Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critica...Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis.展开更多
Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte...Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte plays a crucial role in these processes,significantly impacting the stability and reversibility of Zn^(2+)deposition.Therefore,pH-buffer tris(hydroxymethyl)amino methane(tris)is chosen as a versatile electrolyte additive to address these issues.Tris can buffer electrolyte pH at Zn/electrolyte interface by protonated/deprotonated nature of amino group,optimize the coordination environment of zinc solvate ions by its strong interaction with zinc ions,and simultaneously create an in-situ stable solid electrolyte interface membrane on the zinc anode surface.These synergistic effects effectively restrain dendrite formation and side reactions,resulting in a highly stable and reversible Zn anode,thereby enhancing the electrochemical performance of AZIBs.The Zn||Zn battery with 0.15 wt%tris additives maintains stable cycling for 1500 h at 4 mA·cm^(−2) and 1120 h at 10 mA·cm^(−2).Furthermore,the Coulombic efficiency reaches~99.2%at 4 mA·cm^(−2)@1 mAh·cm^(−2).The Zn||NVO full batteries also demonstrated a stable specific capacity and exceptional capacity retention.展开更多
A new multi function voltage-mode universal biquadratic filter using single Voltage Differencing Differential Input Buffered Amplifier (VD-DIBA), two capacitors and one resistor is proposed. The proposed configuration...A new multi function voltage-mode universal biquadratic filter using single Voltage Differencing Differential Input Buffered Amplifier (VD-DIBA), two capacitors and one resistor is proposed. The proposed configuration has four inputs and one output and can realize all the five standard filters from the same circuit configuration. The presented biquad filter offers low active and passive sensitivities. The validity of proposed universal biquadratic filter has been verified by SPICE simulation using 0.35 μm MIETEC technology.展开更多
Current MSM switching fabric has poor performance under unbalanced traffic. This paper presents an alternative, novel Central-stage Buffered Three-stage Clos switching (CB-3Clos) fabric and proves that this fabric can...Current MSM switching fabric has poor performance under unbalanced traffic. This paper presents an alternative, novel Central-stage Buffered Three-stage Clos switching (CB-3Clos) fabric and proves that this fabric can emulate output queuing switch without any speedup. By analyzing the condition to satisfy the central-stage load-balance, this paper also proposes a Central-stage Load-balanced-based Distributed Scheduling algorithm (CLDS) for CB-3Clos. The results show that, compared with Concurrent Round-Robin based Dispatching (CRRD) algorithm based on MSM, CLDS algorithm has high throughput irrespective with the traffic model and better performance in mean packet delay.展开更多
This paper proposes a new filter biquad circuit, which utilizes three Current Differencing Buffered Amplifiers (CDBA), two capacitors and five resistors, and operates in the trans-resistance mode. This multi-input and...This paper proposes a new filter biquad circuit, which utilizes three Current Differencing Buffered Amplifiers (CDBA), two capacitors and five resistors, and operates in the trans-resistance mode. This multi-input and single-output multifunction filter uses only grounded capacitors. All the employed resistors are either grounded or virtually grounded, which is an important parameter for its implementation as an integrated circuit. The circuit enjoys independent tunability of angular frequency and bandwidth. The 0.5 μm technology process parameters have been utilized to test and verify the performance characteristics of the circuit using PSPICE. The non-ideal analysis and sensitivity analysis, transient response, Monte-Carlo analysis and calculations of total harmonic distortion have also been shown.展开更多
Each biological system possesses a widely unrecognized buffer system to maintain acid-base balance to a specific pH. The skin pH is crucial for physiological skin function. In aged or diseased skin, pH increase is obs...Each biological system possesses a widely unrecognized buffer system to maintain acid-base balance to a specific pH. The skin pH is crucial for physiological skin function. In aged or diseased skin, pH increase is observed and may negatively affect skin health. Skin care products with a pH that is slightly more acidic than the average normal skin pH and have an adequate buffering capacity, are considered beneficial for the skin. However, the buffer capacity of these products also plays an important role. In the present study, a possible normalization or acidification of skin surface pH and influence on skin hydration and skin barrier function was assessed via application of buffered skin care products that are formulated with pH ≤ 4.5. 48 subjects aged above 50 were treated with three different skin care products (Vitamin C Spheres, Collagen Spray, and Collagen Mask) and skin surface pH, skin hydration and barrier integrity were assessed before treatment start and after 4 weeks. The results show that after 4-week treatment with Vitamin C, the skin pH is acidified. Treatment with Collagen Spray and Collagen Mask showed maintenance of a physiological skin pH. Subgroup analysis of subjects that had a higher than average skin pH at study start demonstrated that all three tested skin care products were able to acidify the skin surface. In addition, skin hydration was also increased for two of the three tested products, whereas skin barrier is not significantly changed. This demonstrates that buffered skin care products formulated to a pH ≤ 4.5 are able to acidify and maintain physiological skin pH and may contribute to a physiological skin function.展开更多
