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A Prediction of the Excess Partial Molar Free Energies of MgCl_2 in the KCI-MgCl_2-LiCl Molten Salt System Containing MgCl_2 below 0.5 from Thermodynamic Properties of Binary Systems 被引量:2
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作者 Quanru ZHANG, Yuangao LI and Zheng FANG (Department of Chemistry, Central South University of Technology, Changsha 410083, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2000年第1期85-87,共3页
The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI... The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI-MgCl_2 and LiCI-MgCl_2, by means of a model on the assumptions that the electrolytes in the solution are treated as independent particles instead of their ion forms and the interchange energy between the component pair KCI-LiCl is ignored when compared with those of component pairs KCl-MgCl_2 and MgCl_2-LiCl. The interchange energies, wKCl-MgCl_2 and wMgcCl_2-Licl, are obtained as-70000 and -13800 J.mol-1, from the corresponding binary solutions, respectively. 展开更多
关键词 KCI Free A Prediction of the Excess Partial Molar Free Energies of MgCl2 in the KCI-MgCl2-LiCl Molten Salt System Containing MgCl2 below 0.5 from Thermodynamic Properties of binary systems LICL
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Calculation of Gas-Liquid Critical Curves for Binary Systems Containing Methane
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作者 朱荣娇 李洪玲 +2 位作者 郝纪双 李贺松 田宜灵 《Transactions of Tianjin University》 EI CAS 2009年第4期276-282,共7页
The critical curves for binary systems of methane combined with nitrogen, carbon monoxide, carbon dioxide, ethane, propane, butane and water at temperatures from 125 K to 650 K and pressures from 3.5 MPa to 250 MPa we... The critical curves for binary systems of methane combined with nitrogen, carbon monoxide, carbon dioxide, ethane, propane, butane and water at temperatures from 125 K to 650 K and pressures from 3.5 MPa to 250 MPa were calculated by using Heilig-Franck equation of state. This equation of state contains a repulsion term and an attraction term for intermolecular interaction. With pairwise combination rules for these potentials, three adjustable parameters are needed. The results showed that the critical curves of the former six binary systems belonged to type I, and CH4+H2O system belonged to type III. The calculated data were compared with the experimental data,which yielded good results for the pressure-temperature, pressure-composition and temperature-composition behaviors of the seven systems. Moreover, the values of the adjustable parameters were obtained from the calculation of the critical curves. They can also be used for other relevant calculation. 展开更多
关键词 critical curves binary systems METHANE CALCULATION
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A New Symmetric Model for Predicting Ternary Thermodynamic Properties from its Three Binary Systems
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作者 K.-C.Chou R.-Q.Li 《Rare Metals》 SCIE EI CAS CSCD 1989年第4期12-17,共6页
A new symmetric model for predicting ternary thermodynamic properties from its three binary systems has been presented. The application of this new model to the prediction of the ternary mixing enthalpy of Ga-Bi-Sn sy... A new symmetric model for predicting ternary thermodynamic properties from its three binary systems has been presented. The application of this new model to the prediction of the ternary mixing enthalpy of Ga-Bi-Sn system and the ternary excess Gibbs energy of AgCl-LiCl-KCl system shows that the calculated results are close to the experimental data. 展开更多
关键词 A New Symmetric Model for Predicting Ternary Thermodynamic Properties from its Three binary systems
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ASSESSMENT AND OPTIMIZATION OF THE PHASE DIAGRAMS AND THERMODYNAMIC DATA OF SOME BINARY SYSTEMS CONTAINING PRASEODYMIUM CHLORIDES
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作者 乔芝郁 王明生 +1 位作者 郑朝贵 段淑贞 《Journal of Rare Earths》 SCIE EI CAS CSCD 1990年第2期92-98,共7页
In this paper a critical assessment and optimization of the phase diagrams and thermodynamic properties of the PrCl_3-MCl(M=Li,Na)and PrCl_3-MCl_2(M=Mg,Ca,Sr,Ba) binary systems have been per- formed.The assessed and o... In this paper a critical assessment and optimization of the phase diagrams and thermodynamic properties of the PrCl_3-MCl(M=Li,Na)and PrCl_3-MCl_2(M=Mg,Ca,Sr,Ba) binary systems have been per- formed.The assessed and optimized binary phase diagrams and thermodynamic data with self consistency are a better basis for constructing multicomponent phase diagrams. 展开更多
