The whole melting curve of iron ore during sintering process was obtained,and the melting characteristics of iron ore were defined and explained. The whole melting process of mixture,mixed by iron ore and CaO reagent ...The whole melting curve of iron ore during sintering process was obtained,and the melting characteristics of iron ore were defined and explained. The whole melting process of mixture,mixed by iron ore and CaO reagent at basicity of 2.0 and 4.0,respectively,was observed using a SiC heating furnace with camcorder unit,and the melting curves of mixture that were relative height vs temperature curves were obtained. Besides,the melting characteristics of iron ore during sintering were introduced through defining some points in the melting curves,such as liquid forming temperature,inflexion temperature and flowing temperature,and the meaning of different shapes of the melting curves was clarified.展开更多
A new method （gas-based separation plus melt separation） has been proposed to remove phosphorus of the high phosphorus iron ore which was 1.25 % of phosphorus content and 50. 0% of iron content. HSC chemistry packag...A new method （gas-based separation plus melt separation） has been proposed to remove phosphorus of the high phosphorus iron ore which was 1.25 % of phosphorus content and 50. 0% of iron content. HSC chemistry package and the coexistence theory of slag structure were adopted for theoretical analysis. The gas-based reduction was carried out using a fixed bed reactor and the ore sample of 80 g with an average particle size of 2 mm were reduced using CO or H2 at temperature of 1 073 K for 5 hours. 50 g of the reduced sample with 3.0% CaO as additive was then subjected to melt separation in an electric furnace at temperature of 1 873 K under Ar atmosphere. In each run, SEM, EDS, optical microscopic examination and chemical analysis of the reduced ore sample, the metal sample and the slag sample were conducted. Results of all gas-based reduction experiments showed that iron metallization ratios were some 65% and the phosphorus compounds in the ore remained unchanged. It was agreed well with the simula- tions except for the iron metallization rate being less than predicted value; this difference was attributed to kinetics. Results of melt separation experiments showed that P content in metal samples is 0.33% （metal sample from H2 reduction product） and 0.27% （metal sample from CO reduction product）. The phosphorus partition ratios of both cases were less than predicted values. Some P in the metal samples existed as slag inclusion was considered to be the reason for this discrepancy.展开更多
Long-standing controversy persists over the presence and role of iron-rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron-rich and silica-rich melt inclusions observed in thin-sections ar...Long-standing controversy persists over the presence and role of iron-rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron-rich and silica-rich melt inclusions observed in thin-sections are considered as direct evidence for the presence of iron-rich melt, yet unequivocal outcrop-scale evidence of iron-rich melts are still lacking in volcanic rock-hosted iron deposits. Submarine volcanic rock-hosted iron deposits, which are mainly distributed in the western and eastern Tianshan Mountains in Xinjiang, are important resources of iron ores in China, but it remains unclear whether iron-rich melts have played a role in the mineralization of such iron ores. In this study, we observed abundant iron-rich agglomerates in the brecciated andesite lava of the Heijianshan submarine volcanic rock-hosted iron deposit, Eastern Tianshan, China. The iron-rich agglomerates occur as irregular and angular masses filling fractures of the host brecciated andesite lava. They show concentric potassic alteration with silicification or epidotization rims, indicative of their formation after the wall rocks. The iron-rich agglomerates have porphyritic and hyalopilitic textures, and locally display chilled margins in the contact zone with the host rocks. These features cannot be explained by hydrothermal replacement of wall rocks （brecciated andesite lava） which is free of vesicle and amygdale, rather they indicate direct crystallization of the iron-rich agglomerates from iron-rich melts. We propose that the iron-rich agglomerates were formed by open-space filling of volatile-rich iron-rich melt in fractures of the brecciated andesite lava. The iron-rich agglomerates are compositionally similar to the wall-rock brecciated andesite lava, but have much larger variation. Based on mineral assemblages, the iron-rich agglomerates are subdivided into five types, i.e., albite-magnetite type, albite-K-feldspar- magnetite type, K-feldspar-magnetite type, epidote-magnetite type and quartz-magnetite type, representing that products formed at different stages during the evolution of a magmatic-hydrothermal system. The albite-magnetite type represents the earliest crystallization product from a residual iron- rich melt; the albite-K-feldspar-magnetite and K-feldspar-magnetite types show features of magmatic- hydrothermal transition, whereas the epidote-magnetite and quartz-magnetite types represent products of hydrothermal alteration. The occurrence of iron-rich agglomerates provides macroscopic evidence for the presence of iron-rich melts in the mineralization of the Heijianshan iron deposit. It also indicates that iron mineralization of submarine volcanic rock-hosted iron deposits is genetically related to hydrothermal fluids derived from iron-rich melts.展开更多
