The mixed-quadriligand bismuth complex [Bi(S2CNEt2)2(NO3)]?[1,10-Phen] has been synthesized, and its crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic, space gro...The mixed-quadriligand bismuth complex [Bi(S2CNEt2)2(NO3)]?[1,10-Phen] has been synthesized, and its crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P21/n with a = 10.074(17), b = 15.05(2), c = 18.99(3) ?, β = 98.85(3)o, V = 2845(8) ?3, Z = 4, F(000) = 1464, Dc = 1.746 g/cm3, μ = 6.523 mm-1, R = 0.0333 and wR = 0.0703. In this complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry.展开更多
Antibiotic resistance is one of the major issues in the medical field and a potential threat to human health.However,newly emerging antimicrobial compounds failed to combat antimicrobial resistance developed by bacter...Antibiotic resistance is one of the major issues in the medical field and a potential threat to human health.However,newly emerging antimicrobial compounds failed to combat antimicrobial resistance developed by bacterial pathogens.Recently,a bismuth-based complex has been developed to eradicate antimicrobial-resistant microorganism infections.The complex is known as organobismuth(III)phosphinate,which is said to be a potential broad-spectrum antimicrobial agent.This complex has been incorporated into the nanocellulose suspension to fabricate a biomedical composite for various applications.The composite can be fabricated by two methods namely vacuum filtration and spray coating.In this paper,the surface and topography of the composite are investigated and discussed in terms of SEM micrographs and their antimicrobial potential.This review focuses on the organo-bismuth nanocellulose composite and its biomedical application in the future.展开更多
Under hydrothermal conditions,isonicotinic acid reacted with BiCl 3 to give 1D zigzag chain complex [（C 6 H 6 NO 2） 2 ·（BiCl 5）·2H 2 O] n （1）.Single-crystal X-ray determination shows that compound 1 cr...Under hydrothermal conditions,isonicotinic acid reacted with BiCl 3 to give 1D zigzag chain complex [（C 6 H 6 NO 2） 2 ·（BiCl 5）·2H 2 O] n （1）.Single-crystal X-ray determination shows that compound 1 crystal-lizes in the monoclinic system,space group C2/c with a=13.115（3）,b=19.957（4）,c=7.9374（16）,β=97.45（3）°,Z=4,V=2060.0（8） 3,C 12 H 16 BiCl 5 N 2 O 6,D c=2.162 g/cm 3,M r=670.50,λ（MoKa）=0.71073,μ=9.237 mm-1,F（000）=1272,R=0.0208 and wR=0.0503.Dielectric constant of compound 1 was measured at different conditions.Measurements on the dielectric properties of 1 showed that the 1D chain coordination polymer exhibited a dipolar chain relaxation process and a relatively high dielectric constant.展开更多
A novel dimer of the bismuth(Ⅲ) complex with dithiotetrahydropyrrolocarbamate, [Bi(S_2CNC_4H_8)_2·(NO_3)]_2, was synthesized and the crystal structure was determined by X-ray single crystal diffraction. The crys...A novel dimer of the bismuth(Ⅲ) complex with dithiotetrahydropyrrolocarbamate, [Bi(S_2CNC_4H_8)_2·(NO_3)]_2, was synthesized and the crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to a monoclinic system with space group P2_1/n, a=0.64718(13) nm, b=2.6738(6) nm, c=1.0423(2) nm, β=106.384(3)°, Z=4, V=1.730(3) nm^3, D_c=2.163 g/cm^3, μ=10.682 mm^(-1), F(000)=1072, R=0.0329, wR=0.0659. The structure shows a distorted pentagonal bipyramidal configuration with the seven-coordinated central Bi atom. In the crystal, the molecular packing in the unit cell reveals that the two adjacent molecules are symmetrically linked each other in the dimer by virtue of a couple of Bi-S interaction.展开更多
The photocatalytic degradation on the bismuth containing complex oxide was revised in detail including the synthesis and classification of photocatalyts, and then the photocatalytic reaction, scavenger, and the mechan...The photocatalytic degradation on the bismuth containing complex oxide was revised in detail including the synthesis and classification of photocatalyts, and then the photocatalytic reaction, scavenger, and the mechanism of reaction. In particular, the perspectives of photocatalytic degradation on the bismuth containing oxide were analyzed in detail.展开更多