关键词 ASSESSMENT AND OPTIMIZATION OF THE PHASE DIAGRAMS AND THERMODYNAMIC DATA OF SOME binary systems CONTAINING PRASEODYMIUM CHLORIDES
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Magnetic interaction in ultra-compact binary systems
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作者 Kinwah Wu 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2009年第7期725-744,共20页
This article reviews the current works on ultra-compact double-degenerate binaries in the presence of magnetic interaction, in particular, unipolar induction. The orbital dynamics and evolution of compact white-dwarf ... This article reviews the current works on ultra-compact double-degenerate binaries in the presence of magnetic interaction, in particular, unipolar induction. The orbital dynamics and evolution of compact white-dwarf pairs are discussed in detail. Models and predictions of electron cyclotron masers from unipolar-inductor compact binaries and unipolar-inductor white-dwarf planetary systems are presented. Einstein-Laub effects in compact binaries are briefly discussed. 展开更多
关键词 stars binaries close - stars white dwarfs - gravitational waves - masers - radio continuum stars - X-rays binaries -- planetary systems
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Development of thermodynamic database of the Mn-RE(RE=rare earth metals)binary systems
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作者 Hongjian Ye Jiang Wang +2 位作者 Qing Chen Guanghui Rao Huaiying Zhou 《Materials Genome Engineering Advances》 2024年第2期53-82,共30页
In this work,eight Mn-RE(RE=Ce,Pr,Sm,Tb,Er,Tm,Lu,and Y)binary systems were reassessed thermodynamically by the CALPHAD method based on the reported optimizations and experimental information.Self-consistent thermodyna... In this work,eight Mn-RE(RE=Ce,Pr,Sm,Tb,Er,Tm,Lu,and Y)binary systems were reassessed thermodynamically by the CALPHAD method based on the reported optimizations and experimental information.Self-consistent thermodynamic parameters to describe Gibbs energies of various phases in eight Mn-RE binary systems were obtained.The calculated phase equilibria and thermodynamic properties of eight Mn-RE binary systems are in good accor-dance with the experimental results.Furthermore,phase equilibria and ther-modynamic properties of 13 Mn-RE(RE=La,Ce,Pr,Nd,Sm,Gd,Tb,Dy,Ho,Er,Tm,Lu,and Y)binary systems were discussed systematically in combination with the present calculations and the reported optimizations.A trend was found for the variation of phase equilibria and thermodynamic properties of the Mn-RE binary systems.In general,as the RE atomic number increases,the enthalpies of mixing of liquid alloys as well as the enthalpies of formation of the intermetallic compounds become increasingly negative,and the formation temperatures of the intermetallic compounds become higher.The results provide a complete set of self-consistent thermodynamic parameters for the Mn-RE binary systems,and a thermodynamic database of 13 Mn-RE binary systems was finally achieved. 展开更多
关键词 Mn-RE binary systems phase equilibria THERMODYNAMIC
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The fast rotation of companions of compact objects in close binary systems 被引量:1
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作者 ABLIMIT Iminhaji Lü GuoLiang 《Science China Chemistry》 SCIE EI CAS 2013年第3期663-669,共7页
We have performed Monte Carlo simulations of the rotation of single stars and companions of compact objects(The compact objects are white dwarfs(WDs) and neutron stars(NSs)) in close binaries.We present a comparison b... We have performed Monte Carlo simulations of the rotation of single stars and companions of compact objects(The compact objects are white dwarfs(WDs) and neutron stars(NSs)) in close binaries.We present a comparison between the rotation of companions of compact objects and that of single stars.We find that the rotation of the companions of compact objects is on average faster than that of the single stars.According to the distribution of the orbital period and the rotation angular velocity,we find that the rotation of the companions of compact objects is mostly accelerated by stable mass transfer.Tidal forces of the compact object can also affect the rotation of companion. 展开更多
