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MODELING OF A MICROPOLAR THIN FILM FLOW WITH RAPIDLY VARYING THICKNESS AND NON-STANDARD BOUNDARY CONDITIONS
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作者 María ANGUIANO Francisco Javier SUÁREZ-GRAU 《Acta Mathematica Scientia》 2026年第1期209-242,共34页
In this paper,we study the asymptotic behavior of the micropolar fluid flow through a thin domain,assuming zero Dirichlet boundary condition on the top boundary,which is rapidly oscillating,and non-standard boundary c... In this paper,we study the asymptotic behavior of the micropolar fluid flow through a thin domain,assuming zero Dirichlet boundary condition on the top boundary,which is rapidly oscillating,and non-standard boundary conditions on the flat bottom.Assuming“Reynolds roughness regime”,in which the thickness of the domain is very small compared to the wavelength of the roughness(i.e.a very slight roughness),we rigorously derive a generalized Reynolds equation for pressure,clearly showing the roughness-induced effects.Moreover,we give expressions for the average velocity and microrotation. 展开更多
关键词 micropolar fluid thin-film flow rapidly oscillating boundary nonzero boundary conditions HOMOGENIZATION
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Mechanisms of Pore-Grain Boundary Interactions Influencing Nanoindentation Behavior in Pure Nickel: A Molecular Dynamics Study
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作者 Chen-Xi Hu Wu-Gui Jiang +1 位作者 Jin Wang Tian-Yu He 《Computers, Materials & Continua》 2026年第1期368-388,共21页
THE mechanical response and deformation mechanisms of pure nickel under nanoindentation were systematically investigated using molecular dynamics(MD)simulations,with a particular focus on the novel interplay between c... THE mechanical response and deformation mechanisms of pure nickel under nanoindentation were systematically investigated using molecular dynamics(MD)simulations,with a particular focus on the novel interplay between crystallographic orientation,grain boundary(GB)proximity,and pore characteristics(size/location).This study compares single-crystal nickel models along[100],[110],and[111]orientations with equiaxed polycrystalline models containing 0,1,and 2.5 nm pores in surface and subsurface configurations.Our results reveal that crystallographic anisotropy manifests as a 24.4%higher elastic modulus and 22.2%greater hardness in[111]-oriented single crystals compared to[100].Pore-GB synergistic effects are found to dominate the deformation behavior:2.5 nm subsurface pores reduce hardness by 25.2%through stress concentration and dislocation annihilation at GBs,whereas surface pores enable mechanical recovery via accelerated dislocation generation post-collapse.Additionally,size-dependent deformation regimes were identified,with 1 nm pores inducing negligible perturbation due to rapid atomic rearrangement,in contrast with persistent softening in 2.5 nm pores.These findings establish atomic-scale design principles for defect engineering in nickel-based aerospace components,demonstrating how crystallographic orientation,pore configuration,and GB interactions collectively govern nanoindentation behavior. 展开更多
关键词 Pure nickel NANOINDENTATION molecular dynamics PORE grain boundary
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Typhoon Kompasu(2118)simulation with planetary boundary layer and cloud physics parameterization improvements
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作者 Xiaowei Tan Zhiqiu Gao Yubin Li 《Atmospheric and Oceanic Science Letters》 2026年第1期41-46,共6页
This study introduces a new ocean surface friction velocity scheme and a modified Thompson cloud microphysics parameterization scheme into the CMA-TYM model.The impact of these two parameterization schemes on the pred... This study introduces a new ocean surface friction velocity scheme and a modified Thompson cloud microphysics parameterization scheme into the CMA-TYM model.The impact of these two parameterization schemes on the prediction of the movement track and intensity of Typhoon Kompasu in 2021 is examined.Additionally,the possible reasons for their effects on tropical cyclone(TC)intensity prediction are analyzed.Statistical results show that both parameterization schemes improve the predictions of Typhoon Kompasu’s track and intensity.The influence on track prediction becomes evident after 60 h of model integration,while the significant positive impact on intensity prediction is observed after 66 h.Further analysis reveals that these two schemes affect the timing and magnitude of extreme TC intensity values by influencing the evolution of the TC’s warm-core structure. 展开更多