A bismuth（Ⅲ） complex 1 （H2-4,4＇-bipy）[Bi（HPPA）5]（H2PPA）.4H2O （H2PPA = p- hydroxy- phenylacetic acid, 4,4＇-bipy = 4,4＂-bipyridyl） was hydrothermally synthesized from p-hydroxy-phenylacetic acid （H2PPA）,...A bismuth（Ⅲ） complex 1 （H2-4,4＇-bipy）[Bi（HPPA）5]（H2PPA）.4H2O （H2PPA = p- hydroxy- phenylacetic acid, 4,4＇-bipy = 4,4＂-bipyridyl） was hydrothermally synthesized from p-hydroxy-phenylacetic acid （H2PPA）, Bi（NO3）3＂6H20 and 4,4＇-bipyridyl, and characterized by elemental analysis, IR, molar conductivity and TG. The single-crystal X-ray diffraction studies demonstrated that the complex is of monoclinic system, space group P21 with a = 10.928（7）, b = 22.558（7）, c = 11.313（7） A, β = 91.864（4）°, V = 2787.7（4） A3, Z = 2, C58H61BiN2O22, Mr = 1347.07, F（000） = 1364, Dc= 1.605 g/cm-3, p（MoKa） = 3.247 mm-1, the final R = 0.0269 and wR = 0.0540 for 9776 observed reflections with I 〉 2or（I）. The bismuth（I/I） is seven-coordinated with O atoms, forming a monocapped octahedral geometry. Complex 1 further forms a 3D supramolecular architecture by hydrogen bonds and π-π stacking interactions. Moreover, the interaction between the complex and DNA was studied by EtBr fluoescent probe.展开更多
Two novel complexes, [Bi（III）（S2CNBn Et）3] 1 and [Bi（III）（S2CNPPPy-2）3] 2, were synthesized and characterized by elemental analysis, IR, ^1H NMR, ^13C NMR, TG-DTG and X-ray single-crystal diffraction. The stru...Two novel complexes, [Bi（III）（S2CNBn Et）3] 1 and [Bi（III）（S2CNPPPy-2）3] 2, were synthesized and characterized by elemental analysis, IR, ^1H NMR, ^13C NMR, TG-DTG and X-ray single-crystal diffraction. The structure reveals that complex 1 belongs to the monoclinic system, space group P21/c with a = 11.457（5）, b = 17.437（8）, c = 33.439（14）, β= 98.499（8）o, Z = 4, V = 6607（5）3, Dc = 1.689 g·cm^-3, F（000） = 3328, μ= 5.742 mm^-1, the final R = 0.0906, w R = 0.1678 and S = 1.032. The structure indicates that complex 2 belongs to the triclinic system, space group P1 with a = 12.608（9）, b = 12.622（8）, c = 12.49（6）, α = 102.652（15）, β = 103.013（14）, γ = 109.698（10）o, Z = 1, V = 1762.3（19）3, Dc = 1.741 g·cm^-3, F（000） = 916, μ = 5.395 mm^-1, the final R = 0.048 2, w R = 0.1206 and S =1.046. In the two complexes, each six-coordinated Bi（III） atom adopts a pentagonal pyramidal configuration with six sulfur atoms from three ligands, and the dimmer structures are formed by weak interactions of Bi···S between two molecules. The anticancer activities of the two complexes were studied by evaluating their cytotoxicities against several human cancer cell lines using the MTT assay. Results indicated complex 2 showed moderate cytotoxic effects on the selected cancer cells.展开更多
Two novel complexes,[（C9H18NS2）3Sb（III）]（1） and [（C9H18NS2）3Bi（III）]（2）,were synthesized and characterized by elemental analysis,IR,TG and X-ray single-crystal diffraction.Both 1 and 2 crystallize in the m...Two novel complexes,[（C9H18NS2）3Sb（III）]（1） and [（C9H18NS2）3Bi（III）]（2）,were synthesized and characterized by elemental analysis,IR,TG and X-ray single-crystal diffraction.Both 1 and 2 crystallize in the monoclinic system,P21/c space group.The data for 1：a = 1.6964（3）,b = 1.02149（17）,c = 2.5650（3） nm,β = 121.824（8）°,Z = 4,V = 3.7766（10） nm^3,Dc = 1.293 g·cm^-3,F（000） = 1536,μ = 1.082 mm^-1,the final R = 0.0500,wR = 0.1562 and S =1.072.The data for 2：a = 1.6802（9）,b = 1.0256（6）,c = 2.5083（10） nm,β = 121.77（3）°,Z = 4,V = 3.675（3） nm^3,Dc = 1.486 g·cm^-3,F（000） = 1664,μ = 5.159 mm^-1,the final R = 0.0481,wR = 0.1055 and S =1.076.The coordinated geometry of the central M（III） with six sulfur atoms from three ligands is a distorted pentagonal pyramid configuration.The dimer structural system is formed by the weak interactions of M…S and C-H…S between two molecules.The complexes were valued for their antibacterial activities by agar-streak method.It was found that 1 is active against the four test bacterial organisms.展开更多