Realizing the boron and iron separation through selective reduction and melting separation of boron-bearing iron con- centrate is of great significance for the utilization of crude ludwigite. The reduction and melting...Realizing the boron and iron separation through selective reduction and melting separation of boron-bearing iron con- centrate is of great significance for the utilization of crude ludwigite. The reduction and melting separation mechanism of boron-bearing iron concentrate/coal composite pellet was systematically investigated. The reduction and melting separation test of small size pellet was performed to reveal the evolution of slag and iron in the melting separation process. The isothermal reduction experiment showed the relationship between reduction stage and melting separation stage, and the step reduction and melting separation was perfectly achieved. Coal particles existed through the reduction and melting separation process and finally formed brown residue around the separated product. The pellet could not realize melting separation when the B2O3 content in the concentrate was lower than 6.00 wt%.展开更多
Iron carbon agglomerates(ICA)are the composite burden for low-carbon blast furnace(BF)ironmaking.In order to optimize the reactivity of ICA according to the evolution characteristics of ICA in the BF smelting process,...Iron carbon agglomerates(ICA)are the composite burden for low-carbon blast furnace(BF)ironmaking.In order to optimize the reactivity of ICA according to the evolution characteristics of ICA in the BF smelting process,the evolution behavior and mechanism of different reactive ICA under simulated BF smelting conditions were studied.The results show that the existence of more sillimanite and aluminosilicate and less active sites of metallic iron will weaken gasification reaction and carburization ability of ICA-1(containing 10%iron ore).It weakens the promoting effect of ICA-1 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron.The aluminosilicate with a high melting point decreases,the low melting point slag phase and Fe–Si alloy increase,and many active sites of metallic iron exist,which strengthen the gasification reaction and carburization ability of ICA-2(containing 30%iron ore).The promoting effect of ICA-2 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron is significantly improved.The gasification reaction capacity of ICA-3(containing 35%iron ore)is reduced,and the improvement in ICA-3 on the softening–melting performance of mixed burdens is reduced.The appropriate proportion of iron ore in ICA is about 30%.展开更多
Microstructure strongly influences the mechanical properties of cast iron. By inoculating the melt with proper inoculants, foreign substrates are brought into the melt and eventually the graphite can crystallize on th...Microstructure strongly influences the mechanical properties of cast iron. By inoculating the melt with proper inoculants, foreign substrates are brought into the melt and eventually the graphite can crystallize on them. The elements and substrates that really play a role for nucleation are yet unknown. Until now there is very little knowledge about the fundamentals of nucleation, such as composition and morphology of nuclei. In this work we utilized EN-GJL-200 as a base material and examined several produced specimens. The specimens were cast with and without inoculants and quenched at different solidification states. Specimens were also examined with a high and low oxygen concentration, but the results showed that different oxygen contents have no influence on the nucleation in cast iron melts. Our research was focused on the microscopic examination and phase-field simulations. For studying the samples we applied different analytical methods, where SEM-EDS, -WDS were proved to be most effective. The simulations were conducted by using the software MICRESS, which is based on a multiphase-field model and has been coupled directly to the TCFE3 thermodynamic database from TCAB. On the basis of the experimental investigations a nucleation mechanism is proposed, which claims MnS precipitates as the preferred site for graphite nucleation. This theory is supported by the results of the phase-field simulations.展开更多
The difference of conductivity between primary iron-rich phases and aluminum melt has been used to separate them by electromagnetic force (EMF) which is induced by imposing a direct electric current and a steady magne...The difference of conductivity between primary iron-rich phases and aluminum melt has been used to separate them by electromagnetic force (EMF) which is induced by imposing a direct electric current and a steady magnetic field in molten Al-Si alloy. Theoretical analysis and experiments on self-designed electromagnetic separation indicates that primary needle-like β phases are difficult to separate; while primary α iron-rich phases can be separated by electromagnetic separation. Primary iron-rich phases have been removed from the melt successfully when the molten metal flows horizontally through separation channel. The iron content is reduced from 1.13% to 0.41%.展开更多
