In modern engineering,enhancing boiling heat transfer efficiency is crucial for optimizing energy use and several industrial processes involving different types of materials.This study explores the enhancement of pool...In modern engineering,enhancing boiling heat transfer efficiency is crucial for optimizing energy use and several industrial processes involving different types of materials.This study explores the enhancement of pool boiling heat transfer potentially induced by combining perforated copper particles on a heated surface with a sodium dodecyl sulfate(SDS)surfactant in saturated deionized water.Experiments were conducted at standard atmospheric pressure,with heat flux ranging from 20 to 100 kW/m2.The heating surface,positioned below the layer of freely moving copper beads,allowed the particle layer to shift due to liquid convection and steam nucleation.The study reports on the influence of copper bead diameter(2,3,4,and 5 mm),particle quantity,arrangement,and SDS concentration(20,200,and 500 ppm).It is shown that the combination of 5 mm particles and a 500 ppm SDS concentration can yield a remarkable 139%improvement in heat transfer efficiency.As demonstrated by direct flow visualization,bubble formation occurs primarily in the gaps between the particles and the heated surface,with the presence of SDS reducing bubble size and accelerating bubble detachment.展开更多
This study investigates the flow boiling heat transfer coefficient and pressure gradient of refrigerant R410A inmicro-channel flat tubes.Experiments were conducted at saturation temperatures ranging from 25℃ to 30℃,...This study investigates the flow boiling heat transfer coefficient and pressure gradient of refrigerant R410A inmicro-channel flat tubes.Experiments were conducted at saturation temperatures ranging from 25℃ to 30℃,mass fluxes between 198 and 305 kg/m^(2)s,and heat fluxes from 9.77 to 20.18 kW/m^(2),yielding 99 sets of local heat transfer coefficient data.The results show that increasing heat flux and mass flux enhances the heat transfer coefficient,although the rate of enhancement decreases with increasing vapor quality.Conversely,higher saturation temperatures slightly reduce the heat transfer coefficient.Additionally,the experimental findings reveal discrepancies in the accuracy of existing pressure drop and heat transfer coefficient prediction models under the studied conditions.This study recommends using the Kimand Mudawar correlation to predict pressure gradients within the tested range,with aMean Error(ME)of−5.24%observed in this study.For heat transfer coefficients,the Cooper and Kandlikar correlations are recommended,achieving a Mean Absolute Error(MAE)of approximately 22%.This research provides value for performance prediction and parameter selection of micro-channel technology in broader application scenarios within heating,ventilation and air-conditioning fields.展开更多
In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 k...In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 kg/(m2 s),saturation temperatures of 293,298,and 303 K,and inlet sub-cooling of 5,10,and 15 K.The analysis of the experimental results provides the following conclusions:a reduced mass flux and lower subcooling correspond to a diminished degree of superheat at the boiling inception wall;conversely,an elevated saturation temperature results in a reduced amount of superheat at the boiling inception wall.Furthermore,an increase in sub-cooling and saturation temperature will enhance heat transfer efficiency.The wall temperature is mostly influenced by variations in saturation temperature and is minimally related to changes in mass flux and subcooling degree.An increase in mass flux results in a greater pressure drop attributed to heightened frictional pressure loss.The variation in pressure drop with respect to sub-cooling is minimal,while an increased saturation temperature correlates with a reduced pressure drop due to the formation of smaller bubbles and lowered frictional pressure loss at high saturation pressures.This study thoroughly examines and summarizes the effects of mass flow rate,saturation temperature,and subcooling on the flow-boiling heat transfer and pressure drop characteristics of R1234yf.Furthermore,the new correlation has 93.42%of the predicted values fall within a 15%mean absolute error,exhibiting a mean absolute error of 5.75%.It provides a superior method for predicting the flow-boiling heat transfer coefficients of R1234yf in the heat sink of parallel microchannels compared to existing correlations.展开更多
Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.Ho...Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.However,the continuous rise in power density of electronic components imposesmore stringent requirements on the heat transfer capability of microchannel flow boiling.HFE-7100,a dielectric coolant with favorable thermophysical properties,has become a focal point of research for enhancing flow boiling performance in open microchannels.The flow boiling heat transfer performance ofHFE-7100 was investigated in this study by fabricating micro-nano composite structures on the bottom surface of open microchannels using laser ablation technology.Based on visualization results,a comparative analysis was conducted on the bubble dynamics and flow pattern characteristics of HFE-7100 flow boiling in micronano structured open microchannels(MNSOMC)and smooth-surface open microchannels(SSOMC),to elucidate the enhancement mechanism of micro-nano structures on flow boiling heat transfer in open microchannels.The results indicate that the surface structures and strong wettability of MNSOMC accelerated bubble nucleation and departure.Moreover,bubbles in the channel tended to coalesce along the flow direction,forming elongated slug bubbles with high aspect ratios,which enabled efficient thin film evaporation in conjunction with intense nucleate boiling,thereby significantly enhancing flow boiling heat transfer.Under the experimental conditions of this study,the maximum enhancements in the heat transfer coefficient(HTC)and critical heat flux(CHF)of HFE-7100 inMNSOMC were 33.4%and 133.1%,respectively,with the CHF reaching up to 1542.3 kW⋅m^(−2).Furthermore,due to the superior wettability and capillary wicking capability of the micro-nano composite structures,the significant enhancement in flow boiling heat transfer was achieved without incurring a noticeable pressure drop penalty.展开更多
