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The time-fractional(2+1)-dimensional Heisenberg ferromagnetic spin chain equation:its Lie symmetries,exact solutions and conservation laws
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作者 Jicheng Yu Yuqiang Feng 《Communications in Theoretical Physics》 2025年第5期21-30,共10页
In this paper,the Lie symmetry analysis method is applied to the(2+1)-dimensional time-fractional Heisenberg ferromagnetic spin chain equation.We obtain all the Lie symmetries admitted by the governing equation and re... In this paper,the Lie symmetry analysis method is applied to the(2+1)-dimensional time-fractional Heisenberg ferromagnetic spin chain equation.We obtain all the Lie symmetries admitted by the governing equation and reduce the corresponding(2+1)-dimensional fractional partial differential equations with the Riemann–Liouville fractional derivative to(1+1)-dimensional counterparts with the Erdélyi–Kober fractional derivative.Then,we obtain the power series solutions of the reduced equations,prove their convergence and analyze their dynamic behavior graphically.In addition,the conservation laws for all the obtained Lie symmetries are constructed using the new conservation theorem and the generalization of Noether operators. 展开更多
关键词 Lie symmetries fractional partial differential equation Heisenberg ferromagnetic spin chain equation power series solutions conservation laws
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Low Mantle Perovskite:Solid Solution, Spin State of Iron and Water Solubility 被引量:1
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作者 LI Lin LI Qing LI Sheng-Rong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第6期1884-1894,共11页
Silicate perovskites((Mg, Fe)SiO 3 and CaS iO 3) are believed to be the major constituent minerals in the lower mantle. The phase relation, solid solution, spin state of iron and water solubility related to the lo... Silicate perovskites((Mg, Fe)SiO 3 and CaS iO 3) are believed to be the major constituent minerals in the lower mantle. The phase relation, solid solution, spin state of iron and water solubility related to the lower mantle perovskite are of great effect on the geodynamics of the Earth's interior and on ore mineralization. Previous studies indicate that a large amount of iron coupled with aluminum can incorporate into magnesium perovskite, but this is discordant with the disproportionation of(Mg,Fe)SiO 3 perovskite into iron-free MgS i O3 perovskite and hexagonal phase(Mg0.6Fe0.4)SiO 3 in the Earth's lower mantle. MnS iO 3 is the first chemical component confirmed to form wide range solid solution with Ca SiO 3 perovskite and complete solid solution with MgS i O3 perovskite at the P-T conditions in the lower mantle, and addition of Mn Si O3 will strongly affects the mutual solubility between Mg Si O3 and CaS iO 3. The spin state of iron is deeply depends on the site occupation of the Fe3+or Fe2+, the synthesis and the annealing conditions of the sample. It seems that the spin state of Fe2+ in the lower mantle perovskite can be settled as high spin, however, the existence of intermediate spin or low spin state of Fe2+ in perovskite has not been clarified. Moreover, different results have also been reported for the spin state of Fe3+ in perovskite. The water solubility of the lower mantle perovskite is related with its composition. In pure Mg SiO 3 perovskite, only less than 500 ppm water was reported. Al–Mg Si O3 perovskite or Al–Fe–MgS iO 3 perovskite in the lower mantle accommodates water of 1100 to 1800 ppm. Further experiments are necessary to clarify the detailed conditions for perovskite solid solution, to reliably analyze the valence and spin states of iron in the coexisting iron-bearing phases, and to compare the water solubility of different phases at different layers for deeply understanding the geodynamics of the Earth's interior and ore mineralization. 展开更多
