Nitrate pollution is a severe threat to the fragile ecosystems in karst regions.However,our knowledge of the sources and transformations of nitrate in karst cave groundwater is still limited.This study aimed to invest...Nitrate pollution is a severe threat to the fragile ecosystems in karst regions.However,our knowledge of the sources and transformations of nitrate in karst cave groundwater is still limited.This study aimed to investigate the temporal and spatial patterns of nitrate dynamics in the underground water of karst caves located on the south bank of the Qingjiang River in central China,through a comprehensive application of multiple approaches,such as hydrochemistry,nitrogen and oxygen isotope compositions of nitrate,and a Bayesian isotope mixing model(SIMMR).During the sampling period(from December 2018 to December 2019),the nitrate concentration did not show an apparent temporal variation;meanwhile,no water samples in this study had a nitrate concentration higher than the limit for drinking water,but the nitrate concentration in karst underground rivers is significantly higher than that in surface water.The results of the comprehensive analyses revealed that the predominant nitrate sources included nitrification in soil and chemical fertilizer,which had mean percentages of 43%and 32%,respectively.The source contribution varied in the outlet water among different caves.The soil-derived nitrate in the underground water from the Shizi Cave accounted for the highest proportion(49%),while chemical-fertilizer-derived nitrate in the underground water from the Mishui Cave accounted for the highest proportion(36%).The dualisotope signatures of nitrate supported a major influence on nitrogen dynamics in the cave underground from nitrification.These findings suggest that nitrate carried by underground rivers in karst caves should be alerted when making the nitrate balance in rivers flowing through karst areas.展开更多
In Southwestern China,the development of karst landforms and planation surfaces is closely related to local tectonics,fluvial incision,and base level changes,and climate changes.However,researches on when these karst ...In Southwestern China,the development of karst landforms and planation surfaces is closely related to local tectonics,fluvial incision,and base level changes,and climate changes.However,researches on when these karst landforms and planation surfaces formed and how they evolved along drainage development are scarce.Fortunately,horizontal caves with numerous fluvial deposits in high karst mountains can be served as time markers in landform evolution.Here we select large horizontal caves to perform studies of geomorphology,sedimentology,and geochronology.Fieldwork revealed that more than 25 km long horizontal cave passages are perched 1500 m higher than the local base level,but filled with several phases of fluvial sediments and breakdown slabs.The first phase of fluvial gravels and related cave drainage was dated back to 6.4 Ma using cosmogenic nuclide burial dating,and the stalagmite covering the cave collapse was dated by the U-Pb method to be older than 1.56 Ma.These results show that the continuous horizontal cave drainage system and the planation surface were developed before the Late Miocene.The lowering process of the base level as a result of the sharp fluvial incision and water level lowering,along with the regional uplift,led to the abandonment of the horizontal cave and the elevated planation surface at the Late Miocene.After that,the phase of cave collapse,thick fluvial sand,and clay sediments in the recharge of cave areas were deposited at around 1.6 Ma and during the Middle Pleistocene,respectively.Subsequently,speleothems were widely deposited on the collapse and clay sediments during the period from 600 to 90 ka,whereas the deposition of cave fluvial sediments terminated suddenly.The tectonic could control the denudation of surface caprocks and the development of karst conduits before the Late Miocene,whereas the river incision acted as the main driver for the base level lowering and the destruction of the horizontal cave drainage at high altitudes.In addition,the rapid incision and retreat of Silurian gorges finally caused the formation of karst mesas in the Middle Pleistocene.展开更多
