Here we report a generalizable strategy for the synthesis of rare-earth metal–organic frameworks(RE-MOFs)with 12-connected RE_(9)clusters and shp topology.A total of 26 isostructural RE-MOFs(JNU-205-RE and JNU-206-RE...Here we report a generalizable strategy for the synthesis of rare-earth metal–organic frameworks(RE-MOFs)with 12-connected RE_(9)clusters and shp topology.A total of 26 isostructural RE-MOFs(JNU-205-RE and JNU-206-RE)were obtained from two X-shaped tetracarboxylate linkers,4,4′,4′′,4′′′-benzene-2,3,5,6-tetrayl-tetrabenzoate(BTEB)and 4,4′,4′′,4′′′-pyrazine-2,3,5,6-tetrayl-tetrabenzoate(BTTB).展开更多
基金financially supported by the National Natural Science Foundation of China(nos 21731002,21975104,22101099 and 22150004)the Major Program of Guangdong Basic and Applied Research(2019B030302009)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(no.2020A1515011005)the Special Fund Project for Science and Technology of Guangdong(STKJ2021172).We thank the high performance public computing service platform of Jinan University for providing computing resources.
文摘Here we report a generalizable strategy for the synthesis of rare-earth metal–organic frameworks(RE-MOFs)with 12-connected RE_(9)clusters and shp topology.A total of 26 isostructural RE-MOFs(JNU-205-RE and JNU-206-RE)were obtained from two X-shaped tetracarboxylate linkers,4,4′,4′′,4′′′-benzene-2,3,5,6-tetrayl-tetrabenzoate(BTEB)and 4,4′,4′′,4′′′-pyrazine-2,3,5,6-tetrayl-tetrabenzoate(BTTB).