关键词 Tropical cyclone Numerical simulation Planetary boundary layer parameterization SCHEME Cloud physics scheme
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A Boundary Element Reconstruction (BER) Model for Moving Morphable Component Topology Optimization
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作者 Zhao Li Hongyu Xu +2 位作者 Shuai Zhang Jintao Cui Xiaofeng Liu 《Computers, Materials & Continua》 2026年第1期2213-2230,共18页
The moving morphable component(MMC)topology optimization method,as a typical explicit topology optimization method,has been widely concerned.In the MMC topology optimization framework,the surrogate material model is m... The moving morphable component(MMC)topology optimization method,as a typical explicit topology optimization method,has been widely concerned.In the MMC topology optimization framework,the surrogate material model is mainly used for finite element analysis at present,and the effectiveness of the surrogate material model has been fully confirmed.However,there are some accuracy problems when dealing with boundary elements using the surrogate material model,which will affect the topology optimization results.In this study,a boundary element reconstruction(BER)model is proposed based on the surrogate material model under the MMC topology optimization framework to improve the accuracy of topology optimization.The proposed BER model can reconstruct the boundary elements by refining the local meshes and obtaining new nodes in boundary elements.Then the density of boundary elements is recalculated using the new node information,which is more accurate than the original model.Based on the new density of boundary elements,the material properties and volume information of the boundary elements are updated.Compared with other finite element analysis methods,the BER model is simple and feasible and can improve computational accuracy.Finally,the effectiveness and superiority of the proposed method are verified by comparing it with the optimization results of the original surrogate material model through several numerical examples. 展开更多
关键词 Topology optimization MMC method boundary element reconstruction surrogate material model local mesh
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A survey of panel aeroelasticity in shock-dominated flow:Perspectives from fluid-structure interactions and shock wave-boundary layer interactions
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作者 Aiming SHI Yiwen HE 《Chinese Journal of Aeronautics》 2026年第1期210-229,共20页
As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises s... As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles. 展开更多
关键词 Aeroelasticity Fluid structure interaction Modal decomposition Shock boundary layer interactions Shock waves
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Existence,Uniqueness and Stability of Bounded Solutions for Minkowski-Curvature Problems with Asymptotic Boundary Conditions
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作者 Tianlan CHEN Xuying TANG 《Journal of Mathematical Research with Applications》 2026年第1期57-70,共14页
In this article,we show the existence,uniqueness and stability of bounded solutions to the following quasilinear problems with mean curvature operator(φ'(x′(t)))′=f(t,x),t≥t_(0),lim_(t→∞)x(t)=ψ_(0),lim_(t→... In this article,we show the existence,uniqueness and stability of bounded solutions to the following quasilinear problems with mean curvature operator(φ'(x′(t)))′=f(t,x),t≥t_(0),lim_(t→∞)x(t)=ψ_(0),lim_(t→∞)x′(t)e^(t)=0,where t_(0) and ψ_(0) are real constants,φ(s)=s/√1−s^(2),s∈R with s∈(−1,1),f:[t_(0),∞)×R→R satisfies the Lipschitz or Osgood-type conditions. 展开更多
关键词 mean curvature operator UNIQUENESS asymptotic boundary conditions bounded solution
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Topological Corner States due to Boundary Defects
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作者 Yiqi Zhang Yuwei Hu +1 位作者 Yongdong Li Ce Shang 《Chinese Physics Letters》 2026年第1期44-48,共5页
