and stretchintermittently from north to south. (2) The P-T conditions of the high-pressure eclogites and ul-tra-high pressure eclogites have been estimated. The former are formed at 450-550℃ and1.4-1.6 GPa; while the latter at 650-870℃ and >2.7-2.9 GPa in the Dabie area and at820-1000℃ and >2.8-3.1 GPa in the Sulu area. The metamorphic temperatures of the eclogitesincrease progressively from west to east. (3) The ultra-high pressure eclogites were subjected to 5stages of metamorphism: pre-eclogite epidote amphibolite facies, peak coesite eclogite facies,post-eclogite amphibolite facies, epidote-blueschist facies or epidote amphibolite facies andgreenschist facies. The general features of the PTt path of the ultra-high pressure eclogite are:clockwise pattern, progressive metamorphism being a process of slow increasing temperature andrapid increasing pressure, and the retrogressive section with nearly isothermal decompression atthe early stage, isobaric cooling at the middle stage and nearly isothermal decompression at thelate stage. (4) At least two stages of high-pressure metamorphism occurred in the orogenic belt:the high-pressure eclogite and ultra-high pressure eclogite were formed by the subduction of theoceanic crust northward beneath the North China plate or the Dabie block during theCaledonian; while the epidote-blueschist belt came into being by subdution and collision be-tween the two continental plates during the Indosinian. (5) Due to the continuous sequentialsubduction of the cold plate, the ultra high-presssure metamorphic rocks were uplifted to thecrust by the underplating processes. They can be preserved just because of the 'frozen effect' re-sulting from the continuous subduction of the cold plate. (6) The carbonates, such as magnesite,breunnerite, aragonite and dolomite, and the H_2O-bearing minerals, such as phengite, epidoteand zoisite, were stable during the high-pressure and/or ultra-high pressure metamorphism.展开更多
The Niutougou gold deposit, located in the center of the Xiong'ershan gold district, western Henan Province, is a large gold deposit with many quartz porphyries found in the area. Based on the field geological invest...The Niutougou gold deposit, located in the center of the Xiong'ershan gold district, western Henan Province, is a large gold deposit with many quartz porphyries found in the area. Based on the field geological investigation of quartz porphyry of Niutougou gold deposit and by using the cathodoluminescence (CL) images analysis and in situ LA-ICP-MS U-Pb isotope dating method of zircons, the inner structure, trace element compositions and U-Pb age of the zircons separated from quartz porphyry were analyzed and determined. Cathodoluminescence (CL) images of zircons show clear magmatic zonations. Trace element analyses of zircons reveal that all zircons show high concentrations of Th, U, and HREE, and the REE patterns of depletion in LREE, with a positive Ce anomaly. Zircon LA-ICP-MS U-Pb dating results show that the quartz porphyry in the Niutougou gold deposit was formed at 159.714-0.99 Ma (about 160 Ma), belonging to the product of magmatic activity in late Middle Jurassic. Combined with the geological characteristics of the Niutougou gold deposit, the formation age of the quartz porphyry and the analysis of the formation age of the granite body exposed in the Niutougou gold deposit, the study suggests that the metallogenic epoch of the Niutougou gold deposit may be Yanshanian in age.展开更多
In this paper we present new zircon U-Pb ages,whole-rock major and trace element analyses,and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture.Our aim ...In this paper we present new zircon U-Pb ages,whole-rock major and trace element analyses,and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture.Our aim is to constrain the Early Permian-Late Triassic tectonic evolution of the region.Zircons from the magmatic rocks of the Tuotuohe region are euhedralsubhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios (0.4-4.6),indicating a magmatic origin.The zircon U-Pb ages obtained using LA-ICP-MS are 281 ± 1 Ma,258 ± 1 Ma,244 ± 1 Ma,and 216 ± 1 Ma,which indicate magmatism in the Early Permian-Late Triassic.A diorite from Bashihubei (BSHN) has SiO2 =57.18-59.97 wt%,Al2O3=15.70-16.53 wt%,and total alkalis (Na2O + K2O) =4.46-6.34 wt%,typical of calc-alkaline and metaluminous series.A gabbro from Bashibadaoban (BSBDB) belongs to the alkaline series,and is poor in SiO2 (45.46-54.03 wt%) but rich in Al2O3 (16.19-17.39 wt%) and total alkalis (Na2O + K2O =5.48-6.26 wt%).The BSHN diorite and the BSBDB gabbro both display an enrichment of LREEs and LILEs and depletion of HFSEs,and they have no obvious Eu anomaly; they have relatively low MgO contents (2.54-4.93 wt%),Mg# values of 43 to 52,and low Cr and Ni contents (8.07-33.6 ppm and 4.41-14.2 ppm,respectively),indicating they differentiated from primitive mantle magmas.They have low Nb/U,Ta/ U,and Ce/Pb ratios (1.3-9.6,0.2-0.8,and 0.1-18.1,respectively),and their initial Hf isotopic ratios range from +9.6 to +16.9 (BSHN diorite) and +6.5 to +12.6 (BSBDB gabbro),suggesting their primary magmas were derived mainly from the partial melting of a mantle wedge that had been metasomatized by subduction fluids.Taking all the new data together,we conclude that the western and eastern segment of the Jinshajiang suture regions underwent identical processes of evolution in the Early Permian-Late Triassic:oceanic crust subduction before the Early Permian,continental collision during the Early-Middle Triassic,and post-collisional extension from the Late Triassic.展开更多
Two robust precipitation reconstructions were conducted by combining tree-ring chronologies, dryness/wetness indices from historical documents, and climate data from the global grid. It was found that the recurrent dr...Two robust precipitation reconstructions were conducted by combining tree-ring chronologies, dryness/wetness indices from historical documents, and climate data from the global grid. It was found that the recurrent drought history of a region can help us understand the variability of precipitation. Several dry/wet periods during the past four centuries and potential cycles of precipitation variation were determined. Furthermore, the reconstructions are not only consistent well with each other in North-central China, but also in good agreement with variations of precipitation in northeastern Mongolia, the Longxi area in Gangsu Province and the Dulan area of Qinghai Province, and the snow accumulation of the Guliya glacier. These synchronous variations indicate that it is valuable to study various climate records, find common information and determine the driving force of climate change.展开更多
