The angular spectrum of spontaneous emission in a two-dimensional undulator free-electron laser is analyzed theoretically. Numerical calculation shows that the 3-th harmonic spontaneous emission power density can be g...The angular spectrum of spontaneous emission in a two-dimensional undulator free-electron laser is analyzed theoretically. Numerical calculation shows that the 3-th harmonic spontaneous emission power density can be greatly enhanced by using a two-dimensional undulator, for which l=s, so the harmonic number can be selected by selecting l. Therefore, the higher harmonic operation of a free-electron laser can be realized selectively.展开更多
On the basis of the second order solution of two-dimensional random gravity waves in finite uniform depth,which is rederived by a perturbation expansion method,the analytical expression of the second order spectrum is...On the basis of the second order solution of two-dimensional random gravity waves in finite uniform depth,which is rederived by a perturbation expansion method,the analytical expression of the second order spectrum is strictly deduced, and for infinite depth, the correct form of the kernel function is given for each octant do main.In fact,the present study improves and corrects the generally accepted results obtained by Tick展开更多
Proposed is a two-dimensional(2D)spectrum analysis system for acquiring the statistical information of radioactive particles on two dimensions,i.e.energy and time.Based on pulse width modulation readout circuit,such a...Proposed is a two-dimensional(2D)spectrum analysis system for acquiring the statistical information of radioactive particles on two dimensions,i.e.energy and time.Based on pulse width modulation readout circuit,such a system with 4-channels is designed,which converts the radiation signal into a rectangular pulse signal with pulse width modulated.The pulse width,occurrence time,and pulse count of the rectangular pulses are measured simultaneously with digital counters,so that the 2D spectra on energy and time of the radioactive particles can be obtained efficiently based on bi-parameter statistical analysis.A prototype of this 2D system is tested with gamma rays from 241Am isotopes,from which both the correlated 2D spectra and the independent spectra on energy and time are obtained.The energy spectra of four channels shows all characteristic peaks of 241Am gamma rays,among which the full-energy peak at 59.5keV exhibits energy resolution of about 5-6%,suggesting a good energy resolution and channel uniformity of the system.The regression of the time spectra of the characteristic peaks can give the time constants of each characteristic peak,revealing the time characteristics of the nuclear reactions in the radiative source.展开更多
In this study, we selected adult normal pituitary gland tissues from six patients during operations for pituitary microadenomas via the transsphenoidal approach for extended normal pituitary tissue resection around th...In this study, we selected adult normal pituitary gland tissues from six patients during operations for pituitary microadenomas via the transsphenoidal approach for extended normal pituitary tissue resection around the tumor, and analyzed the protein expression of human normal pituitary using two-dimensional high-performance liquid chromatography combined with LTQ-Orbitrap mass spectrometry proteomics technology. The ten most highly expressed proteins in normal human pituitary were： alpha 3 type VI collagen isoform 5 precursor （abundance among tall pituitary proteins 1.30%）, fibrinogen beta chain preproprotein （0.99%）, vimentin （0.73%）, prolactin （0.69%）, ATP synthase, H~ transporting and mitochondrial F1 complex beta subunit precursor （0.52%）, keratin I （0.49%）, growth hormone （0.45%）, carbonic anhydrase I （0.40%）, heat shock protein 90 kDa I （0.31%）, and annexin V （0.30%）. Based on the biological function classifications of these proteins, the top three categories by content were neuroendocrine proteins （abundance among all pituitary proteins, 40.1%）, catalytic and metabolic proteins （28.3%）, and cell signal transduction proteins （9.8%）. Based on cell positioning classification, the top three categories were cell organelle （24.5%） membrane （20.8%）, and cytoplasm （13.0%）. Based on biological process classification, the top three categories of proteins are involved in physiological processes （42.9%）, cellular processes （40.4%）, and regulation of biological processes （9.1%）. Our experimental findings indicate that a protein expression profile database of normal human pituitary can be precisely and efficiently established by proteomics technology.展开更多