This research explores the characteristics of boiling in inclined pipes,a domain of great importance in engineering.Employing an experimental visualization technique,the boiling dynamics of deionizedwater are examined...This research explores the characteristics of boiling in inclined pipes,a domain of great importance in engineering.Employing an experimental visualization technique,the boiling dynamics of deionizedwater are examined at varying inclination angles,paying special attention to the emerging flow patterns.The findings demonstrate that the inclination angle significantly impacts flow pattern transitions within the 0°to 90°range.As the heat flux rises,bubbles form in the liquid.The liquid’s inertia extends the bubble-wall contact time,thereby delaying the onset of bulk bubble flow.Beyond a 90°inclination,however,the patterning behavior is more influenced by the fluid velocity.At low speeds,incomplete pipe filling results in a large liquid plug hindering flow,while high speeds lead to full pipe filling.In general,gravity,inertia,buoyancy forces,and capillary forces are themain influential factors in the considered problem.However,an analysis of the heat transfer coefficient and boiling curve for different inclination angles reveals that the observed variations are essentially due to corresponding changes in the flow pattern.Finally,an optimal mass flux and inclination angle,able to minimize total entropy generation and improve heat transfer efficiency,are determined by means of an entropy generation analysis.展开更多
Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of th...Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of the geometric and system parameters on heat transfer characteristics in helically coiled tubes are investigated by collecting large amounts of experimental data and analyzing the heat transfer mechanisms. The existing correlations are divided into two categories,and they are calculated with the experimental data.The Dn factor is introduced to take into account the effect of a complex geometrical structure on flow boiling heat transfer.A new correlation is developed for predicting the flow boiling heat transfer coefficients in the helically coiled tubes,which is validated by the experimental data of R134a flow boiling heat transfer in them;and the average relative error and root mean square error of the new correlation are calculated.The results show that the new correlation agrees well with the experimental data,indicating that the new correlation can be used for predicting flow boiling heat transfer characteristics in the helically coiled tubes.展开更多
Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles...Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles with deionized water as a medium are experimentally studied at atmospheric and sub-atmospheric pressures,respectively.The experimental results indicate that the boiling heat transfer coefficients of the two types of tube bundles increase with the increase in pressure under vacuum conditions as they behave under ordinary pressure.As the pressure varies from 10 to 100 kPa,it also can be seen that the heat transfer coefficient of the sintered porous surface tube is increased by 0.2 to 4 times compared with the smooth one under the same operating parameters.In addition,the experimental data show that a definite bundle effect exists in both sintered porous surface tubes and smooth tubes under vacuum conditions.展开更多
Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR s...Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.展开更多
Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa....Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients.展开更多
Compared with port fuel injection engines, direct injection(DI) gasoline engine is becoming the mainstream of gasoline engines because of its higher fuel economy and excellent transient response. It has been proven th...Compared with port fuel injection engines, direct injection(DI) gasoline engine is becoming the mainstream of gasoline engines because of its higher fuel economy and excellent transient response. It has been proven that fuel spray characteristics in DI engines are crucial to the performance and emission quality of the engine. Flash boiling spray has great potential to achieve high fuel economy and low emission by dramatically improving the fuel atomization and vaporization and it has different spray-air interaction behavior as compared with non-flash boiling one, while its mechanism is more complex as compared with subcooled spray. We investigate the time-resolved spatial velocity field of the spray using 2-camera high-speed 3 D3 C(3-dimension 3-component)tomographic particle image velocimetry(PIV) diagnostic technique. A 10 mm thick laser sheet is used to illuminate the fuel spray. Characteristics of both non-flash and flash boiling sprays are studied. A single-hole injector is mounted within a heat exchanger so that different fuel temperature can be accessed. In the experiment, n-pentane is used as the fuel. For the non-flash boiling spray, the velocity field of the liquid spray is mostly consistent to the injection direction. With the increase of the degree of superheat(Do S), the overall velocity scale decreases especially at the spray tip. Meanwhile, larger swirls occur at the lower part of the flash boiling spray, which means stronger spray-air interaction occurs at a higher Do S.展开更多
The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet sub...The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet subcooling from 4.7 to 15.0℃, heat flux from 0.11 to 8.9 kW/m2 and mass flux from 218. 2 to 443. 7 kg/（ m2 · s ）. The heat flux, superheat and temperature undershoot at the ONB are analyzed in vertical helically-coiled tubes. Also, the effects of mass flux, system pressure, inlet subcooling and geometric parameters on the ONB are studied. The results demonstrate that the inception heat flux and superheat increase with increasing mass flux and inlet subcooling, but decrease with increasing system pressure and helix diameter. The pitch of the helical coil has a slight effect on the wall superheat and heat flux at the ONB. The correlation of heat flux at the ONB of subcooled flow boiling in helical coil is developed based on the experimental data, and it shows a good agreement with the experimental data.展开更多