Lead isotopic analytic data of 30 ores gathered from the Zhuanmiao boron deposit, Wengquangou boron (iron) deposit and its Dongtaizi Ore Member constitute three isochrons, the corresponding ages of which are 1902 ...Lead isotopic analytic data of 30 ores gathered from the Zhuanmiao boron deposit, Wengquangou boron (iron) deposit and its Dongtaizi Ore Member constitute three isochrons, the corresponding ages of which are 1902 ± 12 Ma, 1852 ± 9 Ma and 1917 ± 48 Ma. Lead isotopic analyses of marble from the Xiquegou Member of the Qingchenzi orefield yield a Pb-Pb isochron age of 1844 ± 27 Ma. 40Ar-39Ar quick neutron activation dating of phlogopites and microclines coexisting with ore minerals in the Wengquangou boron (iron) and Zhuanmiao boron deposits shows that: (1) the phlogopite from the Wengquangou has a plateau age of 1923 ± 1.5 Ma and an isochron age of 1924 ± 2.5 Ma; (2) the microcline from the Wengquangou has the plateau age of 1407 ± 5.4 Ma and 220 ± 12 Ma and an isochron age of 1403 ± 19 Ma; (3) the phlogopites from the Zhuanmiao yield a plateau age 1918 ± 1.3 Ma and an isochron age of 1918 ± 2.9 Ma; (4) the microclines from the Zhuanmiao yield the plateau age of 1420 ± 16 Ma and 250 ± 8 Ma and an isochron age of 1425 ± 19 Ma and 269 ± 16 Ma. These ages indicate that the eastern Liaoning area happened around 1900 Ma, an important tectonomagmatic event, which is consistent with the worldwide Mid-Proterozoic tectonomagmatic event. During this period, the Proterozoic Liaohe Group was folded and underwent strong normal metamorphism, and the (hydrothermal) sedimentary boron deposits (or source beds) formed earlier were strongly superimposed by mineralization, resulting in enrichment of boron; later regional geological processes made little contribution to the formation of the boron deposits. Lead isotopic components show that the U-Pb and Th-Pb isotopic system reached homogenization in the ores whereas only the U-Pb isotopic system reached homogenization in the marble from the Xiquegou district, which indicates that the boron deposits superimposed in the studied area endured a relatively strong process of hydrothermal migmatization during the end phase of early Proterozoic metamorphism.展开更多
Based on the Rb-Sr isochron dating results, this paper suggests that the alkaline intrusive belt at the east foot of the Taihang-Da Hinggan Mountains were formed between 135 and 122 Ma. And the alkaline intrusives in ...Based on the Rb-Sr isochron dating results, this paper suggests that the alkaline intrusive belt at the east foot of the Taihang-Da Hinggan Mountains were formed between 135 and 122 Ma. And the alkaline intrusives in the north and south sections of this belt have entirely different Sr, Nd and Pb isotopic characteristics, i.e., all the rocks in the south section have positive εSr(t) and negative εNd(t) values and all those in the north have the opposite values. On the εSr(t) versus εNd(t) correlation diagram, the samples from the south are concentrated along the enriched mantle evolution trend lines and nearby, while those from the north fall along the depleted mantle trend lines and nearby. On the Pb isotope composition diagram, most of the samples from the south section fall on the mantle Pb evolution line and nearby, while those from the north lie between the Pb evolution lines of the mantle and the erogenic belt. The above-stated isotopic characteristics not only indicate that the source rocks of the alkaline intrusives in the south section have a close connection to materials from the enriched mantle reservoir, while those in the north are related to materials from the depleted one, but also reveal that the upper mantle below the North China platform is enriched and that below the Inner Mongolia geosyncline is depleted.展开更多
Shadong deposit is the first large-scale tungsten deposit found in the East Tianshan orogenic belt, and the geologic characteristics of the deposit indicate that the deeply concealed granite body is ge- netically rela...Shadong deposit is the first large-scale tungsten deposit found in the East Tianshan orogenic belt, and the geologic characteristics of the deposit indicate that the deeply concealed granite body is ge- netically related with the mineralization. The LA-ICPMS U-Pb age of zircons from the Shadong concealed granite obtained in this research is 239±2.0 Ma, belonging to the Middle Triassic. The whole rock samples are metaiuminous to slightly peraluminous (A/CNK=0.95-1.02) with low contents of SiO2 (64.0 wt.%-68.5 wt.%) and low K2O/Na2O ratios (0.73-0.96). The samples reveal enrichment of K, Rb, Th and depletion of Nb, Ta, P, Ti and have a negative slope from La to Lu (LaN/YbN=16.29-36.8) with weak negative Eu anom- aly (Eu/Eu*= 0.71-0.82). Initial ^87Sr/^86Sr ratios of whole rock range of 0.706 59-0.707 75, eNd(t) values range from -1.77 to -2.53 and εnf(t) values of zircon are between 2.54 and 4.90. The lithogeochemistry and Sr-Nd-Hf isotopic characteristics revealed that the concealed granite in Shadong tungsten deposit is I-type granite, and occurs in an intraplate tectonic setting. The magma mixing during intraplating of mantle de- rived magma intruding into the crust in Indosinian Period is the major formation mechanism of the granite. Of which, the proportion of mantle derived magma ranges from 58% to 60%, and the crustal materials are mainly the metamorphic basement of Xingxingxia Group of Mesoproterozoic Changcheng System, which may orovide the main source of ore forming metals of Shadong tungsten deposit.展开更多
基金supported by the National Natural Science Foundation(41831174)National Key Research and Development Program of China(2017YFA0603300)China Scholarship Council(CSC,202018006010083).
