As a crucial component of the Earth’s climate system,Antarctic sea ice has demonstrated significant variability over the satellite era.Here,we identify a remarkable decadal transition in the total Antarctic Sea Ice E...As a crucial component of the Earth’s climate system,Antarctic sea ice has demonstrated significant variability over the satellite era.Here,we identify a remarkable decadal transition in the total Antarctic Sea Ice Extent(SIE).The stage from 1979 to 2006 is characterized by high-frequency(i.e.,seasonal to interannual)temporal variability in SIE and zonal asymmetry in Sea Ice Concentration(SIC),which is primarily under the control of the Amundsen Sea Low(ASL).After 2007,however,sea ice changes exhibit a more spatially homogeneous pattern in SIC and a more temporally long-lasting mode in SIE.Further analysis reveals that sea ice-ocean interaction plays a major role in the low-frequency(i.e.,multiannual)variability of Antarctic sea ice from 2007−22.The related physical process is inferred to manifest as a strong coupling between the surface and the subsurface ocean layers,involving enhanced vertical convection and the downward delivery of the surface anomalies related to ice melting and freezing processes,thus maintaining the SIE anomalies for a longer time.Furthermore,this process mainly occurs in the Amundsen-Bellingshausen Sea(ABS)sector,and the weakened subsurface ocean stratification is the key factor triggering the coupling process in this region.We find that the Circumpolar Deep Water(CDW)over the ABS sector continued to shoal before 2007 and remained stable thereafter.It is speculated that the shoaling of the CDW may be a possible driver leading to the weakening of the subsurface stratification.展开更多
Thermoelectric coolers utilizing the Peltier effect have dominated the field of solid-state cooling but their efficiency is hindered by material limitations.Alternative routes based on the Thomson and Nernst effects o...Thermoelectric coolers utilizing the Peltier effect have dominated the field of solid-state cooling but their efficiency is hindered by material limitations.Alternative routes based on the Thomson and Nernst effects offer new possibilities.Here,we present a comprehensive investigation of the thermoelectric properties of 1T-TiSe_(2),focusing on these effects around the charge density wave transition(≈200 K).The abrupt Fermi surface reconstruction associated with this transition leads to an exceptional peak in the Thomson coefficient of 450μVK^(-1) at 184 K,surpassing the Seebeck coefficient.Furthermore,1T-TiSe_(2) exhibits a remarkably broad temperature range(170-400 K)with a Thomson coefficient exceeding 190μV K^(-1),a characteristic highly desirable for the development of practical Thomson coolers with extended operational ranges.Additionally,the Nernst coefficient exhibits an unusual temperature dependence,increasing with temperature in the normal phase,which we attribute to bipolar conduction effects.The combination of solid-solid pure electronic phase transition to a semimetallic phase with bipolar transport is identified as responsible for the unusual Nernst trend and the unusually large Thomson coefficient over a broad temperature range.展开更多
Two-dimensional van der Waals(vdW)magnetic materials,characterized by their tunable magnetism,spin transport properties,and remarkable quantum effects,provide significant promise for the development of efficient,low-p...Two-dimensional van der Waals(vdW)magnetic materials,characterized by their tunable magnetism,spin transport properties,and remarkable quantum effects,provide significant promise for the development of efficient,low-power spintronic devices.Intriguingly,the rare earth tritelluride(RTe3)materials have attracted great attention due to their unique magnetic structure,exotic electronic properties,multiple charge density wave(CDW),and superconductivity under pressure.Here,we report the successful synthesis of high-quality DyTe_(3)single crystals using a self-flux method.DyTe_(3)shows an antiferromagnetic transition at 4.5 K and demonstrates the magnetic field-induced ferromagnetism.The high-quality DyTe_(3)single crystal demonstrates outstanding transport properties,featuring a high carrier mobility of approximately1.4×10^(4)cm^(2)·V^(-1)·s^(-1)and large linear magnetoresistance of 1300%.Furthermore,distinct Shubnikov-de Haas(SdH)oscillations are observed in DyTe_(3),revealing a small Fermi pocket and an effective mass of 0.24 me.Remarkably,the unconventional in-plane negative magnetoresistances appear along the a-axis below 2 T and c-axis until 9 T from 2 K to17 K,which are attributed to the complex helimagnetic structures caused by CDW coupling and weak single-ion anisotropy.Our findings offer a significant platform for understanding the complex magnetoresistance behavior and quantum transport effects in RTe3-type materials,holding great promise for advancing applications in electronic and spintronic devices.展开更多