The main focus of the research was to correlate the microstructure with dielectric and magnetic properties of Bi1-xBaxFeO3 samples. Bi1-xBaxFeO3 samples（x = 0.1, 0.2 and 0.3） were synthesized by the conventional sol...The main focus of the research was to correlate the microstructure with dielectric and magnetic properties of Bi1-xBaxFeO3 samples. Bi1-xBaxFeO3 samples（x = 0.1, 0.2 and 0.3） were synthesized by the conventional solid-state reaction method using nano-powders of Bi2O3, Fe2O3, and BaCO3. Thereafter, field emission scanning electron microscope and X-ray diffraction（XRD） techniques were used to examine the structure and phase of the samples. Phase analysis by XRD indicated that the single-phase perovskite structure was formed with possible increment in lattice parameter with increasing Ba doping. Complex permeability（u＇iand u＇＇i） measured using impedance analyzer confirmed the increase in magnetic property with increasing Ba doping. Finally, dielectric constant（k） was analyzed as a function of temperature at different frequencies. Dielectric constant as high as 2900 was attained in this research for Bi0.8Ba0.2FeO3 sample due to reduction in leakage current at this composition.展开更多
The polargraphic behavior of Bi(Ⅲ)-NOTP complex has been investigated inaqueous solution. It was found that under the conditions of pH 3.0 and of 0.02 mol/L NH_4Cl, theBi(Ⅲ)-NOTP system gives a sensitive second orde...The polargraphic behavior of Bi(Ⅲ)-NOTP complex has been investigated inaqueous solution. It was found that under the conditions of pH 3.0 and of 0.02 mol/L NH_4Cl, theBi(Ⅲ)-NOTP system gives a sensitive second order derivative wave at -0.340 V(vs SCE), which isproved to be an adsorptive complex wave. The composition of the complex is Bi(Ⅲ):NOTP. Furthermore,the peak current is linear to the concentration of Bi(Ⅲ) in the range from 3.0x10^(-8) to5.0x10^(-6) mol/L. Artificial and practical samples have been detected with high sensitivity andreceptivity.展开更多
A new solid bismuth complex,[C9H8ON]3·2H2O,was synthesized by bismuth trichloride and 8-hydroxyquinoline(8-Hhq) in dilute HCl.The complex was characterized by elemental analysis,XRD,TG-DSC and FT-IR.The IR result...A new solid bismuth complex,[C9H8ON]3·2H2O,was synthesized by bismuth trichloride and 8-hydroxyquinoline(8-Hhq) in dilute HCl.The complex was characterized by elemental analysis,XRD,TG-DSC and FT-IR.The IR result shows that the heterocyclic nitrogen atom of 8Hhq bonds to H+,and coordinates with Bi3+.The fluorescent spectra and UV-Vis spectra of the title compound were carried out.展开更多
基金This project was supported by the National Natural Science Foundation of China (No. 20271025) and Natural Science Foundation of Shandong Province (No. L2003B01)
文摘The mixed-quadriligand bismuth complex [Bi(S2CNEt2)2(NO3)]?[1,10-Phen] has been synthesized, and its crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P21/n with a = 10.074(17), b = 15.05(2), c = 18.99(3) ?, β = 98.85(3)o, V = 2845(8) ?3, Z = 4, F(000) = 1464, Dc = 1.746 g/cm3, μ = 6.523 mm-1, R = 0.0333 and wR = 0.0703. In this complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry.
文摘Antibiotic resistance is one of the major issues in the medical field and a potential threat to human health.However,newly emerging antimicrobial compounds failed to combat antimicrobial resistance developed by bacterial pathogens.Recently,a bismuth-based complex has been developed to eradicate antimicrobial-resistant microorganism infections.The complex is known as organobismuth(III)phosphinate,which is said to be a potential broad-spectrum antimicrobial agent.This complex has been incorporated into the nanocellulose suspension to fabricate a biomedical composite for various applications.The composite can be fabricated by two methods namely vacuum filtration and spray coating.In this paper,the surface and topography of the composite are investigated and discussed in terms of SEM micrographs and their antimicrobial potential.This review focuses on the organo-bismuth nanocellulose composite and its biomedical application in the future.