文摘Accurate reconstructed series are crucial for studying the differences in regional hydroclimatic variations in Europe over the past millennium.Using hierarchical clustering analysis and stepwise regression methods,we reconstructed yearly time series of the summer standardized precipitation evapotranspiration index(SPEl)for six European regions over the past millennium.Our analysis also revealed prominent regional hydroclimatic differences in multidecadal signals over the past 500 years.For instance,in the 1500s-1570s(from the beginning of the 1500s to the end of the 1570s),drying trends were observed in northern and southeastern Europe,whereas southwestern Europe experienced a wetting trend.Moreover,drying trends were observed in northern and central Europe in the 1640s-1670s.Additionally,wetting trends were observed in western and central Europe during the 1830s-1850s,with drying trends in northern and southeastern Europe.Notably,the hydroclimatic variations in most European regions showed drying trends in the 1920s-1950s,especially in southern Europe.By utilizing large amounts of tree-ring samples and directly comparing regional hydroclimatic variations,our reconstructions provide a consistent and comprehensive dataset for further analysis.The reconstructed dataset is available at https://doi.org/10.57760/sciencedb.07215.
基金Project supported by the National Natural Science Foundation of China
文摘Recently, because of the importance of research into environmental change and thanks to the overlap of some branches of sciences, there has been great advance in dendrochronology. The response of ring-width growth to variation of ecological en- vironment system has become one of the major projects in earth science and ecology.
基金financially supported by the project of the National Observation and Research Station of the Institute of Geology,China Earthquake Administration(Grant No.NORSCBS22-06)the Youth Science and Technology Development Project of the Jilin Earthquake Agency(Grant No.JZQ-202402)+1 种基金the Earthquake Science and Technology Spark Project(Grant No.XH23013B)the China Scholarship Council(Grant No.202104190014)。
文摘Cenozoic trachytes are characteristic of some active volcanic fields in China.In particular,the origin and mechanisms of the evolution of trachytes from the Tianchi(Changbaishan)volcano(TV,China/North Korea)are poorly known.Here,we present new geochronological,geochemical and isotopic data on two trachytic suites outcropping on the northern and southern upper slopes of TV.Detailed zircon laser ablation-multicollector-inductively coupled plasma-mass spectrometry(LA-MC-ICP-MS)U-Pb dating,Rb-Sr isochron dating of plagioclase and hornblende,^(40)Ar/^(39)Ar chronology with mineral chemistry,whole-rock element and Sr-Nd-Pb isotope data are used to explore their origins and evolutionary mechanisms during the late Middle Pleistocene.Our data indicate that the trachytes mainly consist of sanidine,orthoclase and plagioclase,with minor albite,quartz and hornblende.They formed at 0.353-0.346 Ma(lava flow from the northern slope)and 0.383-0.311 Ma(lava flow from the southern slope),respectively.The TV trachytes are characterized by high K_(2)O/Na_(2)O and AR values,with low A/CNK and Mg~#values.They are enriched in rare earth elements(REEs;except Eu),depleted in Sr and Ba,crystallizing at 742-858℃.The TV trachytes have high(^(87)Sr/^(86)Sr)_i values(0.70776-0.71195),positiveε_(Nd)(t)values(0.61-2.93)and radiogenic^(206)Pb/^(204)Pb values(17.515-17.806).These values are similar to those of the Pleistocene and Holocene TV trachytes.Geochemical data indicate that they were formed by fractional crystallization from a basaltic melt and assimilated upper crust material.The trace element pattern of the studied trachytes is consistent with an evolution from basaltic melts representative of an enriched mantle source.The vent from which the trachytic magma was erupted probably collapsed inside the caldera during the TV'Millennium'eruption(ME)in 946 AD.The contemporaneous emission of basaltic and trachytic magma during the Middle-Late Pleistocene suggests the coexistence of fissural basaltic volcanism and central-type trachytic volcanism,the latter of which was associated with a magma chamber in the upper crust during the TV cone-construction stage.
基金supported by The Special Funds for Natural Resource Development in Jiangsu Province(2200113-35)The Central Financial Geological Survey Project of the China Geological Survey(DD20230800702).
文摘The Ning-Wu Basin is an important part of the Middle-Lower Yangtze River Metallogenic Belt in eastern China.It contains well-preserved Mesozoic volcanic sequences that document significant geodynamic evolution.However,uncertainties surrounding the ages of eruptions and the temporal relationships between the four main volcanic cycles—the Longwangshan,Dawangshan,Gushan and Niangniangshan formations—have hindered our understanding of magmatic pulsation and its connection to iron mineralisation.Here,high-precision LA-ICP-MS zircon U-Pb dating of four fresh volcanic samples(one per formation)reveals weighted mean ages of 132.3±1.0 Ma(Longwangshan;MSWD=1.3),130.4±1.6 Ma(Dawangshan;MSWD=1.3),128.1±1.9 Ma(Gushan;MSWD=2.0)and 127.2±1.1 Ma(Niangniangshan;MSWD=0.23).These dates constrain volcanic activity to the Early Cretaceous Valanginian-Hauterivian interval and show a systematic trend of increasingly younger ages spanning~8 Ma(133-125 Ma).This magmatism can be subdivided into three phases:initiation(133-132 Ma),peak activity(132-130 Ma)and cessation(128-125 Ma).The episodic volcanism correlates with the accelerating rollback of the Pacific subduction zone,which drives crustal melting and asthenospheric upwelling.Notably,these cycles supplied the thermal energy,fluids and iron-rich melts that were essential for the formation of porphyritic iron deposits in the basin.By establishing a highresolution chronostratigraphic framework,this study sheds light on the spatiotemporal evolution of the Ning-Wu Basin,elucidating the coupling between crust-mantle dynamics,volcanic cyclicity and ore-forming processes across eastern China’s metallogenic belt.
