Supercapacitors,comprising electrical double-layer capacitors(EDLCs)and pseudocapa-citors,are widely acknowledged as high-power energy storage devices.However,their local structures and fundamental mechanisms remain p...Supercapacitors,comprising electrical double-layer capacitors(EDLCs)and pseudocapa-citors,are widely acknowledged as high-power energy storage devices.However,their local structures and fundamental mechanisms remain poorly understood,and suitable experimental techniques for investigation are also lacking.Recently,nuclear magnetic resonance(NMR)has emerged as a powerful tool for addressing these fundamental issues with high local sensitivity and non-invasiveness.In this paper,we first review the limi-tations of existing characterization methods and highlight the advantages of NMR in investigating mechanisms of supercapacitors.Subsequently,we introduce the basic prin-ciple of ring current effect,NMR-active nuclei,and various NMR techniques employed in exploring energy storage mechanisms including cross polarization(CP)magic angle spinning(MAS)NMR,multiple-quantum(MQ)MAS,two-dimensional exchange spec-troscopy(2D-EXSY)NMR,magnetic resonance imaging(MRI)and pulsed-field gradient(PFG)NMR.Based on this,recent progress in investigating energy storage mechanisms in EDLCs and pseudocapacitors through various NMR techniques is discussed.Finally,an outlook on future directions for NMR research in supercapacitors is offered.展开更多
Reliability is a persistent challenge in power electronics, with component failures significantly compromising system performance. Capacitors, widely used in power converters for filtering, contribute to approximately...Reliability is a persistent challenge in power electronics, with component failures significantly compromising system performance. Capacitors, widely used in power converters for filtering, contribute to approximately 30% of failures, predominantly due to electrochemical corrosion leading to capacitance degradation and catastrophic breakdowns. This paper presents a novel capacitor-free solid-state power filter(SSPF) for three-phase inverters, offering a transformative approach to mitigate reliability issues associated with conventional inductor-capacitor(LC) and active output filters(AOFs). Unlike AOFs, which depend on compact LC structures, the SSPF eliminates capacitors entirely, circumventing their inherent failure modes. Leveraging advanced solid-state devices and transformer technology, the SSPF achieves superior filtering performance, enhances system reliability, and significantly reduces component count, utilizing half the metal-oxidesemiconductor field effect transistor(MOSFET) switches required by AOFs. This design not only lowers costs but also improves efficiency. Simulation and experimental results demonstrate the SSPF's capability to deliver a sinusoidal output voltage at the fundamental frequency. These attributes position the SSPF as a robust, cost-effective, and innovative solution for modern power electronics applications.展开更多
Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains...Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.展开更多
CuS nanoplatelets arrays grown on graphene nanosheets are successfully synthesized via a facile lowtemperature solvothermal reaction with graphene oxide（GO）, CH;CSNH;and Cu（CH;COO）;·H;O as the reactants. CH;C...CuS nanoplatelets arrays grown on graphene nanosheets are successfully synthesized via a facile lowtemperature solvothermal reaction with graphene oxide（GO）, CH;CSNH;and Cu（CH;COO）;·H;O as the reactants. CH;CSNH;plays an important role in being the reducing agent for GO and the sulfur source of CuS. Supercapacitive performance of the graphene/CuS nanocomposite as active electrode materials has been evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy measurements. The results indicate that graphene/CuS electrode delivers a high capacitance of 497.8 F g;at a current density of 0.2 A g;, which outperforms bare CuS electrode. This excellent performance is ascribed to the short diffusion path and large surface area of the unique hierarchical nanostructure with nanoflakes building blocks for bulk accessibility of faradaic reaction.展开更多
As a promising energy-storage device,the hybrid lithium-ion capacitor coupling with both a large energy density battery-type anode and a high power density capacitor-type cathode is attracting great attention.For the ...As a promising energy-storage device,the hybrid lithium-ion capacitor coupling with both a large energy density battery-type anode and a high power density capacitor-type cathode is attracting great attention.For the sake of improving the energy density of hybrid lithium-ion capacitor,the free-standing anodes with good electrochemical performance are essential.Herein,we design an effective electrospinning strategy to prepare free-standing MnS/Co4S3/Ni3S2/Ni/C-nanofibers(TMSs/Ni/C-NFs)film and firstly use it as a binder-free anode for hybrid lithium-ion capacitor.We find that the carbon nanofibers can availably prevent MnS/Co4S3/Ni3S2/Ni nanoparticles from aggregation as well as significantly improve the electrochemical performance.Therefore,the binder-free TMSs/Ni/C-NFs membrane displays an ultrahigh reversible capacity of 1246.9 m Ah g-1at 100 m A g-1,excellent rate capability(398 mAh g-1 at2000 mA g-1),and long-term cyclic endurance.Besides,we further assemble the hybrid lithium-ion capacitor,which exhibits a high energy density of 182.0 Wh kg-1at 121.1 W kg-1(19.0 Wh kg-1 at 3512.5 W kg-1)and remarkable cycle life.展开更多
