Overcoming kinetic limitations in the acidic oxygen reduction reaction(ORR)demands Pt-based catalysts with optimized surface adsorption.Herein,we engineer hierarchical PtPd dendrite nanocrystals(PtPd NDs)featuring pre...Overcoming kinetic limitations in the acidic oxygen reduction reaction(ORR)demands Pt-based catalysts with optimized surface adsorption.Herein,we engineer hierarchical PtPd dendrite nanocrystals(PtPd NDs)featuring precisely tailored asymmetric sites and high-index facets(HIFs)to overcome the kinetic limitations in acidic media.Controlled Pd incorporation disrupts symmetry of the single-oriented crystal plane,generating inhomogeneous strain and promoting HIFs exposure.This synergistic structural engineering optimizes the adsorption/desorption of oxygen-containing intermediates,significantly accelerating ORR kinetics.Consequently,PtPd NDs deliver exceptional mass activity(MA=1.37 A mg_(Pt)^(-1),11.42 times higher than Pt/C)and remarkable stability(83.9%MA retention after durability testing).In H_(2)-Air fuel cells,PtPd NDs also achieve higher peak power density versus Pt/C cathodes.In situ synchrotron radiation infrared spectroscopy and theoretical studies reveal that the synergistic effect between asymmetric sites and HIFs stimulates the strain field and causes a downward shift in the d-band center,thereby lowering the*OOH formation barrier and weakening intermediate adsorption,directly boosting the ORR performance.This work underscores the critical role of facet and site engineering in designing high-performance fuel cell electrocatalysts.展开更多
This study focuses on reconstructing the"reader-centered"paradigm in the teaching of high school English literary text reading,supported by Reception Aesthetics as its theoretical foundation.High school Engl...This study focuses on reconstructing the"reader-centered"paradigm in the teaching of high school English literary text reading,supported by Reception Aesthetics as its theoretical foundation.High school English literary text reading plays a significant role in cultivating students'language proficiency,cultural awareness,and aesthetic literacy.However,the current teaching practice in this area remains dominated by the traditional"teacher-centered"approach,which restricts students'active participation and the realization of the pluralistic value of literary texts.By integrating core concepts of Reception Aesthetics-such as"horizon of expectations,""structure of appeal,"and"interpretive community"-this research addresses the gap in existing studies,which have largely focused on the application of Reception Aesthetics in Chinese language teaching or college English instruction.Using literature research and classroom practice analysis,the study reconstructs the"reader-centered"paradigm across three dimensions:teaching objectives,teaching process,and evaluation methods.It also identifies practical challenges,including uneven student participation,time constraints,and difficulties in the teacher's role adaptation,and proposes corresponding optimization strategies.Practical results demonstrate that this paradigm effectively enhances students'reading engagement,text interpretation skills,and critical thinking.Future research may further expand text types and integrate information technology to continuously improve teaching effectiveness.展开更多
The hydrazine oxidation-assisted hydrogen generation system significantly expands the applicability of hydrogen production technology.However,the complex intermediate transformations involved in the hydrazine oxidatio...The hydrazine oxidation-assisted hydrogen generation system significantly expands the applicability of hydrogen production technology.However,the complex intermediate transformations involved in the hydrazine oxidation reaction(HzOR)and hydrogen evolution reaction(HER)desperately need the development of dual-functional catalysts.Manipulating the d-band center of metal catalysts has been identified as one of the most effective approaches to enhance catalytic activity.Herein,Ir nanoparticles(NPs)anchored in B,N-codoped porous carbon(Ir@BNC)were developed and demonstrate excellent performances for both HER and HzOR in an alkaline medium,achieving 10 mA cm^(-2) at-25 and 18 mV,respectively.The overall hydrazine splitting(OHzS)electrolyzer reaches 200 mA cm^(-2) with a cell voltage of just 0.68 V.The direct liquid N2H4/H2O_(2) fuel cell(DHHPFC)assembly with Ir@BNC can achieve a maximum power density of 199.2 mW cm^(-2) at room temperature.Furthermore,an H2 production system using an OHzS device powered by DHHPFC realizes hydrogen production at a stable rate(53.08 mol h^(-1) m^(-2)).In-situ Raman tests and theoretical calculations unravel the metal-support interaction between Ir NPs and B,N-codoped porous carbon,optimizing the electronic structure and regulating the d-band center of Ir,reducing the adsorption energy of H*intermediates and N2H4 molecules,thus promoting the reaction processes of HER and HzOR.展开更多
Organic-inorganic metal halides(OIMHs)have emerged as highly promising novel multifunctional optoelectronic materials,owing to their easily adjustable properties from a variety of combinations of different components....Organic-inorganic metal halides(OIMHs)have emerged as highly promising novel multifunctional optoelectronic materials,owing to their easily adjustable properties from a variety of combinations of different components.But it is still difficult and rare to realize highly tunable multicolor luminescence within the same material.In this work,we successfully incorporated three adjustable emission centers in OIMHs to synthesize a novel OIMH(NEA)_(2)MnBr_(4),with each emission center capable of emitting one of the primary colors—red,green,and blue.The green and red emissions originate from the tetrahedron and octahedron structures in the Mn-based frame,while the blue can be attributed to the contribution of organic components.Additionally,to achieve comparable emission intensity among the three primary colors,we enhanced the blue emission performance by optimizing the ratio of organic structure components and incorporating chirality in the OIMHs.The resulting high-quality films can be obtained by spin-coating method with a photoluminescence quantum yields of up to 96%.More interestingly,by the dual manipulation of excitation wavelength and temperature,the sample can be emitted at least seven distinct colors including a standard white luminescence at(0.33,0.33),opening up promising prospects for multicolor luminescence applications such as high-end anti-counterfeiting technology,light-emitting diodes,X-ray imaging,latent fingerprints,humidity detection,and so on.Therefore,based on application scenarios and requirements,our research on this highly tunable luminescent OIMH material lays a solid foundation for further development of various functional properties of related materials.展开更多