The characteristics of some elements in inoculant were analyzed.The effect of the morphology of instantaneous inoculant on its melting velocity was studied.When the inoculants pass through the same sieve number,the vo...The characteristics of some elements in inoculant were analyzed.The effect of the morphology of instantaneous inoculant on its melting velocity was studied.When the inoculants pass through the same sieve number,the volume and the ratio of surface area to volume are different.It is evident from the theoretical analysis and experiment under some conditions that the melting velocity of inoculant depends on the morphology of inoculant.The morphology of inoculant during production should be controlled carefully.展开更多
This paper studied the changing principles of carbon content in direct reduction iron (DRI) and liquid iron in the COREX melting gasifier. Under the normal working conditions of experimental equipment, liquid nitrogen...This paper studied the changing principles of carbon content in direct reduction iron (DRI) and liquid iron in the COREX melting gasifier. Under the normal working conditions of experimental equipment, liquid nitrogen was poured into the melting gasifier from its tuyere to cool down quickly. And then seven cross sections were made to study the carburization reaction and its characteristics of the solid iron and the liquid iron, and also the reaction of carbon between the slag and the metal. According to the results, the influences of the thickness of the semi-coke layer and the temperature on the carbon content of liquid iron in the COREX melting gasifier were confirmed.展开更多
A model of iron ore sintering was built with consideration of fuel combustion, catalysis of sinter mixture as well as formation of melt and mineral, which was verified via sintering pot tests and showed a good fit to ...A model of iron ore sintering was built with consideration of fuel combustion, catalysis of sinter mixture as well as formation of melt and mineral, which was verified via sintering pot tests and showed a good fit to the experi- mental results. The effect of bed depth on temperature was reflected by the residence time in high-temperature zone, rather than the top value of the temperature, which was weakened by melt formation as well as hematite decomposi- tion. Moreover, the effect of bed depth, fuel content and distribution on sintering process was different, which was reflected by temperature profiles and the rule of calcium ferrite formation. The formation of melt as well as magnetite was a process which was decided by kinetic factors, while the formation of calcium ferrite was related to fuel blend- ing conditions, which is determined by thermodynamics when the fuel ratio inside sinter granules is low or fuel con- tent is high, otherwise, it is determined by kinetics.展开更多
The cast-steel creeper tread is a part with complex external surface and internal shape,having a hot spot cased by the uneven wall thickness.As the hot spot is far away from the gating system and the feeding channel i...The cast-steel creeper tread is a part with complex external surface and internal shape,having a hot spot cased by the uneven wall thickness.As the hot spot is far away from the gating system and the feeding channel is narrow,it is difficult to be fed by setting up a casting head,leading easily to shrinkage and causing great problems for investment casting.In this paper,the qualified castings can be successfully poured by feeding method of insert chill iron melt,smart design and placement process of chill,to realize simultaneous solidification of castings.The shrinkage of creeper tread is solved and the precision of castings is improved.This method exhibits easy operation,excellent feeding effect and simplified gating system to improve yield rate.Furthermore,it could save raw material,reduce waste product and lower product cost by using the insert chill iron melt in investment casting.The production practices showed that the qualified castings can be successfully poured by increasing feeding pressure,placing an internal chill to adjust the temperature of hot junction segments and realizing simultaneous solidification of castings.展开更多
This study developed a direct reduction route to smelt refractory high-phosphorus iron ores by using hydrogen rich gas.The effects of temperature,gas composition,and gangue on the reduction behavior of iron ore pellet...This study developed a direct reduction route to smelt refractory high-phosphorus iron ores by using hydrogen rich gas.The effects of temperature,gas composition,and gangue on the reduction behavior of iron ore pellets were investigated.Additionally,the migration behavior of phosphorus throughout the reduction-smelting process was examined.The apparent activation energy of the reduction process increased from 64.2 to 194.2 kJ/mol.Increasing the basicity from 0.5 to 0.9 increased the metallization rate from 85.9%to 89.2%.During the reduction process,phosphorus remained in the gangue phase.Carbon deposition and phosphorus removal behaviors of the pellets were investigated and correlated with the gas composition,temperature,pressure,metallization rate,and basicity.Increasing the FeO and CaO contents led to an increase in the liquidus temperature.A high metallization rate of the pellets reduced the phosphorus removal rate but increased the carbon content of the final iron product.Increasing basicity restricted the migration of phosphorus and improved the rate of phosphorus removal.The optimum dephosphorization parameters were separation temperature of 1823 K,basicity of 2.0,and metallization rate of 82.3%.This study presents a high-efficiency and low carbon method for smelting high-phosphorus iron ores.展开更多