The cheap commercial activated carbon (AC) was improved through the secondary activation under steam in the presence of FeCl2 catalyst in the temperature range of 800-950℃ and its application in electric double layer...The cheap commercial activated carbon (AC) was improved through the secondary activation under steam in the presence of FeCl2 catalyst in the temperature range of 800-950℃ and its application in electric double layer capacitors (EDLCs) with organic electrolyte was studied. The re-activation of AC results in the increases in both specific capacitance and high rate capability of EDLCs. For AC treated under optimized conditions, its discharge specific capacitance increases up to 55.65 F/g, an increase of about 33% as compared to the original AC, and the high rate capability was increased significantly. The good performances of EDLC with improved AC were correlated to the increasing mesoporous ratio.展开更多
An analysis model of the dV/dt capability for a metal-oxide-semiconductor （MOS） controlled thyristor （MCT） is developed. It is shown that, in addition to the P-well resistance reported previously, the existence of...An analysis model of the dV/dt capability for a metal-oxide-semiconductor （MOS） controlled thyristor （MCT） is developed. It is shown that, in addition to the P-well resistance reported previously, the existence of the OFF-FET channel resistance in the MCT may degrade the dV/dt capability. Lower P-well and N-well dosages in the MCT are useful in getting a lower threshold voltage of OFF-FET and then a higher dV/dt immunity. However, both dosages are restricted by the requirements for the blocking property and the forward conduction capability. Thus, a double variable lateral doping （DVLD） technique is proposed to realize a high dV/dt immunity without any sacrifice in other properties. The accuracy of the developed model is verified by comparing the obtained results with those from simulations. In addition, this DVLD MCT features mask-saving compared with the conventional MCT fabrication process. The excellent device performance, coupled with the simple fabrication, makes the proposed DVLP MCT a promising candidate for capacitor discharge applications.展开更多
There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of t...There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of traditional rechargeable batteries with the superior power density and long life of supercapacitors(SCs).Nevertheless,the development of LICs is still hampered by limited kinetic processes and capacity mismatch between the cathode and anode.Metal-organic frameworks(MOFs)and their derivatives have received significant attention because of their extensive specific surface area,different pore structures and topologies,and customizable functional sites,making them compelling candidate materials for achieving high-performance LICs.MOF-derived carbons,known for their exceptional electronic conductivity and large surface area,provide improved charge storage and rapid ion transport.MOF-derived transition metal oxides contribute to high specific capacities and improved electrochemical stability.Additionally,MOF-derived metal compounds/carbons provide combined effects that increase both the capacitive and Faradaic reactions,leading to a superior overall performance.The review begins with an overview of the fundamental principles of LICs,followed by an exploration of synthesis strategies and ligand selection for MOF-based composite materials.It then analyzes the advantages of original MOFs and their derived materials,such as carbon materials and metal compounds,in enhancing LIC performance.Finally,the review discusses the major challenges faced by MOFs and their derivatives in LIC applications and offers future research directions and recommendations.展开更多
Pd-Al2O3-Si capacitors with Ru nanocrystals are fabricated and electrically characterized for nonvolatile memory application. While keeping the entire insulator Al2O3 thickness fixed, the memory window has a strong de...Pd-Al2O3-Si capacitors with Ru nanocrystals are fabricated and electrically characterized for nonvolatile memory application. While keeping the entire insulator Al2O3 thickness fixed, the memory window has a strong dependence on the tunneling layer thickness under low operating voltages, whereas it has weak dependence under high operating voltages. As for the optimal configuration comprised of 6-nm tunneling layer and 22-nm blocking layer, the resulting memory window increases from 1.5 V to 5.3 V with bias pulse increasing from 10-5 s to 10-2 s under ±7 V. A ten-year memory window as large as 5.2 V is extrapolated at room temperature after ±8 V/1 ms programming/erasing pulses.展开更多
A nano-composite polymer gel electrolyte was prepared using titanium oxide nanowire,poly(vinyl alcohol)(PVA),lithium salt and organic solvent N-methyl-2-pyrrolidone(NMP).The obtained electrolyte has the potential for ...A nano-composite polymer gel electrolyte was prepared using titanium oxide nanowire,poly(vinyl alcohol)(PVA),lithium salt and organic solvent N-methyl-2-pyrrolidone(NMP).The obtained electrolyte has the potential for application in electrochemical capacitor,the PVA in it is in an amorphous state.The ionic conductivities of electrolytes increased after addition of the nanowire,and the electrolyte with 3%(ω) of nanowire exhibited the highest ionic conductivity of 3.2 mS/cm at 20℃,as measured by electrochemical impedance spectroscopy.The temperature dependence of the conductivity was found to be in agreement with the Arrhenius equation.Functioning as separator and electrolyte,this nano-composite PVA gel electrolyte was used to assemble the electrochemical capacitor with active carbon film as electrodes.The compositing of nanowire may extend the life of electrochemical capacitors as they keep more than 90% of their capacitance after 5000 cycles of charging and discharging.展开更多