D-T_(2)two-dimensional nuclear magnetic resonance(2D NMR)logging technology can distinguish pore fluid types intuitively,and it is widely used in oil and gas exploration.Many 2D NMR inversion methods(e.g.,truncated si...D-T_(2)two-dimensional nuclear magnetic resonance(2D NMR)logging technology can distinguish pore fluid types intuitively,and it is widely used in oil and gas exploration.Many 2D NMR inversion methods(e.g.,truncated singular value decomposition(TSVD),Butler-Reds-Dawson(BRD),LM-norm smoothing,and TIST-L1 regularization methods)have been proposed successively,but most are limited to numerical simulations.This study focused on the applicability of different inversion methods for NMR logging data of various acquisition sequences,from which the optimal inversion method was selected based on the comparative analysis.First,the two-dimensional NMR logging principle was studied.Then,these inversion methods were studied in detail,and the precision and computational efficiency of CPMG and diffusion editing(DE)sequences obtained from oil-water and gas-water models were compared,respectively.The inversion results and calculation time of truncated singular value decomposition(TSVD),Butler-Reds-Dawson(BRD),LM-norm smoothing,and TIST-L1 regularization were compared and analyzed through numerical simulations.The inversion method was optimized to process SP mode logging data from the MR Scanner instrument.The results showed that the TIST-regularization and LM-norm smoothing methods were more accurate for the CPMG and DE sequence echo trains of the oil-water and gas-water models.However,the LM-norm smoothing method was less time-consuming,making it more suitable for logging data processing.A case study in well A25 showed that the processing results by the LM-norm smoothing method were consistent with GEOLOG software.This demonstrates that the LM-norm smoothing method is applicable in practical NMR logging processing.展开更多
A novel analytical imaging algorithm is proposed for the strip-map mode of airborne bistatic squint SAR with unparallel trajectories. The algorithm derives the two-dimensional （2D） spectrum formula of the point targ...A novel analytical imaging algorithm is proposed for the strip-map mode of airborne bistatic squint SAR with unparallel trajectories. The algorithm derives the two-dimensional （2D） spectrum formula of the point target echo by using the contribution ratios of Doppler frequency modulation ratios of the transmitter and receiver as the weighting coefficients. Through decoupling the target position against the tracks of the transmitter and receiver, the range parameter and the azimuth one in the spectrum formula are separated. In 2D frequency domain, 2D Chirp-Z transform （2D-CZT） is applied to correcting the migrations of the echo along the range and azimuth after the bistatic deformation term has been compensated, so the target image is precisely focused. The advantage of the algorithm is easy to be expanded to the virtual wide swath by blocking the radar data along the range and azimuth to limit the 2D residual migrations. Simulation results confirm the validity of the 2D-CZT algorithm.展开更多
With appropriate geometry configuration, helicopter- borne rotating synthetic aperture radar （ROSAR） can break through the limitations of monostatic synthetic aperture radar （SAR） on forward-looking imaging. With ...With appropriate geometry configuration, helicopter- borne rotating synthetic aperture radar （ROSAR） can break through the limitations of monostatic synthetic aperture radar （SAR） on forward-looking imaging. With this capability, ROSAR has extensive potential applications, such as self-navigation and self-landing. Moreover, it has many advantages if combined with the frequency modulated continuous wave （FMCW） technology. A novel geometric configuration and an imaging algorithm for helicopter-borne FMCW-ROSAR are proposed. Firstly, by per- forming the equivalent phase center principle, the separated trans- mitting and receiving antenna system is equalized to the case of system configuration with antenna for both transmitting and receiving signals. Based on this, the accurate two-dimensional spectrum is obtained and the Doppler frequency shift effect in- duced by the continuous motion of the platform during the long pulse duration is compensated. Next, the impacts of the velocity approximation error on the imaging algorithm are analyzed in de- tail, and the system parameters selection and resolution analysis are presented. The well-focused SAR image is then obtained by using the improved Omega-K algorithm incorporating the accurate compensation method for the velocity approximation error. FJnally, correctness of the analysis and effectiveness of the proposed al- gorithm are demonstrated through simulation results.展开更多