基金funded by the Program of Science and Technology Department of Jiangxi Province(2023KDG01002 and 2023KDG01003)the National Natural Science Foundation of China(42062006 and 41962007)+1 种基金the Key Research and Development Program of Jiangxi Province(20223BBG71015)the Personnel Training Project of Jiangxi Bureau of Geology(2023JXDZKJRC02,2022JXDZKJRC04,and 2024JXDZKJRC05).
文摘The Tong’an-Baishuidong mining district(TBMD),located in the eastern section of the Jiangnan Orogen,is a newly discovered granite-type lithium mining district.Thisstudy presents new monazite U-Pb chronological,whole-rock geochemical,and Nd-Pb isotopic data to reveal the petrogenesis and geodynamic setting of the Wutang granites in the TBMD.The monazite U-Pb age of 145.8±1.0 Ma indicates that the granites were emplaced at the end of the Late Jurassic.Whole-rock geochemical results demonstrate that the Wutang granites are enriched in SiO_(2)(72.80-73.40 wt%)but depleted in CaO(0.44-0.90 wt%)and MgO+TiO_(2)+TFeO(1.79-2.05 wt%).These granites exhibit negative Eu anomalies(δEu=0.3−0.4)and high aluminum saturation indexes(A/CNK=1.2−1.6),differentiation indexes(DI=90-92),and Rb/Sr ratios(4.7-8.1).They also have moderate Ba contents(239-278 ppm)and low Sr contents(52.7-82.0 ppm)as well as low Nb/Ta(2.2-5.3)and Zr/Hf(21.3-31.5)ratios.All these indicate that they are highly fractionated granites.Additionally,these granites contain 5-10 wt%muscovite but no hornblende,with calculated corundum contents of 2.3-5.5 wt%.They have low high-field strength element(HFSE)contents(Zr+Nb+Ce+Y=182-202 ppm)and zircon saturation temperatures(700-770℃),with Th and Y negatively linked with Rb.These petrographic and geochemi-cal features further reveal that the Wutang granites belong to highly fractionated S-type granites.TheεNd(t)values of these granites range from−9.03 to−8.23,corresponding to two-stage model ages(T DM2)of 1488-1553 Ma.The initial Pb isotope ratios are:(206 Pb/^(204)Pb)i=18.38-18.55,(^(207)Pb/^(204)Pb)i=15.67-15.68,and(^(208)Pb/^(204)Pb)i=38.62-38.67.These Nd-Pb isotopic results demonstrate that the parental magma originated from the partial melting of ancient crustal materials.In the meantime,the TBMD in the eastern section of the Jiangnan Orogen was in a compression-extension transitional setting associated with the episodic subduction of the Paleo-Pacific Plate.
基金Foundation: National Natural Science Foundation of China, No.41501208 The Global Change Program of Ministry of Science and Technology of China, No.2016YFA0600503 The U.S. National Science Foundation, No.ATM-0502489
文摘Paleo-dune deposits have been widely used as a proxy indicator of past dune ac- tivity, which is further used to reconstruct paleoclimates. However, recent studies have criti- cally examined the reproducibility of dune chronologies and the complexity of paleo-dune deposits as paleoenvironmental records. This paper addresses questions on the paleoenvi- ronmental implications of dune chronostratigraphies that have been raised by those reviews, in the specific case of crescentic dunes, using a case study from the Mu Us dune field, north-central China. The processes of turn-over and stabilization of relatively small crescentic dunes are first investigated by observational evidence. In combination with the analysis of a simplified sand preservation model and stratigraphic records, the effect of dune morphody- namics on sand preservation is demonstrated. It is especially evident that thick, nearly in- stantaneously deposited sand units record dune stabilization near the very end of a dune activity episode, while thin sand units may signal the preservation of sand deposited earlier in episodes of activity. Interpreting the distribution of luminescence ages that indicate sand deposition over time is not as simple as assumed in some previous work. Low frequency of sand ages could indicate an interval of either dune field stabilization or extensive dune activity but poor sand preservation. A peak of sand age frequency likely represents a shift in dune field activity towards stabilization, not a peak of active dune extent, especially if it partially overlaps with an independently identified interval of stabilization (e.g. one recorded by pa- leosols). The nature and magnitude of these biases in the distribution of sand ages over time are strongly affected by the magnitude of net sand accumulation, which is in turn related to sand supply, transport capacity and sand availability, and ultimately climate change. Rela- tively short dune stabilization and turn-over time (101 to 102 yrs) indicate that dune geomor- phic processes can quickly respond to short-term disturbance, but the chronology of that response must be interpreted in light of how those processes influence age distributions.
基金supported by China National Natural Science Foundation Grant 49732070.