In the complex multicore chip system,network on-chip(NoC)is viewed as a kind of system interconnection that can substitute the traditional interconnect networks,which will improve the system performance and communicat...In the complex multicore chip system,network on-chip(NoC)is viewed as a kind of system interconnection that can substitute the traditional interconnect networks,which will improve the system performance and communication efficiency.With regard to the complex and large scale NoC,simple and efficient routing nodes are the critical factors to achieve low-cost and low-congestion communication performance.This paper proposes an unbuffered switch architecture and makes detailed analysis of the mechanism of buffer in the switch architecture.According to the simulation results,the S-mesh using the unbuffered switch architecture is better in terms of the optimal performance in message latency than some typical NoC architectures,such as 2D-mesh,Fat-tree,Butterfly,Octagon and so on.The synthesis results of design compiler indicate that the unbuffered switch has obvious advantages of achieving cost and operating speed for the chips.展开更多
Integrated photonics has emerged as a promising alternative for data communication and computing,ferroelectric BaTiO_(3)^(-)(BTO)stands out for its exceptional electro-optic response among candidate materials.However,...Integrated photonics has emerged as a promising alternative for data communication and computing,ferroelectric BaTiO_(3)^(-)(BTO)stands out for its exceptional electro-optic response among candidate materials.However,direct epitaxial growth of BTO entails a fundamental trade-off:substrates with low refractive index are required for strong optical confinement,yet those with large lattice mismatch degrade film crystalline quality and electro-optic performance.We report a buffer-free,strain-engineered approach to integrate high-performance BTO thin films directly on LaAlO3-Sr2TaAlO6(LSAT)oxide-insulator substrates.By exploiting a self-buffer layer formed during the initial growth stage,we achieve periodic in-plane strain modulation that stabilizes a polymorphic phase boundary with orthorhombic polar nanoregions,yielding a Pockels coefficient exceeding 358 pm V^(-1)and a Curie temperature raised to 200℃.Leveraging this material platform,we demonstrate the first realization of a Mach-Zehnder modulator using epitaxial BTO on LSAT.The device exhibits a half-wave voltage-length product of 0.7 V cm at 1550 nm,which closely matches finite-element simulations,and supports a 6-dB electro-optic bandwidth of 28 GHz.Our results validate BTO on LSAT as a viable photonic platform for scalable,low-voltage and high-speed modulators.展开更多
Thetechnical,economic,and environmental performance of solar hot-water(SWH)systems for Swedish residential apartments—where approximately 80%of household energy is devoted to space heating and sanitary hotwater produ...Thetechnical,economic,and environmental performance of solar hot-water(SWH)systems for Swedish residential apartments—where approximately 80%of household energy is devoted to space heating and sanitary hotwater production—was assessed.Two collector types,flat plate(FP)and evacuated tube(ET),were simulated in TSOL Pro 5.5 for five major cities(Stockholm,Goteborg,Malmo,Uppsala,Linkoping).Climatic data and cold-water temperatures were sourced fromMeteonorm7.1,and economic parameters were derived fromrecent national statistics and literature.All calculations explicitly accounted for heat losses from collectors,storage tanks,and internal and external piping systems,and established solar-fraction equations and NPV methodology were applied.Sensitivity analyseswere conducted to determine optimal collector area and hot-water storage volume.Additionally,a Monte Carlo uncertainty analysis(10,000 iterations,±10%)and break-even subsidy/carbon-credit assessments were performed.The discount rate for NPV calculations was set at 0% for capital interest with a 5%reinvestment return over a 25-year lifespan.The highest annual solar heat yield(8017.5 kWh)was obtained in Malmo with 32 m^(2) of ET collectors,meeting 52.7%of total heating demand.Annual CO_(2) emissions were avoided by FP and ET systems by approximately~9.07 and~10.55 tonnes,respectively.Economic analysis showed that no payback was achieved without government allowance;however,at a$0.05/m^(2) allowance,positive NPV was exhibited at all stations.Lower levelized heat costs were delivered by FP systems,while ET systems demonstrated consistent superiority under climatic and economic variability according to the Monte Carlo analysis.Optimal design parameters were identified as 32 collectors and a 1680 L heating buffer tank,and Sankey diagrams highlighted collector losses as the dominant inefficiency.It was concluded that properly designed SWH systems,when supported by targeted subsidies,can significantly reduce fossil-fuel demand and CO_(2) emissions in Swedish residential buildings.This work provides the first city-specific technical–economic–environmental dataset for Sweden,establishes a foundation for a national solar-heating atlas,and informs policymaking toward 100%renewable energy targets;beyond the baseline evaluation,explicit subsidy and carbon-price thresholds,quantified uncertainty ranges,and loss-flow visualizations are also provided,reinforcing the robustness and policy relevance of the findings.展开更多