13 kinds of iron ores （6 from Australia and 7 from Brazil） were studied on their properties concerning CW （Combined Water） decomposition, FezO3 decomposition and softening-melting in air atmosphere through the cha...13 kinds of iron ores （6 from Australia and 7 from Brazil） were studied on their properties concerning CW （Combined Water） decomposition, FezO3 decomposition and softening-melting in air atmosphere through the characterization method of TG-DSC （Thermogravimetry-Differential Scanning Caloremetry ）. The experimental results of the Australian ores and Brazilian ores differ in terms of the initial temperature, temperature range and endothermic amount of CW decomposition,and besides, the content of CW. It is estimated that for every percent increase of CW content in sintering raw material, the extra thermal amount absorbed in the process is about 1.83 x 104 kJ, which equals to the thermal capacity of 0.625 kg of standard coal burning up completely. As to the decomposition of Fe203 ,the initial temperatures, terminal temperatures and temperature ranges of the Australian and Brazilian ores are quite close. However, the endothermic amount of Fe2O3 decomposition of the two turns out rather different： the endothermic capacity of Fe2O3 decomposition of the Australian ores is greater than that of the Brazilian ores. Furthermore, the liquid amount generated in the softening-melting process is closely related to the SiO2 content in iron ore. The higher SiO2 content the ore contains, the more liquid volume it will generate in the softening-melting process of iron ore.展开更多
Sequential melting theory is applied to reteal that fluctuation of chemical composition ofmelted iron in cupola is caused by the process of sequential melting. Fluctuation is incvitable andcyclc. Usting microcornputer...Sequential melting theory is applied to reteal that fluctuation of chemical composition ofmelted iron in cupola is caused by the process of sequential melting. Fluctuation is incvitable andcyclc. Usting microcornputer dynamic simulation has confirmed that the fluctuation situation ofchemical composition cf melted iron is contistent with actuaa production on the whole.展开更多
基金Item Sponsored by National Key Fundamental Research and Development Project of China (2006BAE03A01)
文摘The whole melting curve of iron ore during sintering process was obtained,and the melting characteristics of iron ore were defined and explained. The whole melting process of mixture,mixed by iron ore and CaO reagent at basicity of 2.0 and 4.0,respectively,was observed using a SiC heating furnace with camcorder unit,and the melting curves of mixture that were relative height vs temperature curves were obtained. Besides,the melting characteristics of iron ore during sintering were introduced through defining some points in the melting curves,such as liquid forming temperature,inflexion temperature and flowing temperature,and the meaning of different shapes of the melting curves was clarified.
基金Sponsored by National Natural Science Foundation of China and Baosteel(50834007)
文摘A new method （gas-based separation plus melt separation） has been proposed to remove phosphorus of the high phosphorus iron ore which was 1.25 % of phosphorus content and 50. 0% of iron content. HSC chemistry package and the coexistence theory of slag structure were adopted for theoretical analysis. The gas-based reduction was carried out using a fixed bed reactor and the ore sample of 80 g with an average particle size of 2 mm were reduced using CO or H2 at temperature of 1 073 K for 5 hours. 50 g of the reduced sample with 3.0% CaO as additive was then subjected to melt separation in an electric furnace at temperature of 1 873 K under Ar atmosphere. In each run, SEM, EDS, optical microscopic examination and chemical analysis of the reduced ore sample, the metal sample and the slag sample were conducted. Results of all gas-based reduction experiments showed that iron metallization ratios were some 65% and the phosphorus compounds in the ore remained unchanged. It was agreed well with the simula- tions except for the iron metallization rate being less than predicted value; this difference was attributed to kinetics. Results of melt separation experiments showed that P content in metal samples is 0.33% （metal sample from H2 reduction product） and 0.27% （metal sample from CO reduction product）. The phosphorus partition ratios of both cases were less than predicted values. Some P in the metal samples existed as slag inclusion was considered to be the reason for this discrepancy.