A high production efficiency synthesis method was used to produce a stacked vanadium nitride nanoparticle structure with an inexpensive raw material as an anode material and high surface area polystyrene was used the ...A high production efficiency synthesis method was used to produce a stacked vanadium nitride nanoparticle structure with an inexpensive raw material as an anode material and high surface area polystyrene was used the cathode material for lithium ion hybrid capacitors. The Li-HCs cell displayed an excellent specific capacitance of 64.2 F·g^-1 at a current density of 0.25 A·g^-1 and a wide potential window of 0.01 to 3.5 V. Furthermore, the device exhibited a high energy density of 109.3 W·h·kg^-1 at a power density of 512.3 W·kg^-1 and retained an energy density of 69.2 W·h·kg^-1 at a high power density of 3 498.9 W· kg^-1 at 2 A·g^-1. Due to the short synthesis time and simple raw materials, this method is suitable for industrial production.展开更多
In this work manganese oxide(MnO_(2))is modified with silico-tungstic acid(STA).Three samples are synthesized by the co-precipitation method.The powders obtained after elaboration are characterized by X-ray diffractio...In this work manganese oxide(MnO_(2))is modified with silico-tungstic acid(STA).Three samples are synthesized by the co-precipitation method.The powders obtained after elaboration are characterized by X-ray diffraction(XRD),Scanning Electron Microscopy(SEM)imaging coupled to Electron Dispersive Spectroscopy(EDS)analysis and Brunauer-Emmet-Teller(BET)for their surface area determination.The effect of the modification of the manganese oxide with STA on its surface is determined.It is shown that MnO_(2)modified with STA exhibits better cumulative high specific surface areas and mesoporous volumes areas.For example,the sample fabricates with 10%STA(MnO_(2)–10%STA)has a BET surface area of 153.6 m^(2)·g^(-1)and volume area 0.92 cm^(3)·g^(-1)whereas the sample without STA(MnO_(2)–0%STA)has a surface area of 132.57 m^(2)·g^(-1)and a mesoporous area of 0.26 cm^(3)·g^(-1).The electrochemical performance analysis of the different working electrodes prepared for super-capacitors applications is carried out using cyclic voltammetry(CV).,using a solution of 0.5 M K_(2)SO_(4)as an electrolyte in potential range of-0.4 and 0.9 V at a sweep speed of 10 mV/s.The CV results are correlated to those of the BET surface and mesoporous areas values Accordingly,it is shown that samples spiked with STA exhibit higher electrochemical double layer capacitance than those of none modified with STA.These measurements respectively give 38 F·g^(-1),and 181 F·g^(-1)for MnO2 without STA(MnO_(2)–0%STA),and MnO_(2)modified with 10%STA(MnO_(2)–5%STA).展开更多
In recent years, application of carbon-based nano material to electrode material has been paid attention, however, due to its higher cost, it would be difficult to put it into practical use. Then, we have proposed to ...In recent years, application of carbon-based nano material to electrode material has been paid attention, however, due to its higher cost, it would be difficult to put it into practical use. Then, we have proposed to make nano carbon fiber with lower production cost. The purpose of our research was, to apply our nano carbon fiber to electrical double-layer capacitor electrode. We used cotton candy method to make nano fiber, and applied microwave heating for carbonization. By applying nano carbon fiber to electrical double-layer capacitor electrode, we got results that thicker electrode containing nano carbon fiber leads to lower resistance value, compared with electrode without containing nano carbon fiber. From this result, it was indicated that by containing nano carbon fiber, the electric bypass was formed in the electrode.展开更多
To investigate the influence of expansion pretreatment for materials on carbon structure, activated carbons （ACs） were prepared from corncob with/without expansion pretreatment by KOH activation, the structure prope...To investigate the influence of expansion pretreatment for materials on carbon structure, activated carbons （ACs） were prepared from corncob with/without expansion pretreatment by KOH activation, the structure properties of which were determined based on N2 adsorption isotherm at 77 K. The results show that the expansion pretreatment for corncobs is beneficial to the preparation of ACs with high surface area. The specific surface area of the AC derived from corncob with expansion pretreatment （AC-1） is 32.5% larger than that without expansion pretreatment （AC-2）. Furthermore, to probe the potential application of corncob-based ACs in electric double-layer capacitor （EDLC）, the prepared ACs were used as electrode materials to assemble EDLC, and its electrochemical performance was investi- gated. The results indicate that the specific capacitance of AC-I is 276 F/g at 50 mA/g, which increases by 27% com- pared with that of AC-2 （217 F/g）. As electrode materials, AC-1 presents a better electrochemical performance than AC-2, including a higher voltage maintenance ratio and a lower leakage current.展开更多
The multi-layer ceramic capacitor (MLCC) alignment system aims at the inter-process automation between the first and the second plastic processes.As a result of testing performance verification of MLCC alignment syste...The multi-layer ceramic capacitor (MLCC) alignment system aims at the inter-process automation between the first and the second plastic processes.As a result of testing performance verification of MLCC alignment system,the average alignment rates are 95% for 3216 chip,88.5% for 2012 chip and 90.8% for 3818 chip.The MLCC alignment system can be accepted for practical use because the average manual alignment is just 80%.In other words,the developed MLCC alignment system has been upgraded to a great extent,compared with manual alignment.Based on the successfully developed MLCC alignment system,the optimal transfer conditions have been explored by using RSM.The simulations using ADAMS has been performed according to the cube model of CCD.By using MiniTAB,the model of response surface has been established based on the simulation results.The optimal conditions resulted from the response optimization tool of MiniTAB has been verified by being assigned to the prototype of MLCC alignment system.展开更多