关键词 ROTATION companions of compact objects close binary systems spin and orbital period
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ORTHOGONAL POLYNOMIAL EXPANSIONS OF THERMODYNAMICPROPERTIES OF BINARY AND TERNARY SYSTEMS 被引量:1
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作者 Y.Su L.Liu Z.C.Wang 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1998年第5期329-334,共6页
Orthogonal polynomial expansions are ased to present integral properties of binary and ternary sgstems. The partial property of each component can be expressed with the same set of coeffcients. It was shown that the c... Orthogonal polynomial expansions are ased to present integral properties of binary and ternary sgstems. The partial property of each component can be expressed with the same set of coeffcients. It was shown that the coefficients are completely independent. Ternary system of Pb-Sb-Sn and its three binary sub-systems are calculated as example. 展开更多
关键词 orthogonal polynomial thermodynamic property binary andternary systems
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H–He Demixing Driven by Anisotropic Hydrogen Diffusion
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作者 Xiaoju Chang Dongdong Kang +1 位作者 Bo Chen Jiayu Dai 《Chinese Physics Letters》 2025年第5期33-42,共10页
The dynamics of phase separation in H–He binary systems within gas giants such as Jupiter and Saturn exhibit remarkable complexity, yet lack systematic investigation. Through large-scale machine-learning-accelerated ... The dynamics of phase separation in H–He binary systems within gas giants such as Jupiter and Saturn exhibit remarkable complexity, yet lack systematic investigation. Through large-scale machine-learning-accelerated molecular dynamics simulations spanning broad temperature-pressure-composition(2000–10000 K, 1–7 Mbar,pure H to pure He) regimes, we systematically determine self and mutual diffusion coefficients in H–He systems and establish a six-dimensional framework correlating temperature, pressure, helium abundance, phase separation degree, diffusion coefficients, and anisotropy. Key findings reveal that hydrogen exhibits active directional migration with pronounced diffusion anisotropy, whereas helium passively aggregates in response. While the conventional mixing rule underestimates mutual diffusion coefficients by neglecting velocity cross-correlations,the assumption of an ideal thermodynamic factor(Q = 1) overestimates them due to unaccounted non-ideal thermodynamic effects—both particularly pronounced in strongly phase-separated regimes. Notably, hydrogen's dual role, anisotropic diffusion and bond stabilization via helium doping, modulates demixing kinetics. Large-scale simulations(216,000 atoms) propose novel phase-separation paradigms, such as “hydrogen bubble/wisp” formation, challenging the classical “helium rain” scenario, striving to bridge atomic-scale dynamics to planetary-scale phase evolution. 展开更多
关键词 molecular dynamics simulations gas giants helium diffusion h he systems hydrogen diffusion determine self mutual diffusion coefficients h he binary systems dynamics phase separation
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A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO_4-H_2O and NaF-H_2O binary solutions and NaClO_4-NaF-H_2O ternary solution 被引量:1
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作者 Xue-min Yang Wei-jie Zhao +2 位作者 Han-jie Guo Qiang Zhang Jian Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2010年第5期546-557,共12页
A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary strong electrolyte aqueous solutions was develo... A thermodynamic model of calculating mass action concentrations for structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions and NaClO4-NaF-H2O ternary strong electrolyte aqueous solutions was developed based on the ion and molecule coexistence theory (IMCT). A transformation coefficient was needed to compare the calculated mass action concentration and the reported activity, because they were usually obtained at different standard states and concentration units. The results show that transformation coefficients between the calculated mass action concentrations and the reported activities of the same components change in a very narrow range. The transformed mass action concentrations of structural units or ion couples in NaClO4-H2O and