In conventional higher-order topological insulators(HOTIs),the emergence of topological states can be explained by using the nonzero bulk polarization index.However,corner states emerge in HOTIs with incomplete bounda... In conventional higher-order topological insulators(HOTIs),the emergence of topological states can be explained by using the nonzero bulk polarization index.However,corner states emerge in HOTIs with incomplete boundary unit cells(i.e.,boundary defects)even though the bulk polarization is zero,which challenges the conventional understanding of HOTIs.Here,based on a Kekul´e-distorted honeycomb lattice with incomplete unit cells,we reveal that incomplete unit cells exhibit fractional charges through the analysis of Wannier centers by developing a compensation method and creating the concept of Wannier center domain(WCD)which is the smallest region that one Wannier center occupies.This method compensates for the missing parts of these boundary incomplete unit cells with additional WCDs to make them complete.The compensated WCDs automatically carry the corresponding charge,and this charge together with that of the incomplete unit cell constitutes the total charge of the complete unit cell after compensation.We conclude that the emergence of corner states is attributed to the filling anomaly,which is a fundamental mechanism.Our results refresh the understanding of HOTIs,especially those with structural discontinuities,and provide a novel design for topological states which have application value in producing optical functional devices. 展开更多
关键词 unit cellswe higher order topological insulators topological corner states boundary unit cells ieboundary incomplete unit cells bulk polarization index fractional charges emergence topological states
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Collaborative Area Coverage Method for UAV Swarm Under Complex Boundary Conditions:A Region Partitioning Approach
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作者 Jiabin Yu Haocun Wang +4 位作者 Bingyi Wang Yang Lu Xin Zhang Qian Sun Zhiyao Zhao 《Journal of Bionic Engineering》 2026年第1期524-548,共25页
Unmanned aerial vehicles(UAVs)are widely utilized in area coverage tasks due to their flexibility and efficiency in geo-graphic information acquisition.However,complex boundary conditions in actual water area maps oft... Unmanned aerial vehicles(UAVs)are widely utilized in area coverage tasks due to their flexibility and efficiency in geo-graphic information acquisition.However,complex boundary conditions in actual water area maps often reduce coverage efficiency.To address this issue,this paper proposes a map preprocessing algorithm that linearizes boundary lines and processes concave areas into concave polygons,followed by gridding the map.Additionally,a collaborative area coverage method for UAV swarms is introduced based on region partitioning,which considers the comprehensive cost of energy consumption and time.An improved Hungarian algorithm is utilized for region partitioning,and a Dubins-A*-based plow-ing area full coverage path planning method is proposed to achieve path smoothing and collaborative coverage of each partition.Two sets of simulation experiments are conducted.The first experiment verifies the effectiveness of the map preprocessing algorithm,and the second compares the proposed collaborative area coverage algorithm with other methods,demonstrating its performance advantages. 展开更多
关键词 Complex boundaries UAV swarm Collaborative area coverage Map preprocessing Region partitioning
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BIOLOGICAL INVASION PROBLEM WITH FREE BOUNDARY NONLOCAL DIFFUSION EQUATION 被引量:2
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作者 HE Yu-rong ZHANG Ya-rong 《数学杂志》 2025年第1期48-56,共9页
In order to better describe the phenomenon of biological invasion,this paper introduces a free boundary model of biological invasion.Firstly,the right free boundary is added to the equation with logistic terms.Secondl... In order to better describe the phenomenon of biological invasion,this paper introduces a free boundary model of biological invasion.Firstly,the right free boundary is added to the equation with logistic terms.Secondly,the existence and uniqueness of local solutions are proved by the Sobolev embedding theorem and the comparison principle.Finally,according to the relevant research data and contents of red fire ants,the diffusion area and nest number of red fire ants were simulated without external disturbance.This paper mainly simulates the early diffusion process of red fire ants.In the early diffusion stage,red fire ants grow slowly and then spread over a large area after reaching a certain number. 展开更多
关键词 Free boundary biological invasion differential equation
