This study explored the performances of CZTS-based thin-film solar cell with three novel buffer layer materials ZnS, CdS, and CdZnS, as well as with variation in thickness of buffer and absorber-layer, doping concentr...This study explored the performances of CZTS-based thin-film solar cell with three novel buffer layer materials ZnS, CdS, and CdZnS, as well as with variation in thickness of buffer and absorber-layer, doping concentrations of absorber-layer material and operating temperature. Our aims focused to identify the most optimal thin-film solar cell structure that offers high efficiency and lower toxicity which are desirable for sustainable and eco-friendly energy sources globally. SCAPS-1D, widely used software for modeling and simulating solar cells, has been used and solar cell fundamental performance parameters such as open-circuited voltage (), short-circuited current density (), fill-factor() and efficiency() have been optimized in this study. Based on our simulation results, it was found that CZTS solar cell with Cd<sub>0.4</sub>Zn<sub>0.6</sub>S as buffer-layer offers the most optimal combination of high efficiency and lower toxicity in comparison to other structure investigated in our study. Although the efficiency of Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS are comparable, Cd<sub>0.4</sub>Zn<sub>0.6</sub>S is preferable to use as buffer-layer for its non-toxic property. In addition, evaluation of performance as a function of buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS showed that optimum buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S was in the range from 50 to 150nm while ZnS offered only 50 – 75 nm. Furthermore, the temperature dependence performance parameters evaluation revealed that it is better to operate solar cell at temperature 290K for stable operation with optimum performances. This study would provide valuable insights into design and optimization of nanotechnology-based solar energy technology for minimizing global energy crisis and developing eco-friendly energy sources sustainable and simultaneously.展开更多
Co-ZnO films were prepared on oxidised silicon by magnetron sputtering at room temperature both with and without a ZnO buffer-layer. The Co-ZnO films consisted of Co particles dispersed in a semiconductor matrix. The ...Co-ZnO films were prepared on oxidised silicon by magnetron sputtering at room temperature both with and without a ZnO buffer-layer. The Co-ZnO films consisted of Co particles dispersed in a semiconductor matrix. The combination of a Co-ZnO layer and a ZnO buffer-layer has a higher magnetoresistance than the Co-ZnO layer alone on an insulating Si substrate. The causes of this effect were investigated using X-ray photoelectron spectroscopy, depth profiling using Auger electron spectroscopy and electrical resistance as well as measurements of the change in the saturation magnetisation, the field cooled- and zero field cooled-magnetisation. This work has shown clearly what criteria are needed to optimise the magnetoresistance and how these conditions may be met by adding a buffer-layer thus making granular films based on ZnO more suitable for applications as field sensors.展开更多
The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal con...The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal concept in drifts in clay formation with backfilled bentonite buffer is represented numerically using the CODE BRIGHT developed by the Technical University of Catalonia in Barcelona.The parameters of clay and bentonite used in the simulation are determined by laboratory and in situ experiments.The calculation results are presented to show the hydro-mechanical（HM） processes during the operation phase and the THM processes in the after-closure phase.According to the simulation results,the most probable critical processes for the disposal project have been represented and analyzed.The work also provides an input for additional development regarding the design,assessment and validation of the HLW disposal concept.展开更多
Dynamic spectrum access (DSA) scheme in Cognitive Radio (CR) can solve the current problem of scarce spectrum resource effectively, in which the unlicensed users (i.e. Second Users, SUs) can access the licensed spectr...Dynamic spectrum access (DSA) scheme in Cognitive Radio (CR) can solve the current problem of scarce spectrum resource effectively, in which the unlicensed users (i.e. Second Users, SUs) can access the licensed spectrum in opportunistic ways without interference to the licensed users (i.e. Primary Users, PUs). However, SUs have to vacate the spectrum because of PUs coming, in this case the spectrum switch occurs, and it leads to the increasing of SUs’ delay. In this paper, we proposed a Variable Service Rate (VSR) scheme with the switch buffer as to real-time traffic (such as VoIP, Video), in order to decrease the average switch delay of SUs and improve the other performance. Different from previous studies, the main characteristics of our studying of VSR in this paper as follows: 1) Our study is on the condition of real-time traffic and we establish three-dimension Markov model;2) Using the internal optimization strategy, including switching buffer, optimizing buffer and variable service rate;3) As to the real-time traffic, on the condition of meeting the Quality of Service(QoS) on dropping probability, the average switch delay is decreased as well as improving the other performance. By extensive simulation and numerical analysis, the performance of real-time traffic is improved greatly on the condition of ensuring its dropping probability. The result fully demonstrates the feasibility and effectiveness of the variable service rate scheme.展开更多