A simulation method for measurement of the cross-section of the^(14)N(n,a)^(11)B reaction with gas and solid samples using a gridded ionization chamber(GIC)has been established.Using the simulation,the experimental sp...A simulation method for measurement of the cross-section of the^(14)N(n,a)^(11)B reaction with gas and solid samples using a gridded ionization chamber(GIC)has been established.Using the simulation,the experimental spectra of both^(14)N(n,a)^(11)B events and background from other reactions can be predicted,and the experimental scheme can be optimized.According to the simulation results,the optimal experimental parameters,including the pressure of the working gas and the compositions of the working gas and the sample,can be determined.In addition,the simulation results can be used to determine the valid event area and calculate the detection efficiency for valid events.A measurement of the cross-sections of the^(14)N(n,a)^(11)B reaction at E_(n)=4.25,4.50,4.75,5.00,5.25,and 5.50 MeV,based on the 4.5-MV Van de Graff accelerator at Peking University(PKU)using a GIC as the detector for the outgoing a particles,has been performed.The good agreement of the spectra from the simulation and experiment demonstrated the universality of this simulation method,which can be used to accurately measure neutroninduced light-charged particle emission reactions.展开更多
Objective： To investigate the innate characters of 3 endometriosis （EMT） syndromes, blood stasis （BS）, qi stagnation and blood stasis （QSBS） as well as Shen （Kidney） deficiency and blood stasis （KDBS） in te...Objective： To investigate the innate characters of 3 endometriosis （EMT） syndromes, blood stasis （BS）, qi stagnation and blood stasis （QSBS） as well as Shen （Kidney） deficiency and blood stasis （KDBS） in terms of proteomics, lay a molecular biological basis for the differentiation of various blood stasis syndromes of EMT, establish a EMT microscopic syndrome differentiation and diagnosis system in terms of proteomics, discover the evolution principles and therapeutic targets of these EMT syndromes, and search their significant molecular markers and genetic intervention targets. Methods： Six specimens from the ectopic and entopic endometrium tissues of patients with EMT in each syndrome, BS, QSBS as well as KDBS, in the early proliferative phase of the menstrual cycle, and 6 specimens from normal endometrium tissues in the early proliferative phase of the menstrual cycle were obtained. Three groups were formed in each syndrome by mixing two random specimens in equal amount, and then their respective two-dimensional electrophoresis graphs were obtained after total protein extraction. Finally, the detected differences in protein expression were identified through matrix-assisted laser desorption Ionization-time of flight mass spectrometry （MALDI-TOF/MS） and protein database. Results： The results of differential proteins expressed in each syndrome were shown as follows： BS syndrome had 2 differential proteins in entopic endometrium and 1 differential protein in ectopic endometrium; KDBS syndrome had 3 in entopic endometrium and 3 in ectopic endometrium; and QSBS syndrome had 3 in entopic endometrium and 4 in ectopic endometrium. It was found out that annexin was highly expressed in both entopic and ectopic endometrium of KDBS syndrome; and myosin light chain 3 was highly expressed in both entopic and ectopic endometrium of QSBS syndrome. Conclusion： There are differential protein expressions among the 3 EMT syndromes, which might be the inner origin of syndrome characters, and these differential proteins might be the candidate biomarkers for the pathogenesis of various EMT syndromes.展开更多
Since the study of the nuclear magnetic resonance （NMR）spectra of a number of sixmembered ring compounds reported by Lemieux et al. in 1958, the chemical shift and coupling constant for H<sub>1</sub> hav...Since the study of the nuclear magnetic resonance （NMR）spectra of a number of sixmembered ring compounds reported by Lemieux et al. in 1958, the chemical shift and coupling constant for H<sub>1</sub> have been used extensively to identify anomeric isomers in carbohydrate compounds. In 1-O-acyl-tetra-O-acetyl-β-O-hexapyranose, the anomeric proton of the展开更多