The main drawback in the utilization of geothermal resources arises from the precipitation of secondary minerals within wells, pipelines, steam separators, turbines and other surface equipment in form of scales. Scale...The main drawback in the utilization of geothermal resources arises from the precipitation of secondary minerals within wells, pipelines, steam separators, turbines and other surface equipment in form of scales. Scale formation is an outcome of the alteration of various rocks dissolved in geothermal fluids that find their way into a reservoir. Once geothermal fluids ascend to the surface, hydrostatic pressure decreases toward a phase separation level that permits the dissolved gases such as CO<sub>2</sub>, H<sub>2</sub>S and H<sub>2</sub>, and steam to separate from the liquid phase by “boiling”. Stripping of these volatiles may increase fluid pH, leading to precipitation and deposition of secondary minerals. The study sought to establish the relationship between water-rock interaction and secondary mineral precipitates at the surface and deep fluid at different temperatures during depressurisation boiling and cooling. Samples were collected from selected Olkaria wells;OW-38A, OW-910 and OW-910A. The analysis of the results outlined deep fluid Alkali-Chloride waters and surface steam-heated Alkali-Bicarbonate and acidic Sulphate-Chloride waters. Various models suggested adiabatic boiling, conductive cooling and possible mixing and dilution in the wells. Hydrothermal alteration minerals were found to be in equilibrium with the geothermal fluids at varying temperatures, and the secondary minerals controlled the chemistry of the reservoir. Silica-saturated solutions precipitated silica in OW-910 and OW-910A, which may have resulted from rapid cooling following mixing with cold surface water.展开更多
Various enhanced surfaces have been proposed over the years to improve boiling heat transfer. This paper introduces an experimental setup designed for boiling demonstration in the graduate-level Heat Transfer course. ...Various enhanced surfaces have been proposed over the years to improve boiling heat transfer. This paper introduces an experimental setup designed for boiling demonstration in the graduate-level Heat Transfer course. The pool boiling performance of water under atmospheric pressure of 1.025 bar is investigated by using several structured surfaces at heat fluxes of 28 and 35 kW/m<sup>2</sup>. Surfaces with holes, rectangular grooves, and mushroom fins are manufactured by an NC-controlled vertical milling machine. The heat flux versus excess temperature graph is plotted by using thermocouple measurements of water and base temperatures of the boiling vessel. The separation, rise, and growth of individual vapor bubbles from the surface during boiling were recorded with a digital camera. The results for the plain surface are compared to the Rohsenow correlation. The enhancement of heat transfer coefficient (h) ranged between 15% - 44.5% for all structured surfaces. The highest heat transfer coefficient enhancement is observed between 41% - 56.5% for holed surface-3 (405 holes) compared to the plain surface. The excess temperature dropped around 29% - 34% for holed surface-3 (405 holes) compared to the plain surface. The heat transfer coefficient increases as the spacing between channels or holes decreases. While the bubbles on holed and mushroomed surfaces were spherical, the bubbles on the flat and grooved surfaces were observed as formless. The suggested economical test design could be appropriate to keep students focused and participating in the classroom.展开更多
Boiling processing is commonly used in post-harvest handling of White Paeony Root （WPR）, in order to whiten the herbal materials and preserve the bright color, since such WPR is empirically considered to possess a h...Boiling processing is commonly used in post-harvest handling of White Paeony Root （WPR）, in order to whiten the herbal materials and preserve the bright color, since such WPR is empirically considered to possess a higher quality. The present study was designed to investigate whether and how the boiling processing affects overall quality of WPR. First, an ultra-high performance liquid chromatography quadrupole/time-of-flight mass spectrometry-based metabolomics approach coupled with multivariate statistical analysis was developed to compare the holistic quality of boiled and un-boiled WPR samples. Second, ten major components in WPR samples boiled for different durations were quantitatively determined using high performance liquid chromatography to further explore the effects of boiling time on the holistic quality of WPR, meanwhile the appearance of the processed herbal materials was observed. The results suggested that the boiling processing conspicuously affected the holistic quality of WPR by simultaneously and inconsistently altering the chemical compositions and that short-time boiling processing between 2 and 10 rain could both make the WPR bright-colored and improve tile contents of major bioactive components, which were not achieved either without boiling or with prolonged boiling. In conclusion, short-term boiling （2-10 min） is recommended for post-harvest handling of WPR.展开更多
