Fluorescence detecting both organic and inorganic analytes has aroused tremendous scientific interests, because fluorescence techniques have high sensitivity and are easy to operate. A new threedimensional(3D) MOF {[(...Fluorescence detecting both organic and inorganic analytes has aroused tremendous scientific interests, because fluorescence techniques have high sensitivity and are easy to operate. A new threedimensional(3D) MOF {[(CH_(3))_(2)NH_(2)][Zn_(3)(bbip)(BTDI)1.5(OH)]·DMF·MeOH·3H_(2)O}n(JXUST-13, bbip = 2,6-bis(benzimidazol-1-yl)pyridine and H_(4)BTDI = 5,5-(benzo[c][1,2,5]thiadiazole-4,7-diyl)diisophthalic acid)with new 4,4,8-connceted topology has been successfully synthesized and structurally characterized. Importantly, JXUST-13 could recognize H_(2)PO_(4)-and acetylacetone(Acac) by obvious fluorescence blue shift and slight enhancement with the detection limits of 2.70 μmol/L and 0.21 mmol/L, respectively. In addition, JXUST-13 exhibits relatively good thermal stability, chemical stabilities as well as reusability, and the analytes could be distinguished by naked eye and fluorescence test paper. Remarkably, JXUST-13 is the first dual-responsive MOF sensor based on fluorescence blue shift for the detection of H_(2)PO_(4)-and Acac with good selectivity in a handy, economic, and environmentally friendly manner.展开更多
There are many blue shifted Galaxies in our universe. Here we will see old simulations to make such predictions from the output graphs using SITA simulations. There are four new simulations also presented here. In the...There are many blue shifted Galaxies in our universe. Here we will see old simulations to make such predictions from the output graphs using SITA simulations. There are four new simulations also presented here. In these sets of simulations, different point masses are placed in different distances in a 3D Cartesian coordinate grid;and these point masses are allowed to move on universal gravitation force (UGF) acting on each mass at that instant of time at its position. The output pictures depict the three dimensional orbit formations of point masses after some iterations. In an orbit so formed, some Galaxies are coming near (Blue shifted) and some are going away (Red shifted). In this paper, the simulations predicted the existence of a large number of Blue shifted Galaxies, in an expanding universe, in 2004 itself. Over 8300 blue shifted galaxies have been discovered extending beyond the Local Group by Hubble Space Telescope (HST) in the year 2009. Thus Dynamic Universe model predictions came true.展开更多
Experiment on quantum well intermixing (QWI) of InGaAsP QWs by impurity free vacancy diffusion (IFVD) using SiO 2 encapsulation is reported.A maximum band gap wavelength blue shift as large as 200nm is realized.Furt...Experiment on quantum well intermixing (QWI) of InGaAsP QWs by impurity free vacancy diffusion (IFVD) using SiO 2 encapsulation is reported.A maximum band gap wavelength blue shift as large as 200nm is realized.Furthermore,an FP laser blue shifted 21nm by QWI is fabricated with characteristics comparable with the as grown one.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 22061019, 21861018, 22161019 and 12174172)the NSF of Jiangxi Province (No. 20202ACBL213001)+4 种基金Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry(No. 20212BCD42018)Fujian Key Laboratory of Functional Marine Sensing Materials,Minjiang University (No. MJUKF-FMSM202010)the Youth Jinggang Scholars Program in Jiangxi Province (No.QNJG2019053)the Two Thousand Program in Jiangxi Province (No.jxsq2019201068)the Special Foundation for Postgraduate Innovation in Jiangxi Province (No. YC_(2)020-B155)。
文摘Fluorescence detecting both organic and inorganic analytes has aroused tremendous scientific interests, because fluorescence techniques have high sensitivity and are easy to operate. A new threedimensional(3D) MOF {[(CH_(3))_(2)NH_(2)][Zn_(3)(bbip)(BTDI)1.5(OH)]·DMF·MeOH·3H_(2)O}n(JXUST-13, bbip = 2,6-bis(benzimidazol-1-yl)pyridine and H_(4)BTDI = 5,5-(benzo[c][1,2,5]thiadiazole-4,7-diyl)diisophthalic acid)with new 4,4,8-connceted topology has been successfully synthesized and structurally characterized. Importantly, JXUST-13 could recognize H_(2)PO_(4)-and acetylacetone(Acac) by obvious fluorescence blue shift and slight enhancement with the detection limits of 2.70 μmol/L and 0.21 mmol/L, respectively. In addition, JXUST-13 exhibits relatively good thermal stability, chemical stabilities as well as reusability, and the analytes could be distinguished by naked eye and fluorescence test paper. Remarkably, JXUST-13 is the first dual-responsive MOF sensor based on fluorescence blue shift for the detection of H_(2)PO_(4)-and Acac with good selectivity in a handy, economic, and environmentally friendly manner.
文摘There are many blue shifted Galaxies in our universe. Here we will see old simulations to make such predictions from the output graphs using SITA simulations. There are four new simulations also presented here. In these sets of simulations, different point masses are placed in different distances in a 3D Cartesian coordinate grid;and these point masses are allowed to move on universal gravitation force (UGF) acting on each mass at that instant of time at its position. The output pictures depict the three dimensional orbit formations of point masses after some iterations. In an orbit so formed, some Galaxies are coming near (Blue shifted) and some are going away (Red shifted). In this paper, the simulations predicted the existence of a large number of Blue shifted Galaxies, in an expanding universe, in 2004 itself. Over 8300 blue shifted galaxies have been discovered extending beyond the Local Group by Hubble Space Telescope (HST) in the year 2009. Thus Dynamic Universe model predictions came true.
文摘Experiment on quantum well intermixing (QWI) of InGaAsP QWs by impurity free vacancy diffusion (IFVD) using SiO 2 encapsulation is reported.A maximum band gap wavelength blue shift as large as 200nm is realized.Furthermore,an FP laser blue shifted 21nm by QWI is fabricated with characteristics comparable with the as grown one.