BaFe_(12)O_(19)(BaM)thin films with thicknesses ranging from 15 nm–200 nm were deposited on Al_(2)O_(3)(0001)substrates by pulsed laser deposition(PLD).X-ray diffraction patterns show that a buffer layer with a thick...BaFe_(12)O_(19)(BaM)thin films with thicknesses ranging from 15 nm–200 nm were deposited on Al_(2)O_(3)(0001)substrates by pulsed laser deposition(PLD).X-ray diffraction patterns show that a buffer layer with a thickness of nearly 60 nm forms on the substrate,and then a c-axis perpendicularly oriented Ba M thin film grows on the buffer layer.Atomic force microscopy results indicate that the Ba M thin film exhibits a spiral island growth mode on the buffer layer.Magnetic hysteresis loop results confirm that the buffer layer exhibits no significant magnetic anisotropy,while the Ba M thin film exhibits perpendicular magnetic anisotropy.The out-of-plane coercivity decreases with increasing Ba M thin-film thickness due to the combined effect of grain size growth and lattice strain relaxation.The 200 nm thick film exhibits optimum magnetic properties with M_(s)=319 emu/cm^(3) and H_(c)=1546 Oe.展开更多
Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision...Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision process is formulated as a Markov decision process(MDP)model to maximize the modularity.Corresponding key partitioning constraints on parallel restoration are considered.Second,based on the partitioning objective and constraints,the reward function of the partitioning MDP model is set by adopting a relative deviation normalization scheme to reduce mutual interference between the reward and penalty in the reward function.The soft bonus scaling mechanism is introduced to mitigate overestimation caused by abrupt jumps in the reward.Then,the deep Q network method is applied to solve the partitioning MDP model and generate partitioning schemes.Two experience replay buffers are employed to speed up the training process of the method.Finally,case studies on the IEEE 39-bus test system demonstrate that the proposed method can generate a high-modularity partitioning result that meets all key partitioning constraints,thereby improving the parallelism and reliability of the restoration process.Moreover,simulation results demonstrate that an appropriate discount factor is crucial for ensuring both the convergence speed and the stability of the partitioning training.展开更多
When IC technology is scaled into the very deep sub-micron regime, the optical proximity effects （OPE） turn into noticeable in optical lithography. Consequently, clock skew becomes more and more susceptible to proce...When IC technology is scaled into the very deep sub-micron regime, the optical proximity effects （OPE） turn into noticeable in optical lithography. Consequently, clock skew becomes more and more susceptible to process variations, such as OPE. In this paper, we propose a new buffered clock tree routing algorithm to prevent the influence of OPE and process variations to clock skew. Based on the concept of BSF （branch sensitivity factor）, our algorithm manages to reduce the skew sensitivity of the clock tree in the topology generation. The worst case skew due to the wire width change has been estimated, and proper buffers are inserted to avoid large capacitance load. Experimental results show that our algorithm can produce a more reliable, processinsensitive clock tree, and control clock skews in their permissible range evidently.展开更多
The effects of Ni buffer layer on the giant magnetoresistance structure of Co/Cu/Co sandwich are investigated systematically in this paper.It is found that Ni buffer layer can induce the crystallization of the lower N...The effects of Ni buffer layer on the giant magnetoresistance structure of Co/Cu/Co sandwich are investigated systematically in this paper.It is found that Ni buffer layer can induce the crystallization of the lower Ni/Co layer and produce small coercivity,thus enlarging the difference in the magnetic behavior between the two magnetic layers in the sandwich.Moreover,the use of the Ni buffer layer can also improve the interface flatness in the sandwich.All these factors enhance the sensitivity of the Ni buffered sandwich.展开更多