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Elevated temperature magnetic microstructures and demagnetization mechanism for grain boundary diffused dual-main-phase(Nd,Ce)-Fe-B magnets 被引量:2
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作者 Yifei Xiao Lele Zhang +7 位作者 Wei Yang Tao Liu Qisong Sun Xiaolong Song Yikun Fang Anhua Li Minggang Zhu Wei Li 《Journal of Materials Science & Technology》 2025年第4期10-23,共14页
The combination of dual-main-phase(DMP)(Nd,Ce)-Fe-B magnets and grain boundary diffusion process(GBDP)is currently a research topic for obtaining high-cost performance materials in rare earth permanent magnet fields.T... The combination of dual-main-phase(DMP)(Nd,Ce)-Fe-B magnets and grain boundary diffusion process(GBDP)is currently a research topic for obtaining high-cost performance materials in rare earth permanent magnet fields.The novel structural features of GBDP(Nd,Ce)-Fe-B magnets give a version of different domain reversal processes from those of non-diffused magnets.In this work,the in-situ magnetic domain evolution of the DMP magnets was observed at elevated temperatures,and the temperature demagnetization and coercivity mechanism of the GBDP dual-main-phase(Nd,Ce)-Fe-B magnets are discussed.The results show that the shell composition of different types of grains in DMP magnets is similar,while the magnetic microstructure results indicate the Ce-rich grains tend to demagnetize first.Dy-rich shell with a high anisotropic field caused by GBDP leads to an increase in the nucleation field,which enhances the coercivity.It is found that much more grains exhibit single domain characteristics in the remanent state for GBDP dual-main-phase(Nd,Ce)-Fe-B magnets.In addition,the grains that undergo demagnetization first are Ce-rich or Nd-rich grains,which is different from that of non-diffused magnets.These results were not found in previous studies but can be intuitively characterized from the perspective of magnetic domains in this work,providing a new perspective and understanding of the performance improvement of magnetic materials. 展开更多
关键词 Magnetic microstructures Dual-main-phase (Nd Ce)-Fe-B Diffused Dy Rare earth permanent magnet materials Grain boundary diffusion process(GBDP)
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Utility and influence mechanism of densification modulation on grain boundary diffusion in NdFeB magnets 被引量:1
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作者 San'gen Luo Munan Yang +4 位作者 Shuwei Zhong Sajjad Ur Rehman Jiajie Li Xiaoqiang Yu Bin Yang 《Journal of Rare Earths》 2025年第3期569-577,I0006,共10页
Grain boundary diffusion technology is pivotal in the preparation of high-performance NdFeB magnets.This study investigates the factors that affect the efficiency of grain boundary diffusion,starting from the properti... Grain boundary diffusion technology is pivotal in the preparation of high-performance NdFeB magnets.This study investigates the factors that affect the efficiency of grain boundary diffusion,starting from the properties of the diffusion matrix.Through the adjustment of the sintering process,we effectively prepared magnets with varied densities that serve as the matrix for grain boundary diffusion with TbH,diffusion.The mobility characteristics of the Nd-rich phase during the densification stage are leveraged to ensure a more extensive distribution of heavy rare earth elements within the magnets.According to the experimental results,the increase in coercivity of low-density magnets after diffusion is significantly greater than that of relatively high-density magnets.The coercivity values measured are 805.32 kA/m for low-density magnets and 470.3 kA/m for high-density magnets.Additionally,grain boundary diffusion notably enhances the density of initial low-density magnets,addressing the issue of low density during the sintering stage.Before the diffusion treatment,the Nd-rich phases primarily concentrate at the triangular grain boundaries,resulting in an increased number of cavity defects in the magnets.These cavity defects contain atoms in a higher energy state,making them more prone to transition.Consequently,the diffusion activation energy at the void defects is lower than the intracrystalline diffusion activation energy,accelerating atom diffusion.The presence of larger cavities also provides more space for atom migration,thereby promoting the diffusion process.After the diffusion treatment,the proportion of bulk Nd-rich phases significantly decreases,and they infiltrate between the grains to fill the cavity defects,forming continuous fine grain boundaries.Based on these observations,the study aims to explore how to utilize this information to develop an efficient technique for grain boundary diffusion. 展开更多