NaF-H2O binary solutions agree well with the reported activities. The transformed mass action concentrations of structural units or ion couples in NaClO4-NaF-H2O ternary solution are also in good agreement with the reported activities in a total ionic strength range from 0.1 to 0.9 mol/kg H2O by the 0.1 mol/kg step with different ionic strength fractions of 0, 0.2, 0.4, 0.5, 0.6, 0.8, and 1, respectively. The results indicate that the developed thermodynamic model can reveal the structural characteristics of binary and ternary strong electrolyte aqueous solutions, and the calculated mass action concentrations of structural units or ion couples also strictly follow the mass action law. 展开更多
关键词 binary systems ternary systems thermodynamic model activity coefficient structural unit
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Thermodynamic modeling of the Ge-La binary system
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作者 Miao Liu Chang-rong Li +2 位作者 Zhen-min Du Cui-ping Guo Chun-ju Niu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第8期689-698,共10页
The Ge-La binary system was critically assessed by means of the calculation of phase diagram (CALPHAD) technique. The asso- ciate model was used for the liquid phase containing the constituent species Ge, La, Ge3La5... The Ge-La binary system was critically assessed by means of the calculation of phase diagram (CALPHAD) technique. The asso- ciate model was used for the liquid phase containing the constituent species Ge, La, Ge3La5, and Ge1.7La. The terminal solid solution diamond-(Ge) with a small solubility of La was described using the substitutional model, in which the excess Gibbs energy was formulated with the Redlich-Kister equation. The compounds with homogeneity ranges, μ(Gel.7La), β(Ge1.7La), and (GeLa), were modeled using two sublatrices asα(Ge,La)l.7La, β(Ge,La)l.7La, and (Ge,La)(Ge,La), respectively. The intermediate phases with no solubility ranges, Ge4Las, GeaLa4, Ge3Las, and GeLa3, were treated as stoichiometric compounds. The three allotropic modifications of La, dhcp-La, fcc-La, and bcc-La, were kept as pure element phases since no solubility of Ge in La was reported. A set of self-consistent thermodynamic parameters of the Ge-La binary system was obtained. The calculation results agree well with the available experimental data from literatures. 展开更多
关键词 hydrogen storage alloys binary systems GERMANIUM LANTHANUM THERMODYNAMICS modeling phase diagrams
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Modelling of Impedance Matching Circuit with Digital Capacitor in Narrowband Power Line Communication
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作者 Chin Pin Rui Nader Nassif Barsoum +1 位作者 Arthur Wong Kok Ming Wong Kiing Ing 《Journal of Energy and Power Engineering》 2014年第1期201-207,共7页
Power line communication technology is used in various applications, from high voltage network to the low voltage network, as it is the only wired communication technology that is comparable with wireless communicatio... Power line communication technology is used in various applications, from high voltage network to the low voltage network, as it is the only wired communication technology that is comparable with wireless communication network. It works by injecting a modulated carrier wave into the electric cables from one transceiver to another. But still, the noise level and impedance mismatch are still the main concern of this technology, particularly in the low voltage network in residential area. Power line has additive non-white noise and extremely harsh environment for communication. At the same time, there is signal attenuation along the power line caused by the impedance mismatch in the power line network. Even though these problems can be controlled using a band-pass filter and an impedance matching circuit respectively, but the impedances in the power line are time and location variant and it is rather difficult to design a circuit that allows maximum power transfer in the system all the time. Thus in this paper, a new adaptive impedance matching circuits is proposed for narrowband power line communication. This methodology is derived based on the RLC band-pass filter circuit. This concept is designed to achieve simpler configuration and higher matching resolution. 展开更多
关键词 Impedance matching band-pass filter binary systems digital capacitor narrowband power line communication.
