Recently,single-crystal-to-single-crystal conversion has been a hot topic in the field of metal-organic framework(MOF)materials,which could improve the stability and properties due to structural changes.A new Tb^(Ⅲ)-...Recently,single-crystal-to-single-crystal conversion has been a hot topic in the field of metal-organic framework(MOF)materials,which could improve the stability and properties due to structural changes.A new Tb^(Ⅲ)-based MOF([Tb_(4)(BTDI)_(3)(DMF)_(4)]_(n),JXUST-12)has been designed and synthesized by the incorporation of Tb^(Ⅲ)ions and H4BTDI ligands(5,5’-(benzo[c][1,2,5]thiadiazole-4,7-diyl)diisophthalic acid)featuring a fluorescent unit.展开更多
基金supported by the National Natural Science Foundation of China(22061019,21861018 and 22161019)the Natural Science Foundation of Jiangxi Province of China(20202ACBL213001 and 20182BCB22010)+2 种基金Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry(20212BCD42018)the Youth Jinggang Scholars Program in Jiangxi Province(QNJG2019053)the Two Thousand Talents Program in Jiangxi Province(jxsq2019201068).
文摘Recently,single-crystal-to-single-crystal conversion has been a hot topic in the field of metal-organic framework(MOF)materials,which could improve the stability and properties due to structural changes.A new Tb^(Ⅲ)-based MOF([Tb_(4)(BTDI)_(3)(DMF)_(4)]_(n),JXUST-12)has been designed and synthesized by the incorporation of Tb^(Ⅲ)ions and H4BTDI ligands(5,5’-(benzo[c][1,2,5]thiadiazole-4,7-diyl)diisophthalic acid)featuring a fluorescent unit.