关键词 NdFeB magnets DENSITY Grain boundary diffusion Defect utility Rare earths
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Formation and solute segregation for an asymmetric tilt boundary on{1012}twin boundaries 被引量:1
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作者 Qiang Yang Shuhui Lv +3 位作者 Peng Chen Zefeng Xie Shuo Zhou Xin Qiu 《Journal of Magnesium and Alloys》 2025年第2期583-591,共9页
Asymmetric tilt boundaries on conventional twin boundaries(TBs)are significant for understanding the role of twins on coordinating plastic deformation in many metallic alloys.However,the formation modes of many asymme... Asymmetric tilt boundaries on conventional twin boundaries(TBs)are significant for understanding the role of twins on coordinating plastic deformation in many metallic alloys.However,the formation modes of many asymmetric tilt boundaries are hard to be accounted for based on traditional theoretical models,and the corresponding solute segregation is complex.Herein,atomic structures of a specific asymmetric boundary on{1012}TBs were reveled using aberration-corrected high-angle annular dark-field scanning transmission electron microscopy(HAADF-STEM),molecular dynamics(MD)and density functional theory(DFT)simulations.Reaction between<a60>M dislocations and the{1012}TB can generate a~61°/25°asymmetric tilt boundary.The segregation of Gd and Zn atoms is closely related to the aggregateddislocations and the interfacial interstices of the asymmetric tilt boundary,which is energetically favorable in reducing the total system energy. 展开更多
关键词 Magnesium alloy Transmission electron microscopy Twin boundary DISLOCATION SEGREGATION
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Study of an adaptive bump control mechanism for shock wave/boundary layer interactions in supersonic flows 被引量:1
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作者 Shan-Shan Tian Liang Jin +2 位作者 Wei Huang Yang Shen Kai An 《Theoretical & Applied Mechanics Letters》 2025年第4期319-330,共12页
The stability of supersonic inlets faces challenges due to various changes in flight conditions,and flow control methods that address shock wave/boundary layer interactions under only one set of conditions cannot meet... The stability of supersonic inlets faces challenges due to various changes in flight conditions,and flow control methods that address shock wave/boundary layer interactions under only one set of conditions cannot meet developmental requirements.This paper proposes an adaptive bump control scheme and employs dynamic mesh technology for numerical simulation to investigate the unsteady control effects of adaptive bumps.The obtained results indicate that the use of moving bumps to control shock wave/boundary layer interactions is feasible.The adaptive control effects of five different bump speeds are evaluated.Within the range of bump speeds studied,the analysis of the flow field structure reveals the patterns of change in the separation zone area during the control process,as well as the relationship between the bump motion speed and the control effect on the separation zone.It is concluded that the moving bump endows the boundary layer with additional energy. 展开更多
关键词 Shock wave/boundary layer interaction ADAPTIVE Flow control BUMP Supersonic flow
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Space Division and WGAN-GP Based Fast Generation Method of Practical Dynamic Security Region Boundary 被引量:1
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作者 Yanli Liu Ruipeng Jia 《Engineering》 2025年第8期75-85,共11页
Fast and accurate transient stability analysis is crucial to power system operation.With high penetration level of wind power resources,practical dynamic security region(PDSR)with hyper plane expression has outstandin... Fast and accurate transient stability analysis is crucial to power system operation.With high penetration level of wind power resources,practical dynamic security region(PDSR)with hyper plane expression has outstanding advantages in situational awareness and series of optimization problems.The precondition of obtaining accurate PDSR boundary is to locate sufficient points around the boundary(critical points).Therefore,this paper proposes a space division and Wasserstein generative adversarial