To address the lack of systematic studies on heavy metal fluorescent probes in typical buffer solutions,this study developed a Fe^(3+)and Cu^(2+)fluorescent probe,DHU‑NP‑4,based on a naphthalimide fluorophore.Comparat...To address the lack of systematic studies on heavy metal fluorescent probes in typical buffer solutions,this study developed a Fe^(3+)and Cu^(2+)fluorescent probe,DHU‑NP‑4,based on a naphthalimide fluorophore.Comparative analysis of the probe's performance in various buffer systems revealed that buffers with high organic content are unsuitable for evaluating such probes.Furthermore,the pH of the solvent system was found to significantly influence the probe's behavior.Under highly acidic conditions(pH≤2),DHU‑NP‑4 exhibited exceptional specificity for Fe^(3+),while in alkaline conditions,it demonstrated high specificity for Cu^(2+).Leveraging these properties,the probe enabled the quantitative detection of Fe^(3+)and Cu^(2+)in solution.展开更多
Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and wate...Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and waterproof properties of MIM nanocapacitors.However,interfacial atomic diffusion poses a major obstacle,preventing the high-voltage MIM-AECs exploitation and thereby hampering their potential and advantages in high-power and high-energy-density applications.Here,an innovative high-voltage MIM-AECs were fabricated.The AlPO_(4)buffer layer is formed on AlO(OH)/AAO/Al surface by using H_(3)PO_(4)treatment,then a stable van der Waals(vdW)SnO_(2)/AlPO_(4)/AAO/Al multilayer was constructed via atomic layer deposition(ALD)technology.Due to higher diffusion barrier and lower carrier migration of SnO_(2)/AlPO_(4)/AAO interfaces,Sn atom diffusion is inhibited and carrier acceleration by electric field is weakened,guaranteeing high breakdown field strength of dielectric AAO and avoiding local breakdown risks.Through partial etching to hydrated AlO(OH)by H_(3)PO_(4)treatment,the tunnel was further opened up to facilitate subsequent ALD-SnO_(2)entry,thus obtaining a high SnO_(2)coverage.The SnO_(2)/AlPO_(4)/AAO/Al capacitors show a comprehensive performance in high-voltage(260 V),hightemperature(335℃),high-humidity(100%RH)and high-frequency response(100 k Hz),outperforming commercial solid-state AECs,and high-energy density(8.6μWh/cm^(2)),markedly exceeding previously reported MIM capacitors.The work lays the foundation for next-generation capacitors with highvoltage,high-frequency,high-temperature and high-humidity resistance.展开更多
The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such sof...The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such soft rock geological conditions,the large deformation of the surrounding rock can easily lead to the failure of supporting structures,including shotcrete cracks,spalling,and steel arch distortion.To improve the lining support performance during the large deformation of squeezed surrounding rock,this work selects aluminum foam with densities of 0.25 g/cm3,0.42 g/cm3 and 0.61 g/cm3 as the buffer layer material and carries out uniaxial confined compression tests.Through the evaluation and analysis of energy absorption and the comparison of the yield pressure of aluminum foam with those of other cushioning materials and yield pressure support systems,the strength,deformation and energy absorption of aluminum foam with a density of 0.25 g/cm3 meet the yield pressure performance requirements.The numerical model of the buffer layer yielding support system is then established via the finite element analysis software ABAQUS,and the influence of the buffer layer setting on the lining support is analyzed.Compared with the conventional support scheme,the addition of an aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining.The maximum and minimum principal stresses of the primary support are reduced by 13%and 15%,respectively.The maximum and minimum principal stresses of the secondary lining are reduced by 15%and 12%,respectively,and the displacement deformation of the secondary lining position is reduced by 15%.In summary,the application of aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining,improve the stress safety of the support and reduce the deformation of the support.展开更多
Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and...Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and dark states,allowing for the precise localization of isolated emission patterns and the super-resolution reconstruction from millions of localized positions of single fluorophores.A critical factor influencing localization precision is the photo-switching behavior of fluorophores,which is affected by the imaging buffer.The imaging buffer typically comprises oxygen scavengers,photo-switching reagents,and refractive index regulators.Oxygen scavengers help prevent photobleaching,photo-switching reagents assist in facilitating the conversion of fluorophores,and refractive index regulators are used to adjust the refractive index of the solution.The synergistic interaction of these components promotes stable blinking of fluorophores,reduces irreversible photobleaching,and thereby ensures high-quality super-resolution imaging.This review provides a comprehensive overview of the essential compositions and functionalities of imaging buffers used in STORM,serving as a valuable resource for researchers seeking to select appropriate imaging buffers for their experiments.展开更多
文摘Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis.
