In this paper, a pseudopotential-based multiplerelaxation-time lattice Boltzmann model is proposed for multicomponent/multiphase flow systems. Unlike previous models in the literature, the present model not only enabl...In this paper, a pseudopotential-based multiplerelaxation-time lattice Boltzmann model is proposed for multicomponent/multiphase flow systems. Unlike previous models in the literature, the present model not only enables the study of multicomponent flows with different molecular weights, different viscosities and different Schmidt numbers, but also ensures that the distribution function of each component evolves on the same square lattice without invoking ad- ditional interpolations. Furthermore, the Chapman-Enskog analysis shows that the present model results in the correct hydrodynamic equations, and satisfies the indifferentiability principle. The numerical validation exercises further demonstrate that the favorable performance of the present model.展开更多
To clarify the ambiguity on negative Boltzmann temperature in literature, we study the Carnot and the Otto cycle with one of the heat reservoirs at the negative Boltzmann temperature based on a canonical ensemble desc...To clarify the ambiguity on negative Boltzmann temperature in literature, we study the Carnot and the Otto cycle with one of the heat reservoirs at the negative Boltzmann temperature based on a canonical ensemble description. The work extraction, entropy production and the efficiency of these cycles are explored. Conditions for constructing and properties of these thermodynamic cycles are elucidated. We find that the apparent "violation" of the second law of thermodynamics in these cycles are due to the fact that the traditional definition of thermodynamic efficiency is inappropriate in this situation. When properly understanding the efficiency and the adiabatic processes, in which the system crosses over "absolute ZERO" in a limit sense, the Carnot cycle with one of the heat reservoirs at a negative Boltzmann temperature can be understood straightforwardly, and it contradicts neither the second nor the third law of thermodynamics. Hence, negative Boltzmann temperature is a consistent concept in thermodynamics. We use a two-level system and an Ising spin system to illustrate our central results.展开更多
基金supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China (62311)supported by the National Natural Science Foundation of China(51006040)+1 种基金the Hong Kong Scholar Programthe National Science Fund for Distinguished Young Scholars of China (51125024)
文摘In this paper, a pseudopotential-based multiplerelaxation-time lattice Boltzmann model is proposed for multicomponent/multiphase flow systems. Unlike previous models in the literature, the present model not only enables the study of multicomponent flows with different molecular weights, different viscosities and different Schmidt numbers, but also ensures that the distribution function of each component evolves on the same square lattice without invoking ad- ditional interpolations. Furthermore, the Chapman-Enskog analysis shows that the present model results in the correct hydrodynamic equations, and satisfies the indifferentiability principle. The numerical validation exercises further demonstrate that the favorable performance of the present model.
基金Support from the National Science Foundation of China under Grants Nos.11375012,11534002The Recruitment Program of Global Youth Experts of China
文摘To clarify the ambiguity on negative Boltzmann temperature in literature, we study the Carnot and the Otto cycle with one of the heat reservoirs at the negative Boltzmann temperature based on a canonical ensemble description. The work extraction, entropy production and the efficiency of these cycles are explored. Conditions for constructing and properties of these thermodynamic cycles are elucidated. We find that the apparent "violation" of the second law of thermodynamics in these cycles are due to the fact that the traditional definition of thermodynamic efficiency is inappropriate in this situation. When properly understanding the efficiency and the adiabatic processes, in which the system crosses over "absolute ZERO" in a limit sense, the Carnot cycle with one of the heat reservoirs at a negative Boltzmann temperature can be understood straightforwardly, and it contradicts neither the second nor the third law of thermodynamics. Hence, negative Boltzmann temperature is a consistent concept in thermodynamics. We use a two-level system and an Ising spin system to illustrate our central results.