基金financially supported by the Geological Survey Program of China(grants No.K1410 and DD20160346)the National Natural Foundation of China(grants No.41672078 and 41402067)
文摘Long-standing controversy persists over the presence and role of iron-rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron-rich and silica-rich melt inclusions observed in thin-sections are considered as direct evidence for the presence of iron-rich melt, yet unequivocal outcrop-scale evidence of iron-rich melts are still lacking in volcanic rock-hosted iron deposits. Submarine volcanic rock-hosted iron deposits, which are mainly distributed in the western and eastern Tianshan Mountains in Xinjiang, are important resources of iron ores in China, but it remains unclear whether iron-rich melts have played a role in the mineralization of such iron ores. In this study, we observed abundant iron-rich agglomerates in the brecciated andesite lava of the Heijianshan submarine volcanic rock-hosted iron deposit, Eastern Tianshan, China. The iron-rich agglomerates occur as irregular and angular masses filling fractures of the host brecciated andesite lava. They show concentric potassic alteration with silicification or epidotization rims, indicative of their formation after the wall rocks. The iron-rich agglomerates have porphyritic and hyalopilitic textures, and locally display chilled margins in the contact zone with the host rocks. These features cannot be explained by hydrothermal replacement of wall rocks （brecciated andesite lava） which is free of vesicle and amygdale, rather they indicate direct crystallization of the iron-rich agglomerates from iron-rich melts. We propose that the iron-rich agglomerates were formed by open-space filling of volatile-rich iron-rich melt in fractures of the brecciated andesite lava. The iron-rich agglomerates are compositionally similar to the wall-rock brecciated andesite lava, but have much larger variation. Based on mineral assemblages, the iron-rich agglomerates are subdivided into five types, i.e., albite-magnetite type, albite-K-feldspar- magnetite type, K-feldspar-magnetite type, epidote-magnetite type and quartz-magnetite type, representing that products formed at different stages during the evolution of a magmatic-hydrothermal system. The albite-magnetite type represents the earliest crystallization product from a residual iron- rich melt; the albite-K-feldspar-magnetite and K-feldspar-magnetite types show features of magmatic- hydrothermal transition, whereas the epidote-magnetite and quartz-magnetite types represent products of hydrothermal alteration. The occurrence of iron-rich agglomerates provides macroscopic evidence for the presence of iron-rich melts in the mineralization of the Heijianshan iron deposit. It also indicates that iron mineralization of submarine volcanic rock-hosted iron deposits is genetically related to hydrothermal fluids derived from iron-rich melts.
基金The authors would like to express their gratitude for the financial support of the China Postdoctoral Science Foundation （No. 2016M600919） and National Natural Science Foundation of China （No. 51274033）.
文摘Realizing the boron and iron separation through selective reduction and melting separation of boron-bearing iron con- centrate is of great significance for the utilization of crude ludwigite. The reduction and melting separation mechanism of boron-bearing iron concentrate/coal composite pellet was systematically investigated. The reduction and melting separation test of small size pellet was performed to reveal the evolution of slag and iron in the melting separation process. The isothermal reduction experiment showed the relationship between reduction stage and melting separation stage, and the step reduction and melting separation was perfectly achieved. Coal particles existed through the reduction and melting separation process and finally formed brown residue around the separated product. The pellet could not realize melting separation when the B2O3 content in the concentrate was lower than 6.00 wt%.
基金This work was financially supported by the National Natural Science Foundation of China-Liaoning Joint Funds(U1808212)National Natural Science Foundation of China(52074080)Xingliao Talent Plan(XLYC1902118).