文摘Based on geological, chronological, geochemical and Nd isotopic studies of the high-grade basement of the Qilian terrane, the authors have drawn the following main conclusions: (1) the high-grade basement of the Qilian terrane consists mainly of meta-argillo-arenaceous rocks and granites and its bulk part was formed in the period of 0.8–1.0 Ga (the Jinningian period); (2) most of the meta-argillo-arenaceous rocks and granitic rocks have strong negative Eu and Ba anomalies (Eu/Eu*= 0.47–0.71 and Ba/Ba*=0.16–0.64), with fDM and ENd (1.0 Ga) ranging from 1.87 to 2.26 Ga and from ?8.54 to ?4.06 respectively, showing relatively high maturity; and (3) the Jinningian granitic rocks are a typical product of continent-continent collision, being probably related to the formation of the supercontinent Rodinia. These studies, combined with the study of high-grade basement rocks near the Qilian terrane, suggest that before the Jinningian period, the Qilian-Qaidam northern-margin terrane and Dunhuang-Alxa terrane were separated from each other, belonging to different plate systems of the North China craton and Yangtze platform respectively. The Qilian orogenic belt was the same as or similar to the Qiling orogenic belt in terms of the geological evolution history at least before the Jinningian period.
基金Funding for this research was provided by a NSERC Discovery Grant(No.RGPIN/341715-2013)to S.Hubbard and a Queen Eliz-abethⅡscholarship from the University of Calgary to D.Coutts
文摘The calculation of a maximum depositional age(MDA)from a detrital zircon sample can provide insight into a variety of geological problems.However,the impact of sample size and calculation method on the accuracy of a resulting MDA has not been evaluated.We use large populations of synthetic zircon dates(N≈25,000)to analyze the impact of varying sample size(n),measurement uncertainty,and the abundance of neardepositional-age zircons on the accuracy and uncertainty of 9 commonly used MDA calculation methods.Furthermore,a new method,the youngest statistical population is tested.For each method,500 samples of n synthetic dates were drawn from the parent population and MDAs were calculated.The mean and standard deviation of each method ove r the 500 trials at each n-value(50-1000,in increments of 50)were compa red to the known depositional age of the synthetic population and used to compare the methods quantitatively in two simulation scenarios.The first simulation scenario varied the proportion of near-depositional-age grains in the synthetic population.The second scenario varied the uncertainty of the dates used to calculate the MDAs.Increasing sample size initially decreased the mean residual error and standard deviation calculated by each method.At higher n-values(>~300 grains),calculated MDAs changed more slowly and the mean resid ual error increased or decreased depending on the method used.Increasing the p roportion of near-depositional-age grains and lowering measurement uncertainty decreased the number of measurements required for the calculated MDAs to stabilize and decreased the standard deviation in calculated MDAs of the 500 samples.Results of the two simulation scenarios show that the most successful way to increase the accuracy of a calculated M DA is by acquiring a large number of low-uncertainty measurements(300300)approach is used if the calculation of accurate MDAs are key to research goals.Other acquisition method s,such as high-to moderate-precision measurement methods(e.g.,1%-5%,2σ)acquiring low-to moderate-n datasets(50300).Additionally,they are most susceptible to producing erroneous MDAs due to contamination in the field or laboratory,or through disturbances of the youngest zircon’s U-Pb systematics(e.g.,lead loss).More conservative methods that still produce accurate MDAs and are less susceptible to contamination or lead loss include:youngest grain cluster at 1σunce rtainty(YGC 1σ),youngest grain clusterat 2σuncertainty(YGC 2σ),and youngest statistical population(YSP).The ages calculated by these methods may be more useful and appealing when fitting calculated MDAs in to pre-existing chronostratigraphic frameworks,as they are less likely to be younger than the true depositional age.From the results of our numerical models we illustrate what geologic processes(i.e.,tectonic or sedimentary)can be resolved using MDAs derived from strata of different ages.
基金China's National Key Basic Research Project(No.200ICB409810) China's National Scientific and Technical Project"Compositive Research of Exploration of Preponderant Metallic Resources in Xinjiang”(No.2001BA609A-07-18).
文摘There have been conflicting ideas about the Indosinian mineralization in E. Xinjiang, a subject that has attracted many geologists' attention over a long period. Isotopic dating shows that the Shiyingtan gold deposit located on the southern margin of the Turpan-Hami basin has a quartz fluid inclusion Rb-Sr isochron age of 237±9 Ma (95% conf.); the Shuangfengshan gold deposit on the southern margin of the Junggar orogenic belt has a quartz fluid inclusion Rb-Sr isochron age of 226 ±21 Ma (95% conf.); the Weiya vanadium-titanium magnetite in the E. Tianshan mountains has a mineral-whole rock Sm-Nd isochron age of 220 ±30 Ma (95% conf.); the Jinwozi and Jinwozi 210 gold deposits in the E. Tianshan mountains have quartz fluid inclusion Rb-Sr isochron ages of 228±22 Ma (95% conf.) and 230±6 Ma (95% conf.), respectively; and the Xiaobaishitouquan scheelite deposit in the E. Tianshan mountains has a quartz fluid inclusion Rb-Sr isochron age of 248±7 Ma (95% conf.). The metallogenetic ages mentioned above prove the existence of Indosinian mineralization in E. Xinjiang, and the metallogenetic event might have been related to Triassic intraplate magmatic evolution, intra-continent subduction, strike-slip shoving and ductile shearing in the studied area, representing another mineralization peak after the Late Paleozoic.