关键词 solid solution spin state of iron water solubility PEROVSKITE low mantle
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Jingwei Intelligent:Providing versatile textile equipment and full-process solution
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《China Textile》 2025年第5期31-31,共1页
Jingwei Intelligent Textile Machinery Co.,Ltd.is a globally leading enterprise in the R&D and manufacturing of textile machinery,affiliated with China National Machinery Industry Group(SINOMACH).As the first moder... Jingwei Intelligent Textile Machinery Co.,Ltd.is a globally leading enterprise in the R&D and manufacturing of textile machinery,affiliated with China National Machinery Industry Group(SINOMACH).As the first modern textile machinery manufacturing base in New China,the company has developed over 70 years to establish a full lifecycle service capability of"machines+components+services+modifications."Its core products,such as Ring Spinning Frames and Combers,feature internationally advanced technologies.With products exported to over 40 countries and regions,the company is committed to providing global customers with intelligent,green textile equipment and full-process solutions. 展开更多
关键词 ring spinning frames R D textile machinery combers intelligent textile equipment textile machineryaffiliated full process solutions
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Exact solutions of an Ising spin chain with a spin-1 impurity
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作者 黄旭初 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第3期515-521,共7页
An exact solution of a single impurity model is hard to derive since it breaks translation invariance symmetry. We present the exact solution of the spin-1/2 transverse Ising chain imbedded by a spin-1 impurity. Using... An exact solution of a single impurity model is hard to derive since it breaks translation invariance symmetry. We present the exact solution of the spin-1/2 transverse Ising chain imbedded by a spin-1 impurity. Using the hole decompo- sition scheme, we exactly solve the spin-1 impurity in two subspaces which are generated by a conserved hole operator. The impurity enlarges the energy deformation of the ground state above a pure transverse Ising system without impurity. The specific heat coefficient shows a small anomaly at low temperature for finite size. This indicates that the impurity can tune the ground state from a magnetic impurity space to a non-magnetic impurity space, which only exists for spin-1 impurity comparing with spin-1/2 impurity and a pure transverse Ising chain without impurity. These behaviors essentially come from adding impurity freedom, which induces a competition between hole and fermion excitation depending on the coupling strength with its neighbor and the single-ion anisotropy. 展开更多
关键词 exact solution spin chain IMPURITY
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Exact Solution to Spin Squeezing of the Arbitrary-Range Spin Interaction and Transverse Field Model
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作者 陈星 张振伟 +3 位作者 赵环 王暖让 杨仁福 冯克明 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第10期62-66,共5页