Inverse heat conduction method (IHCM) is one of the most effective approaches to obtaining the boiling heat transfer coefficient from measured results. This paper focuses on its application in cryogenic boiling heat t...Inverse heat conduction method (IHCM) is one of the most effective approaches to obtaining the boiling heat transfer coefficient from measured results. This paper focuses on its application in cryogenic boiling heat transfer. Experiments were conducted on the heat transfer of a stainless steel block in a liquid nitrogen bath, with the assumption of a 1D conduction condition to realize fast acquisition of the temperature of the test points inside the block. With the inverse-heat conduction theory and the explicit finite difference model, a solving program was developed to calculate the heat flux and the boiling heat transfer coefficient of a stainless steel block in liquid nitrogen bath based on the temperature acquisition data. Considering the oscillating data and some unsmooth transition points in the inverse-heat-conduction calculation result of the heat-transfer coefficient, a two-step data-fitting procedure was proposed to obtain the expression for the boiling heat transfer coefficients. The coefficient was then verified for accuracy by a comparison between the simulation results using this expression and the verifying experimental results of a stainless steel block. The maximum error with a revised segment fitting is around 6%, which verifies the feasibility of using IHCM to measure the boiling heat transfer coefficient in liquid nitrogen bath.展开更多
The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier tran...The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS). The acid class(heteroatom number), type(z numbers) and carbon number distributions were positively characterized. It was found out that the total acid number(TAN) of SL crude decreased after true boiling point distillation, and the abundance of O2 class in mass spectra was also found to be reduced from 67.6% to 34.5% in SL TBP mixed crude as measured by MS spectra, indicating to a potential carboxylic acid decomposition. However, it was interesting that the carboxylic acids type distribution in both oils was almost the same although their relative abundance in SL TBP mixed crude turned to be much lower, suggesting that various petroleum carboxylic acid types have the similar thermal decomposition reaction behavior. Furthermore, for each O2 type of acids in SL TBP mixed crude, the abundance of carboxylic acids with carbon number higher than 35 was reduced greatly, especially for those with carbon number higher than 60, the mass peaks of which were nearly totally removed, indicating that the large carboxylic acid molecules in heavy fractions decomposed more significantly because of longer heating time during the true boiling point distillation process. As a result, the reduction of TAN may be caused by the thermal decomposition of carboxylic acids especially those with high carbon number, suggesting that quick distillation or much lower pressure is required to avoid the thermal decomposition.展开更多
A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distr...A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distribution function.It could distinguish most of isomers that include cis-or trans-structure from organic compounds.Contributions for hydrocarbons and hydrocarbon derivatives containing oxygen,nitrogen,chlorine,bromine and sulfur,are given.Compared with the predictions,results made use of the most common existing group contribution methods,the overall average absolute difference of boiling point predictions of 417 organic compounds is 4.2 K;and the average absolute percent derivation is 1.0%,which is compared with 12.3 K and 3.2% with the method of Joback,12.1 K and 3.1% with the method of Constantinou-Gani.This new position contribution groups method is not only much more accurate but also has the advantages of simplicity and stability.展开更多
This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accur...This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accurately by connecting separate lubricant oil circuit with test section in parallel. It was built up by retrofitting a multiple air-conditioner and installing three oil-separators in serials at the compressor outlet. And so the lubricant oil in the discharged refrigerant gas of compressor can be removed completely.The refrigerant flow rate through test section can be bypassed by the by-path circuit of indoor unit.This experimental rig has advantages such as on-line and continuous oil injection, short time of obtaining stability, flexible operation, simple control, which lead to high efficiency in the research of flow boiling heat transfer of refrigerant and lubricant oil mixture.展开更多
Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of ca...Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate （CaCO3）, which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal （calcite and aragonite） are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.展开更多
Prediction of primary quality variables in real time with adaptation capability for varying process conditions is a critical task in process industries.This article focuses on the development of non-linear adaptive so...Prediction of primary quality variables in real time with adaptation capability for varying process conditions is a critical task in process industries.This article focuses on the development of non-linear adaptive soft sensors for prediction of naphtha initial boiling point(IBP)and end boiling point(EBP)in crude distillation unit.In this work,adaptive inferential sensors with linear and non-linear local models are reported based on recursive just in time learning(JITL)approach.The different types of local models designed are locally weighted regression(LWR),multiple linear regression(MLR),partial least squares regression(PLS)and support vector regression(SVR).In addition to model development,the effect of relevant dataset size on model prediction accuracy and model computation time is also investigated.Results show that the JITL model based on support vector regression with iterative single data algorithm optimization(ISDA)local model(JITL-SVR:ISDA)yielded best prediction accuracy in reasonable computation time.展开更多
基金supported by the National Natural Science Foundation of China(Project No.52166004)the National Key Research and Development Program of China(Project No.2022YFC3902000)+2 种基金the Major Science and Technology Special Project of Yunnan Province(Project Nos.202202AG050007202202AG050002)the Research on the Development of Complete Sets of Technology for Extraction of Aromatic Substances from Tobacco Waste and Its Application,Applied Research-Pyrolysis Process Technology Research(2023QT01).