基金supported by the Natural Science Foundation of Jiangsu Province (BK2008029)
文摘Under hydrothermal conditions,isonicotinic acid reacted with BiCl 3 to give 1D zigzag chain complex [（C 6 H 6 NO 2） 2 ·（BiCl 5）·2H 2 O] n （1）.Single-crystal X-ray determination shows that compound 1 crystal-lizes in the monoclinic system,space group C2/c with a=13.115（3）,b=19.957（4）,c=7.9374（16）,β=97.45（3）°,Z=4,V=2060.0（8） 3,C 12 H 16 BiCl 5 N 2 O 6,D c=2.162 g/cm 3,M r=670.50,λ（MoKa）=0.71073,μ=9.237 mm-1,F（000）=1272,R=0.0208 and wR=0.0503.Dielectric constant of compound 1 was measured at different conditions.Measurements on the dielectric properties of 1 showed that the 1D chain coordination polymer exhibited a dipolar chain relaxation process and a relatively high dielectric constant.
基金Supported by the Natural Science Foundation of Shandong Province(No.L2 0 0 3B0 1) and the State Key L aboratory ofCrystal MaterialsShandong Universit
文摘A novel dimer of the bismuth(Ⅲ) complex with dithiotetrahydropyrrolocarbamate, [Bi(S_2CNC_4H_8)_2·(NO_3)]_2, was synthesized and the crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to a monoclinic system with space group P2_1/n, a=0.64718(13) nm, b=2.6738(6) nm, c=1.0423(2) nm, β=106.384(3)°, Z=4, V=1.730(3) nm^3, D_c=2.163 g/cm^3, μ=10.682 mm^(-1), F(000)=1072, R=0.0329, wR=0.0659. The structure shows a distorted pentagonal bipyramidal configuration with the seven-coordinated central Bi atom. In the crystal, the molecular packing in the unit cell reveals that the two adjacent molecules are symmetrically linked each other in the dimer by virtue of a couple of Bi-S interaction.
基金Supported by the Self-raised Project for the Basic Research for Application of Yunnan Province(2013FZ109)the Follow-up Project of Qujing Normal University for the National Natural Science Foundation(2106512005)+1 种基金the Innovation and Entrepreneurship Project for College Students of Qujing Normal Universitythe Project for Innovation Team of the Applied Chemical Material Preparation of Qujing Normal University(2106531001)
文摘The photocatalytic degradation on the bismuth containing complex oxide was revised in detail including the synthesis and classification of photocatalyts, and then the photocatalytic reaction, scavenger, and the mechanism of reaction. In particular, the perspectives of photocatalytic degradation on the bismuth containing oxide were analyzed in detail.
基金supported by the Natural Science Foundation of Zhejiang Province(LY12B01003)
文摘A bismuth（Ⅲ） complex 1 （H2-4,4＇-bipy）[Bi（HPPA）5]（H2PPA）.4H2O （H2PPA = p- hydroxy- phenylacetic acid, 4,4＇-bipy = 4,4＂-bipyridyl） was hydrothermally synthesized from p-hydroxy-phenylacetic acid （H2PPA）, Bi（NO3）3＂6H20 and 4,4＇-bipyridyl, and characterized by elemental analysis, IR, molar conductivity and TG. The single-crystal X-ray diffraction studies demonstrated that the complex is of monoclinic system, space group P21 with a = 10.928（7）, b = 22.558（7）, c = 11.313（7） A, β = 91.864（4）°, V = 2787.7（4） A3, Z = 2, C58H61BiN2O22, Mr = 1347.07, F（000） = 1364, Dc= 1.605 g/cm-3, p（MoKa） = 3.247 mm-1, the final R = 0.0269 and wR = 0.0540 for 9776 observed reflections with I 〉 2or（I）. The bismuth（I/I） is seven-coordinated with O atoms, forming a monocapped octahedral geometry. Complex 1 further forms a 3D supramolecular architecture by hydrogen bonds and π-π stacking interactions. Moreover, the interaction between the complex and DNA was studied by EtBr fluoescent probe.