High energy density capacitor is a key device to power supply source for electromagnetic gun (EMG) system, and extending its lifetime is important for increasing the reliability of the power source. Working in high el...High energy density capacitor is a key device to power supply source for electromagnetic gun (EMG) system, and extending its lifetime is important for increasing the reliability of the power source. Working in high electric field could affect the capacitor lifetime, and this effect on metallized polypropylene film capacitors (MPPFCs) in pulsed-power applications is studied and presented. Experimental re- sults show that the lifetime of MPPFCs decreases with the increasing peak value of charged electric field, and this decrease could be described by function (L/L0) ∝ (E/E0)–m, where, m=7.32. The lifetime of MPPFCs also decreases with the increase of the reversal coeffi- cients in underdamped circuits, which could be described by (L/L0) ∝ (ln(1/K0)/(ln(1/K))–b, where, b=0.7. These results provide a basis for the lifetime prediction of MPPFCs in pulsed-power applications.展开更多
Aqueous electrolytes are safe,economic,and environmentally friendly.However,they have a narrow potential window.On the other hand,organic electrolytes exhibit good thermodynamic stability but are inflammable and moist...Aqueous electrolytes are safe,economic,and environmentally friendly.However,they have a narrow potential window.On the other hand,organic electrolytes exhibit good thermodynamic stability but are inflammable and moisture sensitive.In this study,we prepared water-PEG-lipid ternary electrolytes(TEs).To combine the advantages of water,polyethylene glycol(PEG)and propylene carbonate(PC).The nonflammable mixed electrolytes exhibited a wide potential window of about 2.8 V due to the beneficial effects of PEG and PC.Using these TEs,a lithium manganate-active carbon ion capacitor could be operated at 2.4 V with an energy density of 32 Wh/kg,based on the total active electrode material(current density of 3.3 m A/cm^(2)).This value was significantly higher than that achieved using an aqueous electrolyte,thereby rationalizing the higher energy density.展开更多
This work presents an implementation of an innovative single phase multilevel inverter using capacitors with reduced switches. The proposed Capacitor pattern H-bridge Multilevel Inverter (CPHMLI) topology consists of ...This work presents an implementation of an innovative single phase multilevel inverter using capacitors with reduced switches. The proposed Capacitor pattern H-bridge Multilevel Inverter (CPHMLI) topology consists of a proper number of Capacitor connected with switches and power sources. The advanced switching control supplied by Pulse Width Modulation (PDPWM) to attain mixed staircase switching state. The charging and discharging mode are achieved by calculating the voltage error at the load. Furthermore, to accomplish the higher voltage levels at the output with less number of semiconductors switches and simple commutation designed using CPHMLI topology. To prove the performance and effectiveness of the proposed approach, a set of experiments performed under various load conditions using MATLAB tool.展开更多
In order to realize accurate bilinear transformation from s- to z-domain,a novelswitched-capacitor configuration is proposed in the light of principles of dual-rate sampling and chargeconservation,which has also been ...In order to realize accurate bilinear transformation from s- to z-domain,a novelswitched-capacitor configuration is proposed in the light of principles of dual-rate sampling and chargeconservation,which has also been used for building a 5th-order elliptic lowpass filter.The filter issimulated and measured in typical 0.34 μm/3.3 V Si CMOS process models,special full differentialoperational amplifiers and CMOS transfer gate switches,which achieves 80 MHz sampling rate,17.8MHz cutoff frequency,0.052 dB maximum passband ripple,42.1 dB minimum stopband attenuation and74 mW quiescent power dissipation.At the same time,the dual-rate sampling topology breaks thetraditional restrictions of filter introduced by unit-gain bandwidth and slew rate of operational amplifiersand also improves effectively their performances in high-frequency applications.It has been applied forthe design of an anti-alias filter in analog front-end of video decoder IC with 15 MHz signal frequencyyet.展开更多
Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and wate...Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and waterproof properties of MIM nanocapacitors.However,interfacial atomic diffusion poses a major obstacle,preventing the high-voltage MIM-AECs exploitation and thereby hampering their potential and advantages in high-power and high-energy-density applications.Here,an innovative high-voltage MIM-AECs were fabricated.The AlPO_(4)buffer layer is formed on AlO(OH)/AAO/Al surface by using H_(3)PO_(4)treatment,then a stable van der Waals(vdW)SnO_(2)/AlPO_(4)/AAO/Al multilayer was constructed via atomic layer deposition(ALD)technology.Due to higher diffusion barrier and lower carrier migration of SnO_(2)/AlPO_(4)/AAO interfaces,Sn atom diffusion is inhibited and carrier acceleration by electric field is weakened,guaranteeing high breakdown field strength of dielectric AAO and avoiding local breakdown risks.Through partial etching to hydrated AlO(OH)by H_(3)PO_(4)treatment,the tunnel was further opened up to facilitate subsequent ALD-SnO_(2)entry,thus obtaining a high SnO_(2)coverage.The SnO_(2)/AlPO_(4)/AAO/Al capacitors show a comprehensive performance in high-voltage(260 V),hightemperature(335℃),high-humidity(100%RH)and high-frequency response(100 k Hz),outperforming commercial solid-state AECs,and high-energy density(8.6μWh/cm^(2)),markedly exceeding previously reported MIM capacitors.The work lays the foundation for next-generation capacitors with highvoltage,high-frequency,high-temperature and high-humidity resistance.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.22075064)National Key Laboratory Projects(No.SYSKT20230056).
