The positron lifetimes of some compounds with NaCl-type crystal structure are calculated with the method of atomic superposition approximation （ATSUP） based on the theories of local-density-approximation （LDA） and...The positron lifetimes of some compounds with NaCl-type crystal structure are calculated with the method of atomic superposition approximation （ATSUP） based on the theories of local-density-approximation （LDA） and general- gradient-approximation （GGA）. The systematical results are fitted to a curve as a function of lattice constants. The positron bulk lifetimes of some other compounds with NaCl-type crystal structure, which are deduced from the systematical results, are in agreement with the experimental results given in other literature.展开更多
Recent developments in acceptor–donor–acceptor(A–D–A) type non-fullerene acceptors have led to substantial improvements in bulk-heterojunction polymer solar cells efficiency. The device performance strongly depend...Recent developments in acceptor–donor–acceptor(A–D–A) type non-fullerene acceptors have led to substantial improvements in bulk-heterojunction polymer solar cells efficiency. The device performance strongly depends on photoactive layer morphology, as the molecular packing, donor–acceptor interface and phase separation significantly affect the charge-transfer states and charge carrier dynamics. In this review, we start with a brief introduction of the techniques most effectively utilized to characterize multiphase morphology. Then, we summarize recent progress in A–D–A type acceptors, with the emphasis on understanding the molecular structure–morphology–performance relationships. Finally, an outlook on correlating morphological characteristics with photovoltage losses is presented for further improving device performance.展开更多
A kind of inorganic-organic hybrid semiconductor composite nanoparticles： Dawson-type phosphomolybdate- doped polypyrrole （P2Mo18-PPy） was designed and prepared using microemulsion oxidation-polymerization at room ...A kind of inorganic-organic hybrid semiconductor composite nanoparticles： Dawson-type phosphomolybdate- doped polypyrrole （P2Mo18-PPy） was designed and prepared using microemulsion oxidation-polymerization at room temperature and characterized by TEM and IR. The P2Mo18-PPy was used as a bulk-modifier to fabricate a chemically modified carbon paste electrode（CPE） by direct mixing, which represents the example of polyoxometalates（ POMs）- doped semiconductor polymer nanoparticles modified electrode. Both the advantage of POMs-doped polymer and the surface-renewal property of the CPE were fully utilized. The electrochemical behavior of the P2Mo18-PPY bulk-modified CPE（P2Mo18-PPy-CPE） was investigated with cyclic voltammetry. Three couples of reversible redox peaks were observed in the range from ＋ 800 to 0 mV, which corresponded to the reduction and oxidation through two-, four- and six-electron processes, respectively. The P2 Mo18-PPY-CPE showed a high electrocatalytic activity for the reduction of nitrite, which expanded the application of POMs-doped semiconductor polymer nanoparticles.展开更多
In this paper, bulk viscous Bianchi type V cosmological model with generalized Chaplygin gas, dynamical gravitational and cosmological constants has been investigated. We are assuming the condition on metric potential...In this paper, bulk viscous Bianchi type V cosmological model with generalized Chaplygin gas, dynamical gravitational and cosmological constants has been investigated. We are assuming the condition on metric potential . To obtain deterministic model, we have considered physically plausible relations like , and the generalized Chaplygin gas is described by equation of state . A new set of exact solutions of Einstein’s field equations has been obtained in Eckart theory, truncated theory and full causal theory. Physical behavior of the models has been discussed.展开更多
This paper deals with the Bianchi type I anisotropic models of the universe, filled with a bulk viscous cosmic fluid, in the presence of variable gravitational and cosmological constants. Some exact solutions of Einst...This paper deals with the Bianchi type I anisotropic models of the universe, filled with a bulk viscous cosmic fluid, in the presence of variable gravitational and cosmological constants. Some exact solutions of Einstein’s gravitational field equations with bulk viscosity, gravitational and cosmological constants have been obtained. Several well known forms of cosmological terms have been considered to discuss the effect of cosmological variables. The new cosmological models presented in this paper approaches to isotropic model with evolution of universe. The physical and dynamical properties of the models have also been discussed.展开更多
This paper is devoted to studying the generalized Chaplygin gas models in Bianchi type III space- time geometry with time varying bulk viscosity, cosmological and gravitational constants. We are considering the condit...This paper is devoted to studying the generalized Chaplygin gas models in Bianchi type III space- time geometry with time varying bulk viscosity, cosmological and gravitational constants. We are considering the condition on metric potential . Also to obtain deterministic models we have considered physically reasonable relations like , and the equation of state for generalized Chaplygin gas given by . A new set of exact solutions of Einstein’s field equations has been obtained in Eckart theory, truncated theory and full causal theory. Physical behaviour of the models has been discussed.展开更多
In this study, we used strippable LR 115 type 2 which is a Solid State Nuclear Track Detector (SSNTD) widely known for radon gas detection and measurement. The removed thickness of the active layer of samples of this ...In this study, we used strippable LR 115 type 2 which is a Solid State Nuclear Track Detector (SSNTD) widely known for radon gas detection and measurement. The removed thickness of the active layer of samples of this SSNTD, were determined by measuring the average initial thickness (before etching) and residual thickness after 80 to 135 minutes chemical etching in the standard conditions, using an electronic comparator. These results allowed the calculation of the bulk etch rate of this detector in a simple way. The mean value obtained is (3.21 ± 0.21) μm/h. This value is in close agreement with those reported by different authors. It is an important parameter for alpha track counting on the sensitive surface of this polymeric detector after chemical etching because track density depends extremely on its removed layer. This SSNTD was then used for environmental radon gas monitoring in Côte d’Ivoire.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 10675114 and 10835006)the Important Direction Project of the Chinese Academy of Sciences
文摘The positron lifetimes of some compounds with NaCl-type crystal structure are calculated with the method of atomic superposition approximation （ATSUP） based on the theories of local-density-approximation （LDA） and general- gradient-approximation （GGA）. The systematical results are fitted to a curve as a function of lattice constants. The positron bulk lifetimes of some other compounds with NaCl-type crystal structure, which are deduced from the systematical results, are in agreement with the experimental results given in other literature.