基金supported by the Fund of Xuzhou Science and Technology Key R&D Program(Social Development)Project(No.KC22289)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX22_2783).
文摘Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte plays a crucial role in these processes,significantly impacting the stability and reversibility of Zn^(2+)deposition.Therefore,pH-buffer tris(hydroxymethyl)amino methane(tris)is chosen as a versatile electrolyte additive to address these issues.Tris can buffer electrolyte pH at Zn/electrolyte interface by protonated/deprotonated nature of amino group,optimize the coordination environment of zinc solvate ions by its strong interaction with zinc ions,and simultaneously create an in-situ stable solid electrolyte interface membrane on the zinc anode surface.These synergistic effects effectively restrain dendrite formation and side reactions,resulting in a highly stable and reversible Zn anode,thereby enhancing the electrochemical performance of AZIBs.The Zn||Zn battery with 0.15 wt%tris additives maintains stable cycling for 1500 h at 4 mA·cm^(−2) and 1120 h at 10 mA·cm^(−2).Furthermore,the Coulombic efficiency reaches~99.2%at 4 mA·cm^(−2)@1 mAh·cm^(−2).The Zn||NVO full batteries also demonstrated a stable specific capacity and exceptional capacity retention.
文摘A new multi function voltage-mode universal biquadratic filter using single Voltage Differencing Differential Input Buffered Amplifier (VD-DIBA), two capacitors and one resistor is proposed. The proposed configuration has four inputs and one output and can realize all the five standard filters from the same circuit configuration. The presented biquad filter offers low active and passive sensitivities. The validity of proposed universal biquadratic filter has been verified by SPICE simulation using 0.35 μm MIETEC technology.
基金Funded by the National Basic Research Program of China (No.2007CB307102)National High Tech Research and Development Program of China (No.2005AA121210)National Natural Science Foundation of China (No. 60572042)
文摘Current MSM switching fabric has poor performance under unbalanced traffic. This paper presents an alternative, novel Central-stage Buffered Three-stage Clos switching (CB-3Clos) fabric and proves that this fabric can emulate output queuing switch without any speedup. By analyzing the condition to satisfy the central-stage load-balance, this paper also proposes a Central-stage Load-balanced-based Distributed Scheduling algorithm (CLDS) for CB-3Clos. The results show that, compared with Concurrent Round-Robin based Dispatching (CRRD) algorithm based on MSM, CLDS algorithm has high throughput irrespective with the traffic model and better performance in mean packet delay.
文摘This paper proposes a new filter biquad circuit, which utilizes three Current Differencing Buffered Amplifiers (CDBA), two capacitors and five resistors, and operates in the trans-resistance mode. This multi-input and single-output multifunction filter uses only grounded capacitors. All the employed resistors are either grounded or virtually grounded, which is an important parameter for its implementation as an integrated circuit. The circuit enjoys independent tunability of angular frequency and bandwidth. The 0.5 μm technology process parameters have been utilized to test and verify the performance characteristics of the circuit using PSPICE. The non-ideal analysis and sensitivity analysis, transient response, Monte-Carlo analysis and calculations of total harmonic distortion have also been shown.
文摘Each biological system possesses a widely unrecognized buffer system to maintain acid-base balance to a specific pH. The skin pH is crucial for physiological skin function. In aged or diseased skin, pH increase is observed and may negatively affect skin health. Skin care products with a pH that is slightly more acidic than the average normal skin pH and have an adequate buffering capacity, are considered beneficial for the skin. However, the buffer capacity of these products also plays an important role. In the present study, a possible normalization or acidification of skin surface pH and influence on skin hydration and skin barrier function was assessed via application of buffered skin care products that are formulated with pH ≤ 4.5. 48 subjects aged above 50 were treated with three different skin care products (Vitamin C Spheres, Collagen Spray, and Collagen Mask) and skin surface pH, skin hydration and barrier integrity were assessed before treatment start and after 4 weeks. The results show that after 4-week treatment with Vitamin C, the skin pH is acidified. Treatment with Collagen Spray and Collagen Mask showed maintenance of a physiological skin pH. Subgroup analysis of subjects that had a higher than average skin pH at study start demonstrated that all three tested skin care products were able to acidify the skin surface. In addition, skin hydration was also increased for two of the three tested products, whereas skin barrier is not significantly changed. This demonstrates that buffered skin care products formulated to a pH ≤ 4.5 are able to acidify and maintain physiological skin pH and may contribute to a physiological skin function.