Nitrification,a central process in the marine nitrogen cycle,produces regenerated nitrate in the euphotic zone and emits N_(2)O,a potent greenhouse gas as a by-product.The regulatory mechanisms of nitrification in the...Nitrification,a central process in the marine nitrogen cycle,produces regenerated nitrate in the euphotic zone and emits N_(2)O,a potent greenhouse gas as a by-product.The regulatory mechanisms of nitrification in the Southern Ocean,which is a critical region for CO_(2)sequestration and radiative benefits,remain poorly understood.Here,we investigated the in situ and dark nitrification rates in the upper 500 m and conducted substrate kinetics experiments across the Indian Sector in the Cosmonaut and Cooperation seas in the late austral summer.Our findings indicate that light inhibition of nitrification decreases exponentially with depth,exhibiting a light threshold of 0.53%photosynthetically active radiation.A positive relationship between dark nitrification and apparent oxygen utilization suggests a dependence on substrate availability from primary production.Importantly,an increased NH_(4)^(+) supply can act as a buffer against photo-inhibitory damage.Globally,substrate affinity(α)increases with depth and transitions from light to dark,decreases with increasing ambient NH_(4)^(+)and exhibits a latitudinal distribution,reflecting substrate utilization strategies.We also reveal that upwelling in Circumpolar Deep Water(CDW)stimulates nitrification through the introduction of potentially higher iron and deep diverse nitrifying microorganisms with higherα.We conclude that although light is the primary limiting factor for nitrification in summer,coupling between substrate availability and CDW upwelling can overcome this limitation,thereby alleviating photoinhibition by up to 45%±5.3%.展开更多
As the climate change signs become more noticeable, the concern to prioritize sustainability within the AEC industry intensifies. This particularly pertained to issues related to the demand of resources, the excessive...As the climate change signs become more noticeable, the concern to prioritize sustainability within the AEC industry intensifies. This particularly pertained to issues related to the demand of resources, the excessive consumption of raw materials, and the associated generated waste. Presently, the construction industry is ranked among the industries that are accountable for the global generation of solid waste and energy consumption, leading to detrimental environmental effects. Nonetheless, over the years, construction methods, technological innovations, and building practices have made considerable progress, influenced by a growing emphasis on sustainability, especially in energy conservation and in adopting the Industrialized Production layer of Construction 4.0 (i.e., modular prefabrication, 3D concrete printing, and BIM). The concept of Circular Economy (CE) has been identified as a potential solution to achieve sustainability in building construction through the design, construction, and end-of-life deconstruction processes that enhance the management of waste based on the framework that is related to reducing, reusing, and recycling. Moreover, information and data related to geolocation complement advanced digital technologies by providing a collaborative platform that supports the application of CE as a practical approach to sustainability. Thus, this study will provide a straightforward methodology for developing a model that integrates BIM and sustainable design with Circular Economy’s concept to enhance the sustainability of construction projects to minimize their waste based on various construction methods (i.e., conventional, modular, and 3D concrete printing). The proposed model interrelates tools and data for the evaluation and planning strategies for the construction and deconstruction waste (CDW) management at the design stage, including estimating the quantities of the wasted materials, quantifying the production rates of selected equipment for the waste handling (loading and hauling) at the various stages of a project as well their associated cost. The proposed model will help users to calculate the quantity of construction and deconstruction waste (CDW) during the design of buildings based on their different construction methods at the early stage by using the concept of Design for Deconstruction (DfD);sustainable construction methods;and deconstruction process for waste management, which will lead to the suitable construction method.展开更多
运用有限系统密度矩阵重整化群算法(FS-DMRG),研究拓展Bose-Hubbard模型(即在标准BoseHubbard模型的基础上加入最近邻格点间的粒子相互排斥作用V)发生相变的特征。通过计算系统的局域粒子数密度、单粒子能隙以及压缩系数,分析了系统在...运用有限系统密度矩阵重整化群算法(FS-DMRG),研究拓展Bose-Hubbard模型(即在标准BoseHubbard模型的基础上加入最近邻格点间的粒子相互排斥作用V)发生相变的特征。通过计算系统的局域粒子数密度、单粒子能隙以及压缩系数,分析了系统在不同状态下的特征,得到了不同于标准Bose-Hubbard模型的新量子态——Charge Density Wave(CDW)态。通过分析产生特殊粒子分布方式的原因及其物理性质,得出了发生相变的临界条件。展开更多
