A novel 2-D sheet inorganic-organic hybrid cadmium polymer, [CdBr2（bpdo）]n （bpdo = N,N＇-O,O-4,4’-bipyridine） has been hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal X-r...A novel 2-D sheet inorganic-organic hybrid cadmium polymer, [CdBr2（bpdo）]n （bpdo = N,N＇-O,O-4,4’-bipyridine） has been hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal crystallizes in monoclinic, space group C2/c, with a = 16.336（3）, b = 3,9904（5）, c = 18,479（3） ]A, β = 91.640（6）°, Mr = 460.40, V= 1204.1（3）A3, Z = 4, Dc = 2,540 g/cm^3, p = 8.439 mm^-1, F（000） = 864, R = 0.0314 and wR = 0.0733 for 1069 observed reflections （Ⅰ 〉 2σ（Ⅰ））. X-ray diffraction reveals that the title compound consists of the 2-D inorganic-organic hybrid sheet constructed from [CdBr2]n chains and bpdo bridges in the packing motif of …ABAB… The title compound exhibits intense blue photoltmainescence in the solid state at room temperature.展开更多
A new three-dimensional porous lanthanide coordination polymer{[Dy(L)(μ2-bpdo)0.5(μ_(4)-bpdo)0.5(CH_(3)OH)]·ClO_(4)·3CH_(3)OH}_(n)(2)featuring slow magnetic relaxation has been successfully assembled by re...A new three-dimensional porous lanthanide coordination polymer{[Dy(L)(μ2-bpdo)0.5(μ_(4)-bpdo)0.5(CH_(3)OH)]·ClO_(4)·3CH_(3)OH}_(n)(2)featuring slow magnetic relaxation has been successfully assembled by reacting a superparamagnetic chain complex{[Dy(HL)(H_(2)O)_(2)(CH_(3)OH)_(2)]·2Cl·CH_(3)OH}_(n)(1)with an organic bridging ligand,namely,_(4),_(4)’-bipyridine-N,N’-dioxide(bpdo)(H2L=N’-(2-hydroxybenzylidene)-picolinohydrazide).展开更多
A novel three-dimensional porous dysprosium coordination polymer{[Dy_(2)L_(2)(bpdo)_(2)(H_(2)O)(CH_(3)OH)]·2ClO4·2CH_(3)CN}_(n)(1)has been successfully assembled by combining a superparamagnetic building blo...A novel three-dimensional porous dysprosium coordination polymer{[Dy_(2)L_(2)(bpdo)_(2)(H_(2)O)(CH_(3)OH)]·2ClO4·2CH_(3)CN}_(n)(1)has been successfully assembled by combining a superparamagnetic building block of[DyLCl(CH_(3)OH)]_(2)with the organic ligand 4,4’-bipyridine-N,N’-dioxide(bpdo)(H_(2)L=N’-(_(2)-hydroxybenzylidene)picolinohydrazide).展开更多
基金the NNSFC (No. 20173063)the State Key Basic Research and Development Plan of China (001CB 108906)the NSF of Fujian Province (E0020001)
文摘A novel 2-D sheet inorganic-organic hybrid cadmium polymer, [CdBr2（bpdo）]n （bpdo = N,N＇-O,O-4,4’-bipyridine） has been hydrothermally synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal crystallizes in monoclinic, space group C2/c, with a = 16.336（3）, b = 3,9904（5）, c = 18,479（3） ]A, β = 91.640（6）°, Mr = 460.40, V= 1204.1（3）A3, Z = 4, Dc = 2,540 g/cm^3, p = 8.439 mm^-1, F（000） = 864, R = 0.0314 and wR = 0.0733 for 1069 observed reflections （Ⅰ 〉 2σ（Ⅰ））. X-ray diffraction reveals that the title compound consists of the 2-D inorganic-organic hybrid sheet constructed from [CdBr2]n chains and bpdo bridges in the packing motif of …ABAB… The title compound exhibits intense blue photoltmainescence in the solid state at room temperature.
基金supported by the National Natural Science Foundation of China(No.21671024)the National Key Basic Research Program of China(2013CB933402).We thank Prof.Zhenqiang Wang of the University of South Dakota for helpful comments.
文摘A new three-dimensional porous lanthanide coordination polymer{[Dy(L)(μ2-bpdo)0.5(μ_(4)-bpdo)0.5(CH_(3)OH)]·ClO_(4)·3CH_(3)OH}_(n)(2)featuring slow magnetic relaxation has been successfully assembled by reacting a superparamagnetic chain complex{[Dy(HL)(H_(2)O)_(2)(CH_(3)OH)_(2)]·2Cl·CH_(3)OH}_(n)(1)with an organic bridging ligand,namely,_(4),_(4)’-bipyridine-N,N’-dioxide(bpdo)(H2L=N’-(2-hydroxybenzylidene)-picolinohydrazide).
基金supported by the National Natural Science Foundation of China(No 21671024)National Key Basic Research Program of China(2013CB933402).
文摘A novel three-dimensional porous dysprosium coordination polymer{[Dy_(2)L_(2)(bpdo)_(2)(H_(2)O)(CH_(3)OH)]·2ClO4·2CH_(3)CN}_(n)(1)has been successfully assembled by combining a superparamagnetic building block of[DyLCl(CH_(3)OH)]_(2)with the organic ligand 4,4’-bipyridine-N,N’-dioxide(bpdo)(H_(2)L=N’-(_(2)-hydroxybenzylidene)picolinohydrazide).