We investigate spin squeezing effects of trapped ions in an off-resonance optical potential system using the arbitrary range spin spin interaction and transverse field model. The collective spin noises at any time are... We investigate spin squeezing effects of trapped ions in an off-resonance optical potential system using the arbitrary range spin spin interaction and transverse field model. The collective spin noises at any time are analyzed exactly. The general expression of spin squeezing factor is presented for arbitrary-range spin interaction. For the nearest-neighbor and next-nearest neighbor spin interaction model, the analytic solutions are reduced from the general expressions. It is shown that the maximum spin squeezing is enhanced for the general arbitrary-range spin interaction compared with the nearest-neighbor interaction model as the long-range interaction with arbitrary sites enforces stronger correlation. 展开更多
关键词 of on for in Exact solution to spin Squeezing of the Arbitrary-Range spin Interaction and Transverse Field Model is
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Solution Space Coupling in the Random K-Satisfiability Problem 被引量:1
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作者 曾颖 周海军 《Communications in Theoretical Physics》 SCIE CAS CSCD 2013年第9期363-374,共12页
The random K-satisfiability (K-SAT) problem is very diffcult when the clause density is close to the satisfiability threshold. In this paper we study this problem from the perspective of solution space coupling. We ... The random K-satisfiability (K-SAT) problem is very diffcult when the clause density is close to the satisfiability threshold. In this paper we study this problem from the perspective of solution space coupling. We divide a given difficult random K-SAT formula into two easy sub-formulas and let the two corresponding solution spaces to interact with each other through a coupling field x. We investigate the statistical mechanical property of this coupled system by mean field theory and computer simulations. The coupled system has an ergodicity-breaking (clustering) transition at certain critical value Xd of the coupling field. At this transition point, the mean overlap value between the solutions of the two solution spaces is very close to 1. The mean energy density of the coupled system at its clustering transition point is less than the mean energy density of the original K-SAT problem at the temperature-induced clustering transition point. The implications of this work for designing new heuristic K-SAT solvers are discussed. 展开更多
关键词 constraint satisfaction spin glass clustering transition belief propagation solution space
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On the Role of Differentiation Parameter in a Bound State Solution of the Klein-Gordon Equation
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作者 B.C.Lütfüo?lu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2019年第3期267-273,共7页
Recently, the bound state solutions of a confined Klein-Gordon particle under the mixed scalar-vector generalized symmetric Woods-Saxon potential in one spatial dimension have been investigated. The obtained results r... Recently, the bound state solutions of a confined Klein-Gordon particle under the mixed scalar-vector generalized symmetric Woods-Saxon potential in one spatial dimension have been investigated. The obtained results reveal that in the spin symmetric limit discrete spectrum exists, while in the pseudo-spin symmetric limit it does not.In this manuscript, new insights and information are given by employing an analogy of the variational principle. The role of the difference of the magnitudes of the vector and scalar potential energies, namely the differentiation parameter,on the energy spectrum is examined. It is observed that the differentiation parameter determines the measure of the energy spectrum density by modifying the confined particle's mass-energy in addition to narrowing the spectrum interval length. 展开更多