基金Supported by the National High Technology Research and Development Program of China(No.2009AA01Z105)the Ministry of EducationIntel Special Foundation for Information Technology(No.MOE-INTEL-08-05)the Postdoctoral Science Foundation of China(No.20080440942,200902432)
文摘In the complex multicore chip system,network on-chip(NoC)is viewed as a kind of system interconnection that can substitute the traditional interconnect networks,which will improve the system performance and communication efficiency.With regard to the complex and large scale NoC,simple and efficient routing nodes are the critical factors to achieve low-cost and low-congestion communication performance.This paper proposes an unbuffered switch architecture and makes detailed analysis of the mechanism of buffer in the switch architecture.According to the simulation results,the S-mesh using the unbuffered switch architecture is better in terms of the optimal performance in message latency than some typical NoC architectures,such as 2D-mesh,Fat-tree,Butterfly,Octagon and so on.The synthesis results of design compiler indicate that the unbuffered switch has obvious advantages of achieving cost and operating speed for the chips.
基金supported by Ministry of Education of China Scientific Research Innovation Capability Support Project for Young Faculty under Grant No.ZYGXQNJSKYCXNLZCXM-M17the Basic Science Center Project of National Natural Science Foundation of China(NSFC)under Grant No.52388201,NSFC grants No.U24A2009 and 12474087+2 种基金Beijing Municipal Natural Science Foundation under Grant No.JQ24011 and Z240008by China Postdoctoral Science Foundation under Grant No.2023M741873.supported by Synergetic Extreme Condition User Facility(SECUF,https://cstr.cn/31123.02.SECUF).
文摘Integrated photonics has emerged as a promising alternative for data communication and computing,ferroelectric BaTiO_(3)^(-)(BTO)stands out for its exceptional electro-optic response among candidate materials.However,direct epitaxial growth of BTO entails a fundamental trade-off:substrates with low refractive index are required for strong optical confinement,yet those with large lattice mismatch degrade film crystalline quality and electro-optic performance.We report a buffer-free,strain-engineered approach to integrate high-performance BTO thin films directly on LaAlO3-Sr2TaAlO6(LSAT)oxide-insulator substrates.By exploiting a self-buffer layer formed during the initial growth stage,we achieve periodic in-plane strain modulation that stabilizes a polymorphic phase boundary with orthorhombic polar nanoregions,yielding a Pockels coefficient exceeding 358 pm V^(-1)and a Curie temperature raised to 200℃.Leveraging this material platform,we demonstrate the first realization of a Mach-Zehnder modulator using epitaxial BTO on LSAT.The device exhibits a half-wave voltage-length product of 0.7 V cm at 1550 nm,which closely matches finite-element simulations,and supports a 6-dB electro-optic bandwidth of 28 GHz.Our results validate BTO on LSAT as a viable photonic platform for scalable,low-voltage and high-speed modulators.
文摘Thetechnical,economic,and environmental performance of solar hot-water(SWH)systems for Swedish residential apartments—where approximately 80%of household energy is devoted to space heating and sanitary hotwater production—was assessed.Two collector types,flat plate(FP)and evacuated tube(ET),were simulated in TSOL Pro 5.5 for five major cities(Stockholm,Goteborg,Malmo,Uppsala,Linkoping).Climatic data and cold-water temperatures were sourced fromMeteonorm7.1,and economic parameters were derived fromrecent national statistics and literature.All calculations explicitly accounted for heat losses from collectors,storage tanks,and internal and external piping systems,and established solar-fraction equations and NPV methodology were applied.Sensitivity analyseswere conducted to determine optimal collector area and hot-water storage volume.Additionally,a Monte Carlo uncertainty analysis(10,000 iterations,±10%)and break-even subsidy/carbon-credit assessments were performed.The discount rate for NPV calculations was set at 0% for capital interest with a 5%reinvestment return over a 25-year lifespan.The highest annual solar heat yield(8017.5 kWh)was obtained in Malmo with 32 m^(2) of ET collectors,meeting 52.7%of total heating demand.Annual CO_(2) emissions were avoided by FP and ET systems by approximately~9.07 and~10.55 tonnes,respectively.Economic analysis showed that no payback was achieved without government allowance;however,at a$0.05/m^(2) allowance,positive NPV was exhibited at all stations.Lower levelized heat costs were delivered by FP systems,while ET systems demonstrated consistent superiority under climatic and economic variability according to the Monte Carlo analysis.Optimal design parameters were identified as 32 collectors and a 1680 L heating buffer tank,and Sankey diagrams highlighted collector losses as the dominant inefficiency.It was concluded that properly designed SWH systems,when supported by targeted subsidies,can significantly reduce fossil-fuel demand and CO_(2) emissions in Swedish residential buildings.This work provides the first city-specific technical–economic–environmental dataset for Sweden,establishes a foundation for a national solar-heating atlas,and informs policymaking toward 100%renewable energy targets;beyond the baseline evaluation,explicit subsidy and carbon-price thresholds,quantified uncertainty ranges,and loss-flow visualizations are also provided,reinforcing the robustness and policy relevance of the findings.
