Hierarchical Ni/ZSM-22-SBA-15 meso-microporous catalysts(Ni/ZS-x)with different acid properties and diffusion characteristics(acid-diffusion)properties were synthesized successfully and applied to the production of hi...Hierarchical Ni/ZSM-22-SBA-15 meso-microporous catalysts(Ni/ZS-x)with different acid properties and diffusion characteristics(acid-diffusion)properties were synthesized successfully and applied to the production of high-quality jet fuel by the efficient one-step hydrogenation(hydrodeoxygenation,isomerization,and cracking)of oleic acid.The acid-diffusion properties of the catalysts are modulated by tuning the ZSM-22 seed content,and their effects on the hydrogenation reactions were investigated.Acid properties affect the extent of isomerization and cleavage reactions,whereas diffusion properties affect the accessibility of active centers.The balanced acid-diffusion properties are conducive to efficient hydrogenation reactions of oleic acid.The optimal Ni/ZS-3 exhibits the highest jet fuel yield(56.3%,340°C)and superior iso/n-alkane ratio(i/n=3.12)because of its well-balanced acid-diffusion properties.Besides,the possible hydrogenation mechanism of oleic acid is proposed.展开更多
基金sponsored by the National Natural Science Foundation of China(Grant Nos.22308381 and 22522818)Science Foundation of China University of Petroleum-Beijing(Grant Nos.2462023QNXZ002 and 2462023QNXZ005)+1 种基金Beijing Nova Program(Grant No.20220484096)the National Key R&D Program of China(Grant No.2021YFA1501201).
文摘Hierarchical Ni/ZSM-22-SBA-15 meso-microporous catalysts(Ni/ZS-x)with different acid properties and diffusion characteristics(acid-diffusion)properties were synthesized successfully and applied to the production of high-quality jet fuel by the efficient one-step hydrogenation(hydrodeoxygenation,isomerization,and cracking)of oleic acid.The acid-diffusion properties of the catalysts are modulated by tuning the ZSM-22 seed content,and their effects on the hydrogenation reactions were investigated.Acid properties affect the extent of isomerization and cleavage reactions,whereas diffusion properties affect the accessibility of active centers.The balanced acid-diffusion properties are conducive to efficient hydrogenation reactions of oleic acid.The optimal Ni/ZS-3 exhibits the highest jet fuel yield(56.3%,340°C)and superior iso/n-alkane ratio(i/n=3.12)because of its well-balanced acid-diffusion properties.Besides,the possible hydrogenation mechanism of oleic acid is proposed.