关键词 KLEIN-GORDON equation generalized symmetric Woods-Saxon potential BOUND st ate spectrum spin SYMMETRY limit ANALYTIC solutions
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Dynamic characteristics of multi-span spinning beams with elastic constraints under an axial compressive force
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作者 Xiaodong GUO Zhu SU Lifeng WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第2期295-310,共16页
A theoretical model for the multi-span spinning beams with elastic constraints under an axial compressive force is proposed.The displacement and bending angle functions are represented through an improved Fourier seri... A theoretical model for the multi-span spinning beams with elastic constraints under an axial compressive force is proposed.The displacement and bending angle functions are represented through an improved Fourier series,which ensures the continuity of the derivative at the boundary and enhances the convergence.The exact characteristic equations of the multi-span spinning beams with elastic constraints under an axial compressive force are derived by the Lagrange equation.The efficiency and accuracy of the present method are validated in comparison with the finite element method(FEM)and other methods.The effects of the boundary spring stiffness,the number of spans,the spinning velocity,and the axial compressive force on the dynamic characteristics of the multi-span spinning beams are studied.The results show that the present method can freely simulate any boundary constraints without modifying the solution process.The elastic range of linear springs is larger than that of torsion springs,and it is not affected by the number of spans.With an increase in the axial compressive force,the attenuation rate of the natural frequency of a spinning beam with a large number of spans becomes larger,while the attenuation rate with an elastic boundary is lower than that under a classic simply supported boundary. 展开更多
关键词 multi-span spinning beam elastic constraint improved Fourier series free vibration semi-analytical solution
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Hasimoto曲面的运动及其相应的Spin方程的精确解(英文)
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作者 李翊神 陈春丽 《中国科学技术大学学报》 CAS CSCD 北大核心 2000年第3期253-262,共10页
利用测地坐标下的曲面运动与AKNS系统的关系 ,得到Hasimoto曲面运动的精确解 。
关键词 曲面运动 旋转方程 spin方程 Hasimoto曲面
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Double-stretching as an effective and generalizable strategy towards thinner nanofibers in solution blow spinning 被引量:1
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作者 Baopu Zhang Ziwei Li +4 位作者 Zekun Cheng Lei Li Chong Yang Haiyang Wang Hui Wu 《Nano Research》 SCIE EI CSCD 2023年第4期5709-5714,共6页
Solution blow spinning(SBS)applies high-speed airflow to prepare fibers by generating a strong stretching force.It has the advantages of scalable production,tailorable morphologies,and wide applicability.Yet,the SBS s... Solution blow spinning(SBS)applies high-speed airflow to prepare fibers by generating a strong stretching force.It has the advantages of scalable production,tailorable morphologies,and wide applicability.Yet,the SBS strategy can hardly prepare fibers down to the sub-100 nanometers,which limits its performance in demanding applications.Herein,we overcome the limitation of SBS by introducing a second airflow.This novel strategy is termed double-stretching SBS(DS-SBS)because an extra stretching force is exerted on the fiber when it converges with the second airflow.Polyamide6 nanofibers with an average diameter of 80 nm are successfully prepared with the DS-SBS strategy,while the SBS strategy could only prepare submicron fibers with an average diameter of 120 nm.Further,the generality of the DS-SBS strategy to reduce fiber diameter is verified on numerous solute-solvent pairs. 展开更多