文摘A huge thrust system, the North Lhasa Thrust (NLT), was discovered in the northern Lhasa block of the Tibetan Plateau based on geological mapping of the Damxung region and its vicinity, the Deqen-Lunpola traverse and the Amdo-Bam Co profile. The NLT consists of the Dongqiao-Lunpola thrust (DLT), the west Namco thrust (WNT) and the south Damxung thrust (SDT) and ductile shear zones, ophiolite slices and folds extending in a WNW direction. Major thrust faults of the NLT seem to merge into a single deep-seated detachment of the upper-crust and totally displaced southward as far as 100-120 km. Chronological analyses with 39Ar-40Ar of plagioclase and hornblende, Rb-Sr isochron of minerals and fission-tracks of apatite from mylonite within the WNT yield ages of 174-173 Ma, 109 Ma and 44 Ma, showing 3 periods of thrusting in the north Lhasa block caused by subduction of the Tethys oceanic plate and the India-Eurasia continental collision respectively.
文摘The high-Mg diorites, widely occurring in western Shandong, have important implications in the study of the relationship between the Mesozoic magmatism and the nature of the lithosphere and its thinning period in the eastern North China craton (NCC). The Tietonggou and Jinling intrusions are typically representatives. LA-ICP-MS zircon U-Pb dating, major and trace element and Sr-Nd isotopic compositions of the Mesozoic intrusive rocks from western Shandong, eastern China, were analyzed. The weighted mean 106^pb/ 238^U ages from LA-ICP-MS zircon U-Pb dating results for early norite-diorite, late pyroxene-diorite from the Tietonggou intrusion and biotite-diorite from the Jinling intrusion are (131.4±4.9) Ma(n=15), (134. 5±2.3) Ma(n=13), and (132.8±4. 2) Ma(n=12), respectively, implying that they were formed in the Early Cretaceous. The weighted mean 207^pb/ 204^Pb ages for round zircons from late pyroxene-diorite in the Tietonggou intrusion is ( 2 513 ± 54) Ma( n= 8), suggesting that the basement of the North China craton should exist in the research area. The high-Mg diorites are characterized by enrichment in MgO, Na20, and light rare earth elements (LREE), and they are poor in heavy rare earth elements (HREE) and high field strength elements (HFSE), being similar to adakite. The existence of the mantle peridotite xenoliths with a high-Mg feature for these intrusive rocks implies that their primary magma should be derived from the upper mantle. However, Sr-Nd isotopic composi- tions (Is: 0.704 75--0.707 15;ENd (130 Ma) values: --3.95 to -- 13.30), depletion in HFSE, and the occurrence of Archean inherited zircons suggest that crustal materials could be involved in the derivation of the primary magma. The compositional difference between the diorites from the Tietonggou and Jinling intrusions could be attributed to those of magma sources and degrees of partial melting. The Early Cretaceous high-Mg diorites are considered to have been formed by the mixed melting of the delaminated lithosphere (lithospheric mantle + crust) and asthenosphere, based on their geochemistry, the mantlederived xenoliths, and the Early Mesozoic lithospheric evolutionary history of the eastern North China craton.
基金granted by the foundamental research funds for central public welfare research institutes(Grant No.K1313)the Natural Sciences Foundation of China(Grant No.41302080)China State Geological Investigation Program(Grant No.1212011121091,12120114009401)
文摘The Xuhe mafic rocks, located in Ziyang county of Shaanxi Province, are dominated by diabase-porphyrite, gabbro-diabase, diabase, and pyroxene diorite. Primitive mantle-normalized multi-element patterns show that, the Xuhe marie rocks are enriched in large ion lithophile elements (LITE), such as Ba and Pb, depleted in K and Sr for basic rocks, and are depleted in Sr, P and Ti for pyroxene diorite. Chondrite-normalized REE patterns display LREE enrichment (LaN/YbN = 9.34- 13.99) and have normalized patterns for trace element and REE similar to that of typical OIB. Detailed SIMS zircon U-Pb dating yields emplacement ages of 438.4 ± 3.1 Ma for Xuhe mafic rocks. The relatively low MgO (basic rock: 3.11-7.21 wt%; pyroxene diorite: 0.89-1.21 wt% ) and Mg# (0.20- 0.49) for Xuhe mafic rocks suggest that they were possibly originated from an extremely evolved magma. The rising parental mafic magmas underwent pyroxene and plagioclase fractionation. Crustal contamination of pyroxene diorite before emplacement occurred at a higher crustal level compared to other lithology in Xuhe mafic rocks. The degree of partial melt was low (5%-10%) and in garnetspinel transition facies. Sr-Nd isotope of pyroxene diorite and enrichment mantle characteristics for Xuhe mafic rocks suggest that mafic rocks in the North Daba Mountains were derived from a mixture of HIMU, EMII and small amount of EMI components. Furthermore, this study discusses mantle geodynamic significance of Xuhe mafic rocks in the Silurian, which indicates subduction and uplift of magma caused back-arc extension.