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Analysis of Phased-Mission System Reliability and Importance with Imperfect Coverage 被引量:6
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作者 陈光宇 黄锡滋 唐小我 《Journal of Electronic Science and Technology of China》 2005年第2期182-186,共5页
Accounting for static phased-mission systems (PMS) and imperfect coverage (IPC), generalized and integrated algorithm (GPMS-CPR) implemented a synthesis of several approaches into a single methodology whose advantages... Accounting for static phased-mission systems (PMS) and imperfect coverage (IPC), generalized and integrated algorithm (GPMS-CPR) implemented a synthesis of several approaches into a single methodology whose advantages were in the low computational complexity, broad applicability, and easy implementation. The approach is extended into analysis of each phase in the whole mission. Based on Fussell-Vesely importance measure, a simple and efficient importance measure is presented to analyze component’s importance of phased-mission systems considering imperfect coverage. 展开更多
关键词 RELIABILITY binary decision diagram for phased-mission systems generalized and integrated algorithm imperfect coverage model fussell-veseley importance measure
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Robust Superconducting Stability of Ternary Hydride Im3m(Y, Ca)H_(6) upon Decompression
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作者 Kexin Zhang Jianning Guo +3 位作者 Yulong Wang Xinyue Wu Xiaoli Huang Tian Cui 《Chinese Physics Letters》 2025年第11期244-252,共9页
Ternary hydrides, with their superior chemical and structural flexibility over binary systems, open up new avenues for advancing high-performance superconductor research. The Y-Ca-H system is a promising candidate for... Ternary hydrides, with their superior chemical and structural flexibility over binary systems, open up new avenues for advancing high-performance superconductor research. The Y-Ca-H system is a promising candidate for high-temperature superconductors, as both Im3m YH_(6) and Im3m CaH_(6) exhibit similar structures and excellent superconducting properties, while Y and Ca atoms possess close atomic radii and electronegativities.Here, we report the successful synthesis of Im3m(Y, Ca)H_(6) achieving a maximum superconducting transition temperature(T_(c)) approximately 224 K at 155 GPa through five independent high-temperature and high-pressure experiments. Remarkably, the T_(c) of Im3m(Y, Ca)H_(6) remains highly stable(ΔT_(c) ≤ 1 K) during decompression between 148 and 165 GPa, significantly outperforming binary Im3m CaH_(6) and Im3m YH_(6). The enhanced superconducting properties may stem from the cooperative chemical template effect of Y and Ca atoms near the s-d border, which significantly reinforces H lattice stability and thus maintains superior superconductivity.This study highlights the potential of multicomponent cooperative effects in designing hydride superconductors,offering new insights for achieving high-T_(c) hydrides at lower pressures in the future. 展开更多
关键词 binary systems high temperature superconductors superconducting transition temperature ternary hydrides superconducting properties decompression Y Ca H system superconducting stability
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Grain landscape and dielectric properties of ceramics based on sodium,calcium,strontium niobates,depending on the synthesis and sintering conditions,and mechanical processing
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作者 J.Y.Zubarev A.V.Nazarenko +1 位作者 A.V.Nagaenko L.A.Reznitchenko 《Journal of Advanced Dielectrics》 CAS 2022年第1期6-11,共6页
The properties studying results of ceramics based on strontium,calcium and sodium niobates,which vary from the conditions of synthesis,sintering,and mechanical processing,are presented.The evolution of the grain struc... The properties studying results of ceramics based on strontium,calcium and sodium niobates,which vary from the conditions of synthesis,sintering,and mechanical processing,are presented.The evolution of the grain structure of objects is traced depending on their phase filling during concentration changes in the composition and thermodynamic prehistory(preparation conditions). 展开更多
关键词 Layered perovskite-like compounds binary systems pyroniobates of calcium and strontium microstructure mechanoactivation
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