Caves located in the buried hill reservoir of granite bedrock in Bongor Basin,Chad,are excessively small and cannot be identifi ed in conventional refl ection wave imaging profi les because their refl ection character...Caves located in the buried hill reservoir of granite bedrock in Bongor Basin,Chad,are excessively small and cannot be identifi ed in conventional refl ection wave imaging profi les because their refl ection characteristics are suppressed by the strong refl ection of the weathering crust at the top of the buried hill.In contrast to refl ection wave imaging,which refl ects the refl ection characteristics of continuous interfaces,scattered wave imaging refl ects the reflection characteristics of discontinuous geological bodies.Scattering waves can be produced in the presence of discontinuous points,such as karst caves,fractures,and stratum vanishing points.Scattering imaging can accurately provide the location of discontinuous abnormal bodies,highlight the seismic reflection characteristics of caves with weak reflections,and eliminate continuous strong reflections to strengthen the ability of seismic data to distinguish discontinuous geological bodies and solve the inability of seismic data from conventional poststack refl ection wave imaging to identify small caves in buried hills.Three-parameter wavelet spectral decomposition technology is used to depict the boundary of caves accurately in accordance with the strong energy spectral characteristics of caves in the section of the scattering imaging seismic data of the granite bedrock buried hill reservoir.Compared with the attributes extracted from conventional refl ection wave poststack seismic data,those acquired from scattering imaging bodies are more reliable and consistent with the actual location of caves on boreholes and have higher resolution.For connected wells,the attributes extracted from the conventional poststack seismic data can only predict whether caves are developed,whereas those calculated from scattering imaging can not only predict whether caves are present but also refl ects the degree of cave development.On the plane,the attributes obtained from scattering imaging calculation are more consistent with the geological law of cave development.On the basis of this fi nding and in accordance with the results of the three-parameter wavelet spectral decomposition of scattering imaging seismic data,the degree of cave development is classifi ed,and the favorable location for reservoir development in the study area is identifi ed.This solution provides an eff ective way to improve the exploration accuracy of cave-type granite buried hill reservoirs.展开更多
The existence of an intensifying shift in the East Asian summer monsoon(EASM)since~2000 years ago that differs from the decreasing trend of Northern Hemisphere summer insolation remains controversial.Therefore,we comp...The existence of an intensifying shift in the East Asian summer monsoon(EASM)since~2000 years ago that differs from the decreasing trend of Northern Hemisphere summer insolation remains controversial.Therefore,we compared and synthesized stalagmiteδ^(18)O records from eastern China to clarify the EASM trend during this period.A total of 30 caveδ^(18)O records that did not consistently indicate a depleted trend during 2-0 ka.Rather,they included increasing(14 caves),decreasing(8 caves),and non-significant(8 caves)trends.The spatially interpolated trends of caveδ^(18)O suggested spatial differences among three subregions:North China(NC),decreasing trend(5 caves);Central-East China/Yangtze River Valley(CEC),increasing trend(17 caves);South China(SC),decreasing trend(8 caves).The caveδ^(18)O evidence supports spatial differences in precipitation in eastern China that have been substantially demonstrated by observations and model simulations.The decreasingδ^(18)O anomaly from NC and SC was associated with the decreasing sea surface temperature over Pacific Decadal Oscillation region and increasing South Oscillation Index.The increasing CECδ^(18)O anomaly was linked to southward Intertropical Convergence Zone shift and decreasing solar irradiance.Consequently,EASM circulation is jointly forced by external and internal factors at various timescales.展开更多
The chief objective of the article is to learn the spatial characteristics of stress distribution around a shallow buried cylinder Karst cave in limestone strata.Firstly,taking into account the geometry of limestone f...The chief objective of the article is to learn the spatial characteristics of stress distribution around a shallow buried cylinder Karst cave in limestone strata.Firstly,taking into account the geometry of limestone formations,and the characteristics of Karst geomorphology in China,a spatial axialsymmetrical hollow model was established.Concurrently,combining available work and the concept of elasticity,the boundary conditions are determined.Subsequently,Love displacement method was introduced,the expressions of stress components were gained.The diagram characteristics of each stress component are summarized,which are affected by various influencing factors.Finally,in order to prove the rationality of the general solution,numerical simulation was carried out on the basis of practical engineering,and the maximum error is less than 5%.Thus,the analytical solution could represent the spatial characteristics of stress distribution around a shallow buried cylinder Karst cave in limestone strata.展开更多