文摘This study explored the performances of CZTS-based thin-film solar cell with three novel buffer layer materials ZnS, CdS, and CdZnS, as well as with variation in thickness of buffer and absorber-layer, doping concentrations of absorber-layer material and operating temperature. Our aims focused to identify the most optimal thin-film solar cell structure that offers high efficiency and lower toxicity which are desirable for sustainable and eco-friendly energy sources globally. SCAPS-1D, widely used software for modeling and simulating solar cells, has been used and solar cell fundamental performance parameters such as open-circuited voltage (), short-circuited current density (), fill-factor() and efficiency() have been optimized in this study. Based on our simulation results, it was found that CZTS solar cell with Cd<sub>0.4</sub>Zn<sub>0.6</sub>S as buffer-layer offers the most optimal combination of high efficiency and lower toxicity in comparison to other structure investigated in our study. Although the efficiency of Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS are comparable, Cd<sub>0.4</sub>Zn<sub>0.6</sub>S is preferable to use as buffer-layer for its non-toxic property. In addition, evaluation of performance as a function of buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S, ZnS and CdS showed that optimum buffer-layer thickness for Cd<sub>0.4</sub>Zn<sub>0.6</sub>S was in the range from 50 to 150nm while ZnS offered only 50 – 75 nm. Furthermore, the temperature dependence performance parameters evaluation revealed that it is better to operate solar cell at temperature 290K for stable operation with optimum performances. This study would provide valuable insights into design and optimization of nanotechnology-based solar energy technology for minimizing global energy crisis and developing eco-friendly energy sources sustainable and simultaneously.
文摘Co-ZnO films were prepared on oxidised silicon by magnetron sputtering at room temperature both with and without a ZnO buffer-layer. The Co-ZnO films consisted of Co particles dispersed in a semiconductor matrix. The combination of a Co-ZnO layer and a ZnO buffer-layer has a higher magnetoresistance than the Co-ZnO layer alone on an insulating Si substrate. The causes of this effect were investigated using X-ray photoelectron spectroscopy, depth profiling using Auger electron spectroscopy and electrical resistance as well as measurements of the change in the saturation magnetisation, the field cooled- and zero field cooled-magnetisation. This work has shown clearly what criteria are needed to optimise the magnetoresistance and how these conditions may be met by adding a buffer-layer thus making granular films based on ZnO more suitable for applications as field sensors.
基金financed and supported by the German research institute "Gesellschaft für Anlagen-und Reaktorsicherheit (GRS) mbH"
文摘The main objective of this paper is to investigate and analyse the thermo-hydro-mechanical（THM） coupling phenomena and their influences on the repository safety.In this paper,the high-level waste（HLW） disposal concept in drifts in clay formation with backfilled bentonite buffer is represented numerically using the CODE BRIGHT developed by the Technical University of Catalonia in Barcelona.The parameters of clay and bentonite used in the simulation are determined by laboratory and in situ experiments.The calculation results are presented to show the hydro-mechanical（HM） processes during the operation phase and the THM processes in the after-closure phase.According to the simulation results,the most probable critical processes for the disposal project have been represented and analyzed.The work also provides an input for additional development regarding the design,assessment and validation of the HLW disposal concept.
文摘Dynamic spectrum access (DSA) scheme in Cognitive Radio (CR) can solve the current problem of scarce spectrum resource effectively, in which the unlicensed users (i.e. Second Users, SUs) can access the licensed spectrum in opportunistic ways without interference to the licensed users (i.e. Primary Users, PUs). However, SUs have to vacate the spectrum because of PUs coming, in this case the spectrum switch occurs, and it leads to the increasing of SUs’ delay. In this paper, we proposed a Variable Service Rate (VSR) scheme with the switch buffer as to real-time traffic (such as VoIP, Video), in order to decrease the average switch delay of SUs and improve the other performance. Different from previous studies, the main characteristics of our studying of VSR in this paper as follows: 1) Our study is on the condition of real-time traffic and we establish three-dimension Markov model;2) Using the internal optimization strategy, including switching buffer, optimizing buffer and variable service rate;3) As to the real-time traffic, on the condition of meeting the Quality of Service(QoS) on dropping probability, the average switch delay is decreased as well as improving the other performance. By extensive simulation and numerical analysis, the performance of real-time traffic is improved greatly on the condition of ensuring its dropping probability. The result fully demonstrates the feasibility and effectiveness of the variable service rate scheme.