基金support by Research Grants Council of Hong Kong(Grant Nos.15246816 and 15218517)the funding for Project of Strategic Importance provided by the Hong Kong Polytechnic University(Project Code:1-ZE29)the Shenzhen Science and Technology Innovation Commission(Project no.JCYJ20170413154602102)
文摘Recent developments in acceptor–donor–acceptor(A–D–A) type non-fullerene acceptors have led to substantial improvements in bulk-heterojunction polymer solar cells efficiency. The device performance strongly depends on photoactive layer morphology, as the molecular packing, donor–acceptor interface and phase separation significantly affect the charge-transfer states and charge carrier dynamics. In this review, we start with a brief introduction of the techniques most effectively utilized to characterize multiphase morphology. Then, we summarize recent progress in A–D–A type acceptors, with the emphasis on understanding the molecular structure–morphology–performance relationships. Finally, an outlook on correlating morphological characteristics with photovoltage losses is presented for further improving device performance.
基金Supported by Natural Science Foundation of Liaoning Province(No. 20032138) and Education Committee Foundation of Liaon-ing Province(No. 2004F023).
文摘A kind of inorganic-organic hybrid semiconductor composite nanoparticles： Dawson-type phosphomolybdate- doped polypyrrole （P2Mo18-PPy） was designed and prepared using microemulsion oxidation-polymerization at room temperature and characterized by TEM and IR. The P2Mo18-PPy was used as a bulk-modifier to fabricate a chemically modified carbon paste electrode（CPE） by direct mixing, which represents the example of polyoxometalates（ POMs）- doped semiconductor polymer nanoparticles modified electrode. Both the advantage of POMs-doped polymer and the surface-renewal property of the CPE were fully utilized. The electrochemical behavior of the P2Mo18-PPY bulk-modified CPE（P2Mo18-PPy-CPE） was investigated with cyclic voltammetry. Three couples of reversible redox peaks were observed in the range from ＋ 800 to 0 mV, which corresponded to the reduction and oxidation through two-, four- and six-electron processes, respectively. The P2 Mo18-PPY-CPE showed a high electrocatalytic activity for the reduction of nitrite, which expanded the application of POMs-doped semiconductor polymer nanoparticles.
文摘In this paper, bulk viscous Bianchi type V cosmological model with generalized Chaplygin gas, dynamical gravitational and cosmological constants has been investigated. We are assuming the condition on metric potential . To obtain deterministic model, we have considered physically plausible relations like , and the generalized Chaplygin gas is described by equation of state . A new set of exact solutions of Einstein’s field equations has been obtained in Eckart theory, truncated theory and full causal theory. Physical behavior of the models has been discussed.
文摘This paper deals with the Bianchi type I anisotropic models of the universe, filled with a bulk viscous cosmic fluid, in the presence of variable gravitational and cosmological constants. Some exact solutions of Einstein’s gravitational field equations with bulk viscosity, gravitational and cosmological constants have been obtained. Several well known forms of cosmological terms have been considered to discuss the effect of cosmological variables. The new cosmological models presented in this paper approaches to isotropic model with evolution of universe. The physical and dynamical properties of the models have also been discussed.
文摘This paper is devoted to studying the generalized Chaplygin gas models in Bianchi type III space- time geometry with time varying bulk viscosity, cosmological and gravitational constants. We are considering the condition on metric potential . Also to obtain deterministic models we have considered physically reasonable relations like , and the equation of state for generalized Chaplygin gas given by . A new set of exact solutions of Einstein’s field equations has been obtained in Eckart theory, truncated theory and full causal theory. Physical behaviour of the models has been discussed.
文摘In this study, we used strippable LR 115 type 2 which is a Solid State Nuclear Track Detector (SSNTD) widely known for radon gas detection and measurement. The removed thickness of the active layer of samples of this SSNTD, were determined by measuring the average initial thickness (before etching) and residual thickness after 80 to 135 minutes chemical etching in the standard conditions, using an electronic comparator. These results allowed the calculation of the bulk etch rate of this detector in a simple way. The mean value obtained is (3.21 ± 0.21) μm/h. This value is in close agreement with those reported by different authors. It is an important parameter for alpha track counting on the sensitive surface of this polymeric detector after chemical etching because track density depends extremely on its removed layer. This SSNTD was then used for environmental radon gas monitoring in Côte d’Ivoire.