文摘Iron carbon agglomerates(ICA)are the composite burden for low-carbon blast furnace(BF)ironmaking.In order to optimize the reactivity of ICA according to the evolution characteristics of ICA in the BF smelting process,the evolution behavior and mechanism of different reactive ICA under simulated BF smelting conditions were studied.The results show that the existence of more sillimanite and aluminosilicate and less active sites of metallic iron will weaken gasification reaction and carburization ability of ICA-1(containing 10%iron ore).It weakens the promoting effect of ICA-1 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron.The aluminosilicate with a high melting point decreases,the low melting point slag phase and Fe–Si alloy increase,and many active sites of metallic iron exist,which strengthen the gasification reaction and carburization ability of ICA-2(containing 30%iron ore).The promoting effect of ICA-2 on the reduction,softening,and melting of ferrous burdens and the dripping of slag-iron is significantly improved.The gasification reaction capacity of ICA-3(containing 35%iron ore)is reduced,and the improvement in ICA-3 on the softening–melting performance of mixed burdens is reduced.The appropriate proportion of iron ore in ICA is about 30%.
文摘Microstructure strongly influences the mechanical properties of cast iron. By inoculating the melt with proper inoculants, foreign substrates are brought into the melt and eventually the graphite can crystallize on them. The elements and substrates that really play a role for nucleation are yet unknown. Until now there is very little knowledge about the fundamentals of nucleation, such as composition and morphology of nuclei. In this work we utilized EN-GJL-200 as a base material and examined several produced specimens. The specimens were cast with and without inoculants and quenched at different solidification states. Specimens were also examined with a high and low oxygen concentration, but the results showed that different oxygen contents have no influence on the nucleation in cast iron melts. Our research was focused on the microscopic examination and phase-field simulations. For studying the samples we applied different analytical methods, where SEM-EDS, -WDS were proved to be most effective. The simulations were conducted by using the software MICRESS, which is based on a multiphase-field model and has been coupled directly to the TCFE3 thermodynamic database from TCAB. On the basis of the experimental investigations a nucleation mechanism is proposed, which claims MnS precipitates as the preferred site for graphite nucleation. This theory is supported by the results of the phase-field simulations.
文摘The difference of conductivity between primary iron-rich phases and aluminum melt has been used to separate them by electromagnetic force (EMF) which is induced by imposing a direct electric current and a steady magnetic field in molten Al-Si alloy. Theoretical analysis and experiments on self-designed electromagnetic separation indicates that primary needle-like β phases are difficult to separate; while primary α iron-rich phases can be separated by electromagnetic separation. Primary iron-rich phases have been removed from the melt successfully when the molten metal flows horizontally through separation channel. The iron content is reduced from 1.13% to 0.41%.
文摘The characteristics of some elements in inoculant were analyzed.The effect of the morphology of instantaneous inoculant on its melting velocity was studied.When the inoculants pass through the same sieve number,the volume and the ratio of surface area to volume are different.It is evident from the theoretical analysis and experiment under some conditions that the melting velocity of inoculant depends on the morphology of inoculant.The morphology of inoculant during production should be controlled carefully.
文摘This paper studied the changing principles of carbon content in direct reduction iron (DRI) and liquid iron in the COREX melting gasifier. Under the normal working conditions of experimental equipment, liquid nitrogen was poured into the melting gasifier from its tuyere to cool down quickly. And then seven cross sections were made to study the carburization reaction and its characteristics of the solid iron and the liquid iron, and also the reaction of carbon between the slag and the metal. According to the results, the influences of the thickness of the semi-coke layer and the temperature on the carbon content of liquid iron in the COREX melting gasifier were confirmed.