Rapid developments in the electronic information industry drive the increased energy usage and carbon emission of data center buildings,prompting the focus on the energy efficiency and environmental sustainability.Exp...Rapid developments in the electronic information industry drive the increased energy usage and carbon emission of data center buildings,prompting the focus on the energy efficiency and environmental sustainability.Expanded operation envelopes of tropical data centers is assessed to analyze the potential for the building energy savings and carbon emission reduction through collaborative analysis of operation modes(OMs),supply air temperature(SAT),and outdoor air temperature(OAT).The OMs of compression vary with the setpoints of SAT,in which the average exergy efficiency of compressors at alternate operation mode is 6.8%and 8.0%lower than that of double and single compression operations.As SAT rises from 20℃to 32℃,the system exergoeconomic factor increases from 5.4%to 8.0%,and the average carbon cost decreases by 36.5%.Additionally,with just an 8.5%increase in exergy cost(i.e.,Case 8)at OAT rising from 30 to 34℃,the high SAT and low refrigerant charges provide considerable exergy cost advantages versus resisting the OAT fluctuations.Dynamic operation strategies are also proposed and compared to cope with the impacts of tropical environments.Compared to the 26℃SAT baseline,the average energy savings are 9.1-14.7%,indicating the ability to fully utilize outdoor and indoor conditions.展开更多
Siemens and Yangpu Economic Development Zone in Hainan have forged a close partnership in a journey towards green energy transition.SIEMENS Energy,one of the world’s leading energy technology companies,became the fir...Siemens and Yangpu Economic Development Zone in Hainan have forged a close partnership in a journey towards green energy transition.SIEMENS Energy,one of the world’s leading energy technology companies,became the first foreign-funded manufacturer to establish a branch and began construction of a gas turbine assembly base and service center in Hainan on December 18,2025.展开更多
In this paper,we present an extrapolated parallel subgradient projection method with the centering technique for the convex feasibility problem,the algorithm improves the convergence by reason of using centering techn...In this paper,we present an extrapolated parallel subgradient projection method with the centering technique for the convex feasibility problem,the algorithm improves the convergence by reason of using centering techniques which reduce the oscillation of the corresponding sequence.To prove the convergence in a simply way,we transmit the parallel algorithm in the original space to a sequential one in a newly constructed product space.Thus,the convergence of the parallel algorithm is derived with the help of the sequential one under some suitable conditions.Numerical results show that the new algorithm has better convergence than the existing algorithms.展开更多
Multicollinearity constitutes shared variation among predictors that inflates standard errors of regression coefficients. Several years ago, it was proven that the common practice of mean centering in moderated regres...Multicollinearity constitutes shared variation among predictors that inflates standard errors of regression coefficients. Several years ago, it was proven that the common practice of mean centering in moderated regression cannot alleviate multicollinearity among variables comprising an interaction, but merely masks it. Residual centering (orthogonalizing) is unacceptable because it biases parameters for predictors from which the interaction derives, thus precluding interpretation of moderator effects. I propose and validate residual centering in sequential re-estimations of a moderated regression—sequential residual centering (SRC)—by revealing unbiased multicollinearity conditioning across the interaction and its related terms. Across simulations, SRC reduces variance inflation factors (VIF) regardless of distribution shape or pattern of regression coefficients across predictors. For any predictor, the reduced VIF is used to derive a lower standard error of its regression coefficient. A cancer sample illustrates SRC, which allows unbiased interpretations of symptom clusters. SRC can be applied efficiently to alleviate multicollinearity after data collection and shows promise for advancing synergistic frontiers of research.展开更多
By means of programs GTMPAC based- on generalized triangle method,analysis and synthesis of mechanism design in accordance with absolutely graphicalmethod( absolutely germetrical method) are developed.In this paper,we...By means of programs GTMPAC based- on generalized triangle method,analysis and synthesis of mechanism design in accordance with absolutely graphicalmethod( absolutely germetrical method) are developed.In this paper,we make aspecial study about centering- point curve and circling- point curve and couplercurves based on Ball’s points.展开更多
The effects of centering response and explanatory variables as a way of simplifying fitted linear models in the presence of correlation are reviewed and extended to include nonlinear models, common in many biological ...The effects of centering response and explanatory variables as a way of simplifying fitted linear models in the presence of correlation are reviewed and extended to include nonlinear models, common in many biological and economic applications. In a nonlinear model, the use of a local approximation can modify the effect of centering. Even in the presence of uncorrelated explanatory variables, centering may affect linear approximations and related test statistics. An approach to assessing this effect in relation to intrinsic curvature is developed and applied. Mis-specification bias of linear versus nonlinear models also reflects this centering effect.展开更多