关键词 NANOFIBERS solution blow spinning double-stretching computational fluid dynamics
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Six types of spin solitons in three-component Bose-Einstein condensates
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作者 Yu-Hao Wang Ling-Zheng Meng Li-Chen Zhao 《Communications in Theoretical Physics》 SCIE CAS CSCD 2024年第6期57-65,共9页
Exact analytical solutions are good candidates for studying and explaining the dynamics of solitons in nonlinear systems.We further extend the region of existence of spin solitons in the nonlinearity coefficient space... Exact analytical solutions are good candidates for studying and explaining the dynamics of solitons in nonlinear systems.We further extend the region of existence of spin solitons in the nonlinearity coefficient space for the spin-1 Bose-Einstein condensate.Six types of spin soliton solutions can be obtained,and they exist in different regions.Stability analysis and numerical simulation results indicate that three types of spin solitons are stable against weak noise.The non-integrable properties of the model can induce shape oscillation and increase in speed after the collision between two spin solitons.These results further enrich the soliton family for non-integrable models and can provide theoretical references for experimental studies. 展开更多
关键词 Bose-Einstein condensate NON-INTEGRABLE spin soliton exact analytical solution
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Polycaprolactone/polyvinyl pyrrolidone nanofibers developed by solution blow spinning for encapsulation of chlorogenic acid
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作者 Yang Cao Chaoyi Shen +3 位作者 Zhichao Yang Zihan Cai Zian Deng Di Wu 《Food Quality and Safety》 SCIE CSCD 2022年第2期265-274,共10页
Study on the application of nanofibers in food active packaging has been a research hotspot in recent years.In this work,solution blow spinning(SBS)was applied to rapidly fabricate the polycaprolactone(PCL),polyvinyl ... Study on the application of nanofibers in food active packaging has been a research hotspot in recent years.In this work,solution blow spinning(SBS)was applied to rapidly fabricate the polycaprolactone(PCL),polyvinyl pyrrolidone(PVP),and PCL/PVP nanofibrous films to encapsulate chlorogenic acid(CGA).All films showed uniform and smooth nanofibers,and the Fourier transform infrared spectroscopy and X-ray diffraction proved the success of mixed spinning of PCL and PVP.With the increase of PVP content,the thermal stability of the PCL/PVP nanofibrous films improved.The PCL/PVP(weight ratio of 4:1)film possessed better mechanical properties than PCL and PVP films be-cause of the stronger fiber-fiber interactions.The addition of PCL endowed the hydrophobic surfaces to the PCL/PVP films,and the PCL/PVP films had better water vapor barrier ability.The PCL/PVP(4:1)film exhibited the best long-term continuous release of CGA during 72 h.The PVP nanofibrous film exhibited no inhibition against Staphylococcus aureus and Escherichia coli due to the low encapsulation efficiency,but the PCL and PCL/PVP films exhibited good antimicrobial activity.The above results suggested that the nanofibrous fims developed by SBS possess promising prospects in food packaging. 展开更多