基金Item Sponsored by National Natural Science Foundation of China(50974012)National High Technology Research and Development of China(2006AA06Z125)
文摘A model of iron ore sintering was built with consideration of fuel combustion, catalysis of sinter mixture as well as formation of melt and mineral, which was verified via sintering pot tests and showed a good fit to the experi- mental results. The effect of bed depth on temperature was reflected by the residence time in high-temperature zone, rather than the top value of the temperature, which was weakened by melt formation as well as hematite decomposi- tion. Moreover, the effect of bed depth, fuel content and distribution on sintering process was different, which was reflected by temperature profiles and the rule of calcium ferrite formation. The formation of melt as well as magnetite was a process which was decided by kinetic factors, while the formation of calcium ferrite was related to fuel blend- ing conditions, which is determined by thermodynamics when the fuel ratio inside sinter granules is low or fuel con- tent is high, otherwise, it is determined by kinetics.
文摘The cast-steel creeper tread is a part with complex external surface and internal shape,having a hot spot cased by the uneven wall thickness.As the hot spot is far away from the gating system and the feeding channel is narrow,it is difficult to be fed by setting up a casting head,leading easily to shrinkage and causing great problems for investment casting.In this paper,the qualified castings can be successfully poured by feeding method of insert chill iron melt,smart design and placement process of chill,to realize simultaneous solidification of castings.The shrinkage of creeper tread is solved and the precision of castings is improved.This method exhibits easy operation,excellent feeding effect and simplified gating system to improve yield rate.Furthermore,it could save raw material,reduce waste product and lower product cost by using the insert chill iron melt in investment casting.The production practices showed that the qualified castings can be successfully poured by increasing feeding pressure,placing an internal chill to adjust the temperature of hot junction segments and realizing simultaneous solidification of castings.
基金Project(U1960205)supported by the National Natural Science Foundation of ChinaProject(2020ZXA01)supported by China Minmetals Science and Technology Special Plan Foundation。
文摘This study developed a direct reduction route to smelt refractory high-phosphorus iron ores by using hydrogen rich gas.The effects of temperature,gas composition,and gangue on the reduction behavior of iron ore pellets were investigated.Additionally,the migration behavior of phosphorus throughout the reduction-smelting process was examined.The apparent activation energy of the reduction process increased from 64.2 to 194.2 kJ/mol.Increasing the basicity from 0.5 to 0.9 increased the metallization rate from 85.9%to 89.2%.During the reduction process,phosphorus remained in the gangue phase.Carbon deposition and phosphorus removal behaviors of the pellets were investigated and correlated with the gas composition,temperature,pressure,metallization rate,and basicity.Increasing the FeO and CaO contents led to an increase in the liquidus temperature.A high metallization rate of the pellets reduced the phosphorus removal rate but increased the carbon content of the final iron product.Increasing basicity restricted the migration of phosphorus and improved the rate of phosphorus removal.The optimum dephosphorization parameters were separation temperature of 1823 K,basicity of 2.0,and metallization rate of 82.3%.This study presents a high-efficiency and low carbon method for smelting high-phosphorus iron ores.
文摘13 kinds of iron ores （6 from Australia and 7 from Brazil） were studied on their properties concerning CW （Combined Water） decomposition, FezO3 decomposition and softening-melting in air atmosphere through the characterization method of TG-DSC （Thermogravimetry-Differential Scanning Caloremetry ）. The experimental results of the Australian ores and Brazilian ores differ in terms of the initial temperature, temperature range and endothermic amount of CW decomposition,and besides, the content of CW. It is estimated that for every percent increase of CW content in sintering raw material, the extra thermal amount absorbed in the process is about 1.83 x 104 kJ, which equals to the thermal capacity of 0.625 kg of standard coal burning up completely. As to the decomposition of Fe203 ,the initial temperatures, terminal temperatures and temperature ranges of the Australian and Brazilian ores are quite close. However, the endothermic amount of Fe2O3 decomposition of the two turns out rather different： the endothermic capacity of Fe2O3 decomposition of the Australian ores is greater than that of the Brazilian ores. Furthermore, the liquid amount generated in the softening-melting process is closely related to the SiO2 content in iron ore. The higher SiO2 content the ore contains, the more liquid volume it will generate in the softening-melting process of iron ore.
文摘Sequential melting theory is applied to reteal that fluctuation of chemical composition ofmelted iron in cupola is caused by the process of sequential melting. Fluctuation is incvitable andcyclc. Usting microcornputer dynamic simulation has confirmed that the fluctuation situation ofchemical composition cf melted iron is contistent with actuaa production on the whole.