文摘Supercapacitors,comprising electrical double-layer capacitors(EDLCs)and pseudocapa-citors,are widely acknowledged as high-power energy storage devices.However,their local structures and fundamental mechanisms remain poorly understood,and suitable experimental techniques for investigation are also lacking.Recently,nuclear magnetic resonance(NMR)has emerged as a powerful tool for addressing these fundamental issues with high local sensitivity and non-invasiveness.In this paper,we first review the limi-tations of existing characterization methods and highlight the advantages of NMR in investigating mechanisms of supercapacitors.Subsequently,we introduce the basic prin-ciple of ring current effect,NMR-active nuclei,and various NMR techniques employed in exploring energy storage mechanisms including cross polarization(CP)magic angle spinning(MAS)NMR,multiple-quantum(MQ)MAS,two-dimensional exchange spec-troscopy(2D-EXSY)NMR,magnetic resonance imaging(MRI)and pulsed-field gradient(PFG)NMR.Based on this,recent progress in investigating energy storage mechanisms in EDLCs and pseudocapacitors through various NMR techniques is discussed.Finally,an outlook on future directions for NMR research in supercapacitors is offered.
基金curruntly supported by the Purdue University Office of Technology Commercialization under Track Code (PRF 71167-01)。
文摘Reliability is a persistent challenge in power electronics, with component failures significantly compromising system performance. Capacitors, widely used in power converters for filtering, contribute to approximately 30% of failures, predominantly due to electrochemical corrosion leading to capacitance degradation and catastrophic breakdowns. This paper presents a novel capacitor-free solid-state power filter(SSPF) for three-phase inverters, offering a transformative approach to mitigate reliability issues associated with conventional inductor-capacitor(LC) and active output filters(AOFs). Unlike AOFs, which depend on compact LC structures, the SSPF eliminates capacitors entirely, circumventing their inherent failure modes. Leveraging advanced solid-state devices and transformer technology, the SSPF achieves superior filtering performance, enhances system reliability, and significantly reduces component count, utilizing half the metal-oxidesemiconductor field effect transistor(MOSFET) switches required by AOFs. This design not only lowers costs but also improves efficiency. Simulation and experimental results demonstrate the SSPF's capability to deliver a sinusoidal output voltage at the fundamental frequency. These attributes position the SSPF as a robust, cost-effective, and innovative solution for modern power electronics applications.
基金financially supported by the National Natural Science Foundation of China(Nos.22272118,22172111,and 22309134)the Science and Technology Commission of Shanghai Municipality,China(Nos.22ZR1464100,20ZR1460300,and 19DZ2271500)+2 种基金the China Postdoctoral Science Foundation(2022M712402),the Shanghai Rising-Star Program(23YF1449200)the Zhejiang Provincial Science and Technology Project(2022C01182)the Fundamental Research Funds for the Central Universities(2023-3-YB-07)。
文摘Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.
基金supported by the General Project of Anhui Provincial Education Department(TSKJ2016B13)Key Project of Anhui Provincial Education Department(KJ2018A0104)the Startup Fund from AHPU(2015YQQ007)
文摘CuS nanoplatelets arrays grown on graphene nanosheets are successfully synthesized via a facile lowtemperature solvothermal reaction with graphene oxide（GO）, CH;CSNH;and Cu（CH;COO）;·H;O as the reactants. CH;CSNH;plays an important role in being the reducing agent for GO and the sulfur source of CuS. Supercapacitive performance of the graphene/CuS nanocomposite as active electrode materials has been evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy measurements. The results indicate that graphene/CuS electrode delivers a high capacitance of 497.8 F g;at a current density of 0.2 A g;, which outperforms bare CuS electrode. This excellent performance is ascribed to the short diffusion path and large surface area of the unique hierarchical nanostructure with nanoflakes building blocks for bulk accessibility of faradaic reaction.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 51072173, 51272221 and 51302239)Specialized Research Fund for the Doctoral Program of Higher Education (Grant Nos. 20134301130001)the Natural Science Foundation of Hunan Province, China (Grant Nos. 13JJ4051).
文摘As a promising energy-storage device,the hybrid lithium-ion capacitor coupling with both a large energy density battery-type anode and a high power density capacitor-type cathode is attracting great attention.For the sake of improving the energy density of hybrid lithium-ion capacitor,the free-standing anodes with good electrochemical performance are essential.Herein,we design an effective electrospinning strategy to prepare free-standing MnS/Co4S3/Ni3S2/Ni/C-nanofibers(TMSs/Ni/C-NFs)film and firstly use it as a binder-free anode for hybrid lithium-ion capacitor.We find that the carbon nanofibers can availably prevent MnS/Co4S3/Ni3S2/Ni nanoparticles from aggregation as well as significantly improve the electrochemical performance.Therefore,the binder-free TMSs/Ni/C-NFs membrane displays an ultrahigh reversible capacity of 1246.9 m Ah g-1at 100 m A g-1,excellent rate capability(398 mAh g-1 at2000 mA g-1),and long-term cyclic endurance.Besides,we further assemble the hybrid lithium-ion capacitor,which exhibits a high energy density of 182.0 Wh kg-1at 121.1 W kg-1(19.0 Wh kg-1 at 3512.5 W kg-1)and remarkable cycle life.