network with gra-dient penalty(WGAN-GP)based fast generation method of PDSR boundary.First,the typical differential topological characterizations of dynamic security region(DSR)provide strong theoretical foundation that the interior of DSR is hole-free and the boundaries of DSR are tight and knot-free.Then,the space division method is proposed to calculate critical operation area where the PDSR boundary is located,tremen-dously compressing the search space to locate critical points and improving the confidence level of boundary fitting result.Furthermore,the WGAN-GP model is utilized to fast obtain large number of criti-cal points based on learning the data distribution of the small training set aforementioned.Finally,the PDSR boundary with hyperplanes is fitted by the least square method.The case study is tested on the Institute of Electrical and Electronics Engineers(IEEE)39-bus system and the results verify the accuracy and efficiency of the proposed method. 展开更多
关键词 Practical dynamic security region boundary WGAN-GP Space division Critical points Data-model hybrid driven
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Flow-Induced Transverse Vibration of Three Equal-Diameter Cylinders in an Equilateral Triangle Using the Immersed Boundary–Lattice Boltzmann Flux Solver 被引量:1
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作者 Xiaodi Wu Jiaqi Li +1 位作者 Shuo Huang Ruosi Zha 《哈尔滨工程大学学报(英文版)》 2025年第2期437-448,共12页
To explore the relationship between dynamic characteristics and wake patterns,numerical simulations were conducted on three equal-diameter cylinders arranged in an equilateral triangle.The simulations varied reduced v... To explore the relationship between dynamic characteristics and wake patterns,numerical simulations were conducted on three equal-diameter cylinders arranged in an equilateral triangle.The simulations varied reduced velocities and gap spacing to observe flow-induced vibrations(FIVs).The immersed boundary–lattice Boltzmann flux solver(IB–LBFS)was applied as a numerical solution method,allowing for straightforward application on a simple Cartesian mesh.The accuracy and rationality of this method have been verified through comparisons with previous numerical results,including studies on flow past three stationary circular cylinders arranged in a similar pattern and vortex-induced vibrations of a single cylinder across different reduced velocities.When examining the FIVs of three cylinders,numerical simulations were carried out across a range of reduced velocities(3.0≤Ur≤13.0)and gap spacing(L=3D,4D,and 5D).The observed vibration response included several regimes:the desynchronization regime,the initial branch,and the lower branch.Notably,the transverse amplitude peaked,and a double vortex street formed in the wake when the reduced velocity reached the lower branch.This arrangement of three cylinders proved advantageous for energy capture as the upstream cylinder’s vibration response mirrored that of an isolated cylinder,while the response of each downstream cylinder was significantly enhanced.Compared to a single cylinder,the vibration and flow characteristics of this system are markedly more complex.The maximum transverse amplitudes of the downstream cylinders are nearly identical and exceed those observed in a single-cylinder set-up.Depending on the gap spacing,the flow pattern varied:it was in-phase for L=3D,antiphase for L=4D,and exhibited vortex shedding for L=5D.The wake configuration mainly featured double vortex streets for L=3D and evolved into two pairs of double vortex streets for L=5D.Consequently,it well illustrates the coupling mechanism that dynamics characteristics and wake vortex change with gap spacing and reduced velocities. 展开更多
关键词 Flow-induced vibration Equal-diameter cylinders Lattice boltzmann flux solver Immersed boundary method
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Gas migration at the granite-bentonite interface under semirigid boundary conditions in the context of high-level radioactive waste disposal 被引量:1
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作者 Jiangfeng Liu Zhipeng Wang +3 位作者 Jingna Guo Andrey Jivkov Majid Sedighi Jianfu Shao 《Deep Underground Science and Engineering》 2025年第3期422-436,共15页