Molecular interactions of a representative pyrrolidinium-based ionic liquid 1-butyl-l-methyl-pyrrolidinium bis(triflorosulfonyl)-imide([BMPyrr][TFSI])with dimethyl sulfoxide(DMSO)and acetonitrile(AN)have been analyzed...Molecular interactions of a representative pyrrolidinium-based ionic liquid 1-butyl-l-methyl-pyrrolidinium bis(triflorosulfonyl)-imide([BMPyrr][TFSI])with dimethyl sulfoxide(DMSO)and acetonitrile(AN)have been analyzed in this work.Attenuated total reflection Fourier transform infrared spectroscopy(ATR-FTIR)and density functional theory(DFT)calculations are used in the investigation,while excess infrared spectra and two-dimensional correlation spectroscopy are used to explore the data in detail.It has been found that the molecular solvents can interact with TFSI-(mainly with S=O and weakly with S-N-S group).AN interacts feebly with BMPyrr+as compared with the strong interaction of DMSO.The strength of the interactions depends on the electron donating ability of the solvent.Upon mixing,hydrogen bonds regarding C-Hs in cation and S-N-S in anion are weakened,while that regarding S=O in anion is strengthened.Among the C-Hs which are connected directly with the N of the cation,Cl-H is the main interaction site for both DMSO and AN.This means that Cl-H is the most acidic hydrogen in pyrrolidinium cation.展开更多
The phenomenon of group motion is common in nature,ranging from the schools of fish,birds and insects,to avalanches,landslides and sand drift.If we treat objects as collectively moving particles,such phenomena can be ...The phenomenon of group motion is common in nature,ranging from the schools of fish,birds and insects,to avalanches,landslides and sand drift.If we treat objects as collectively moving particles,such phenomena can be studied from a physical point of view,and the research on many-body systems has proved that marvelous effects can arise from the simplest individuals.The motion of numerous individuals presents different dynamic phases related to the ordering of the system.However,it is usually difficult to study the dynamic ordering and its transitions through experiments.Electron bubble states formed in a two-dimensional electron gas,as a type of electron solids,can be driven by an external electric field and provide a platform to study the dynamic collective behaviors.Here,we demonstrate that the noise spectrum is a powerful method to investigate the dynamics of bubble states.We observed not only the phenomena of dynamically ordered and disordered structures,but also unexpected alternations between them.Our results show that a dissipative system can convert between chaotic structures and ordered structures when tuning global parameters,which is concealed in conventional transport measurements of resistance or conductance.Moreover,charging the objects to study the electrical noise spectrum in collective motions can be an additional approach to revealing dynamic ordering transitions.展开更多
文摘The angular spectrum of spontaneous emission in a two-dimensional undulator free-electron laser is analyzed theoretically. Numerical calculation shows that the 3-th harmonic spontaneous emission power density can be greatly enhanced by using a two-dimensional undulator, for which l=s, so the harmonic number can be selected by selecting l. Therefore, the higher harmonic operation of a free-electron laser can be realized selectively.
文摘On the basis of the second order solution of two-dimensional random gravity waves in finite uniform depth,which is rederived by a perturbation expansion method,the analytical expression of the second order spectrum is strictly deduced, and for infinite depth, the correct form of the kernel function is given for each octant do main.In fact,the present study improves and corrects the generally accepted results obtained by Tick
基金supported by the National Natural Science Foundation of China(Grant No.61274048)the National Science Associated Foundation of China(Grant No.10876044)
文摘Proposed is a two-dimensional(2D)spectrum analysis system for acquiring the statistical information of radioactive particles on two dimensions,i.e.energy and time.Based on pulse width modulation readout circuit,such a system with 4-channels is designed,which converts the radiation signal into a rectangular pulse signal with pulse width modulated.The pulse width,occurrence time,and pulse count of the rectangular pulses are measured simultaneously with digital counters,so that the 2D spectra on energy and time of the radioactive particles can be obtained efficiently based on bi-parameter statistical analysis.A prototype of this 2D system is tested with gamma rays from 241Am isotopes,from which both the correlated 2D spectra and the independent spectra on energy and time are obtained.The energy spectra of four channels shows all characteristic peaks of 241Am gamma rays,among which the full-energy peak at 59.5keV exhibits energy resolution of about 5-6%,suggesting a good energy resolution and channel uniformity of the system.The regression of the time spectra of the characteristic peaks can give the time constants of each characteristic peak,revealing the time characteristics of the nuclear reactions in the radiative source.