文摘In modern engineering,enhancing boiling heat transfer efficiency is crucial for optimizing energy use and several industrial processes involving different types of materials.This study explores the enhancement of pool boiling heat transfer potentially induced by combining perforated copper particles on a heated surface with a sodium dodecyl sulfate(SDS)surfactant in saturated deionized water.Experiments were conducted at standard atmospheric pressure,with heat flux ranging from 20 to 100 kW/m2.The heating surface,positioned below the layer of freely moving copper beads,allowed the particle layer to shift due to liquid convection and steam nucleation.The study reports on the influence of copper bead diameter(2,3,4,and 5 mm),particle quantity,arrangement,and SDS concentration(20,200,and 500 ppm).It is shown that the combination of 5 mm particles and a 500 ppm SDS concentration can yield a remarkable 139%improvement in heat transfer efficiency.As demonstrated by direct flow visualization,bubble formation occurs primarily in the gaps between the particles and the heated surface,with the presence of SDS reducing bubble size and accelerating bubble detachment.
基金supported by the National Natural Science Foundation of China(Grant No.52306026)the State Key Laboratory of Air-Conditioning Equipment and System Energy Conservation Open Project(Project No.ACSKL2021KT01)The APC was covered by the Special Innovation Project Fund of the the State Key Laboratory of Air-Conditioning Equipment and System Energy Conservation Open Project(Project No.ACSKL2021KT01).
文摘This study investigates the flow boiling heat transfer coefficient and pressure gradient of refrigerant R410A inmicro-channel flat tubes.Experiments were conducted at saturation temperatures ranging from 25℃ to 30℃,mass fluxes between 198 and 305 kg/m^(2)s,and heat fluxes from 9.77 to 20.18 kW/m^(2),yielding 99 sets of local heat transfer coefficient data.The results show that increasing heat flux and mass flux enhances the heat transfer coefficient,although the rate of enhancement decreases with increasing vapor quality.Conversely,higher saturation temperatures slightly reduce the heat transfer coefficient.Additionally,the experimental findings reveal discrepancies in the accuracy of existing pressure drop and heat transfer coefficient prediction models under the studied conditions.This study recommends using the Kimand Mudawar correlation to predict pressure gradients within the tested range,with aMean Error(ME)of−5.24%observed in this study.For heat transfer coefficients,the Cooper and Kandlikar correlations are recommended,achieving a Mean Absolute Error(MAE)of approximately 22%.This research provides value for performance prediction and parameter selection of micro-channel technology in broader application scenarios within heating,ventilation and air-conditioning fields.
基金supported by the Beijing Municipal Science&Technology Commission(Z231100006123010).
文摘In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 kg/(m2 s),saturation temperatures of 293,298,and 303 K,and inlet sub-cooling of 5,10,and 15 K.The analysis of the experimental results provides the following conclusions:a reduced mass flux and lower subcooling correspond to a diminished degree of superheat at the boiling inception wall;conversely,an elevated saturation temperature results in a reduced amount of superheat at the boiling inception wall.Furthermore,an increase in sub-cooling and saturation temperature will enhance heat transfer efficiency.The wall temperature is mostly influenced by variations in saturation temperature and is minimally related to changes in mass flux and subcooling degree.An increase in mass flux results in a greater pressure drop attributed to heightened frictional pressure loss.The variation in pressure drop with respect to sub-cooling is minimal,while an increased saturation temperature correlates with a reduced pressure drop due to the formation of smaller bubbles and lowered frictional pressure loss at high saturation pressures.This study thoroughly examines and summarizes the effects of mass flow rate,saturation temperature,and subcooling on the flow-boiling heat transfer and pressure drop characteristics of R1234yf.Furthermore,the new correlation has 93.42%of the predicted values fall within a 15%mean absolute error,exhibiting a mean absolute error of 5.75%.It provides a superior method for predicting the flow-boiling heat transfer coefficients of R1234yf in the heat sink of parallel microchannels compared to existing correlations.
基金funded by the National Natural Science Foundation of China(Grant No.52276047)the Open Fund of NationalKey Laboratory of SpacecraftThermal Control(Grant No.NKLST-JJ-202401011)the Beijing Municipal Science&Technology Commission(Grant No.Z231100006123010).
