Combined with DTG analysis, X-Ray diffraction analysis （XRD） and field emission scanning electron microscopy analysis （FSEM） affiliated with energy dispersive spectrometer analysis （EDS）, the early hydration and...Combined with DTG analysis, X-Ray diffraction analysis （XRD） and field emission scanning electron microscopy analysis （FSEM） affiliated with energy dispersive spectrometer analysis （EDS）, the early hydration and carbonation behavior of cement paste compacts incorporated with 30% of dolomite powder at low water to cement ratio （0.15） was investigated. The results showed that early carbonation curing was capable of developing rapid early strength. It is noted that the carbonation duration should be strictly controlled otherwise subsequent hydration might be hindered. Dolomite powder acted as nuclei of crystallization, resulting in acceleration of products formation and refinement of products crystal size. Therefore, as for cement-based material, it was found that early carbonation could reduce cement dosages to a large extent and promote rapid strength gain resulting from rapid formation of products, supplemental enhancement due to water release in the reaction of carbonation, and formation ofnanometer CaCO3 skeleton network at early age.展开更多
Cement-based materials are the foundation of modern buildings but suffer from intensive energy consumption.Utilizing cement-based materials for efficient energy storage is one of the most promising strategies for real...Cement-based materials are the foundation of modern buildings but suffer from intensive energy consumption.Utilizing cement-based materials for efficient energy storage is one of the most promising strategies for realizing zero-energy buildings.However,cement-based materials encounter challenges in achieving excellent electrochemical performance without compromising mechanical properties.Here,we introduce a biomimetic cement-based solid-state electrolyte(labeled as l-CPSSE)with artificially organized layered microstructures by proposing an in situ ice-templating strategy upon the cement hydration,in which the layered micropores are further filled with fast-ion-conducting hydrogels and serve as ion diffusion highways.With these merits,the obtained l-CPSSE not only presents marked specific bending and compressive strength(2.2 and 1.2 times that of traditional cement,respectively)but also exhibits excellent ionic conductivity(27.8 mS·cm^(-1)),overwhelming most previously reported cement-based and hydrogel-based electrolytes.As a proof-of-concept demonstration,we assemble the l-CPSSE electrolytes with cement-based electrodes to achieve all-cement-based solid-state energy storage devices,delivering an outstanding full-cell specific capacity of 72.2 mF·cm^(-2).More importantly,a 5×5 cm^(2) sized building model is successfully fabricated and operated by connecting 4 l-CPSSE-based full cells in series,showcasing its great potential in self-energy-storage buildings.This work provides a general methodology for preparing revolutionary cement-based electrolytes and may pave the way for achieving zero-carbon buildings.展开更多
基金Funded by the National Key Research Program(973 Program)(No.2013CB035901)the National Natural Science Foundation of China(No.51379163)
文摘Combined with DTG analysis, X-Ray diffraction analysis （XRD） and field emission scanning electron microscopy analysis （FSEM） affiliated with energy dispersive spectrometer analysis （EDS）, the early hydration and carbonation behavior of cement paste compacts incorporated with 30% of dolomite powder at low water to cement ratio （0.15） was investigated. The results showed that early carbonation curing was capable of developing rapid early strength. It is noted that the carbonation duration should be strictly controlled otherwise subsequent hydration might be hindered. Dolomite powder acted as nuclei of crystallization, resulting in acceleration of products formation and refinement of products crystal size. Therefore, as for cement-based material, it was found that early carbonation could reduce cement dosages to a large extent and promote rapid strength gain resulting from rapid formation of products, supplemental enhancement due to water release in the reaction of carbonation, and formation ofnanometer CaCO3 skeleton network at early age.
基金support from the National Natural Science Foundation of China(Grant Nos.:52250010 and 52050128)the Natural Science Foundation of Jiangsu Province(Grant No.:BK20230086)+3 种基金L.P.acknowledges support from the National Natural Science Foundation of China(Grant No.:52201242)the Young Elite Scientists Sponsorship Program by CAST(No.2021QNRC001)the Fund of Key Laboratory of Advanced Materials of Ministry of Education(No.AdvMat-2023-12)Z.M.S.acknowledges support from the National Natural Science Foundation of China(Grant No.:U23A20574).
文摘Cement-based materials are the foundation of modern buildings but suffer from intensive energy consumption.Utilizing cement-based materials for efficient energy storage is one of the most promising strategies for realizing zero-energy buildings.However,cement-based materials encounter challenges in achieving excellent electrochemical performance without compromising mechanical properties.Here,we introduce a biomimetic cement-based solid-state electrolyte(labeled as l-CPSSE)with artificially organized layered microstructures by proposing an in situ ice-templating strategy upon the cement hydration,in which the layered micropores are further filled with fast-ion-conducting hydrogels and serve as ion diffusion highways.With these merits,the obtained l-CPSSE not only presents marked specific bending and compressive strength(2.2 and 1.2 times that of traditional cement,respectively)but also exhibits excellent ionic conductivity(27.8 mS·cm^(-1)),overwhelming most previously reported cement-based and hydrogel-based electrolytes.As a proof-of-concept demonstration,we assemble the l-CPSSE electrolytes with cement-based electrodes to achieve all-cement-based solid-state energy storage devices,delivering an outstanding full-cell specific capacity of 72.2 mF·cm^(-2).More importantly,a 5×5 cm^(2) sized building model is successfully fabricated and operated by connecting 4 l-CPSSE-based full cells in series,showcasing its great potential in self-energy-storage buildings.This work provides a general methodology for preparing revolutionary cement-based electrolytes and may pave the way for achieving zero-carbon buildings.