Photocatalysis provides a promising solution to the worldwide shortages of energy and industrially important raw materials by utilizing sunlight for coupled hydrogen(H_(2))production with controllable organic transfor...Photocatalysis provides a promising solution to the worldwide shortages of energy and industrially important raw materials by utilizing sunlight for coupled hydrogen(H_(2))production with controllable organic transformation.Herein,we demonstrate that PtFeNiCoCu high-entropy alloy(HEA)nanocrystals can act as efficient cocatalysts for H_(2)evolution coupled with selective oxidation of cinnamyl alcohol to cinnamaldehyde by cubic cadmium sulfide(CdS)quantum dots(QDs)with uniform sizes of 4.0±0.5 nm.HEA nanocrystals were prepared via a simple solvothermal approach,and were successfully integrated with CdS QDs by an electrostatic self-assembly method to construct HEA/CdS composites.The optimized HEA/CdS sample presented an enhanced photocatalytic H_(2)production rate of 7.15 mmol g^(-1)h^(-1),which was 13 times that of pure CdS QDs.Moreover,a cinnamyl alcohol conversion of 96.2%with cinnamaldehyde selectivity of 99.5%was achieved after photoreaction for 3 h.The integration of HEA with CdS QDs extended the optical absorption edge from 475 to 484 nm.From d-band center analysis,Pt atoms in the HEA are the active sites for H_(2)evolution,exhibiting higher catalytic activity than pure Pt.Meanwhile,the band structure of the CdS QDs enables the oxidative transformation of cinnamyl alcohol to cinnamaldehyde with high selectivity.Moreover,femtosecond transient absorption spectroscopy shows that HEA can significantly promote the separation of photogenerated carriers in CdS,which is vital for achieving enhanced photocatalytic activity.This work inspires atomic-level design of photocatalytic materials for coordinated production of green energy carriers and value-added products.展开更多
Air pollution in China covers a large area with complex sources and formation mechanisms,making it a unique place to conduct air pollution and atmospheric chemistry research.The National Natural Science Foundation of ...Air pollution in China covers a large area with complex sources and formation mechanisms,making it a unique place to conduct air pollution and atmospheric chemistry research.The National Natural Science Foundation of China’s Major Research Plan entitled“Fundamental Researches on the Formation and Response Mechanism of the Air Pollution Complex in China”(or the Plan)has funded 76 research projects to explore the causes of air pollution in China,and the key processes of air pollution in atmospheric physics and atmospheric chemistry.In order to summarize the abundant data from the Plan and exhibit the long-term impacts domestically and internationally,an integration project is responsible for collecting the various types of data generated by the 76 projects of the Plan.This project has classified and integrated these data,forming eight categories containing 258 datasets and 15 technical reports in total.The integration project has led to the successful establishment of the China Air Pollution Data Center(CAPDC)platform,providing storage,retrieval,and download services for the eight categories.This platform has distinct features including data visualization,related project information querying,and bilingual services in both English and Chinese,which allows for rapid searching and downloading of data and provides a solid foundation of data and support for future related research.Air pollution control in China,especially in the past decade,is undeniably a global exemplar,and this data center is the first in China to focus on research into the country’s air pollution complex.展开更多
Unplanned intensive care unit(ICU)admissions(UP-ICU)following initial general ward placement are associated with poor patient outcomes and represent a key quality indicator for healthcare facilities.Healthcare facilit...Unplanned intensive care unit(ICU)admissions(UP-ICU)following initial general ward placement are associated with poor patient outcomes and represent a key quality indicator for healthcare facilities.Healthcare facilities have employed numerous predictive models,such as physiological scores(e.g.,Acute Physiology and Chronic Health Evaluation II,Revised Trauma Score,and Mortality Probability Model II at 24 hours)and anatomical scores(Injury Severity Score and New Injury Severity Score),to identify high-risk patients.Although physiological scores frequently surpass anatomical scores in predicting mortality,their specificity for trauma patients is limited,and their clinical applicability may be limited.Initially proposed for ICU readmission prediction,the stability and workload index for the transfer score has demonstrated inconsistent validity.Machine learning offers a promising alternative.Several studies have shown that machine learning models,including those that use electronic health records(EHR)data,can more accurately predict trauma patients’deaths and admissions to the ICU than traditional scoring systems.These models identify unique predictors that are not captured by existing methods.However,challenges remain,including integration with EHR systems and data entry complexities.Critical care outreach programs and telemedicine can help reduce UP-ICU admissions;however,their effectiveness remains unclear because of costs and implementation challenges,respectively.Strategies to reduce UP-ICU admissions include improving triage systems,implementing evidence-based protocols for ICU patient management,and prioritizing prehospital intervention and stabilization to optimize the“golden hour”of trauma care.To improve patient outcomes and reduce the burden of UPICU admissions,further studies are required to validate and implement these strategies and refine machine learning models.展开更多
The growth of computing power in data centers(DCs)leads to an increase in energy consumption and noise pollution of air cooling systems.Chip-level cooling with high-efficiency coolant is one of the promising methods t...The growth of computing power in data centers(DCs)leads to an increase in energy consumption and noise pollution of air cooling systems.Chip-level cooling with high-efficiency coolant is one of the promising methods to address the cooling challenge for high-power devices in DCs.Hybrid nanofluid(HNF)has the advantages of high thermal conductivity and good rheological properties.This study summarizes the numerical investigations of HNFs in mini/micro heat sinks,including the numerical methods,hydrothermal characteristics,and enhanced heat transfer technologies.The innovations of this paper include:(1)the characteristics,applicable conditions,and scenarios of each theoretical method and numerical method are clarified;(2)the molecular dynamics(MD)simulation can reveal the synergy effect,micro motion,and agglomeration morphology of different nanoparticles.Machine learning(ML)presents a feasiblemethod for parameter prediction,which provides the opportunity for the intelligent regulation of the thermal performance of HNFs;(3)the HNFs flowboiling and the synergy of passive and active technologies may further improve the overall efficiency of liquid cooling systems in DCs.This review provides valuable insights and references for exploring the multi-phase flow and heat transport mechanisms of HNFs,and promoting the practical application of HNFs in chip-level liquid cooling in DCs.展开更多
