Metal-organic frameworks(MOFs)refer to novel crystalline porous materials constructed by linking metal nodes and organic linkers through coordination bonds.Featuring predictable and designable long-range ordered struc...Metal-organic frameworks(MOFs)refer to novel crystalline porous materials constructed by linking metal nodes and organic linkers through coordination bonds.Featuring predictable and designable long-range ordered structures,high surface areas,vip-accessible voids,and easily functionalized channels by pre-or post-modifications,MOFs have attracted much attention in the past two decades.In this review,we discussed the design strategies,synthesis methods,and structural characteristics of MOFs and MOF-derived/composite materials.Meanwhile,the challenges facing MOF research were also discussed.展开更多
基金supported by the National Key Research and Development Program of China(2022YFA1502901)the National Natural Science Foundation of China(22035003,22201137,22371137)the Fundamental Research Funds for the Central Universities(63243115).
文摘Metal-organic frameworks(MOFs)refer to novel crystalline porous materials constructed by linking metal nodes and organic linkers through coordination bonds.Featuring predictable and designable long-range ordered structures,high surface areas,vip-accessible voids,and easily functionalized channels by pre-or post-modifications,MOFs have attracted much attention in the past two decades.In this review,we discussed the design strategies,synthesis methods,and structural characteristics of MOFs and MOF-derived/composite materials.Meanwhile,the challenges facing MOF research were also discussed.