基金supported by the National NaturalScience Foundation of China, No. 81200890
文摘In this study, we selected adult normal pituitary gland tissues from six patients during operations for pituitary microadenomas via the transsphenoidal approach for extended normal pituitary tissue resection around the tumor, and analyzed the protein expression of human normal pituitary using two-dimensional high-performance liquid chromatography combined with LTQ-Orbitrap mass spectrometry proteomics technology. The ten most highly expressed proteins in normal human pituitary were： alpha 3 type VI collagen isoform 5 precursor （abundance among tall pituitary proteins 1.30%）, fibrinogen beta chain preproprotein （0.99%）, vimentin （0.73%）, prolactin （0.69%）, ATP synthase, H~ transporting and mitochondrial F1 complex beta subunit precursor （0.52%）, keratin I （0.49%）, growth hormone （0.45%）, carbonic anhydrase I （0.40%）, heat shock protein 90 kDa I （0.31%）, and annexin V （0.30%）. Based on the biological function classifications of these proteins, the top three categories by content were neuroendocrine proteins （abundance among all pituitary proteins, 40.1%）, catalytic and metabolic proteins （28.3%）, and cell signal transduction proteins （9.8%）. Based on cell positioning classification, the top three categories were cell organelle （24.5%） membrane （20.8%）, and cytoplasm （13.0%）. Based on biological process classification, the top three categories of proteins are involved in physiological processes （42.9%）, cellular processes （40.4%）, and regulation of biological processes （9.1%）. Our experimental findings indicate that a protein expression profile database of normal human pituitary can be precisely and efficiently established by proteomics technology.
基金sponsored by the National Natural Science Foundation of China(Nos.42174149,41774144)the National Major Projects(No.2016ZX05014-001).
文摘D-T_(2)two-dimensional nuclear magnetic resonance(2D NMR)logging technology can distinguish pore fluid types intuitively,and it is widely used in oil and gas exploration.Many 2D NMR inversion methods(e.g.,truncated singular value decomposition(TSVD),Butler-Reds-Dawson(BRD),LM-norm smoothing,and TIST-L1 regularization methods)have been proposed successively,but most are limited to numerical simulations.This study focused on the applicability of different inversion methods for NMR logging data of various acquisition sequences,from which the optimal inversion method was selected based on the comparative analysis.First,the two-dimensional NMR logging principle was studied.Then,these inversion methods were studied in detail,and the precision and computational efficiency of CPMG and diffusion editing(DE)sequences obtained from oil-water and gas-water models were compared,respectively.The inversion results and calculation time of truncated singular value decomposition(TSVD),Butler-Reds-Dawson(BRD),LM-norm smoothing,and TIST-L1 regularization were compared and analyzed through numerical simulations.The inversion method was optimized to process SP mode logging data from the MR Scanner instrument.The results showed that the TIST-regularization and LM-norm smoothing methods were more accurate for the CPMG and DE sequence echo trains of the oil-water and gas-water models.However,the LM-norm smoothing method was less time-consuming,making it more suitable for logging data processing.A case study in well A25 showed that the processing results by the LM-norm smoothing method were consistent with GEOLOG software.This demonstrates that the LM-norm smoothing method is applicable in practical NMR logging processing.