The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are...The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays.展开更多
As the world’s largest digital economy,China has a significant demand for data centers,which are energy-intensive.With an annual growth rate of 28%in installed capacity,these centers are primarily located in the deve...As the world’s largest digital economy,China has a significant demand for data centers,which are energy-intensive.With an annual growth rate of 28%in installed capacity,these centers are primarily located in the developed eastern region,where land and energy resources are limited.This localization poses a major challenge to the industry’s net-zero goal.To address this,China has launched a bold initiative to relocate data centers to the western region,leveraging natural cooling,clean energy,and cost-effective resources.By 2030,this move is expected to reduce emissions from the data center sector by 16%–20%,generating direct economic benefits of approximately 53 billion USD.The success of this initiative can serve as a model for other countries to develop their internet infrastructure.展开更多
BACKGROUND Endoscopic retrograde cholangiopancreatography(ERCP)is an invasive endoscopic procedure used mainly to treat hepato-pancreato-biliary(HPB)diseases.The need for ERCP has increased with the rising number of H...BACKGROUND Endoscopic retrograde cholangiopancreatography(ERCP)is an invasive endoscopic procedure used mainly to treat hepato-pancreato-biliary(HPB)diseases.The need for ERCP has increased with the rising number of HPB diseases over the past decade.Thus,due to increased demand,ERCP is performed at more centers.Currently,it is performed by general surgeons,gastroenterology and invasive radiology specialists in the United States and Europe as recommended by the British Society of Gastroenterology(BSG).AIM To present the results of ERCP procedures from fourteen surgical centers in Türkiye.METHODS Fourteen surgical centers performing ERCP were included in the present study.The age,gender,ERCP indication,success status,post-ERCP complications,ERCP reports and the files of 66993 patients who underwent ERCP were collected from the participating centers.The results are discussed according to the targets declared by the BSG,which are volume load per annum,proportion of successful cannulation(>85%),bile duct clearance rate(>75%),stenting rate for strictures(>80%)and complications(<6%).RESULTS A total of 66993 ERCP procedures were performed in the centers included in the study up to August 2024.29250(43.6%)of the procedures were performed urgently,especially for suppurative cholangitis,biliary tract injuries,etc.The remaining 37743(56.4%)cases were performed electively.50.2%of the patients were female and 49.8%were male.The average ages were 56.5 years for women and 55.9 years for men.General anesthesia was used in 84.1%of the patients while sedation was used in 15.9%.The indications were bile duct stone(78.7%),pancreatic tumor(3.9%),papillary tumor(3.3%),cholangiocarcinoma(2.6%),Oddi sphincter dysfunction(2.4%),bile leakage after cholecystectomy(2%),bile leakage after hydatid cyst surgery(1.9%),biliary stricture(1.7%),and other diseases(3.1%).Hyperamylasemia and post-ERCP pancreatitis were the most common complications as observed in 8.1%of the patients.They were usually self-limited and responded to supportive measures.The frequency of the other complications was also consistent with the literature.CONCLUSION There is a huge shortage of ERCP endoscopists worldwide due to insufficient ERCP training and centers especially in developing and underdeveloped countries.As patients requiring ERCP usually present to surgical practitioners,the incorporation of surgeons into this training program is an effective and reliable solution.The BSG recommends the incorporation of surgeons and radiologists in addition to gastroenterology specialists.This study is the first to present the results of ERCP procedures from fourteen surgical centers throughout Türkiye.The results suggest that the surgical centers included were able to achieve the targets set by the BSG.This study demonstrated that the surgical ERCP units in the present work have reached satisfactory results and provided a reliable and successful ERCP service.There are currently no issues regarding the validity and appropriateness of the surgeons performing ERCP.Therefore,ERCP training should be encouraged in surgeons and more surgical ERCP centers should be provided.展开更多
Development of the telencephalon relies upon several signaling centers-localized cellular populations that supply secreted factors to pattern the cortical neuroepithelium.One such signaling center is the cortical hem,...Development of the telencephalon relies upon several signaling centers-localized cellular populations that supply secreted factors to pattern the cortical neuroepithelium.One such signaling center is the cortical hem,which arises during embryonic development at the telencephalic dorsal midline,adjacent to the choroid plexus and hippocampal primordium(Figure 1A).While the cortical hem has also been described in reptiles and birds,most of our knowledge about the developmental roles of the cortical hem is derived from the analysis in mice.The cortical hem produces several types of secreted molecules,including wingless-related integration site(Wnt)and bone morphogenetic(Bmp)proteins.The cortical hem is particularly important for the development of the hippocampus,which is involved in learning and memory,and the neocortex,which is the most complex brain region that mediates multiple types of behavior and higher cognitive functions(Mangale et al.,2008;Dal-Valle-Anton and Borrell,2022).展开更多
Propelled by the rise of artificial intelligence,cloud services,and data center applications,next-generation,low-power,local-oscillator-less,digital signal processing(DSP)-free,and short-reach coherent optical communi...Propelled by the rise of artificial intelligence,cloud services,and data center applications,next-generation,low-power,local-oscillator-less,digital signal processing(DSP)-free,and short-reach coherent optical communication has evolved into an increasingly prominent area of research in recent years.Here,we demonstrate DSP-free coherent optical transmission by analog signal processing in frequency synchronous optical network(FSON)architecture,which supports polarization multiplexing and higher-order modulation formats.The FSON architecture that allows the numerous laser sources of optical transceivers within a data center can be quasi-synchronized by means of a tree-distributed homology architecture.In conjunction with our proposed pilot-tone assisted Costas loop for an analog coherent receiver,we achieve a record dual-polarization 224-Gb/s 16-QAM 5-km mismatch transmission with reset-free carrier phase recovery in the optical domain.Our proposed DSP-free analog coherent detection system based on the FSON makes it a promising solution for next-generation,low-power,and high-capacity coherent data center interconnects.展开更多