A cruise covering two transects in the Changjiang(Yangtze)estuary in July 2017 was conducted,aiming to explore the sources for riverine NOˉ3 and identify reactions involved in the NO_(3)^(-)transformations along the ...A cruise covering two transects in the Changjiang(Yangtze)estuary in July 2017 was conducted,aiming to explore the sources for riverine NOˉ3 and identify reactions involved in the NO_(3)^(-)transformations along the transport of the Changjiang diluted water(CDW).In the river water,NO_(3)^(-)was fundamentally contributed by chemical fertilizer leakage in the watershed according to isotope signals.Sewage discharge may also be significant on riverine NO_(3)^(-)inventory,while the isotope signal was masked by nitrification.Together with the transport of the CDW,NO_(3)^(-)production was observed in waters with low salinities(<20)and high turbidities.Nitrification resulted from the mineralization of riverine organic nitrogen;therefore,the high turbidity was linked to active production.In the outer plume,coupled with stratification,a significant decrease in NO_(3)^(-)concentration was observed in the surface water.In parallel,enrichment inδ^(15)N-NO_(3)^(-)andδ^(18)O-NO_(3)^(-)was found,indicating biological consumption by phytoplankton.The difference in the stratification intensity between two transects led to variations in NO_(3)^(-)concentrations and isotope compositions.In the benthic water,denitrification(sediment-water interface)and nitrification(bottom water)coexisted.Furthermore,accumulations of NH4+and dissolved organic nitrogen in the bottom water were observed,indicating that nitrification was constrained by oxidant(mainly dissolved oxygen)supplies.展开更多
On-line partial discharge(PD)detection still remains a very challenging task because of the strong electromagnetic interferences.In this paper,a new method of de-noising,using complex Daubechies wavelet(CDW)transform,...On-line partial discharge(PD)detection still remains a very challenging task because of the strong electromagnetic interferences.In this paper,a new method of de-noising,using complex Daubechies wavelet(CDW)transform,has been proposed.It is a relatively recent enhancement to the real-valued wavelet transform because of tow important properties,which are nearly shift-invariant and availability of phase information.Those properties give CDW transform superiority over other real-valued wavelet transform,and then the construction algorithm of CDW is introduced in detail.Secondly,based on the real threshold algorithm of real-valued wavelet transform,complex threshold algorithm is devised.This algorithm take the different characteristics of real part and imaginary part of complex wavelet coefficients into account,it modifies the real and imaginary parts of complex wavelet coefficients respectively.Thirdly,to obtain a real de-noised signal,new combined information series is devised.By applying different combination of real part and imaginary part of de-noised complex signal,a real de-noised signal can be restored with higher peak signal-to-noise ratio(PSNR)and less distortion of original signals.Finally,On-site applications of extracting PD signals from noisy background by the optimal de-noising scheme based on CDW are illustrated.The on-site experimental results show that the optimal de-noising scheme is an effective way to suppress white noise in PD measurement.展开更多
基金supported by the National Natural Science Foundation China(Grant No.42176222).
文摘As a crucial component of the Earth’s climate system,Antarctic sea ice has demonstrated significant variability over the satellite era.Here,we identify a remarkable decadal transition in the total Antarctic Sea Ice Extent(SIE).The stage from 1979 to 2006 is characterized by high-frequency(i.e.,seasonal to interannual)temporal variability in SIE and zonal asymmetry in Sea Ice Concentration(SIC),which is primarily under the control of the Amundsen Sea Low(ASL).After 2007,however,sea ice changes exhibit a more spatially homogeneous pattern in SIC and a more temporally long-lasting mode in SIE.Further analysis reveals that sea ice-ocean interaction plays a major role in the low-frequency(i.e.,multiannual)variability of Antarctic sea ice from 2007−22.The related physical process is inferred to manifest as a strong coupling between the surface and the subsurface ocean layers,involving enhanced vertical convection and the downward delivery of the surface anomalies related to ice melting and freezing processes,thus maintaining the SIE anomalies for a longer time.Furthermore,this process mainly occurs in the Amundsen-Bellingshausen Sea(ABS)sector,and the weakened subsurface ocean stratification is the key factor triggering the coupling process in this region.We find that the Circumpolar Deep Water(CDW)over the ABS sector continued to shoal before 2007 and remained stable thereafter.It is speculated that the shoaling of the CDW may be a possible driver leading to the weakening of the subsurface stratification.
基金S.A.and M.Z.acknowledge support by NSF,grant number 2230352S.S.D.acknowledges support from the UVA Research Innovation AwardK.S.D.and D.L.work on TMDs has been supported by National Science Foundation Grant No.221949.