The corrosion of waste canisters in the deep geological disposal facilities(GDFs)for high-level radioactive waste(HLRW)can generate gas,which escapes from the engineered barrier system through the interfaces between t... The corrosion of waste canisters in the deep geological disposal facilities(GDFs)for high-level radioactive waste(HLRW)can generate gas,which escapes from the engineered barrier system through the interfaces between the bentonite buffer blocks and the host rock and those between the bentonite blocks.In this study,a series of water infiltration and gas breakthrough experiments were conducted on granite and on granite-bentonite specimens with smooth and grooved interfaces.On this basis,this study presents new insights and a quantitative assessment of the impact of the interface between clay and host rock on gas transport.As the results show,the water permeability values from water infiltration tests on granite and granite-bentonite samples(10−19-10−20m^(2))are found to be slightly higher than that of bentonite.The gas permeability of the mock-up samples with smooth interfaces is one order of magnitude larger than that of the mock-up with grooved interfaces.The gas results of breakthrough pressures for the granite and the granite-bentonite mock-up samples are significantly lower than that of bentonite.The results highlight the potential existence of preferential gas migration channels between the rock and bentonite buffer that require further considerations in safety assessment. 展开更多
关键词 gas migration GMZ granite–bentonite interface low-permeability porous medium semirigid boundary
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Microstructure,microchemistry,and micro-magnetism of dysprosium grain boundary diffused(Nd,Ce)-Fe-B magnets 被引量:1
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作者 Yifei Xiao Lele Zhang +6 位作者 Tao Liu Qisong Sun Xiaolong Song Yikun Fang Anhua Li Minggang Zhu Wei Li 《Journal of Rare Earths》 2025年第3期556-568,I0005,共14页
The microstructure of(Nd,Ce)-Fe-B sintered magnets with different diffusion depths was characterized by a magnetic force microscope,and the relationship between the magnetic properties and the local structure of grain... The microstructure of(Nd,Ce)-Fe-B sintered magnets with different diffusion depths was characterized by a magnetic force microscope,and the relationship between the magnetic properties and the local structure of grain boundary diffused magnets is discussed.The domains perpendicular to the c-axis(easy magnetization direction)show a typical maze-like pattern,while those parallel to the c-axis show the characte ristics of plate domains.The significant gradient change is shown in the concentration of Dy with the direction of diffusion from the surface to the interior.Dy diffuses along grain boundaries and(Dy,Nd)_(2)Fe_(14)B layer with a high anisotropy field formed around the grains.Through in-situ electron probe micro-analysis/magnetic force microscopy(EPMA/MFM),it is found that the average domain width decreases,and the proportion of single domain grains increases as diffusion depth increases.This is caused by both the change of concentration and distribution of Dy.The grain boundary diffusion process changes the microstructure and microchemistry inside the magnet,and these local magnetism differences can be reflected by the configuration of the magnetic domain structure. 展开更多
关键词 Magnetic microstructures (Nd Ce)-Fe-B Rare earths Magnetic force microscope Grain boundary diffusion process(GBDP) In-situ
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Promoting homogeneous tungsten doping in LiNiO_(2) through a grain boundary phase induced by excessive lithium 被引量:1
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作者 Junjie Wang Yucen Yan +14 位作者 Zilan Zhao Jiayi Li Gui Luo Duo Deng Wenjie Peng Mingxia Dong Zhixing Wang Guochun Yan Huajun Guo Hui Duan Lingjun Li Shihao Feng Xing Ou Junchao Zheng Jiexi Wang 《Advanced Powder Materials》 2025年第1期1-9,共9页
LiNiO_(2)(LNO)is one of the most promising cathode materials for lithium-ion batteries.Tungsten element in enhancing the stability of LNO has been researched extensively.However,the understanding of the specific dopin... LiNiO_(2)(LNO)is one of the most promising cathode materials for lithium-ion batteries.Tungsten element in enhancing the stability of LNO has been researched extensively.However,the understanding of the specific doping process and existing form of W are still not perfect.This study proposes a lithium-induced grain boundary phase W doping mechanism.The results demonstrate that the introduced W atomsfirst react with the lithium source to generate a Li–W–O phase at the grain boundary of primary particles.With the increase of lithium ratio,W