1Introduction To date,in model-based gait-planning methods,the dynamics of the center of mass(COM)of bipedal robots have been analyzed by establishing their linear inverted pendulum model(LIPM)or extended forms(Owaki ...1Introduction To date,in model-based gait-planning methods,the dynamics of the center of mass(COM)of bipedal robots have been analyzed by establishing their linear inverted pendulum model(LIPM)or extended forms(Owaki et al.,2010;Englsberger et al.,2015;Xie et al.,2020).With regard to model-based gait-generation methods for uphill and downhill terrain,Kuo(2007)simulated human gait using an inverted pendulum,which provided a circular trajectory for the COM rather than a horizontal trajectory.He found that a horizontal COM trajectory consumed more muscle energy.Massah et al.(2012)utilized a 3D LIPM and the concept of zero moment point(ZMP).They developed a trajectory planner using the semi-elliptical motion equations of an NAO humanoid robot and simulated walking on various sloped terrains using the Webots platform.展开更多
基金supported by Yunnan Province Key Research and Development Program(202503AA080007)the Open Project of Yunnan Precious Metals Laboratory Co.,Ltd.(YPML-20240502051and YPML-2023050204)+1 种基金the National Natural Science Foundation of China(12405377)the Science and Technology Planning Project of Yunnan Province(202302AH360001)。
文摘Overcoming kinetic limitations in the acidic oxygen reduction reaction(ORR)demands Pt-based catalysts with optimized surface adsorption.Herein,we engineer hierarchical PtPd dendrite nanocrystals(PtPd NDs)featuring precisely tailored asymmetric sites and high-index facets(HIFs)to overcome the kinetic limitations in acidic media.Controlled Pd incorporation disrupts symmetry of the single-oriented crystal plane,generating inhomogeneous strain and promoting HIFs exposure.This synergistic structural engineering optimizes the adsorption/desorption of oxygen-containing intermediates,significantly accelerating ORR kinetics.Consequently,PtPd NDs deliver exceptional mass activity(MA=1.37 A mg_(Pt)^(-1),11.42 times higher than Pt/C)and remarkable stability(83.9%MA retention after durability testing).In H_(2)-Air fuel cells,PtPd NDs also achieve higher peak power density versus Pt/C cathodes.In situ synchrotron radiation infrared spectroscopy and theoretical studies reveal that the synergistic effect between asymmetric sites and HIFs stimulates the strain field and causes a downward shift in the d-band center,thereby lowering the*OOH formation barrier and weakening intermediate adsorption,directly boosting the ORR performance.This work underscores the critical role of facet and site engineering in designing high-performance fuel cell electrocatalysts.
文摘This study focuses on reconstructing the"reader-centered"paradigm in the teaching of high school English literary text reading,supported by Reception Aesthetics as its theoretical foundation.High school English literary text reading plays a significant role in cultivating students'language proficiency,cultural awareness,and aesthetic literacy.However,the current teaching practice in this area remains dominated by the traditional"teacher-centered"approach,which restricts students'active participation and the realization of the pluralistic value of literary texts.By integrating core concepts of Reception Aesthetics-such as"horizon of expectations,""structure of appeal,"and"interpretive community"-this research addresses the gap in existing studies,which have largely focused on the application of Reception Aesthetics in Chinese language teaching or college English instruction.Using literature research and classroom practice analysis,the study reconstructs the"reader-centered"paradigm across three dimensions:teaching objectives,teaching process,and evaluation methods.It also identifies practical challenges,including uneven student participation,time constraints,and difficulties in the teacher's role adaptation,and proposes corresponding optimization strategies.Practical results demonstrate that this paradigm effectively enhances students'reading engagement,text interpretation skills,and critical thinking.Future research may further expand text types and integrate information technology to continuously improve teaching effectiveness.
基金financially supported by the National Natural Science Foundation of China(52371222,52271211,52303341)the Natural Science Foundation of Hunan Province in China(2025JJ60350,2023JJ50043)+1 种基金Key Research and Development Program of Hunan Province(2023GK2035)HORIZON EUROPE Marie Sklodowska-Curie Actions-2021(101065098)。
文摘The hydrazine oxidation-assisted hydrogen generation system significantly expands the applicability of hydrogen production technology.However,the complex intermediate transformations involved in the hydrazine oxidation reaction(HzOR)and hydrogen evolution reaction(HER)desperately need the development of dual-functional catalysts.Manipulating the d-band center of metal catalysts has been identified as one of the most effective approaches to enhance catalytic activity.Herein,Ir nanoparticles(NPs)anchored in B,N-codoped porous carbon(Ir@BNC)were developed and demonstrate excellent performances for both HER and HzOR in an alkaline medium,achieving 10 mA cm^(-2) at-25 and 18 mV,respectively.The overall hydrazine splitting(OHzS)electrolyzer reaches 200 mA cm^(-2) with a cell voltage of just 0.68 V.The direct liquid N2H4/H2O_(2) fuel cell(DHHPFC)assembly with Ir@BNC can achieve a maximum power density of 199.2 mW cm^(-2) at room temperature.Furthermore,an H2 production system using an OHzS device powered by DHHPFC realizes hydrogen production at a stable rate(53.08 mol h^(-1) m^(-2)).In-situ Raman tests and theoretical calculations unravel the metal-support interaction between Ir NPs and B,N-codoped porous carbon,optimizing the electronic structure and regulating the d-band center of Ir,reducing the adsorption energy of H*intermediates and N2H4 molecules,thus promoting the reaction processes of HER and HzOR.