文摘BaFe_(12)O_(19)(BaM)thin films with thicknesses ranging from 15 nm–200 nm were deposited on Al_(2)O_(3)(0001)substrates by pulsed laser deposition(PLD).X-ray diffraction patterns show that a buffer layer with a thickness of nearly 60 nm forms on the substrate,and then a c-axis perpendicularly oriented Ba M thin film grows on the buffer layer.Atomic force microscopy results indicate that the Ba M thin film exhibits a spiral island growth mode on the buffer layer.Magnetic hysteresis loop results confirm that the buffer layer exhibits no significant magnetic anisotropy,while the Ba M thin film exhibits perpendicular magnetic anisotropy.The out-of-plane coercivity decreases with increasing Ba M thin-film thickness due to the combined effect of grain size growth and lattice strain relaxation.The 200 nm thick film exhibits optimum magnetic properties with M_(s)=319 emu/cm^(3) and H_(c)=1546 Oe.
基金funded by the Beijing Engineering Research Center of Electric Rail Transportation.
文摘Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision process is formulated as a Markov decision process(MDP)model to maximize the modularity.Corresponding key partitioning constraints on parallel restoration are considered.Second,based on the partitioning objective and constraints,the reward function of the partitioning MDP model is set by adopting a relative deviation normalization scheme to reduce mutual interference between the reward and penalty in the reward function.The soft bonus scaling mechanism is introduced to mitigate overestimation caused by abrupt jumps in the reward.Then,the deep Q network method is applied to solve the partitioning MDP model and generate partitioning schemes.Two experience replay buffers are employed to speed up the training process of the method.Finally,case studies on the IEEE 39-bus test system demonstrate that the proposed method can generate a high-modularity partitioning result that meets all key partitioning constraints,thereby improving the parallelism and reliability of the restoration process.Moreover,simulation results demonstrate that an appropriate discount factor is crucial for ensuring both the convergence speed and the stability of the partitioning training.
基金the 863 National Hi-Tech Research and Development Plan of China(Grant No.2005AA1Z1230) the National Natural Science Foundation ofChina(Grant No.90307017).
文摘When IC technology is scaled into the very deep sub-micron regime, the optical proximity effects （OPE） turn into noticeable in optical lithography. Consequently, clock skew becomes more and more susceptible to process variations, such as OPE. In this paper, we propose a new buffered clock tree routing algorithm to prevent the influence of OPE and process variations to clock skew. Based on the concept of BSF （branch sensitivity factor）, our algorithm manages to reduce the skew sensitivity of the clock tree in the topology generation. The worst case skew due to the wire width change has been estimated, and proper buffers are inserted to avoid large capacitance load. Experimental results show that our algorithm can produce a more reliable, processinsensitive clock tree, and control clock skews in their permissible range evidently.
基金This work was supported by the Shanghai Research Center for Applied Physics and Shanghai Research (99JC14003) and Development Foundation for Application Materials (No. 98006).
文摘The effects of Ni buffer layer on the giant magnetoresistance structure of Co/Cu/Co sandwich are investigated systematically in this paper.It is found that Ni buffer layer can induce the crystallization of the lower Ni/Co layer and produce small coercivity,thus enlarging the difference in the magnetic behavior between the two magnetic layers in the sandwich.Moreover,the use of the Ni buffer layer can also improve the interface flatness in the sandwich.All these factors enhance the sensitivity of the Ni buffered sandwich.
文摘To address the lack of systematic studies on heavy metal fluorescent probes in typical buffer solutions,this study developed a Fe^(3+)and Cu^(2+)fluorescent probe,DHU‑NP‑4,based on a naphthalimide fluorophore.Comparative analysis of the probe's performance in various buffer systems revealed that buffers with high organic content are unsuitable for evaluating such probes.Furthermore,the pH of the solvent system was found to significantly influence the probe's behavior.Under highly acidic conditions(pH≤2),DHU‑NP‑4 exhibited exceptional specificity for Fe^(3+),while in alkaline conditions,it demonstrated high specificity for Cu^(2+).Leveraging these properties,the probe enabled the quantitative detection of Fe^(3+)and Cu^(2+)in solution.
