Nowadays,both n-i-p and p-i-n perovskite solar cells（PSCs） device structures are reported to give high performance with photo conversion efficiencies（PCEs） above 20%.The efficiency of the PSCs is fundementally det...Nowadays,both n-i-p and p-i-n perovskite solar cells（PSCs） device structures are reported to give high performance with photo conversion efficiencies（PCEs） above 20%.The efficiency of the PSCs is fundementally determined by the charge selective contact materials.Hence,by introducing proper contact materials with good charge selectivity,one could potentially reduce interfacial charge recombination as well as increase device performance.In the past few years,copious charge selective contact materials have been proposed.Significant improvements in the corresponding devices were observed and the reported PCEs were close to that of classic Spiro-OMeTAD.This mini-review summarizes the state-of-the-art progress of typical electron/hole selective contact materials for efficient perovskite solar cells and an outlook to their development is made.展开更多
Developing an efficient electron transport layer(ETL)through structural modification is essential to produce high-performance perovskite solar cell(PSC)devices.Specifically,the ETL should exhibit low defects,high opti...Developing an efficient electron transport layer(ETL)through structural modification is essential to produce high-performance perovskite solar cell(PSC)devices.Specifically,the ETL should exhibit low defects,high optical transparency,and charge selectivity for ideal electron transport.Herein,we demonstrate(i)the low-temperature fabrication of tin oxide(SnO_(2))ETLs with a bilayer structure,and(ii)inkjetprinting of triple-cation perovskite films.Through the combined use of spin-coating and spray deposition,the optimized SnO_(2)-bilayer ETL shows a nano-granule-textured surface,noticeably fewer defects,and a cascade conduction band position with the inkjet-printed perovskite film.The champion PSC device,based on the SnO_(2)-bilayer ETL and inkjet-printed perovskite film,recorded an outstanding power conversion efficiency(PCE)of~16.9%,which is significantly higher than the device based on the conventional SnO_(2)ETL(PCE~14.8%).The improved photovoltaic performance of the SnO_(2)-bilayer-based device arises mainly from more efficient charge transport and suppressed recombination at the ETL/perovskite interface.The SnO_(2)-bilayer ETL and inkjet-printed perovskite films demonstrated herein can be potentially used for large-scale manufacturing of photovoltaic modules.展开更多
Perovskite solar cells(PSCs)have achieved remarkable advancements in recent years[1].Devices achieving high power conversion efficiencies(PCEs)typically rely on molecular contacts featuring conjugated cores[2].The pla...Perovskite solar cells(PSCs)have achieved remarkable advancements in recent years[1].Devices achieving high power conversion efficiencies(PCEs)typically rely on molecular contacts featuring conjugated cores[2].The planar and conjugated cores facilitate ordered molecular stacking throughπ-πinteractions,thereby enhancing charge transport and selectivity[3,4].展开更多
Osmotic power generation in biomimetic nanofluidic systems has attracted considerable research interest owing to the enhanced performance and long-term stability. Towards practical applications, when extrapolating the...Osmotic power generation in biomimetic nanofluidic systems has attracted considerable research interest owing to the enhanced performance and long-term stability. Towards practical applications, when extrapolating the materials from single-nanopore to multi-pore membranes, conventional viewpoint suggests that, to gain high electric power density, the porosity should be as high as possible. However, recent experimental observations show that the commonly-used linear amplification method largely overestimates the actual performance, particularly at high pore density. Herein, we provide a theoretical investigation to understand the reason. We find a counterintuitive pore-density dependence in high porosity nanofluidic systems that, once the pore density approaches more than lx109 pores/cm2, the overall output electric power goes down with the increasing pore density. The excessively high pore density impairs the charge selectivity and induces strong ion concentration polarization, which undermines the osmotic power generation process. By optimizing the geometric size of the nanopores, the performance degradation can be effectively relieved. These findings clarify the origin of the unsatisfactory performance of the current osmotic nanofluidic power sources, and provide insights to further optimize the device.展开更多
基金the National Natural Science Foundation of China(No.21404045)the financial support from "Hundred Talents Program" of the Haixi Institute Chinese Academy of Sciences(No.1017001)
文摘Nowadays,both n-i-p and p-i-n perovskite solar cells（PSCs） device structures are reported to give high performance with photo conversion efficiencies（PCEs） above 20%.The efficiency of the PSCs is fundementally determined by the charge selective contact materials.Hence,by introducing proper contact materials with good charge selectivity,one could potentially reduce interfacial charge recombination as well as increase device performance.In the past few years,copious charge selective contact materials have been proposed.Significant improvements in the corresponding devices were observed and the reported PCEs were close to that of classic Spiro-OMeTAD.This mini-review summarizes the state-of-the-art progress of typical electron/hole selective contact materials for efficient perovskite solar cells and an outlook to their development is made.
基金financially supported by the Basic Science Research Program(NRF-2021R1A2C2004206)the Creative Materials Discovery Program(NRF-2017M3D1A1039287)through the National Research Foundation(NRF)of Korea,funded by the MSIT+1 种基金supported by the Technology Innovation Program(20016283)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)supported by the selection of a research-oriented professor at Jeonbuk National University in 2023.
文摘Developing an efficient electron transport layer(ETL)through structural modification is essential to produce high-performance perovskite solar cell(PSC)devices.Specifically,the ETL should exhibit low defects,high optical transparency,and charge selectivity for ideal electron transport.Herein,we demonstrate(i)the low-temperature fabrication of tin oxide(SnO_(2))ETLs with a bilayer structure,and(ii)inkjetprinting of triple-cation perovskite films.Through the combined use of spin-coating and spray deposition,the optimized SnO_(2)-bilayer ETL shows a nano-granule-textured surface,noticeably fewer defects,and a cascade conduction band position with the inkjet-printed perovskite film.The champion PSC device,based on the SnO_(2)-bilayer ETL and inkjet-printed perovskite film,recorded an outstanding power conversion efficiency(PCE)of~16.9%,which is significantly higher than the device based on the conventional SnO_(2)ETL(PCE~14.8%).The improved photovoltaic performance of the SnO_(2)-bilayer-based device arises mainly from more efficient charge transport and suppressed recombination at the ETL/perovskite interface.The SnO_(2)-bilayer ETL and inkjet-printed perovskite films demonstrated herein can be potentially used for large-scale manufacturing of photovoltaic modules.
文摘Perovskite solar cells(PSCs)have achieved remarkable advancements in recent years[1].Devices achieving high power conversion efficiencies(PCEs)typically rely on molecular contacts featuring conjugated cores[2].The planar and conjugated cores facilitate ordered molecular stacking throughπ-πinteractions,thereby enhancing charge transport and selectivity[3,4].
文摘Osmotic power generation in biomimetic nanofluidic systems has attracted considerable research interest owing to the enhanced performance and long-term stability. Towards practical applications, when extrapolating the materials from single-nanopore to multi-pore membranes, conventional viewpoint suggests that, to gain high electric power density, the porosity should be as high as possible. However, recent experimental observations show that the commonly-used linear amplification method largely overestimates the actual performance, particularly at high pore density. Herein, we provide a theoretical investigation to understand the reason. We find a counterintuitive pore-density dependence in high porosity nanofluidic systems that, once the pore density approaches more than lx109 pores/cm2, the overall output electric power goes down with the increasing pore density. The excessively high pore density impairs the charge selectivity and induces strong ion concentration polarization, which undermines the osmotic power generation process. By optimizing the geometric size of the nanopores, the performance degradation can be effectively relieved. These findings clarify the origin of the unsatisfactory performance of the current osmotic nanofluidic power sources, and provide insights to further optimize the device.