基金supported by supported by the Basic Research Project of State Key Laboratory of Photovoltaic Science and Technology(No.202401020302)funding support from the National Natural Science Foundation of China(No.62274040 and No.62304046)Shanghai science and technology innovation action plan(No.24DZ3001200)。
文摘Organic-inorganic metal halides(OIMHs)have emerged as highly promising novel multifunctional optoelectronic materials,owing to their easily adjustable properties from a variety of combinations of different components.But it is still difficult and rare to realize highly tunable multicolor luminescence within the same material.In this work,we successfully incorporated three adjustable emission centers in OIMHs to synthesize a novel OIMH(NEA)_(2)MnBr_(4),with each emission center capable of emitting one of the primary colors—red,green,and blue.The green and red emissions originate from the tetrahedron and octahedron structures in the Mn-based frame,while the blue can be attributed to the contribution of organic components.Additionally,to achieve comparable emission intensity among the three primary colors,we enhanced the blue emission performance by optimizing the ratio of organic structure components and incorporating chirality in the OIMHs.The resulting high-quality films can be obtained by spin-coating method with a photoluminescence quantum yields of up to 96%.More interestingly,by the dual manipulation of excitation wavelength and temperature,the sample can be emitted at least seven distinct colors including a standard white luminescence at(0.33,0.33),opening up promising prospects for multicolor luminescence applications such as high-end anti-counterfeiting technology,light-emitting diodes,X-ray imaging,latent fingerprints,humidity detection,and so on.Therefore,based on application scenarios and requirements,our research on this highly tunable luminescent OIMH material lays a solid foundation for further development of various functional properties of related materials.
基金supported by the National Research Foundation,Singapore,funded under Energy Research Testbed and Industry Partnership Funding Initiative,part of the Energy Grid(EG)2.0 programme.
文摘Rapid developments in the electronic information industry drive the increased energy usage and carbon emission of data center buildings,prompting the focus on the energy efficiency and environmental sustainability.Expanded operation envelopes of tropical data centers is assessed to analyze the potential for the building energy savings and carbon emission reduction through collaborative analysis of operation modes(OMs),supply air temperature(SAT),and outdoor air temperature(OAT).The OMs of compression vary with the setpoints of SAT,in which the average exergy efficiency of compressors at alternate operation mode is 6.8%and 8.0%lower than that of double and single compression operations.As SAT rises from 20℃to 32℃,the system exergoeconomic factor increases from 5.4%to 8.0%,and the average carbon cost decreases by 36.5%.Additionally,with just an 8.5%increase in exergy cost(i.e.,Case 8)at OAT rising from 30 to 34℃,the high SAT and low refrigerant charges provide considerable exergy cost advantages versus resisting the OAT fluctuations.Dynamic operation strategies are also proposed and compared to cope with the impacts of tropical environments.Compared to the 26℃SAT baseline,the average energy savings are 9.1-14.7%,indicating the ability to fully utilize outdoor and indoor conditions.
文摘Siemens and Yangpu Economic Development Zone in Hainan have forged a close partnership in a journey towards green energy transition.SIEMENS Energy,one of the world’s leading energy technology companies,became the first foreign-funded manufacturer to establish a branch and began construction of a gas turbine assembly base and service center in Hainan on December 18,2025.
基金Supported by the NNSF of china(11171221)SuppoSed by the Shanghai Municipal Committee of Science and Technology(10550500800)
文摘In this paper,we present an extrapolated parallel subgradient projection method with the centering technique for the convex feasibility problem,the algorithm improves the convergence by reason of using centering techniques which reduce the oscillation of the corresponding sequence.To prove the convergence in a simply way,we transmit the parallel algorithm in the original space to a sequential one in a newly constructed product space.Thus,the convergence of the parallel algorithm is derived with the help of the sequential one under some suitable conditions.Numerical results show that the new algorithm has better convergence than the existing algorithms.
文摘Multicollinearity constitutes shared variation among predictors that inflates standard errors of regression coefficients. Several years ago, it was proven that the common practice of mean centering in moderated regression cannot alleviate multicollinearity among variables comprising an interaction, but merely masks it. Residual centering (orthogonalizing) is unacceptable because it biases parameters for predictors from which the interaction derives, thus precluding interpretation of moderator effects. I propose and validate residual centering in sequential re-estimations of a moderated regression—sequential residual centering (SRC)—by revealing unbiased multicollinearity conditioning across the interaction and its related terms. Across simulations, SRC reduces variance inflation factors (VIF) regardless of distribution shape or pattern of regression coefficients across predictors. For any predictor, the reduced VIF is used to derive a lower standard error of its regression coefficient. A cancer sample illustrates SRC, which allows unbiased interpretations of symptom clusters. SRC can be applied efficiently to alleviate multicollinearity after data collection and shows promise for advancing synergistic frontiers of research.
文摘By means of programs GTMPAC based- on generalized triangle method,analysis and synthesis of mechanism design in accordance with absolutely graphicalmethod( absolutely germetrical method) are developed.In this paper,we make aspecial study about centering- point curve and circling- point curve and couplercurves based on Ball’s points.
文摘The effects of centering response and explanatory variables as a way of simplifying fitted linear models in the presence of correlation are reviewed and extended to include nonlinear models, common in many biological and economic applications. In a nonlinear model, the use of a local approximation can modify the effect of centering. Even in the presence of uncorrelated explanatory variables, centering may affect linear approximations and related test statistics. An approach to assessing this effect in relation to intrinsic curvature is developed and applied. Mis-specification bias of linear versus nonlinear models also reflects this centering effect.
文摘Photocatalysis provides a promising solution to the worldwide shortages of energy and industrially important raw materials by utilizing sunlight for coupled hydrogen(H_(2))production with controllable organic transformation.Herein,we demonstrate that PtFeNiCoCu high-entropy alloy(HEA)nanocrystals can act as efficient cocatalysts for H_(2)evolution coupled with selective oxidation of cinnamyl alcohol to cinnamaldehyde by cubic cadmium sulfide(CdS)quantum dots(QDs)with uniform sizes of 4.0±0.5 nm.HEA nanocrystals were prepared via a simple solvothermal approach,and were successfully integrated with CdS QDs by an electrostatic self-assembly method to construct HEA/CdS composites.The optimized HEA/CdS sample presented an enhanced photocatalytic H_(2)production rate of 7.15 mmol g^(-1)h^(-1),which was 13 times that of pure CdS QDs.Moreover,a cinnamyl alcohol conversion of 96.2%with cinnamaldehyde selectivity of 99.5%was achieved after photoreaction for 3 h.The integration of HEA with CdS QDs extended the optical absorption edge from 475 to 484 nm.From d-band center analysis,Pt atoms in the HEA are the active sites for H_(2)evolution,exhibiting higher catalytic activity than pure Pt.Meanwhile,the band structure of the CdS QDs enables the oxidative transformation of cinnamyl alcohol to cinnamaldehyde with high selectivity.Moreover,femtosecond transient absorption spectroscopy shows that HEA can significantly promote the separation of photogenerated carriers in CdS,which is vital for achieving enhanced photocatalytic activity.This work inspires atomic-level design of photocatalytic materials for coordinated production of green energy carriers and value-added products.