关键词 solution blow spinning POLYCAPROLACTONE polvinyl prrolidone chlorogenic acid long-term continuous release
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醇解度和纺丝液含量对聚乙烯醇静电纺纳米纤维隔膜性能的影响 被引量:1
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作者 毕谷帅 张锦中 +1 位作者 唐晓峰 查刘生 《化工新型材料》 北大核心 2025年第3期141-145,共5页
以聚乙烯醇(PVA)为成纤聚合物,以水为溶剂,通过静电纺丝技术制备了锂离子电池用纳米纤维隔膜,研究了PVA醇解度和纺丝液含量对隔膜孔隙率、吸液率、热尺寸稳定性、力学性能和电化学性能的影响。结果表明:在纺丝液含量相同的条件下,PVA的... 以聚乙烯醇(PVA)为成纤聚合物,以水为溶剂,通过静电纺丝技术制备了锂离子电池用纳米纤维隔膜,研究了PVA醇解度和纺丝液含量对隔膜孔隙率、吸液率、热尺寸稳定性、力学性能和电化学性能的影响。结果表明:在纺丝液含量相同的条件下,PVA的醇解度越高,隔膜的孔隙率、吸液率、抗拉强度、热尺寸稳定性和离子电导率呈逐渐增大的趋势;在PVA醇解度相同的条件下,随着纺丝液含量的增加,隔膜的孔隙率和离子电导率逐渐升高,抗拉强度呈下降趋势;PVA的醇解度和纺丝液含量对隔膜的电化学稳定性影响很小。 展开更多
关键词 锂离子电池 纳米纤维隔膜 聚乙烯醇 静电纺丝 醇解度 纺丝液含量
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丝胶蛋白与丙烯腈共聚纺丝液的制备及性能
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作者 朱金玉 马利杰 +2 位作者 刘蕴莹 程隆棣 张瑞云 《上海纺织科技》 2025年第3期66-71,共6页
以50wt%硫氰酸钠水溶液为溶剂,制备了不同丝胶蛋白/丙烯腈比例的丝胶蛋白/丙烯腈共聚纺丝原液。测定了聚合产物的特征峰、转化率、黏均分子量以及纺丝原液的稳态剪切流变性能。结果表明:共聚物同时具有丝胶蛋白的酰胺特征峰和聚丙烯腈... 以50wt%硫氰酸钠水溶液为溶剂,制备了不同丝胶蛋白/丙烯腈比例的丝胶蛋白/丙烯腈共聚纺丝原液。测定了聚合产物的特征峰、转化率、黏均分子量以及纺丝原液的稳态剪切流变性能。结果表明:共聚物同时具有丝胶蛋白的酰胺特征峰和聚丙烯腈的氰基特征峰;引发剂质量分数增加,共聚物转化率升高,最高为78.5%,黏均分子量则随之减小;丝胶蛋白/丙烯腈共聚纺丝原液的表观黏度会随剪切速率的增加而减小,属于切力变稀型的非牛顿流体;温度升高,纺丝液表观黏度减小,剪敏性降低。 展开更多
关键词 丝胶蛋白 丙烯腈 纺丝液 表观黏度
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密胺纤维的改性研究进展
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作者 何利华 刘志凌 +2 位作者 李慧霞 蒋凡顺 张建勋 《河南化工》 2025年第9期16-20,共5页
密胺纤维作为新型高效阻燃材料,凭借其原料成本低、无熔滴特性以及耐高温和耐化学腐蚀性能,在阻燃领域具有重要应用价值。然而,其前驱体密胺树脂作为典型的热固性高分子材料,存在可纺性差的技术瓶颈。研究表明,提升纺丝液的稳定性和成... 密胺纤维作为新型高效阻燃材料,凭借其原料成本低、无熔滴特性以及耐高温和耐化学腐蚀性能,在阻燃领域具有重要应用价值。然而,其前驱体密胺树脂作为典型的热固性高分子材料,存在可纺性差的技术瓶颈。研究表明,提升纺丝液的稳定性和成纤性是优化纤维基础性能的关键;而进一步增强纤维的力学性能和阻燃性则可有效拓展其在高附加值领域的应用范围。从提升纺丝液性能和纤维性能两方面,系统梳理了近年来国内外在密胺纤维改性领域的创新成果,为突破密胺纤维的产业化应用瓶颈提供理论依据和技术参考。 展开更多
关键词 密胺纤维 改性 纺丝液 力学性能 极限氧指数
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溶喷纺PVA纤维的制备及性能
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作者 文洪权 刘奇 +2 位作者 曹群香 罗杰 陈丽杰 《现代纺织技术》 北大核心 2025年第6期1-8,共8页
为了制备绿色、高效的水溶性纳米纤维,对以聚乙烯醇(PVA)为原料和以水为溶剂的溶液喷射纺丝技术进行了研究。结果发现:将冷凝干燥、吸附干燥和红外加热等技术与溶喷纺丝工艺集于一体,降低了环境湿度对水溶液纺丝性能的影响;调整纺丝液... 为了制备绿色、高效的水溶性纳米纤维,对以聚乙烯醇(PVA)为原料和以水为溶剂的溶液喷射纺丝技术进行了研究。结果发现:将冷凝干燥、吸附干燥和红外加热等技术与溶喷纺丝工艺集于一体,降低了环境湿度对水溶液纺丝性能的影响;调整纺丝液性质、优化牵引风量和溶液流速等参数,改善了PVA纤维的表面形貌;采用酒石酸(TA)作为交联剂,增强了纤维的耐水性和热稳定性。研究结果可提升PVA水溶液溶喷纺丝性能,拓宽其在催化、过滤、储能、传感及生物医用等领域的应用前景。 展开更多
关键词 溶喷纺丝 聚乙烯醇 纳米纤维 交联改性
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闪蒸纺丝减压式喷头结构优化数值模拟
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作者 刘帅飞 夏磊 +3 位作者 杨友强 西鹏 魏金刚 黄赞义 《产业用纺织品》 2025年第1期22-34,共13页
为优化闪蒸纺丝减压式喷头结构,以公开的闪蒸减压式喷头结构为基础,构建多种结构参数的几何模型,然后利用Fluent软件模拟计算闪蒸纺丝液在不同结构参数喷头内的流动状态与运动轨迹,分析纺丝液的速度及压力的分布与变化趋势,并结合闪蒸... 为优化闪蒸纺丝减压式喷头结构,以公开的闪蒸减压式喷头结构为基础,构建多种结构参数的几何模型,然后利用Fluent软件模拟计算闪蒸纺丝液在不同结构参数喷头内的流动状态与运动轨迹,分析纺丝液的速度及压力的分布与变化趋势,并结合闪蒸纺丝过程中的相分离原理、气泡成核原理等,得到不同减压式喷头结构对纺丝液速度、压力及涡量的影响。结果表明:喷头结构不变,改变纺丝液的初始压力,减压率不变;减压孔内径与喷丝孔内径之比决定了闪蒸纺丝液的压降幅度,内径比相同,减压率也相同。在初始压力12 MPa的纺丝条件下,为减少能量损耗,保持纺丝液的均匀流动性及提高纺丝液成核质量,减压孔内径与喷丝孔内径之比以1.2为最佳,减压孔出射角度与喷丝孔入射角度分别以90°和100°为最佳,减压室内径和长度分别以30 mm和70 mm为最佳。研究结果可从理论角度指导优化闪蒸纺丝工艺,为闪蒸纺丝减压式喷头结构优化提供参考。 展开更多
关键词 闪蒸纺丝 减压式喷头 结构优化 数值模拟 减压室 纺丝液 速度 压力 涡量
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Smooth Solution to the 1-Dimensional Spin Equations of Antiferromagnets 被引量:1
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作者 ShiJinDING BoLingGUO 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2004年第5期899-912,共14页
In this paper,the global existence and uniqueness of a smooth solution to the periodic initial-value problem of the spin equations of antiferromagnets in 1 dimension are proved.