基金The authors are grateful for the National Natural Science Foundation of China (20003005) the Natural Science Foundation of Jiangsu Province (BQ2000009).
文摘The cheap commercial activated carbon (AC) was improved through the secondary activation under steam in the presence of FeCl2 catalyst in the temperature range of 800-950℃ and its application in electric double layer capacitors (EDLCs) with organic electrolyte was studied. The re-activation of AC results in the increases in both specific capacitance and high rate capability of EDLCs. For AC treated under optimized conditions, its discharge specific capacitance increases up to 55.65 F/g, an increase of about 33% as compared to the original AC, and the high rate capability was increased significantly. The good performances of EDLC with improved AC were correlated to the increasing mesoporous ratio.
基金supported by the National Natural Science Foundation of China(Grant No.U1330114)the Advance Research Program,China(GrantNo.51308030407)the Opening Project of Science and Technology on Reliability Physics and Application Technology of Electronic Component Laboratory,China(Grant No.ZHD201201)
文摘An analysis model of the dV/dt capability for a metal-oxide-semiconductor （MOS） controlled thyristor （MCT） is developed. It is shown that, in addition to the P-well resistance reported previously, the existence of the OFF-FET channel resistance in the MCT may degrade the dV/dt capability. Lower P-well and N-well dosages in the MCT are useful in getting a lower threshold voltage of OFF-FET and then a higher dV/dt immunity. However, both dosages are restricted by the requirements for the blocking property and the forward conduction capability. Thus, a double variable lateral doping （DVLD） technique is proposed to realize a high dV/dt immunity without any sacrifice in other properties. The accuracy of the developed model is verified by comparing the obtained results with those from simulations. In addition, this DVLD MCT features mask-saving compared with the conventional MCT fabrication process. The excellent device performance, coupled with the simple fabrication, makes the proposed DVLP MCT a promising candidate for capacitor discharge applications.
文摘There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of traditional rechargeable batteries with the superior power density and long life of supercapacitors(SCs).Nevertheless,the development of LICs is still hampered by limited kinetic processes and capacity mismatch between the cathode and anode.Metal-organic frameworks(MOFs)and their derivatives have received significant attention because of their extensive specific surface area,different pore structures and topologies,and customizable functional sites,making them compelling candidate materials for achieving high-performance LICs.MOF-derived carbons,known for their exceptional electronic conductivity and large surface area,provide improved charge storage and rapid ion transport.MOF-derived transition metal oxides contribute to high specific capacities and improved electrochemical stability.Additionally,MOF-derived metal compounds/carbons provide combined effects that increase both the capacitive and Faradaic reactions,leading to a superior overall performance.The review begins with an overview of the fundamental principles of LICs,followed by an exploration of synthesis strategies and ligand selection for MOF-based composite materials.It then analyzes the advantages of original MOFs and their derived materials,such as carbon materials and metal compounds,in enhancing LIC performance.Finally,the review discusses the major challenges faced by MOFs and their derivatives in LIC applications and offers future research directions and recommendations.
基金Project supported by the National Key Technology Research and Development Program of China(Grant No.2009ZX02302-002)the National Natural Science Foundation of China(Grant No.61274088)the Program for New Century Excellent Talents in University of Ministry of Education of China(Grant No.NCET-08-0127)
文摘Pd-Al2O3-Si capacitors with Ru nanocrystals are fabricated and electrically characterized for nonvolatile memory application. While keeping the entire insulator Al2O3 thickness fixed, the memory window has a strong dependence on the tunneling layer thickness under low operating voltages, whereas it has weak dependence under high operating voltages. As for the optimal configuration comprised of 6-nm tunneling layer and 22-nm blocking layer, the resulting memory window increases from 1.5 V to 5.3 V with bias pulse increasing from 10-5 s to 10-2 s under ±7 V. A ten-year memory window as large as 5.2 V is extrapolated at room temperature after ±8 V/1 ms programming/erasing pulses.
基金Supported by the Key Program of Knowledge Innovation Project Sanctified by CAS(No.KGCX2-YW-341)
文摘A nano-composite polymer gel electrolyte was prepared using titanium oxide nanowire,poly(vinyl alcohol)(PVA),lithium salt and organic solvent N-methyl-2-pyrrolidone(NMP).The obtained electrolyte has the potential for application in electrochemical capacitor,the PVA in it is in an amorphous state.The ionic conductivities of electrolytes increased after addition of the nanowire,and the electrolyte with 3%(ω) of nanowire exhibited the highest ionic conductivity of 3.2 mS/cm at 20℃,as measured by electrochemical impedance spectroscopy.The temperature dependence of the conductivity was found to be in agreement with the Arrhenius equation.Functioning as separator and electrolyte,this nano-composite PVA gel electrolyte was used to assemble the electrochemical capacitor with active carbon film as electrodes.The compositing of nanowire may extend the life of electrochemical capacitors as they keep more than 90% of their capacitance after 5000 cycles of charging and discharging.