文摘Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.However,the continuous rise in power density of electronic components imposesmore stringent requirements on the heat transfer capability of microchannel flow boiling.HFE-7100,a dielectric coolant with favorable thermophysical properties,has become a focal point of research for enhancing flow boiling performance in open microchannels.The flow boiling heat transfer performance ofHFE-7100 was investigated in this study by fabricating micro-nano composite structures on the bottom surface of open microchannels using laser ablation technology.Based on visualization results,a comparative analysis was conducted on the bubble dynamics and flow pattern characteristics of HFE-7100 flow boiling in micronano structured open microchannels(MNSOMC)and smooth-surface open microchannels(SSOMC),to elucidate the enhancement mechanism of micro-nano structures on flow boiling heat transfer in open microchannels.The results indicate that the surface structures and strong wettability of MNSOMC accelerated bubble nucleation and departure.Moreover,bubbles in the channel tended to coalesce along the flow direction,forming elongated slug bubbles with high aspect ratios,which enabled efficient thin film evaporation in conjunction with intense nucleate boiling,thereby significantly enhancing flow boiling heat transfer.Under the experimental conditions of this study,the maximum enhancements in the heat transfer coefficient(HTC)and critical heat flux(CHF)of HFE-7100 inMNSOMC were 33.4%and 133.1%,respectively,with the CHF reaching up to 1542.3 kW⋅m^(−2).Furthermore,due to the superior wettability and capillary wicking capability of the micro-nano composite structures,the significant enhancement in flow boiling heat transfer was achieved without incurring a noticeable pressure drop penalty.
基金supported by the National Natural Science Foundation of China(Project No.52166004)the National Key Research and Development Program of China(Project No.2022YFC3902000)the Major Science and Technology Special Project of Yunnan Province(Project Nos.202202AG050007,202202AG050002).
文摘This research explores the characteristics of boiling in inclined pipes,a domain of great importance in engineering.Employing an experimental visualization technique,the boiling dynamics of deionizedwater are examined at varying inclination angles,paying special attention to the emerging flow patterns.The findings demonstrate that the inclination angle significantly impacts flow pattern transitions within the 0°to 90°range.As the heat flux rises,bubbles form in the liquid.The liquid’s inertia extends the bubble-wall contact time,thereby delaying the onset of bulk bubble flow.Beyond a 90°inclination,however,the patterning behavior is more influenced by the fluid velocity.At low speeds,incomplete pipe filling results in a large liquid plug hindering flow,while high speeds lead to full pipe filling.In general,gravity,inertia,buoyancy forces,and capillary forces are themain influential factors in the considered problem.However,an analysis of the heat transfer coefficient and boiling curve for different inclination angles reveals that the observed variations are essentially due to corresponding changes in the flow pattern.Finally,an optimal mass flux and inclination angle,able to minimize total entropy generation and improve heat transfer efficiency,are determined by means of an entropy generation analysis.
基金The National Natural Science Foundation of China(No.50776055,51076084)
文摘Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of the geometric and system parameters on heat transfer characteristics in helically coiled tubes are investigated by collecting large amounts of experimental data and analyzing the heat transfer mechanisms. The existing correlations are divided into two categories,and they are calculated with the experimental data.The Dn factor is introduced to take into account the effect of a complex geometrical structure on flow boiling heat transfer.A new correlation is developed for predicting the flow boiling heat transfer coefficients in the helically coiled tubes,which is validated by the experimental data of R134a flow boiling heat transfer in them;and the average relative error and root mean square error of the new correlation are calculated.The results show that the new correlation agrees well with the experimental data,indicating that the new correlation can be used for predicting flow boiling heat transfer characteristics in the helically coiled tubes.
基金The National Natural Science Foundation of China(No.50706012)
文摘Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles with deionized water as a medium are experimentally studied at atmospheric and sub-atmospheric pressures,respectively.The experimental results indicate that the boiling heat transfer coefficients of the two types of tube bundles increase with the increase in pressure under vacuum conditions as they behave under ordinary pressure.As the pressure varies from 10 to 100 kPa,it also can be seen that the heat transfer coefficient of the sintered porous surface tube is increased by 0.2 to 4 times compared with the smooth one under the same operating parameters.In addition,the experimental data show that a definite bundle effect exists in both sintered porous surface tubes and smooth tubes under vacuum conditions.
基金This study was sponsored by the Research Funding for Key Laboratory of Cellulose and Ligno cellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences (No. LCLC-2004-158)the National Natural Science Foundation of Fujian(No. Z0513015)
文摘Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.
基金Century Programme of Chinese Academy of Sciences.
文摘Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients.
基金the National Natural Science Foundation of China(No.51376119)
文摘Compared with port fuel injection engines, direct injection(DI) gasoline engine is becoming the mainstream of gasoline engines because of its higher fuel economy and excellent transient response. It has been proven that fuel spray characteristics in DI engines are crucial to the performance and emission quality of the engine. Flash boiling spray has great potential to achieve high fuel economy and low emission by dramatically improving the fuel atomization and vaporization and it has different spray-air interaction behavior as compared with non-flash boiling one, while its mechanism is more complex as compared with subcooled spray. We investigate the time-resolved spatial velocity field of the spray using 2-camera high-speed 3 D3 C(3-dimension 3-component)tomographic particle image velocimetry(PIV) diagnostic technique. A 10 mm thick laser sheet is used to illuminate the fuel spray. Characteristics of both non-flash and flash boiling sprays are studied. A single-hole injector is mounted within a heat exchanger so that different fuel temperature can be accessed. In the experiment, n-pentane is used as the fuel. For the non-flash boiling spray, the velocity field of the liquid spray is mostly consistent to the injection direction. With the increase of the degree of superheat(Do S), the overall velocity scale decreases especially at the spray tip. Meanwhile, larger swirls occur at the lower part of the flash boiling spray, which means stronger spray-air interaction occurs at a higher Do S.