基金supported by the National Natural Science Foundation of China(Nos.42372355,42530706)。
文摘Nitrate pollution is a severe threat to the fragile ecosystems in karst regions.However,our knowledge of the sources and transformations of nitrate in karst cave groundwater is still limited.This study aimed to investigate the temporal and spatial patterns of nitrate dynamics in the underground water of karst caves located on the south bank of the Qingjiang River in central China,through a comprehensive application of multiple approaches,such as hydrochemistry,nitrogen and oxygen isotope compositions of nitrate,and a Bayesian isotope mixing model(SIMMR).During the sampling period(from December 2018 to December 2019),the nitrate concentration did not show an apparent temporal variation;meanwhile,no water samples in this study had a nitrate concentration higher than the limit for drinking water,but the nitrate concentration in karst underground rivers is significantly higher than that in surface water.The results of the comprehensive analyses revealed that the predominant nitrate sources included nitrification in soil and chemical fertilizer,which had mean percentages of 43%and 32%,respectively.The source contribution varied in the outlet water among different caves.The soil-derived nitrate in the underground water from the Shizi Cave accounted for the highest proportion(49%),while chemical-fertilizer-derived nitrate in the underground water from the Mishui Cave accounted for the highest proportion(36%).The dualisotope signatures of nitrate supported a major influence on nitrogen dynamics in the cave underground from nitrification.These findings suggest that nitrate carried by underground rivers in karst caves should be alerted when making the nitrate balance in rivers flowing through karst areas.
基金supported by the foundation of the Institute of Karst Geology,Chinese Academy of Geological Sciences(Nos.201317,2014005,2014034,2016011)National Natural Science Foundation of China(No.41270226)。
文摘In Southwestern China,the development of karst landforms and planation surfaces is closely related to local tectonics,fluvial incision,and base level changes,and climate changes.However,researches on when these karst landforms and planation surfaces formed and how they evolved along drainage development are scarce.Fortunately,horizontal caves with numerous fluvial deposits in high karst mountains can be served as time markers in landform evolution.Here we select large horizontal caves to perform studies of geomorphology,sedimentology,and geochronology.Fieldwork revealed that more than 25 km long horizontal cave passages are perched 1500 m higher than the local base level,but filled with several phases of fluvial sediments and breakdown slabs.The first phase of fluvial gravels and related cave drainage was dated back to 6.4 Ma using cosmogenic nuclide burial dating,and the stalagmite covering the cave collapse was dated by the U-Pb method to be older than 1.56 Ma.These results show that the continuous horizontal cave drainage system and the planation surface were developed before the Late Miocene.The lowering process of the base level as a result of the sharp fluvial incision and water level lowering,along with the regional uplift,led to the abandonment of the horizontal cave and the elevated planation surface at the Late Miocene.After that,the phase of cave collapse,thick fluvial sand,and clay sediments in the recharge of cave areas were deposited at around 1.6 Ma and during the Middle Pleistocene,respectively.Subsequently,speleothems were widely deposited on the collapse and clay sediments during the period from 600 to 90 ka,whereas the deposition of cave fluvial sediments terminated suddenly.The tectonic could control the denudation of surface caprocks and the development of karst conduits before the Late Miocene,whereas the river incision acted as the main driver for the base level lowering and the destruction of the horizontal cave drainage at high altitudes.In addition,the rapid incision and retreat of Silurian gorges finally caused the formation of karst mesas in the Middle Pleistocene.