基金Foundation item： Anhui Province Natural Science Foundation of China （11040606M126）
文摘A novel analytical imaging algorithm is proposed for the strip-map mode of airborne bistatic squint SAR with unparallel trajectories. The algorithm derives the two-dimensional （2D） spectrum formula of the point target echo by using the contribution ratios of Doppler frequency modulation ratios of the transmitter and receiver as the weighting coefficients. Through decoupling the target position against the tracks of the transmitter and receiver, the range parameter and the azimuth one in the spectrum formula are separated. In 2D frequency domain, 2D Chirp-Z transform （2D-CZT） is applied to correcting the migrations of the echo along the range and azimuth after the bistatic deformation term has been compensated, so the target image is precisely focused. The advantage of the algorithm is easy to be expanded to the virtual wide swath by blocking the radar data along the range and azimuth to limit the 2D residual migrations. Simulation results confirm the validity of the 2D-CZT algorithm.
基金supported by the National Basic Research Program of China(2011CB707001)the Fundamental Research Funds for the Central Universities(106112015CDJXY500001CDJZR165505)
文摘With appropriate geometry configuration, helicopter- borne rotating synthetic aperture radar （ROSAR） can break through the limitations of monostatic synthetic aperture radar （SAR） on forward-looking imaging. With this capability, ROSAR has extensive potential applications, such as self-navigation and self-landing. Moreover, it has many advantages if combined with the frequency modulated continuous wave （FMCW） technology. A novel geometric configuration and an imaging algorithm for helicopter-borne FMCW-ROSAR are proposed. Firstly, by per- forming the equivalent phase center principle, the separated trans- mitting and receiving antenna system is equalized to the case of system configuration with antenna for both transmitting and receiving signals. Based on this, the accurate two-dimensional spectrum is obtained and the Doppler frequency shift effect in- duced by the continuous motion of the platform during the long pulse duration is compensated. Next, the impacts of the velocity approximation error on the imaging algorithm are analyzed in de- tail, and the system parameters selection and resolution analysis are presented. The well-focused SAR image is then obtained by using the improved Omega-K algorithm incorporating the accurate compensation method for the velocity approximation error. FJnally, correctness of the analysis and effectiveness of the proposed al- gorithm are demonstrated through simulation results.
基金supported by the National Natural Science Foundation of China(No.12075008)Science and Technology on Nuclear Data Laboratory,China Nuclear Data Centerthe State Key Laboratory of Nuclear Physics and Technology,Peking University(No.NPT2020KFJ22)。
文摘A simulation method for measurement of the cross-section of the^(14)N(n,a)^(11)B reaction with gas and solid samples using a gridded ionization chamber(GIC)has been established.Using the simulation,the experimental spectra of both^(14)N(n,a)^(11)B events and background from other reactions can be predicted,and the experimental scheme can be optimized.According to the simulation results,the optimal experimental parameters,including the pressure of the working gas and the compositions of the working gas and the sample,can be determined.In addition,the simulation results can be used to determine the valid event area and calculate the detection efficiency for valid events.A measurement of the cross-sections of the^(14)N(n,a)^(11)B reaction at E_(n)=4.25,4.50,4.75,5.00,5.25,and 5.50 MeV,based on the 4.5-MV Van de Graff accelerator at Peking University(PKU)using a GIC as the detector for the outgoing a particles,has been performed.The good agreement of the spectra from the simulation and experiment demonstrated the universality of this simulation method,which can be used to accurately measure neutroninduced light-charged particle emission reactions.
基金Supported by National Natural Science Foundation of China(No.30973770)
文摘Objective： To investigate the innate characters of 3 endometriosis （EMT） syndromes, blood stasis （BS）, qi stagnation and blood stasis （QSBS） as well as Shen （Kidney） deficiency and blood stasis （KDBS） in terms of proteomics, lay a molecular biological basis for the differentiation of various blood stasis syndromes of EMT, establish a EMT microscopic syndrome differentiation and diagnosis system in terms of proteomics, discover the evolution principles and therapeutic targets of these EMT syndromes, and search their significant molecular markers and genetic intervention targets. Methods： Six specimens from the ectopic and entopic endometrium tissues of patients with EMT in each syndrome, BS, QSBS as well as KDBS, in the early proliferative phase of the menstrual cycle, and 6 specimens from normal endometrium tissues in the early proliferative phase of the menstrual cycle were obtained. Three groups were formed in each syndrome by mixing two random specimens in equal amount, and then their respective two-dimensional electrophoresis graphs were obtained after total protein extraction. Finally, the detected differences in protein expression were identified through matrix-assisted laser desorption Ionization-time of flight mass spectrometry （MALDI-TOF/MS） and protein database. Results： The results of differential proteins expressed in each syndrome were shown as follows： BS syndrome had 2 differential proteins in entopic endometrium and 1 differential protein in ectopic endometrium; KDBS syndrome had 3 in entopic endometrium and 3 in ectopic endometrium; and QSBS syndrome had 3 in entopic endometrium and 4 in ectopic endometrium. It was found out that annexin was highly expressed in both entopic and ectopic endometrium of KDBS syndrome; and myosin light chain 3 was highly expressed in both entopic and ectopic endometrium of QSBS syndrome. Conclusion： There are differential protein expressions among the 3 EMT syndromes, which might be the inner origin of syndrome characters, and these differential proteins might be the candidate biomarkers for the pathogenesis of various EMT syndromes.