基金supported by the National Natural Science Foundation of China(Grant No.92044303)。
文摘Air pollution in China covers a large area with complex sources and formation mechanisms,making it a unique place to conduct air pollution and atmospheric chemistry research.The National Natural Science Foundation of China’s Major Research Plan entitled“Fundamental Researches on the Formation and Response Mechanism of the Air Pollution Complex in China”(or the Plan)has funded 76 research projects to explore the causes of air pollution in China,and the key processes of air pollution in atmospheric physics and atmospheric chemistry.In order to summarize the abundant data from the Plan and exhibit the long-term impacts domestically and internationally,an integration project is responsible for collecting the various types of data generated by the 76 projects of the Plan.This project has classified and integrated these data,forming eight categories containing 258 datasets and 15 technical reports in total.The integration project has led to the successful establishment of the China Air Pollution Data Center(CAPDC)platform,providing storage,retrieval,and download services for the eight categories.This platform has distinct features including data visualization,related project information querying,and bilingual services in both English and Chinese,which allows for rapid searching and downloading of data and provides a solid foundation of data and support for future related research.Air pollution control in China,especially in the past decade,is undeniably a global exemplar,and this data center is the first in China to focus on research into the country’s air pollution complex.
文摘Unplanned intensive care unit(ICU)admissions(UP-ICU)following initial general ward placement are associated with poor patient outcomes and represent a key quality indicator for healthcare facilities.Healthcare facilities have employed numerous predictive models,such as physiological scores(e.g.,Acute Physiology and Chronic Health Evaluation II,Revised Trauma Score,and Mortality Probability Model II at 24 hours)and anatomical scores(Injury Severity Score and New Injury Severity Score),to identify high-risk patients.Although physiological scores frequently surpass anatomical scores in predicting mortality,their specificity for trauma patients is limited,and their clinical applicability may be limited.Initially proposed for ICU readmission prediction,the stability and workload index for the transfer score has demonstrated inconsistent validity.Machine learning offers a promising alternative.Several studies have shown that machine learning models,including those that use electronic health records(EHR)data,can more accurately predict trauma patients’deaths and admissions to the ICU than traditional scoring systems.These models identify unique predictors that are not captured by existing methods.However,challenges remain,including integration with EHR systems and data entry complexities.Critical care outreach programs and telemedicine can help reduce UP-ICU admissions;however,their effectiveness remains unclear because of costs and implementation challenges,respectively.Strategies to reduce UP-ICU admissions include improving triage systems,implementing evidence-based protocols for ICU patient management,and prioritizing prehospital intervention and stabilization to optimize the“golden hour”of trauma care.To improve patient outcomes and reduce the burden of UPICU admissions,further studies are required to validate and implement these strategies and refine machine learning models.
基金funded by the Science and Technology Project of Tianjin(No.24YDTPJC00680)the National Natural Science Foundation of China(No.52406191).
文摘The growth of computing power in data centers(DCs)leads to an increase in energy consumption and noise pollution of air cooling systems.Chip-level cooling with high-efficiency coolant is one of the promising methods to address the cooling challenge for high-power devices in DCs.Hybrid nanofluid(HNF)has the advantages of high thermal conductivity and good rheological properties.This study summarizes the numerical investigations of HNFs in mini/micro heat sinks,including the numerical methods,hydrothermal characteristics,and enhanced heat transfer technologies.The innovations of this paper include:(1)the characteristics,applicable conditions,and scenarios of each theoretical method and numerical method are clarified;(2)the molecular dynamics(MD)simulation can reveal the synergy effect,micro motion,and agglomeration morphology of different nanoparticles.Machine learning(ML)presents a feasiblemethod for parameter prediction,which provides the opportunity for the intelligent regulation of the thermal performance of HNFs;(3)the HNFs flowboiling and the synergy of passive and active technologies may further improve the overall efficiency of liquid cooling systems in DCs.This review provides valuable insights and references for exploring the multi-phase flow and heat transport mechanisms of HNFs,and promoting the practical application of HNFs in chip-level liquid cooling in DCs.
基金Project supported by the Key R&D Projects in Hunan Province(2021SK2047,2022NK2044)Science and Technology Innovation Program of Hunan Province(2022WZ1022)Superior Youth Project of the Science Research Project of Hunan Provincial Department of Education(22B0211)。
文摘The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays.
基金supported by the Joint Research Project for the Yangtze River Conservation(Phase II),China(2022-LHYJ-02-0401).
文摘As the world’s largest digital economy,China has a significant demand for data centers,which are energy-intensive.With an annual growth rate of 28%in installed capacity,these centers are primarily located in the developed eastern region,where land and energy resources are limited.This localization poses a major challenge to the industry’s net-zero goal.To address this,China has launched a bold initiative to relocate data centers to the western region,leveraging natural cooling,clean energy,and cost-effective resources.By 2030,this move is expected to reduce emissions from the data center sector by 16%–20%,generating direct economic benefits of approximately 53 billion USD.The success of this initiative can serve as a model for other countries to develop their internet infrastructure.
