Chiral separation is of critical importance in many areas spanning from pharmaceutics and agriculture to catalysis.Coordination polymers and metal-organic frameworks have been envisaged for such a purpose.In this stud...Chiral separation is of critical importance in many areas spanning from pharmaceutics and agriculture to catalysis.Coordination polymers and metal-organic frameworks have been envisaged for such a purpose.In this study,the post-synthetic functionalization of the two-dimensional Hofmann clathrate[Ni(H_(2)O)_(2)][Ni(CN)_(4)]with enantiopure phenylethylamines yielding hydrostable chiral clathrates is reported.展开更多
文摘Chiral separation is of critical importance in many areas spanning from pharmaceutics and agriculture to catalysis.Coordination polymers and metal-organic frameworks have been envisaged for such a purpose.In this study,the post-synthetic functionalization of the two-dimensional Hofmann clathrate[Ni(H_(2)O)_(2)][Ni(CN)_(4)]with enantiopure phenylethylamines yielding hydrostable chiral clathrates is reported.