基金Supported by the International Cooperation Project of the Science&Technology Agency of Henan Province(No.134300510013)
文摘Two novel complexes, [Bi（III）（S2CNBn Et）3] 1 and [Bi（III）（S2CNPPPy-2）3] 2, were synthesized and characterized by elemental analysis, IR, ^1H NMR, ^13C NMR, TG-DTG and X-ray single-crystal diffraction. The structure reveals that complex 1 belongs to the monoclinic system, space group P21/c with a = 11.457（5）, b = 17.437（8）, c = 33.439（14）, β= 98.499（8）o, Z = 4, V = 6607（5）3, Dc = 1.689 g·cm^-3, F（000） = 3328, μ= 5.742 mm^-1, the final R = 0.0906, w R = 0.1678 and S = 1.032. The structure indicates that complex 2 belongs to the triclinic system, space group P1 with a = 12.608（9）, b = 12.622（8）, c = 12.49（6）, α = 102.652（15）, β = 103.013（14）, γ = 109.698（10）o, Z = 1, V = 1762.3（19）3, Dc = 1.741 g·cm^-3, F（000） = 916, μ = 5.395 mm^-1, the final R = 0.048 2, w R = 0.1206 and S =1.046. In the two complexes, each six-coordinated Bi（III） atom adopts a pentagonal pyramidal configuration with six sulfur atoms from three ligands, and the dimmer structures are formed by weak interactions of Bi···S between two molecules. The anticancer activities of the two complexes were studied by evaluating their cytotoxicities against several human cancer cell lines using the MTT assay. Results indicated complex 2 showed moderate cytotoxic effects on the selected cancer cells.
基金Project supported by the Science & Technology Innovation Foundation of Henan Province (No. 092102310309)the Natural Science Foundation of Education Department of Henan Province (No. 2011B150025)
文摘Two novel complexes,[（C9H18NS2）3Sb（III）]（1） and [（C9H18NS2）3Bi（III）]（2）,were synthesized and characterized by elemental analysis,IR,TG and X-ray single-crystal diffraction.Both 1 and 2 crystallize in the monoclinic system,P21/c space group.The data for 1：a = 1.6964（3）,b = 1.02149（17）,c = 2.5650（3） nm,β = 121.824（8）°,Z = 4,V = 3.7766（10） nm^3,Dc = 1.293 g·cm^-3,F（000） = 1536,μ = 1.082 mm^-1,the final R = 0.0500,wR = 0.1562 and S =1.072.The data for 2：a = 1.6802（9）,b = 1.0256（6）,c = 2.5083（10） nm,β = 121.77（3）°,Z = 4,V = 3.675（3） nm^3,Dc = 1.486 g·cm^-3,F（000） = 1664,μ = 5.159 mm^-1,the final R = 0.0481,wR = 0.1055 and S =1.076.The coordinated geometry of the central M（III） with six sulfur atoms from three ligands is a distorted pentagonal pyramid configuration.The dimer structural system is formed by the weak interactions of M…S and C-H…S between two molecules.The complexes were valued for their antibacterial activities by agar-streak method.It was found that 1 is active against the four test bacterial organisms.
文摘The main focus of the research was to correlate the microstructure with dielectric and magnetic properties of Bi1-xBaxFeO3 samples. Bi1-xBaxFeO3 samples（x = 0.1, 0.2 and 0.3） were synthesized by the conventional solid-state reaction method using nano-powders of Bi2O3, Fe2O3, and BaCO3. Thereafter, field emission scanning electron microscope and X-ray diffraction（XRD） techniques were used to examine the structure and phase of the samples. Phase analysis by XRD indicated that the single-phase perovskite structure was formed with possible increment in lattice parameter with increasing Ba doping. Complex permeability（u＇iand u＇＇i） measured using impedance analyzer confirmed the increase in magnetic property with increasing Ba doping. Finally, dielectric constant（k） was analyzed as a function of temperature at different frequencies. Dielectric constant as high as 2900 was attained in this research for Bi0.8Ba0.2FeO3 sample due to reduction in leakage current at this composition.
基金This project is financially supported by the National Natural Science Foundation of China (No.29575207) KJCXGC-01 of Northwest Normal University
文摘The polargraphic behavior of Bi(Ⅲ)-NOTP complex has been investigated inaqueous solution. It was found that under the conditions of pH 3.0 and of 0.02 mol/L NH_4Cl, theBi(Ⅲ)-NOTP system gives a sensitive second order derivative wave at -0.340 V(vs SCE), which isproved to be an adsorptive complex wave. The composition of the complex is Bi(Ⅲ):NOTP. Furthermore,the peak current is linear to the concentration of Bi(Ⅲ) in the range from 3.0x10^(-8) to5.0x10^(-6) mol/L. Artificial and practical samples have been detected with high sensitivity andreceptivity.
文摘A new solid bismuth complex,[C9H8ON]3·2H2O,was synthesized by bismuth trichloride and 8-hydroxyquinoline(8-Hhq) in dilute HCl.The complex was characterized by elemental analysis,XRD,TG-DSC and FT-IR.The IR result shows that the heterocyclic nitrogen atom of 8Hhq bonds to H+,and coordinates with Bi3+.The fluorescent spectra and UV-Vis spectra of the title compound were carried out.