文摘The Qinling-Dabie-Sulu high-pressure and ultra-high pressure metamorphic belt wasformed by subduction and collision between the North China and Yangtze plates. The study ofthe eclogite belt is very important in understanding the evolution of the Qinling Dabie orogen. Inthe present paper the geology, petrology, minerology and chronology of the eclogites in the Dabieand Sulu areas are described. The principal conclusions of this work are as follows: (1) Based up-on the field occurrence and the P-T conditions of the eclogites, two types of eclogite can be dis-tinguished: Type 1—the low-temperature and high-pressure eclogite in the mid-late Proterozoicmetamorphic series, and Type 2—the ultra-high pressure eclogite in the late Archaean to earlyProterozoic metamorphic complex. In the Dabie area, the ultra-high-pressure eclogite,high-pressure eclogite and epidote-blueschist units are nearly parallel to each other and stretchintermittently from north to south. (2) The P-T conditions of the high-pressure eclogites and ul-tra-high pressure eclogites have been estimated. The former are formed at 450-550℃ and1.4-1.6 GPa; while the latter at 650-870℃ and >2.7-2.9 GPa in the Dabie area and at820-1000℃ and >2.8-3.1 GPa in the Sulu area. The metamorphic temperatures of the eclogitesincrease progressively from west to east. (3) The ultra-high pressure eclogites were subjected to 5stages of metamorphism: pre-eclogite epidote amphibolite facies, peak coesite eclogite facies,post-eclogite amphibolite facies, epidote-blueschist facies or epidote amphibolite facies andgreenschist facies. The general features of the PTt path of the ultra-high pressure eclogite are:clockwise pattern, progressive metamorphism being a process of slow increasing temperature andrapid increasing pressure, and the retrogressive section with nearly isothermal decompression atthe early stage, isobaric cooling at the middle stage and nearly isothermal decompression at thelate stage. (4) At least two stages of high-pressure metamorphism occurred in the orogenic belt:the high-pressure eclogite and ultra-high pressure eclogite were formed by the subduction of theoceanic crust northward beneath the North China plate or the Dabie block during theCaledonian; while the epidote-blueschist belt came into being by subdution and collision be-tween the two continental plates during the Indosinian. (5) Due to the continuous sequentialsubduction of the cold plate, the ultra high-presssure metamorphic rocks were uplifted to thecrust by the underplating processes. They can be preserved just because of the 'frozen effect' re-sulting from the continuous subduction of the cold plate. (6) The carbonates, such as magnesite,breunnerite, aragonite and dolomite, and the H_2O-bearing minerals, such as phengite, epidoteand zoisite, were stable during the high-pressure and/or ultra-high pressure metamorphism.
基金funded by the Program forthe New Century Excellent Tallents in Ministry of Education (No.NCET-09-0710)the National Natural Science Foundation of China (No.40872068 and40672064)+1 种基金the Program for Changjiang Scholars and Innovative Research Team in Ministry of Education(No.IRT0755)the "111" Project (No.B07011)
文摘The Niutougou gold deposit, located in the center of the Xiong'ershan gold district, western Henan Province, is a large gold deposit with many quartz porphyries found in the area. Based on the field geological investigation of quartz porphyry of Niutougou gold deposit and by using the cathodoluminescence (CL) images analysis and in situ LA-ICP-MS U-Pb isotope dating method of zircons, the inner structure, trace element compositions and U-Pb age of the zircons separated from quartz porphyry were analyzed and determined. Cathodoluminescence (CL) images of zircons show clear magmatic zonations. Trace element analyses of zircons reveal that all zircons show high concentrations of Th, U, and HREE, and the REE patterns of depletion in LREE, with a positive Ce anomaly. Zircon LA-ICP-MS U-Pb dating results show that the quartz porphyry in the Niutougou gold deposit was formed at 159.714-0.99 Ma (about 160 Ma), belonging to the product of magmatic activity in late Middle Jurassic. Combined with the geological characteristics of the Niutougou gold deposit, the formation age of the quartz porphyry and the analysis of the formation age of the granite body exposed in the Niutougou gold deposit, the study suggests that the metallogenic epoch of the Niutougou gold deposit may be Yanshanian in age.
基金funded by the work programs of the China Geological Survey (1212011086020)the National Natural Science Foundation of China (41272093)
文摘In this paper we present new zircon U-Pb ages,whole-rock major and trace element analyses,and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture.Our aim is to constrain the Early Permian-Late Triassic tectonic evolution of the region.Zircons from the magmatic rocks of the Tuotuohe region are euhedralsubhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios (0.4-4.6),indicating a magmatic origin.The zircon U-Pb ages obtained using LA-ICP-MS are 281 ± 1 Ma,258 ± 1 Ma,244 ± 1 Ma,and 216 ± 1 Ma,which indicate magmatism in the Early Permian-Late Triassic.A diorite from Bashihubei (BSHN) has SiO2 =57.18-59.97 wt%,Al2O3=15.70-16.53 wt%,and total alkalis (Na2O + K2O) =4.46-6.34 wt%,typical of calc-alkaline and metaluminous series.A gabbro from Bashibadaoban (BSBDB) belongs to the alkaline series,and is poor in SiO2 (45.46-54.03 wt%) but rich in Al2O3 (16.19-17.39 wt%) and total alkalis (Na2O + K2O =5.48-6.26 wt%).The BSHN diorite and the BSBDB gabbro both display an enrichment of LREEs and LILEs and depletion of HFSEs,and they have no obvious Eu anomaly; they have relatively low MgO contents (2.54-4.93 wt%),Mg# values of 43 to 52,and low Cr and Ni contents (8.07-33.6 ppm and 4.41-14.2 ppm,respectively),indicating they differentiated from primitive mantle magmas.They have low Nb/U,Ta/ U,and Ce/Pb ratios (1.3-9.6,0.2-0.8,and 0.1-18.1,respectively),and their initial Hf isotopic ratios range from +9.6 to +16.9 (BSHN diorite) and +6.5 to +12.6 (BSBDB gabbro),suggesting their primary magmas were derived mainly from the partial melting of a mantle wedge that had been metasomatized by subduction fluids.Taking all the new data together,we conclude that the western and eastern segment of the Jinshajiang suture regions underwent identical processes of evolution in the Early Permian-Late Triassic:oceanic crust subduction before the Early Permian,continental collision during the Early-Middle Triassic,and post-collisional extension from the Late Triassic.