基金The National Natural Science Foundation of China(No.50776055,51076084)the Natural Science Foundation of Shandong Province(No.ZR2016YL005)
文摘The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet subcooling from 4.7 to 15.0℃, heat flux from 0.11 to 8.9 kW/m2 and mass flux from 218. 2 to 443. 7 kg/（ m2 · s ）. The heat flux, superheat and temperature undershoot at the ONB are analyzed in vertical helically-coiled tubes. Also, the effects of mass flux, system pressure, inlet subcooling and geometric parameters on the ONB are studied. The results demonstrate that the inception heat flux and superheat increase with increasing mass flux and inlet subcooling, but decrease with increasing system pressure and helix diameter. The pitch of the helical coil has a slight effect on the wall superheat and heat flux at the ONB. The correlation of heat flux at the ONB of subcooled flow boiling in helical coil is developed based on the experimental data, and it shows a good agreement with the experimental data.
文摘The main drawback in the utilization of geothermal resources arises from the precipitation of secondary minerals within wells, pipelines, steam separators, turbines and other surface equipment in form of scales. Scale formation is an outcome of the alteration of various rocks dissolved in geothermal fluids that find their way into a reservoir. Once geothermal fluids ascend to the surface, hydrostatic pressure decreases toward a phase separation level that permits the dissolved gases such as CO<sub>2</sub>, H<sub>2</sub>S and H<sub>2</sub>, and steam to separate from the liquid phase by “boiling”. Stripping of these volatiles may increase fluid pH, leading to precipitation and deposition of secondary minerals. The study sought to establish the relationship between water-rock interaction and secondary mineral precipitates at the surface and deep fluid at different temperatures during depressurisation boiling and cooling. Samples were collected from selected Olkaria wells;OW-38A, OW-910 and OW-910A. The analysis of the results outlined deep fluid Alkali-Chloride waters and surface steam-heated Alkali-Bicarbonate and acidic Sulphate-Chloride waters. Various models suggested adiabatic boiling, conductive cooling and possible mixing and dilution in the wells. Hydrothermal alteration minerals were found to be in equilibrium with the geothermal fluids at varying temperatures, and the secondary minerals controlled the chemistry of the reservoir. Silica-saturated solutions precipitated silica in OW-910 and OW-910A, which may have resulted from rapid cooling following mixing with cold surface water.
文摘Various enhanced surfaces have been proposed over the years to improve boiling heat transfer. This paper introduces an experimental setup designed for boiling demonstration in the graduate-level Heat Transfer course. The pool boiling performance of water under atmospheric pressure of 1.025 bar is investigated by using several structured surfaces at heat fluxes of 28 and 35 kW/m<sup>2</sup>. Surfaces with holes, rectangular grooves, and mushroom fins are manufactured by an NC-controlled vertical milling machine. The heat flux versus excess temperature graph is plotted by using thermocouple measurements of water and base temperatures of the boiling vessel. The separation, rise, and growth of individual vapor bubbles from the surface during boiling were recorded with a digital camera. The results for the plain surface are compared to the Rohsenow correlation. The enhancement of heat transfer coefficient (h) ranged between 15% - 44.5% for all structured surfaces. The highest heat transfer coefficient enhancement is observed between 41% - 56.5% for holed surface-3 (405 holes) compared to the plain surface. The excess temperature dropped around 29% - 34% for holed surface-3 (405 holes) compared to the plain surface. The heat transfer coefficient increases as the spacing between channels or holes decreases. While the bubbles on holed and mushroomed surfaces were spherical, the bubbles on the flat and grooved surfaces were observed as formless. The suggested economical test design could be appropriate to keep students focused and participating in the classroom.
基金supported by a special fund of China State Administration of Traditional Chinese Medicine(No.201307008-2)National High Technology Research and Development Plan of China(863 Plain)(No.2014AA022204)+1 种基金Jiangsu Province Six Talent Project(YY-007)Jiangsu Branch of China Academy of Chinese Medical Science(No.JSBN1301)
文摘Boiling processing is commonly used in post-harvest handling of White Paeony Root （WPR）, in order to whiten the herbal materials and preserve the bright color, since such WPR is empirically considered to possess a higher quality. The present study was designed to investigate whether and how the boiling processing affects overall quality of WPR. First, an ultra-high performance liquid chromatography quadrupole/time-of-flight mass spectrometry-based metabolomics approach coupled with multivariate statistical analysis was developed to compare the holistic quality of boiled and un-boiled WPR samples. Second, ten major components in WPR samples boiled for different durations were quantitatively determined using high performance liquid chromatography to further explore the effects of boiling time on the holistic quality of WPR, meanwhile the appearance of the processed herbal materials was observed. The results suggested that the boiling processing conspicuously affected the holistic quality of WPR by simultaneously and inconsistently altering the chemical compositions and that short-time boiling processing between 2 and 10 rain could both make the WPR bright-colored and improve tile contents of major bioactive components, which were not achieved either without boiling or with prolonged boiling. In conclusion, short-term boiling （2-10 min） is recommended for post-harvest handling of WPR.