atoms gradually diffuse from the grain boundary phase to the interior layered structure to achieve W doping.The feasibility of grain boundary phase doping is verified byfirst principles calculation.Furthermore,it is found that the Li2WO4 grain boundary phase is an excellent lithium ion conductor,which can protect the cathode surface and improve the rate performance.The doped W can alleviate the harmful H2↔H3 phase transition,thereby inhibiting the generation of microcracks,and improving the electrochemical performance.Consequently,the 0.3 wt%W-doped sample provides a significant improved capacity retention of 88.5%compared with the pristine LNO(80.7%)after 100 cycles at 2.8–4.3 V under 1C. 展开更多
关键词 Lithium ion battery LiNiO_(2) Tungsten doping Grain boundary phase H2↔H3 phase transition
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Novel mechanism of the grain boundary diffusion process with Tb based on the discovery of TbFe_(2) phase 被引量:1
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作者 Wendi Zhang Zilong Wang +5 位作者 Xiaojun Sun Weibin Cui Haijun Peng Wenlong Yan Yang Luo Dunbo Yu 《Journal of Materials Science & Technology》 2025年第11期120-129,共10页
The grain boundary diffusion process(GBDP)has proven to be an effective method for enhancing the coercivity of sintered Nd-Fe-B magnets.However,the limited diffusion depth and thicker shell struc-ture have impeded the... The grain boundary diffusion process(GBDP)has proven to be an effective method for enhancing the coercivity of sintered Nd-Fe-B magnets.However,the limited diffusion depth and thicker shell struc-ture have impeded the further development of magnetic properties.Currently,the primary debates re-garding the mechanism of GBDP with Tb revolve around the dissolution-solidification mechanism and the atomic substitution mechanism.To clarify this mechanism,the microstructure evolution of sintered Nd-Fe-B magnets during the heating process of GBDP has been systematically studied by quenching at different tem peratures.In this study,it was found that the formation of TbFe_(2) phase is related to the dis-solution of _(2)Fe_(14)B grains during GBDP with Tb.The theory of mixing heat and phase separation further confirms that the Nd_(2)Fe_(14)B phase dissolves to form a mixed phase of Nd and TbFe_(2),which then solidifies into the(Nd,Tb)_(2)Fe_(14)B phase.Based on the discovery of the TbFe_(2) phase,the dissolution-solidification mechanism is considered the primary mechanism for GBDP.This is supported by the elemental content of the two typical core-shell structures observed. 展开更多
关键词 Grain boundary diffusion process TbFe_(2)phase Dissolution-solidification mechanism Core-shell structure The theory of mixing heat and phase separation
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Atomic-scale insights into microscopic mechanisms of grain boundary segregation in Al−Cu alloys 被引量:1
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作者 Xiong SHUAI Hong MAO +2 位作者 Sai TANG Yi KONG Yong DU 《Transactions of Nonferrous Metals Society of China》 2025年第1期1-12,共12页
This study aims to clarify the mechanisms for the grain boundary(GB)segregation through investigating the absorption of excess solute atoms at GBs in Al−Cu alloys by using the hybrid molecular dynamics/Monte Carlo sim... This study aims to clarify the mechanisms for the grain boundary(GB)segregation through investigating the absorption of excess solute atoms at GBs in Al−Cu alloys by using the hybrid molecular dynamics/Monte Carlo simulations.Two segregation mechanisms,substitutional and interstitial mechanisms,are observed.The intergranular defects,including dislocations,steps and vacancies,and the intervals in structural units are conductive to the prevalence of interstitial mechanism.And substitutional mechanism is favored by the highly ordered twin GBs.Furthermore,the two mechanisms affect the GB structure differently.It is quantified that interstitial mechanism is less destructive to GB structure than substitutional one,and often leads to a segregation level being up to about 6 times higher than the latter.These findings contribute to atomic scale insights into the microscopic mechanisms about how solute atoms are absorbed by GB structures,and clarify the correlation among intergranular structures,segregation mechanisms and kinetics. 展开更多
关键词 grain boundaries segregation Al−Cu alloy intergranular structure molecular dynamics simulation Monte Carlo simulation
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