In recent decades,annual urban fire incidents,including those involving ancient wooden buildings burned,transportation,and solar panels,have increased,leading to significant loss of human life and property.Addressing ...In recent decades,annual urban fire incidents,including those involving ancient wooden buildings burned,transportation,and solar panels,have increased,leading to significant loss of human life and property.Addressing this issue without altering the surface morphology or interfering with optical behavior of flammable materials poses a substantial challenge.Herein,we present a transparent,low thickness,ceramifiable nanosystem coating composed of a highly adhesive base(poly(SSS1-co-HEMA1)),nanoscale layered double hydroxide sheets as ceramic precursors,and supramolecular melamine di-borate as an accelerator.We demonstrate that this hybrid coating can transform into a porous,fire-resistant protective layer with a highly thermostable vitreous phase upon exposure to flame/heat source.A nanosystem coating of just~100μm thickness can significantly increase the limiting oxygen index of wood(Pine)to 37.3%,dramatically reduce total heat release by 78.6%,and maintain low smoke toxicity(CIT_G=0.016).Detailed molecular force analysis,combined with a comprehensive examination of the underlying flame-retardant mechanisms,underscores the effectiveness of this coating.This work offers a strategy for creating efficient,environmentally friendly coatings with fire safety applications across various industries.展开更多
Some ablation experiments of Ethylene-Propylene-Diene Monomer(EPDM)insulator were carried out in quasi-static low temperature gas environment,gas-phase environment,two-phase environment with Al2O3 grain and high conce...Some ablation experiments of Ethylene-Propylene-Diene Monomer(EPDM)insulator were carried out in quasi-static low temperature gas environment,gas-phase environment,two-phase environment with Al2O3 grain and high concentration Al2O3 grain gas environments.Their charring ablation rate,thickness,surface morphology and main ingredient of the charring layer were analyzed.The experiment results show that the main influent factors for the charring ablation rate are the gas temperature,grain concentration and state of grain impact;the main influent factors for the charring layer thickness are the gas velocity and environment pressure;and the process of SiO2 migrating in the charring layer occur commonly in different gas environments.They provide a foundation for the ablation mechanism research and modeling of EPDM insulator.展开更多
This study numerically simulated and investigated the flow field characteristics of a typical dual-pulse solid rocket motor with a soft pulse separation device through thermal insulation ablation under high-temperatur...This study numerically simulated and investigated the flow field characteristics of a typical dual-pulse solid rocket motor with a soft pulse separation device through thermal insulation ablation under high-temperature dual-pulse erosion.The ablation rate of ethylene-propylene-diene monomer(EPDM)insulator was measured after the experiment.Experimental results were analyzed through scanning electron microscopy and microcomputed tomography.The ablation mechanism of the EPDM insulator under the operation conditions of a dual-pulse solid rocket motor was evaluated by analyzing the results.The results reveal that the internal flow field of the motor with a soft pulse separation device is uniform.The original charred layer existing on the EPDM insulator surface in the first pulse combustor is the decisive factor affecting the final ablation rate of the dual-pulse motor during the second pulse operation,and the ablation characteristic region is easily formed with the exfoliation of the charred layer.The ablation rate difference of the insulator increases with gas velocity.展开更多
基金the financial support from the National Natural Science Foundation of China(524B2168,U22A20149,52173081,and 52273275)。
文摘In recent decades,annual urban fire incidents,including those involving ancient wooden buildings burned,transportation,and solar panels,have increased,leading to significant loss of human life and property.Addressing this issue without altering the surface morphology or interfering with optical behavior of flammable materials poses a substantial challenge.Herein,we present a transparent,low thickness,ceramifiable nanosystem coating composed of a highly adhesive base(poly(SSS1-co-HEMA1)),nanoscale layered double hydroxide sheets as ceramic precursors,and supramolecular melamine di-borate as an accelerator.We demonstrate that this hybrid coating can transform into a porous,fire-resistant protective layer with a highly thermostable vitreous phase upon exposure to flame/heat source.A nanosystem coating of just~100μm thickness can significantly increase the limiting oxygen index of wood(Pine)to 37.3%,dramatically reduce total heat release by 78.6%,and maintain low smoke toxicity(CIT_G=0.016).Detailed molecular force analysis,combined with a comprehensive examination of the underlying flame-retardant mechanisms,underscores the effectiveness of this coating.This work offers a strategy for creating efficient,environmentally friendly coatings with fire safety applications across various industries.
基金Sponsored by the National Nature Science Foundation of China(50876091)
文摘Some ablation experiments of Ethylene-Propylene-Diene Monomer(EPDM)insulator were carried out in quasi-static low temperature gas environment,gas-phase environment,two-phase environment with Al2O3 grain and high concentration Al2O3 grain gas environments.Their charring ablation rate,thickness,surface morphology and main ingredient of the charring layer were analyzed.The experiment results show that the main influent factors for the charring ablation rate are the gas temperature,grain concentration and state of grain impact;the main influent factors for the charring layer thickness are the gas velocity and environment pressure;and the process of SiO2 migrating in the charring layer occur commonly in different gas environments.They provide a foundation for the ablation mechanism research and modeling of EPDM insulator.
基金financially supported by the National Natural Science Foundation of China,under grant numbers 51876177,51276150,and 51576165。
文摘This study numerically simulated and investigated the flow field characteristics of a typical dual-pulse solid rocket motor with a soft pulse separation device through thermal insulation ablation under high-temperature dual-pulse erosion.The ablation rate of ethylene-propylene-diene monomer(EPDM)insulator was measured after the experiment.Experimental results were analyzed through scanning electron microscopy and microcomputed tomography.The ablation mechanism of the EPDM insulator under the operation conditions of a dual-pulse solid rocket motor was evaluated by analyzing the results.The results reveal that the internal flow field of the motor with a soft pulse separation device is uniform.The original charred layer existing on the EPDM insulator surface in the first pulse combustor is the decisive factor affecting the final ablation rate of the dual-pulse motor during the second pulse operation,and the ablation characteristic region is easily formed with the exfoliation of the charred layer.The ablation rate difference of the insulator increases with gas velocity.