文摘Thermoelectric coolers utilizing the Peltier effect have dominated the field of solid-state cooling but their efficiency is hindered by material limitations.Alternative routes based on the Thomson and Nernst effects offer new possibilities.Here,we present a comprehensive investigation of the thermoelectric properties of 1T-TiSe_(2),focusing on these effects around the charge density wave transition(≈200 K).The abrupt Fermi surface reconstruction associated with this transition leads to an exceptional peak in the Thomson coefficient of 450μVK^(-1) at 184 K,surpassing the Seebeck coefficient.Furthermore,1T-TiSe_(2) exhibits a remarkably broad temperature range(170-400 K)with a Thomson coefficient exceeding 190μV K^(-1),a characteristic highly desirable for the development of practical Thomson coolers with extended operational ranges.Additionally,the Nernst coefficient exhibits an unusual temperature dependence,increasing with temperature in the normal phase,which we attribute to bipolar conduction effects.The combination of solid-solid pure electronic phase transition to a semimetallic phase with bipolar transport is identified as responsible for the unusual Nernst trend and the unusually large Thomson coefficient over a broad temperature range.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62488201 and 1240041502)the Ministry of Science and Technology of China(Grant No.2022YFA1204100)+1 种基金the Chinese Academy of Sciences(Grant No.XDB33030100)the Innovation Program of Quantum Science and Technology(Grant No.2021ZD0302700)。
文摘Two-dimensional van der Waals(vdW)magnetic materials,characterized by their tunable magnetism,spin transport properties,and remarkable quantum effects,provide significant promise for the development of efficient,low-power spintronic devices.Intriguingly,the rare earth tritelluride(RTe3)materials have attracted great attention due to their unique magnetic structure,exotic electronic properties,multiple charge density wave(CDW),and superconductivity under pressure.Here,we report the successful synthesis of high-quality DyTe_(3)single crystals using a self-flux method.DyTe_(3)shows an antiferromagnetic transition at 4.5 K and demonstrates the magnetic field-induced ferromagnetism.The high-quality DyTe_(3)single crystal demonstrates outstanding transport properties,featuring a high carrier mobility of approximately1.4×10^(4)cm^(2)·V^(-1)·s^(-1)and large linear magnetoresistance of 1300%.Furthermore,distinct Shubnikov-de Haas(SdH)oscillations are observed in DyTe_(3),revealing a small Fermi pocket and an effective mass of 0.24 me.Remarkably,the unconventional in-plane negative magnetoresistances appear along the a-axis below 2 T and c-axis until 9 T from 2 K to17 K,which are attributed to the complex helimagnetic structures caused by CDW coupling and weak single-ion anisotropy.Our findings offer a significant platform for understanding the complex magnetoresistance behavior and quantum transport effects in RTe3-type materials,holding great promise for advancing applications in electronic and spintronic devices.
基金The National Natural Science Foundation of China under contract No.41721005the Fund of the Ministry of Natural Resources of the People’s Republic of China under contract Nos IRASCC 02-01-01 and 01-01-02C.
文摘Nitrification,a central process in the marine nitrogen cycle,produces regenerated nitrate in the euphotic zone and emits N_(2)O,a potent greenhouse gas as a by-product.The regulatory mechanisms of nitrification in the Southern Ocean,which is a critical region for CO_(2)sequestration and radiative benefits,remain poorly understood.Here,we investigated the in situ and dark nitrification rates in the upper 500 m and conducted substrate kinetics experiments across the Indian Sector in the Cosmonaut and Cooperation seas in the late austral summer.Our findings indicate that light inhibition of nitrification decreases exponentially with depth,exhibiting a light threshold of 0.53%photosynthetically active radiation.A positive relationship between dark nitrification and apparent oxygen utilization suggests a dependence on substrate availability from primary production.Importantly,an increased NH_(4)^(+) supply can act as a buffer against photo-inhibitory damage.Globally,substrate affinity(α)increases with depth and transitions from light to dark,decreases with increasing ambient NH_(4)^(+)and exhibits a latitudinal distribution,reflecting substrate utilization strategies.We also reveal that upwelling in Circumpolar Deep Water(CDW)stimulates nitrification through the introduction of potentially higher iron and deep diverse nitrifying microorganisms with higherα.We conclude that although light is the primary limiting factor for nitrification in summer,coupling between substrate availability and CDW upwelling can overcome this limitation,thereby alleviating photoinhibition by up to 45%±5.3%.