文摘BACKGROUND Endoscopic retrograde cholangiopancreatography(ERCP)is an invasive endoscopic procedure used mainly to treat hepato-pancreato-biliary(HPB)diseases.The need for ERCP has increased with the rising number of HPB diseases over the past decade.Thus,due to increased demand,ERCP is performed at more centers.Currently,it is performed by general surgeons,gastroenterology and invasive radiology specialists in the United States and Europe as recommended by the British Society of Gastroenterology(BSG).AIM To present the results of ERCP procedures from fourteen surgical centers in Türkiye.METHODS Fourteen surgical centers performing ERCP were included in the present study.The age,gender,ERCP indication,success status,post-ERCP complications,ERCP reports and the files of 66993 patients who underwent ERCP were collected from the participating centers.The results are discussed according to the targets declared by the BSG,which are volume load per annum,proportion of successful cannulation(>85%),bile duct clearance rate(>75%),stenting rate for strictures(>80%)and complications(<6%).RESULTS A total of 66993 ERCP procedures were performed in the centers included in the study up to August 2024.29250(43.6%)of the procedures were performed urgently,especially for suppurative cholangitis,biliary tract injuries,etc.The remaining 37743(56.4%)cases were performed electively.50.2%of the patients were female and 49.8%were male.The average ages were 56.5 years for women and 55.9 years for men.General anesthesia was used in 84.1%of the patients while sedation was used in 15.9%.The indications were bile duct stone(78.7%),pancreatic tumor(3.9%),papillary tumor(3.3%),cholangiocarcinoma(2.6%),Oddi sphincter dysfunction(2.4%),bile leakage after cholecystectomy(2%),bile leakage after hydatid cyst surgery(1.9%),biliary stricture(1.7%),and other diseases(3.1%).Hyperamylasemia and post-ERCP pancreatitis were the most common complications as observed in 8.1%of the patients.They were usually self-limited and responded to supportive measures.The frequency of the other complications was also consistent with the literature.CONCLUSION There is a huge shortage of ERCP endoscopists worldwide due to insufficient ERCP training and centers especially in developing and underdeveloped countries.As patients requiring ERCP usually present to surgical practitioners,the incorporation of surgeons into this training program is an effective and reliable solution.The BSG recommends the incorporation of surgeons and radiologists in addition to gastroenterology specialists.This study is the first to present the results of ERCP procedures from fourteen surgical centers throughout Türkiye.The results suggest that the surgical centers included were able to achieve the targets set by the BSG.This study demonstrated that the surgical ERCP units in the present work have reached satisfactory results and provided a reliable and successful ERCP service.There are currently no issues regarding the validity and appropriateness of the surgeons performing ERCP.Therefore,ERCP training should be encouraged in surgeons and more surgical ERCP centers should be provided.
基金supported by R01 NS093009 grant from NIH(to VVC).
文摘Development of the telencephalon relies upon several signaling centers-localized cellular populations that supply secreted factors to pattern the cortical neuroepithelium.One such signaling center is the cortical hem,which arises during embryonic development at the telencephalic dorsal midline,adjacent to the choroid plexus and hippocampal primordium(Figure 1A).While the cortical hem has also been described in reptiles and birds,most of our knowledge about the developmental roles of the cortical hem is derived from the analysis in mice.The cortical hem produces several types of secreted molecules,including wingless-related integration site(Wnt)and bone morphogenetic(Bmp)proteins.The cortical hem is particularly important for the development of the hippocampus,which is involved in learning and memory,and the neocortex,which is the most complex brain region that mediates multiple types of behavior and higher cognitive functions(Mangale et al.,2008;Dal-Valle-Anton and Borrell,2022).
基金supported by the National Natural Science Foundation of China(Grant Nos.62405250 and 62471404)the China Postdoctoral Science Foundation(Grant No.2024M762955)+1 种基金the Key Project of Westlake Institute for Optoelectronics(Grant No.2023GD003)the Optical Com-munication and Sensing Laboratory,School of Engineering,Westlake University.
文摘Propelled by the rise of artificial intelligence,cloud services,and data center applications,next-generation,low-power,local-oscillator-less,digital signal processing(DSP)-free,and short-reach coherent optical communication has evolved into an increasingly prominent area of research in recent years.Here,we demonstrate DSP-free coherent optical transmission by analog signal processing in frequency synchronous optical network(FSON)architecture,which supports polarization multiplexing and higher-order modulation formats.The FSON architecture that allows the numerous laser sources of optical transceivers within a data center can be quasi-synchronized by means of a tree-distributed homology architecture.In conjunction with our proposed pilot-tone assisted Costas loop for an analog coherent receiver,we achieve a record dual-polarization 224-Gb/s 16-QAM 5-km mismatch transmission with reset-free carrier phase recovery in the optical domain.Our proposed DSP-free analog coherent detection system based on the FSON makes it a promising solution for next-generation,low-power,and high-capacity coherent data center interconnects.
基金supported by the National Natural Science Foundation of China(No.12332023)the Zhejiang Provincial Natural Science Foundation of China(No.LY23E050010).
文摘1Introduction To date,in model-based gait-planning methods,the dynamics of the center of mass(COM)of bipedal robots have been analyzed by establishing their linear inverted pendulum model(LIPM)or extended forms(Owaki et al.,2010;Englsberger et al.,2015;Xie et al.,2020).With regard to model-based gait-generation methods for uphill and downhill terrain,Kuo(2007)simulated human gait using an inverted pendulum,which provided a circular trajectory for the COM rather than a horizontal trajectory.He found that a horizontal COM trajectory consumed more muscle energy.Massah et al.(2012)utilized a 3D LIPM and the concept of zero moment point(ZMP).They developed a trajectory planner using the semi-elliptical motion equations of an NAO humanoid robot and simulated walking on various sloped terrains using the Webots platform.