基金supported by the National Natural Science Foundation of China(52477221,52202296)the Natural Science Foundation of Shaanxi Province(2023KXJ-246,2022JQ-048)。
文摘Metal-insulator-metal aluminium electrolytic capacitors(MIM-AECs)combine high capacity-density and high breakdown field strength of solid AECs with high-frequency responsibility,wide workingtemperature window and waterproof properties of MIM nanocapacitors.However,interfacial atomic diffusion poses a major obstacle,preventing the high-voltage MIM-AECs exploitation and thereby hampering their potential and advantages in high-power and high-energy-density applications.Here,an innovative high-voltage MIM-AECs were fabricated.The AlPO_(4)buffer layer is formed on AlO(OH)/AAO/Al surface by using H_(3)PO_(4)treatment,then a stable van der Waals(vdW)SnO_(2)/AlPO_(4)/AAO/Al multilayer was constructed via atomic layer deposition(ALD)technology.Due to higher diffusion barrier and lower carrier migration of SnO_(2)/AlPO_(4)/AAO interfaces,Sn atom diffusion is inhibited and carrier acceleration by electric field is weakened,guaranteeing high breakdown field strength of dielectric AAO and avoiding local breakdown risks.Through partial etching to hydrated AlO(OH)by H_(3)PO_(4)treatment,the tunnel was further opened up to facilitate subsequent ALD-SnO_(2)entry,thus obtaining a high SnO_(2)coverage.The SnO_(2)/AlPO_(4)/AAO/Al capacitors show a comprehensive performance in high-voltage(260 V),hightemperature(335℃),high-humidity(100%RH)and high-frequency response(100 k Hz),outperforming commercial solid-state AECs,and high-energy density(8.6μWh/cm^(2)),markedly exceeding previously reported MIM capacitors.The work lays the foundation for next-generation capacitors with highvoltage,high-frequency,high-temperature and high-humidity resistance.
基金the support of the National Natural Science Foundation of China(Grant No.42207199)Scientific Research Project of Education of Zhejiang Province(No.Y202351343)+1 种基金Zhejiang Postdoctoral Scientific Research Project(Grant Nos.ZJ2022155,ZJ2022156)Zhejiang Province International Science and Technology Cooperation Base Open Fund Project(IBGDP-2023-01)。
文摘The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such soft rock geological conditions,the large deformation of the surrounding rock can easily lead to the failure of supporting structures,including shotcrete cracks,spalling,and steel arch distortion.To improve the lining support performance during the large deformation of squeezed surrounding rock,this work selects aluminum foam with densities of 0.25 g/cm3,0.42 g/cm3 and 0.61 g/cm3 as the buffer layer material and carries out uniaxial confined compression tests.Through the evaluation and analysis of energy absorption and the comparison of the yield pressure of aluminum foam with those of other cushioning materials and yield pressure support systems,the strength,deformation and energy absorption of aluminum foam with a density of 0.25 g/cm3 meet the yield pressure performance requirements.The numerical model of the buffer layer yielding support system is then established via the finite element analysis software ABAQUS,and the influence of the buffer layer setting on the lining support is analyzed.Compared with the conventional support scheme,the addition of an aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining.The maximum and minimum principal stresses of the primary support are reduced by 13%and 15%,respectively.The maximum and minimum principal stresses of the secondary lining are reduced by 15%and 12%,respectively,and the displacement deformation of the secondary lining position is reduced by 15%.In summary,the application of aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining,improve the stress safety of the support and reduce the deformation of the support.
基金funded by the National Natural Science Foundation of China(No.62305041)the Natural Science Foundation of Liaoning Province(No.2023-MS-103)。
文摘Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and dark states,allowing for the precise localization of isolated emission patterns and the super-resolution reconstruction from millions of localized positions of single fluorophores.A critical factor influencing localization precision is the photo-switching behavior of fluorophores,which is affected by the imaging buffer.The imaging buffer typically comprises oxygen scavengers,photo-switching reagents,and refractive index regulators.Oxygen scavengers help prevent photobleaching,photo-switching reagents assist in facilitating the conversion of fluorophores,and refractive index regulators are used to adjust the refractive index of the solution.The synergistic interaction of these components promotes stable blinking of fluorophores,reduces irreversible photobleaching,and thereby ensures high-quality super-resolution imaging.This review provides a comprehensive overview of the essential compositions and functionalities of imaging buffers used in STORM,serving as a valuable resource for researchers seeking to select appropriate imaging buffers for their experiments.