文摘As the climate change signs become more noticeable, the concern to prioritize sustainability within the AEC industry intensifies. This particularly pertained to issues related to the demand of resources, the excessive consumption of raw materials, and the associated generated waste. Presently, the construction industry is ranked among the industries that are accountable for the global generation of solid waste and energy consumption, leading to detrimental environmental effects. Nonetheless, over the years, construction methods, technological innovations, and building practices have made considerable progress, influenced by a growing emphasis on sustainability, especially in energy conservation and in adopting the Industrialized Production layer of Construction 4.0 (i.e., modular prefabrication, 3D concrete printing, and BIM). The concept of Circular Economy (CE) has been identified as a potential solution to achieve sustainability in building construction through the design, construction, and end-of-life deconstruction processes that enhance the management of waste based on the framework that is related to reducing, reusing, and recycling. Moreover, information and data related to geolocation complement advanced digital technologies by providing a collaborative platform that supports the application of CE as a practical approach to sustainability. Thus, this study will provide a straightforward methodology for developing a model that integrates BIM and sustainable design with Circular Economy’s concept to enhance the sustainability of construction projects to minimize their waste based on various construction methods (i.e., conventional, modular, and 3D concrete printing). The proposed model interrelates tools and data for the evaluation and planning strategies for the construction and deconstruction waste (CDW) management at the design stage, including estimating the quantities of the wasted materials, quantifying the production rates of selected equipment for the waste handling (loading and hauling) at the various stages of a project as well their associated cost. The proposed model will help users to calculate the quantity of construction and deconstruction waste (CDW) during the design of buildings based on their different construction methods at the early stage by using the concept of Design for Deconstruction (DfD);sustainable construction methods;and deconstruction process for waste management, which will lead to the suitable construction method.
文摘运用有限系统密度矩阵重整化群算法(FS-DMRG),研究拓展Bose-Hubbard模型(即在标准BoseHubbard模型的基础上加入最近邻格点间的粒子相互排斥作用V)发生相变的特征。通过计算系统的局域粒子数密度、单粒子能隙以及压缩系数,分析了系统在不同状态下的特征,得到了不同于标准Bose-Hubbard模型的新量子态——Charge Density Wave(CDW)态。通过分析产生特殊粒子分布方式的原因及其物理性质,得出了发生相变的临界条件。
基金Supported by the National Natural Science Foundation of China(Nos.41530960,41706081)the Scientifi c Research Foundation of SKLEC(No.2017RCDW04)。
文摘A cruise covering two transects in the Changjiang(Yangtze)estuary in July 2017 was conducted,aiming to explore the sources for riverine NOˉ3 and identify reactions involved in the NO_(3)^(-)transformations along the transport of the Changjiang diluted water(CDW).In the river water,NO_(3)^(-)was fundamentally contributed by chemical fertilizer leakage in the watershed according to isotope signals.Sewage discharge may also be significant on riverine NO_(3)^(-)inventory,while the isotope signal was masked by nitrification.Together with the transport of the CDW,NO_(3)^(-)production was observed in waters with low salinities(<20)and high turbidities.Nitrification resulted from the mineralization of riverine organic nitrogen;therefore,the high turbidity was linked to active production.In the outer plume,coupled with stratification,a significant decrease in NO_(3)^(-)concentration was observed in the surface water.In parallel,enrichment inδ^(15)N-NO_(3)^(-)andδ^(18)O-NO_(3)^(-)was found,indicating biological consumption by phytoplankton.The difference in the stratification intensity between two transects led to variations in NO_(3)^(-)concentrations and isotope compositions.In the benthic water,denitrification(sediment-water interface)and nitrification(bottom water)coexisted.Furthermore,accumulations of NH4+and dissolved organic nitrogen in the bottom water were observed,indicating that nitrification was constrained by oxidant(mainly dissolved oxygen)supplies.
基金Project Supported by National Natural Science Foundation China（50577069）, National Grid Company （2004-SGKJ）.
文摘On-line partial discharge(PD)detection still remains a very challenging task because of the strong electromagnetic interferences.In this paper,a new method of de-noising,using complex Daubechies wavelet(CDW)transform,has been proposed.It is a relatively recent enhancement to the real-valued wavelet transform because of tow important properties,which are nearly shift-invariant and availability of phase information.Those properties give CDW transform superiority over other real-valued wavelet transform,and then the construction algorithm of CDW is introduced in detail.Secondly,based on the real threshold algorithm of real-valued wavelet transform,complex threshold algorithm is devised.This algorithm take the different characteristics of real part and imaginary part of complex wavelet coefficients into account,it modifies the real and imaginary parts of complex wavelet coefficients respectively.Thirdly,to obtain a real de-noised signal,new combined information series is devised.By applying different combination of real part and imaginary part of de-noised complex signal,a real de-noised signal can be restored with higher peak signal-to-noise ratio(PSNR)and less distortion of original signals.Finally,On-site applications of extracting PD signals from noisy background by the optimal de-noising scheme based on CDW are illustrated.The on-site experimental results show that the optimal de-noising scheme is an effective way to suppress white noise in PD measurement.