关键词 spin equations of antiferromagnets Smooth solutions EXISTENCE UNIQUENESS
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丝胶蛋白接枝聚合丙烯腈纺丝液的稳态流变性能
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作者 马利杰 朱金玉 +3 位作者 张瑞云 罗婷婷 吴建华 杨陌 《东华大学学报(自然科学版)》 北大核心 2025年第1期62-69,共8页
为充分利用蚕丝缫丝工艺中的废弃丝胶蛋白,并改善腈纶纤维的吸湿性能,将丝胶蛋白与丙烯腈进行接枝聚合,制备出改性纺丝液,进而探讨其稳态流变性能。采用幂律方程、Arrhenius方程及Spencer-Dillon经验公式等工具,对旋转流变仪取得的数据... 为充分利用蚕丝缫丝工艺中的废弃丝胶蛋白,并改善腈纶纤维的吸湿性能,将丝胶蛋白与丙烯腈进行接枝聚合,制备出改性纺丝液,进而探讨其稳态流变性能。采用幂律方程、Arrhenius方程及Spencer-Dillon经验公式等工具,对旋转流变仪取得的数据进行处理与拟合,深入分析了丝胶蛋白投料比、引发剂偶氮二异丁腈(AIBN)用量、温度、剪切速率等因素对纺丝流变特性的影响。研究结果显示:所有不同丝胶蛋白接枝聚合丙烯腈制备的纺丝液均表现出典型的假塑性流体特征,其非牛顿指数小于1。非牛顿指数随温度的升高而增大,而表观黏度、结构黏指数及稠度系数则随温度的上升而降低,黏流活化能随剪切速率的增加先减小后趋于稳定。丝胶蛋白投料比为15%、AIBN用量为0.8%时,所制纺丝液呈现较高的黏度,且对温度与剪切速率较为敏感。通过适当提高温度,可有效改善可纺性。 展开更多
关键词 稳态流变性能 聚丙烯腈纺丝液 丝胶蛋白 黏度 剪切速率 黏流活化能
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聚乙烯醇/海藻酸钠复合纳米纤维膜的制备及性能
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作者 明贺娜 刘福琛 +4 位作者 郭肖青 孙启航 孙明志 张传杰 刘杰 《产业用纺织品》 2025年第1期7-15,共9页
采用静电纺丝法制备聚乙烯醇(PVA)/海藻酸钠(SA)复合纳米纤维膜,然后采用氯化钙作为交联剂,对PVA/SA复合纳米纤维膜进行交联。研究静电纺丝工艺参数包括PVA溶液与SA溶液质量比、纺丝电压、接收距离对PVA/SA复合纳米纤维膜结构与性能的影... 采用静电纺丝法制备聚乙烯醇(PVA)/海藻酸钠(SA)复合纳米纤维膜,然后采用氯化钙作为交联剂,对PVA/SA复合纳米纤维膜进行交联。研究静电纺丝工艺参数包括PVA溶液与SA溶液质量比、纺丝电压、接收距离对PVA/SA复合纳米纤维膜结构与性能的影响,分析纤维直径及其分布。发现PVA/SA复合纳米纤维膜的最佳静电纺丝工艺参数:质量分数为8%的PVA溶液与质量分数为2%的SA溶液质量比9∶1、纺丝电压22 kV、接收距离10 cm。在此工艺条件下可得到形貌良好、直径分布均匀的PVA/SA复合纳米纤维,其平均直径为60.42 nm。傅里叶变换红外光谱分析、X射线衍射分析和动态接触角测试结果表明:SA的加入使PVA结晶度有所降低;PVA/SA复合纳米纤维膜表现出更强的亲水性,而交联后的纳米纤维膜表现出较强的疏水性。 展开更多
关键词 聚乙烯醇 海藻酸钠 静电纺丝 溶液质量比 纺丝电压 接收距离 纳米纤维膜 交联 亲水性 疏水性
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