文摘Caves located in the buried hill reservoir of granite bedrock in Bongor Basin,Chad,are excessively small and cannot be identifi ed in conventional refl ection wave imaging profi les because their refl ection characteristics are suppressed by the strong refl ection of the weathering crust at the top of the buried hill.In contrast to refl ection wave imaging,which refl ects the refl ection characteristics of continuous interfaces,scattered wave imaging refl ects the reflection characteristics of discontinuous geological bodies.Scattering waves can be produced in the presence of discontinuous points,such as karst caves,fractures,and stratum vanishing points.Scattering imaging can accurately provide the location of discontinuous abnormal bodies,highlight the seismic reflection characteristics of caves with weak reflections,and eliminate continuous strong reflections to strengthen the ability of seismic data to distinguish discontinuous geological bodies and solve the inability of seismic data from conventional poststack refl ection wave imaging to identify small caves in buried hills.Three-parameter wavelet spectral decomposition technology is used to depict the boundary of caves accurately in accordance with the strong energy spectral characteristics of caves in the section of the scattering imaging seismic data of the granite bedrock buried hill reservoir.Compared with the attributes extracted from conventional refl ection wave poststack seismic data,those acquired from scattering imaging bodies are more reliable and consistent with the actual location of caves on boreholes and have higher resolution.For connected wells,the attributes extracted from the conventional poststack seismic data can only predict whether caves are developed,whereas those calculated from scattering imaging can not only predict whether caves are present but also refl ects the degree of cave development.On the plane,the attributes obtained from scattering imaging calculation are more consistent with the geological law of cave development.On the basis of this fi nding and in accordance with the results of the three-parameter wavelet spectral decomposition of scattering imaging seismic data,the degree of cave development is classifi ed,and the favorable location for reservoir development in the study area is identifi ed.This solution provides an eff ective way to improve the exploration accuracy of cave-type granite buried hill reservoirs.
基金National Natural Science Foundation of China,No.42225105National Natural Science Foundation of China,No.42471177,No.42201175,No.41901099+1 种基金The Open Foundation of MOE Key Laboratory of Western China's Environmental System,Lanzhou Universitythe Fundamental Research Funds for the Central Universities,No.lzujbky-2022-kb04。
文摘The existence of an intensifying shift in the East Asian summer monsoon(EASM)since~2000 years ago that differs from the decreasing trend of Northern Hemisphere summer insolation remains controversial.Therefore,we compared and synthesized stalagmiteδ^(18)O records from eastern China to clarify the EASM trend during this period.A total of 30 caveδ^(18)O records that did not consistently indicate a depleted trend during 2-0 ka.Rather,they included increasing(14 caves),decreasing(8 caves),and non-significant(8 caves)trends.The spatially interpolated trends of caveδ^(18)O suggested spatial differences among three subregions:North China(NC),decreasing trend(5 caves);Central-East China/Yangtze River Valley(CEC),increasing trend(17 caves);South China(SC),decreasing trend(8 caves).The caveδ^(18)O evidence supports spatial differences in precipitation in eastern China that have been substantially demonstrated by observations and model simulations.The decreasingδ^(18)O anomaly from NC and SC was associated with the decreasing sea surface temperature over Pacific Decadal Oscillation region and increasing South Oscillation Index.The increasing CECδ^(18)O anomaly was linked to southward Intertropical Convergence Zone shift and decreasing solar irradiance.Consequently,EASM circulation is jointly forced by external and internal factors at various timescales.
基金supported by National Natural Science Foundation of China(42002293,52068019)Hainan Provincial Natural Science Foundation of China(520QN229,422RC599)+2 种基金Independent Innovation Fund Project of Tianjin University and Hainan University(KF2022⁃03)Scientific Research Startup Foundation of Hainan university(KYQD(2R)1969)Systematic Project of Key Laboratory of Geological Hazards on Three Gorges Reservoir Area(Three Gorges University),Ministry of Education(2020KDZ04).
文摘The chief objective of the article is to learn the spatial characteristics of stress distribution around a shallow buried cylinder Karst cave in limestone strata.Firstly,taking into account the geometry of limestone formations,and the characteristics of Karst geomorphology in China,a spatial axialsymmetrical hollow model was established.Concurrently,combining available work and the concept of elasticity,the boundary conditions are determined.Subsequently,Love displacement method was introduced,the expressions of stress components were gained.The diagram characteristics of each stress component are summarized,which are affected by various influencing factors.Finally,in order to prove the rationality of the general solution,numerical simulation was carried out on the basis of practical engineering,and the maximum error is less than 5%.Thus,the analytical solution could represent the spatial characteristics of stress distribution around a shallow buried cylinder Karst cave in limestone strata.