基金supported by the National Natural Sciences Foundation of China (No. 50776075)
文摘Inverse heat conduction method (IHCM) is one of the most effective approaches to obtaining the boiling heat transfer coefficient from measured results. This paper focuses on its application in cryogenic boiling heat transfer. Experiments were conducted on the heat transfer of a stainless steel block in a liquid nitrogen bath, with the assumption of a 1D conduction condition to realize fast acquisition of the temperature of the test points inside the block. With the inverse-heat conduction theory and the explicit finite difference model, a solving program was developed to calculate the heat flux and the boiling heat transfer coefficient of a stainless steel block in liquid nitrogen bath based on the temperature acquisition data. Considering the oscillating data and some unsmooth transition points in the inverse-heat-conduction calculation result of the heat-transfer coefficient, a two-step data-fitting procedure was proposed to obtain the expression for the boiling heat transfer coefficients. The coefficient was then verified for accuracy by a comparison between the simulation results using this expression and the verifying experimental results of a stainless steel block. The maximum error with a revised segment fitting is around 6%, which verifies the feasibility of using IHCM to measure the boiling heat transfer coefficient in liquid nitrogen bath.
基金financially supported by the National Key Basic Research Development Program "973" Project (2006CB202501)
文摘The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS). The acid class(heteroatom number), type(z numbers) and carbon number distributions were positively characterized. It was found out that the total acid number(TAN) of SL crude decreased after true boiling point distillation, and the abundance of O2 class in mass spectra was also found to be reduced from 67.6% to 34.5% in SL TBP mixed crude as measured by MS spectra, indicating to a potential carboxylic acid decomposition. However, it was interesting that the carboxylic acids type distribution in both oils was almost the same although their relative abundance in SL TBP mixed crude turned to be much lower, suggesting that various petroleum carboxylic acid types have the similar thermal decomposition reaction behavior. Furthermore, for each O2 type of acids in SL TBP mixed crude, the abundance of carboxylic acids with carbon number higher than 35 was reduced greatly, especially for those with carbon number higher than 60, the mass peaks of which were nearly totally removed, indicating that the large carboxylic acid molecules in heavy fractions decomposed more significantly because of longer heating time during the true boiling point distillation process. As a result, the reduction of TAN may be caused by the thermal decomposition of carboxylic acids especially those with high carbon number, suggesting that quick distillation or much lower pressure is required to avoid the thermal decomposition.
文摘A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distribution function.It could distinguish most of isomers that include cis-or trans-structure from organic compounds.Contributions for hydrocarbons and hydrocarbon derivatives containing oxygen,nitrogen,chlorine,bromine and sulfur,are given.Compared with the predictions,results made use of the most common existing group contribution methods,the overall average absolute difference of boiling point predictions of 417 organic compounds is 4.2 K;and the average absolute percent derivation is 1.0%,which is compared with 12.3 K and 3.2% with the method of Joback,12.1 K and 3.1% with the method of Constantinou-Gani.This new position contribution groups method is not only much more accurate but also has the advantages of simplicity and stability.
文摘This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accurately by connecting separate lubricant oil circuit with test section in parallel. It was built up by retrofitting a multiple air-conditioner and installing three oil-separators in serials at the compressor outlet. And so the lubricant oil in the discharged refrigerant gas of compressor can be removed completely.The refrigerant flow rate through test section can be bypassed by the by-path circuit of indoor unit.This experimental rig has advantages such as on-line and continuous oil injection, short time of obtaining stability, flexible operation, simple control, which lead to high efficiency in the research of flow boiling heat transfer of refrigerant and lubricant oil mixture.
基金Supported by the Special Funds for Major State Basic Research Projects of China (G2000026304)
文摘Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate （CaCO3）, which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal （calcite and aragonite） are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.
文摘Prediction of primary quality variables in real time with adaptation capability for varying process conditions is a critical task in process industries.This article focuses on the development of non-linear adaptive soft sensors for prediction of naphtha initial boiling point(IBP)and end boiling point(EBP)in crude distillation unit.In this work,adaptive inferential sensors with linear and non-linear local models are reported based on recursive just in time learning(JITL)approach.The different types of local models designed are locally weighted regression(LWR),multiple linear regression(MLR),partial least squares regression(PLS)and support vector regression(SVR).In addition to model development,the effect of relevant dataset size on model prediction accuracy and model computation time is also investigated.Results show that the JITL model based on support vector regression with iterative single data algorithm optimization(ISDA)local model(JITL-SVR:ISDA)yielded best prediction accuracy in reasonable computation time.