基金Funded by the National Natural Science Foundation of China(No.51762031)the Foundation for Innovation Groups of Basic Research in the Gansu Province(No.1606RJIA322)
文摘A high production efficiency synthesis method was used to produce a stacked vanadium nitride nanoparticle structure with an inexpensive raw material as an anode material and high surface area polystyrene was used the cathode material for lithium ion hybrid capacitors. The Li-HCs cell displayed an excellent specific capacitance of 64.2 F·g^-1 at a current density of 0.25 A·g^-1 and a wide potential window of 0.01 to 3.5 V. Furthermore, the device exhibited a high energy density of 109.3 W·h·kg^-1 at a power density of 512.3 W·kg^-1 and retained an energy density of 69.2 W·h·kg^-1 at a high power density of 3 498.9 W· kg^-1 at 2 A·g^-1. Due to the short synthesis time and simple raw materials, this method is suitable for industrial production.
基金financially supported by NSERC(National Science and Engineering Research Council of Canada).
文摘In this work manganese oxide(MnO_(2))is modified with silico-tungstic acid(STA).Three samples are synthesized by the co-precipitation method.The powders obtained after elaboration are characterized by X-ray diffraction(XRD),Scanning Electron Microscopy(SEM)imaging coupled to Electron Dispersive Spectroscopy(EDS)analysis and Brunauer-Emmet-Teller(BET)for their surface area determination.The effect of the modification of the manganese oxide with STA on its surface is determined.It is shown that MnO_(2)modified with STA exhibits better cumulative high specific surface areas and mesoporous volumes areas.For example,the sample fabricates with 10%STA(MnO_(2)–10%STA)has a BET surface area of 153.6 m^(2)·g^(-1)and volume area 0.92 cm^(3)·g^(-1)whereas the sample without STA(MnO_(2)–0%STA)has a surface area of 132.57 m^(2)·g^(-1)and a mesoporous area of 0.26 cm^(3)·g^(-1).The electrochemical performance analysis of the different working electrodes prepared for super-capacitors applications is carried out using cyclic voltammetry(CV).,using a solution of 0.5 M K_(2)SO_(4)as an electrolyte in potential range of-0.4 and 0.9 V at a sweep speed of 10 mV/s.The CV results are correlated to those of the BET surface and mesoporous areas values Accordingly,it is shown that samples spiked with STA exhibit higher electrochemical double layer capacitance than those of none modified with STA.These measurements respectively give 38 F·g^(-1),and 181 F·g^(-1)for MnO2 without STA(MnO_(2)–0%STA),and MnO_(2)modified with 10%STA(MnO_(2)–5%STA).
文摘In recent years, application of carbon-based nano material to electrode material has been paid attention, however, due to its higher cost, it would be difficult to put it into practical use. Then, we have proposed to make nano carbon fiber with lower production cost. The purpose of our research was, to apply our nano carbon fiber to electrical double-layer capacitor electrode. We used cotton candy method to make nano fiber, and applied microwave heating for carbonization. By applying nano carbon fiber to electrical double-layer capacitor electrode, we got results that thicker electrode containing nano carbon fiber leads to lower resistance value, compared with electrode without containing nano carbon fiber. From this result, it was indicated that by containing nano carbon fiber, the electric bypass was formed in the electrode.
基金National Natural Science Foundation of China (No. 50902102 and No. 51172160)
文摘To investigate the influence of expansion pretreatment for materials on carbon structure, activated carbons （ACs） were prepared from corncob with/without expansion pretreatment by KOH activation, the structure properties of which were determined based on N2 adsorption isotherm at 77 K. The results show that the expansion pretreatment for corncobs is beneficial to the preparation of ACs with high surface area. The specific surface area of the AC derived from corncob with expansion pretreatment （AC-1） is 32.5% larger than that without expansion pretreatment （AC-2）. Furthermore, to probe the potential application of corncob-based ACs in electric double-layer capacitor （EDLC）, the prepared ACs were used as electrode materials to assemble EDLC, and its electrochemical performance was investi- gated. The results indicate that the specific capacitance of AC-I is 276 F/g at 50 mA/g, which increases by 27% com- pared with that of AC-2 （217 F/g）. As electrode materials, AC-1 presents a better electrochemical performance than AC-2, including a higher voltage maintenance ratio and a lower leakage current.
基金supported by the Second Stage of Brain Korea 21 Projectssupported (in part) by the Solomon Mechanics Inc
文摘The multi-layer ceramic capacitor (MLCC) alignment system aims at the inter-process automation between the first and the second plastic processes.As a result of testing performance verification of MLCC alignment system,the average alignment rates are 95% for 3216 chip,88.5% for 2012 chip and 90.8% for 3818 chip.The MLCC alignment system can be accepted for practical use because the average manual alignment is just 80%.In other words,the developed MLCC alignment system has been upgraded to a great extent,compared with manual alignment.Based on the successfully developed MLCC alignment system,the optimal transfer conditions have been explored by using RSM.The simulations using ADAMS has been performed according to the cube model of CCD.By using MiniTAB,the model of response surface has been established based on the simulation results.The optimal conditions resulted from the response optimization tool of MiniTAB has been verified by being assigned to the prototype of MLCC alignment system.