文摘Since the study of the nuclear magnetic resonance （NMR）spectra of a number of sixmembered ring compounds reported by Lemieux et al. in 1958, the chemical shift and coupling constant for H<sub>1</sub> have been used extensively to identify anomeric isomers in carbohydrate compounds. In 1-O-acyl-tetra-O-acetyl-β-O-hexapyranose, the anomeric proton of the
基金supported by the National Natural Science Foundation of China(21133009,21473099)
文摘Molecular interactions of a representative pyrrolidinium-based ionic liquid 1-butyl-l-methyl-pyrrolidinium bis(triflorosulfonyl)-imide([BMPyrr][TFSI])with dimethyl sulfoxide(DMSO)and acetonitrile(AN)have been analyzed in this work.Attenuated total reflection Fourier transform infrared spectroscopy(ATR-FTIR)and density functional theory(DFT)calculations are used in the investigation,while excess infrared spectra and two-dimensional correlation spectroscopy are used to explore the data in detail.It has been found that the molecular solvents can interact with TFSI-(mainly with S=O and weakly with S-N-S group).AN interacts feebly with BMPyrr+as compared with the strong interaction of DMSO.The strength of the interactions depends on the electron donating ability of the solvent.Upon mixing,hydrogen bonds regarding C-Hs in cation and S-N-S in anion are weakened,while that regarding S=O in anion is strengthened.Among the C-Hs which are connected directly with the N of the cation,Cl-H is the main interaction site for both DMSO and AN.This means that Cl-H is the most acidic hydrogen in pyrrolidinium cation.
基金The work at PKU was supported by Beijing Natural Science Foundation(Grant No.JQ18002)the NSFC(Grants No.11921005,11674009)+2 种基金the National Key Research and Development Program of China(Grant No.2017YFA0303301)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB28000000)The work at Princeton University was funded by the Gordon and Betty Moore Foundation's EPiQS Initiative,Grant GBMF9615 to L.N.Pfeiffer,and by the National Science Foundation MRSEC grant DMR-1420541.
文摘The phenomenon of group motion is common in nature,ranging from the schools of fish,birds and insects,to avalanches,landslides and sand drift.If we treat objects as collectively moving particles,such phenomena can be studied from a physical point of view,and the research on many-body systems has proved that marvelous effects can arise from the simplest individuals.The motion of numerous individuals presents different dynamic phases related to the ordering of the system.However,it is usually difficult to study the dynamic ordering and its transitions through experiments.Electron bubble states formed in a two-dimensional electron gas,as a type of electron solids,can be driven by an external electric field and provide a platform to study the dynamic collective behaviors.Here,we demonstrate that the noise spectrum is a powerful method to investigate the dynamics of bubble states.We observed not only the phenomena of dynamically ordered and disordered structures,but also unexpected alternations between them.Our results show that a dissipative system can convert between chaotic structures and ordered structures when tuning global parameters,which is concealed in conventional transport measurements of resistance or conductance.Moreover,charging the objects to study the electrical noise spectrum in collective motions can be an additional approach to revealing dynamic ordering transitions.