基金supported by the National Natural Science Foundation of China (No. 40576035), IGCP464Chinese Offshore Investigation and Assessment (No. 908-01-ZH2)
文摘Two robust precipitation reconstructions were conducted by combining tree-ring chronologies, dryness/wetness indices from historical documents, and climate data from the global grid. It was found that the recurrent drought history of a region can help us understand the variability of precipitation. Several dry/wet periods during the past four centuries and potential cycles of precipitation variation were determined. Furthermore, the reconstructions are not only consistent well with each other in North-central China, but also in good agreement with variations of precipitation in northeastern Mongolia, the Longxi area in Gangsu Province and the Dulan area of Qinghai Province, and the snow accumulation of the Guliya glacier. These synchronous variations indicate that it is valuable to study various climate records, find common information and determine the driving force of climate change.
基金supported by the National 973 Project of China(G1999043201)
文摘Lead isotopic analytic data of 30 ores gathered from the Zhuanmiao boron deposit, Wengquangou boron (iron) deposit and its Dongtaizi Ore Member constitute three isochrons, the corresponding ages of which are 1902 ± 12 Ma, 1852 ± 9 Ma and 1917 ± 48 Ma. Lead isotopic analyses of marble from the Xiquegou Member of the Qingchenzi orefield yield a Pb-Pb isochron age of 1844 ± 27 Ma. 40Ar-39Ar quick neutron activation dating of phlogopites and microclines coexisting with ore minerals in the Wengquangou boron (iron) and Zhuanmiao boron deposits shows that: (1) the phlogopite from the Wengquangou has a plateau age of 1923 ± 1.5 Ma and an isochron age of 1924 ± 2.5 Ma; (2) the microcline from the Wengquangou has the plateau age of 1407 ± 5.4 Ma and 220 ± 12 Ma and an isochron age of 1403 ± 19 Ma; (3) the phlogopites from the Zhuanmiao yield a plateau age 1918 ± 1.3 Ma and an isochron age of 1918 ± 2.9 Ma; (4) the microclines from the Zhuanmiao yield the plateau age of 1420 ± 16 Ma and 250 ± 8 Ma and an isochron age of 1425 ± 19 Ma and 269 ± 16 Ma. These ages indicate that the eastern Liaoning area happened around 1900 Ma, an important tectonomagmatic event, which is consistent with the worldwide Mid-Proterozoic tectonomagmatic event. During this period, the Proterozoic Liaohe Group was folded and underwent strong normal metamorphism, and the (hydrothermal) sedimentary boron deposits (or source beds) formed earlier were strongly superimposed by mineralization, resulting in enrichment of boron; later regional geological processes made little contribution to the formation of the boron deposits. Lead isotopic components show that the U-Pb and Th-Pb isotopic system reached homogenization in the ores whereas only the U-Pb isotopic system reached homogenization in the marble from the Xiquegou district, which indicates that the boron deposits superimposed in the studied area endured a relatively strong process of hydrothermal migmatization during the end phase of early Proterozoic metamorphism.
文摘Based on the Rb-Sr isochron dating results, this paper suggests that the alkaline intrusive belt at the east foot of the Taihang-Da Hinggan Mountains were formed between 135 and 122 Ma. And the alkaline intrusives in the north and south sections of this belt have entirely different Sr, Nd and Pb isotopic characteristics, i.e., all the rocks in the south section have positive εSr(t) and negative εNd(t) values and all those in the north have the opposite values. On the εSr(t) versus εNd(t) correlation diagram, the samples from the south are concentrated along the enriched mantle evolution trend lines and nearby, while those from the north fall along the depleted mantle trend lines and nearby. On the Pb isotope composition diagram, most of the samples from the south section fall on the mantle Pb evolution line and nearby, while those from the north lie between the Pb evolution lines of the mantle and the erogenic belt. The above-stated isotopic characteristics not only indicate that the source rocks of the alkaline intrusives in the south section have a close connection to materials from the enriched mantle reservoir, while those in the north are related to materials from the depleted one, but also reveal that the upper mantle below the North China platform is enriched and that below the Inner Mongolia geosyncline is depleted.
基金financially supported by the National Key Technology Research and Development Program of China (No. 2011BAB06B04)
文摘Shadong deposit is the first large-scale tungsten deposit found in the East Tianshan orogenic belt, and the geologic characteristics of the deposit indicate that the deeply concealed granite body is ge- netically related with the mineralization. The LA-ICPMS U-Pb age of zircons from the Shadong concealed granite obtained in this research is 239±2.0 Ma, belonging to the Middle Triassic. The whole rock samples are metaiuminous to slightly peraluminous (A/CNK=0.95-1.02) with low contents of SiO2 (64.0 wt.%-68.5 wt.%) and low K2O/Na2O ratios (0.73-0.96). The samples reveal enrichment of K, Rb, Th and depletion of Nb, Ta, P, Ti and have a negative slope from La to Lu (LaN/YbN=16.29-36.8) with weak negative Eu anom- aly (Eu/Eu*= 0.71-0.82). Initial ^87Sr/^86Sr ratios of whole rock range of 0.706 59-0.707 75, eNd(t) values range from -1.77 to -2.53 and εnf(t) values of zircon are between 2.54 and 4.90. The lithogeochemistry and Sr-Nd-Hf isotopic characteristics revealed that the concealed granite in Shadong tungsten deposit is I-type granite, and occurs in an intraplate tectonic setting. The magma mixing during intraplating of mantle de- rived magma intruding into the crust in Indosinian Period is the major formation mechanism of the granite. Of which, the proportion of mantle derived magma ranges from 58% to 60%, and the crustal materials are mainly the metamorphic basement of Xingxingxia Group of Mesoproterozoic Changcheng System, which may orovide the main source of ore forming metals of Shadong tungsten deposit.