基金Project supported by Opening Foundation of National Engineering Laboratory for UltraHigh Voltage Engineering Technology (Kunming, Guangzhou, China)
文摘High energy density capacitor is a key device to power supply source for electromagnetic gun (EMG) system, and extending its lifetime is important for increasing the reliability of the power source. Working in high electric field could affect the capacitor lifetime, and this effect on metallized polypropylene film capacitors (MPPFCs) in pulsed-power applications is studied and presented. Experimental re- sults show that the lifetime of MPPFCs decreases with the increasing peak value of charged electric field, and this decrease could be described by function (L/L0) ∝ (E/E0)–m, where, m=7.32. The lifetime of MPPFCs also decreases with the increase of the reversal coeffi- cients in underdamped circuits, which could be described by (L/L0) ∝ (ln(1/K0)/(ln(1/K))–b, where, b=0.7. These results provide a basis for the lifetime prediction of MPPFCs in pulsed-power applications.
基金supported by the National Natural Science Foundation of China(No.11975043)the Natural Science Foundation of Shandong Province(No.ZR2017LEM011)。
文摘Aqueous electrolytes are safe,economic,and environmentally friendly.However,they have a narrow potential window.On the other hand,organic electrolytes exhibit good thermodynamic stability but are inflammable and moisture sensitive.In this study,we prepared water-PEG-lipid ternary electrolytes(TEs).To combine the advantages of water,polyethylene glycol(PEG)and propylene carbonate(PC).The nonflammable mixed electrolytes exhibited a wide potential window of about 2.8 V due to the beneficial effects of PEG and PC.Using these TEs,a lithium manganate-active carbon ion capacitor could be operated at 2.4 V with an energy density of 32 Wh/kg,based on the total active electrode material(current density of 3.3 m A/cm^(2)).This value was significantly higher than that achieved using an aqueous electrolyte,thereby rationalizing the higher energy density.
文摘This work presents an implementation of an innovative single phase multilevel inverter using capacitors with reduced switches. The proposed Capacitor pattern H-bridge Multilevel Inverter (CPHMLI) topology consists of a proper number of Capacitor connected with switches and power sources. The advanced switching control supplied by Pulse Width Modulation (PDPWM) to attain mixed staircase switching state. The charging and discharging mode are achieved by calculating the voltage error at the load. Furthermore, to accomplish the higher voltage levels at the output with less number of semiconductors switches and simple commutation designed using CPHMLI topology. To prove the performance and effectiveness of the proposed approach, a set of experiments performed under various load conditions using MATLAB tool.
基金Supported by the National Nature Science Foundation(No. 60072004)and the University Postgraduate Station Foundation of China(No.2000061402)
文摘In order to realize accurate bilinear transformation from s- to z-domain,a novelswitched-capacitor configuration is proposed in the light of principles of dual-rate sampling and chargeconservation,which has also been used for building a 5th-order elliptic lowpass filter.The filter issimulated and measured in typical 0.34 μm/3.3 V Si CMOS process models,special full differentialoperational amplifiers and CMOS transfer gate switches,which achieves 80 MHz sampling rate,17.8MHz cutoff frequency,0.052 dB maximum passband ripple,42.1 dB minimum stopband attenuation and74 mW quiescent power dissipation.At the same time,the dual-rate sampling topology breaks thetraditional restrictions of filter introduced by unit-gain bandwidth and slew rate of operational amplifiersand also improves effectively their performances in high-frequency applications.It has been applied forthe design of an anti-alias filter in analog front-end of video decoder IC with 15 MHz signal frequencyyet.
基金supported by the National Natural Science Foundation of China(52477221,52202296)the Natural Science Foundation of Shaanxi Province(2023KXJ-246,2022JQ-048)。
文摘Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and waterproof properties of MIM nanocapacitors.However,interfacial atomic diffusion poses a major obstacle,preventing the high-voltage MIM-AECs exploitation and thereby hampering their potential and advantages in high-power and high-energy-density applications.Here,an innovative high-voltage MIM-AECs were fabricated.The AlPO_(4)buffer layer is formed on AlO(OH)/AAO/Al surface by using H_(3)PO_(4)treatment,then a stable van der Waals(vdW)SnO_(2)/AlPO_(4)/AAO/Al multilayer was constructed via atomic layer deposition(ALD)technology.Due to higher diffusion barrier and lower carrier migration of SnO_(2)/AlPO_(4)/AAO interfaces,Sn atom diffusion is inhibited and carrier acceleration by electric field is weakened,guaranteeing high breakdown field strength of dielectric AAO and avoiding local breakdown risks.Through partial etching to hydrated AlO(OH)by H_(3)PO_(4)treatment,the tunnel was further opened up to facilitate subsequent ALD-SnO_(2)entry,thus obtaining a high SnO_(2)coverage.The SnO_(2)/AlPO_(4)/AAO/Al capacitors show a comprehensive performance in high-voltage(260 V),hightemperature(335℃),high-humidity(100%RH)and high-frequency response(100 k Hz),outperforming commercial solid-state AECs,and high-energy density(8.6μWh/cm^(2)),markedly exceeding previously reported MIM capacitors.The work lays the foundation for next-generation capacitors with highvoltage,high-frequency,high-temperature and high-humidity resistance.
