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The time-fractional(2+1)-dimensional Heisenberg ferromagnetic spin chain equation:its Lie symmetries,exact solutions and conservation laws
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作者 Jicheng Yu Yuqiang Feng 《Communications in Theoretical Physics》 2025年第5期21-30,共10页
In this paper,the Lie symmetry analysis method is applied to the(2+1)-dimensional time-fractional Heisenberg ferromagnetic spin chain equation.We obtain all the Lie symmetries admitted by the governing equation and re... In this paper,the Lie symmetry analysis method is applied to the(2+1)-dimensional time-fractional Heisenberg ferromagnetic spin chain equation.We obtain all the Lie symmetries admitted by the governing equation and reduce the corresponding(2+1)-dimensional fractional partial differential equations with the Riemann–Liouville fractional derivative to(1+1)-dimensional counterparts with the Erdélyi–Kober fractional derivative.Then,we obtain the power series solutions of the reduced equations,prove their convergence and analyze their dynamic behavior graphically.In addition,the conservation laws for all the obtained Lie symmetries are constructed using the new conservation theorem and the generalization of Noether operators. 展开更多
关键词 Lie symmetries fractional partial differential equation Heisenberg ferromagnetic spin chain equation power series solutions conservation laws
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Low Mantle Perovskite:Solid Solution, Spin State of Iron and Water Solubility 被引量:1
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作者 LI Lin LI Qing LI Sheng-Rong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第6期1884-1894,共11页
Silicate perovskites((Mg, Fe)SiO 3 and CaS iO 3) are believed to be the major constituent minerals in the lower mantle. The phase relation, solid solution, spin state of iron and water solubility related to the lo... Silicate perovskites((Mg, Fe)SiO 3 and CaS iO 3) are believed to be the major constituent minerals in the lower mantle. The phase relation, solid solution, spin state of iron and water solubility related to the lower mantle perovskite are of great effect on the geodynamics of the Earth's interior and on ore mineralization. Previous studies indicate that a large amount of iron coupled with aluminum can incorporate into magnesium perovskite, but this is discordant with the disproportionation of(Mg,Fe)SiO 3 perovskite into iron-free MgS i O3 perovskite and hexagonal phase(Mg0.6Fe0.4)SiO 3 in the Earth's lower mantle. MnS iO 3 is the first chemical component confirmed to form wide range solid solution with Ca SiO 3 perovskite and complete solid solution with MgS i O3 perovskite at the P-T conditions in the lower mantle, and addition of Mn Si O3 will strongly affects the mutual solubility between Mg Si O3 and CaS iO 3. The spin state of iron is deeply depends on the site occupation of the Fe3+or Fe2+, the synthesis and the annealing conditions of the sample. It seems that the spin state of Fe2+ in the lower mantle perovskite can be settled as high spin, however, the existence of intermediate spin or low spin state of Fe2+ in perovskite has not been clarified. Moreover, different results have also been reported for the spin state of Fe3+ in perovskite. The water solubility of the lower mantle perovskite is related with its composition. In pure Mg SiO 3 perovskite, only less than 500 ppm water was reported. Al–Mg Si O3 perovskite or Al–Fe–MgS iO 3 perovskite in the lower mantle accommodates water of 1100 to 1800 ppm. Further experiments are necessary to clarify the detailed conditions for perovskite solid solution, to reliably analyze the valence and spin states of iron in the coexisting iron-bearing phases, and to compare the water solubility of different phases at different layers for deeply understanding the geodynamics of the Earth's interior and ore mineralization. 展开更多
关键词 solid solution spin state of iron water solubility PEROVSKITE low mantle
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Jingwei Intelligent:Providing versatile textile equipment and full-process solution
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《China Textile》 2025年第5期31-31,共1页
Jingwei Intelligent Textile Machinery Co.,Ltd.is a globally leading enterprise in the R&D and manufacturing of textile machinery,affiliated with China National Machinery Industry Group(SINOMACH).As the first moder... Jingwei Intelligent Textile Machinery Co.,Ltd.is a globally leading enterprise in the R&D and manufacturing of textile machinery,affiliated with China National Machinery Industry Group(SINOMACH).As the first modern textile machinery manufacturing base in New China,the company has developed over 70 years to establish a full lifecycle service capability of"machines+components+services+modifications."Its core products,such as Ring Spinning Frames and Combers,feature internationally advanced technologies.With products exported to over 40 countries and regions,the company is committed to providing global customers with intelligent,green textile equipment and full-process solutions. 展开更多
关键词 ring spinning frames R D textile machinery combers intelligent textile equipment textile machineryaffiliated full process solutions
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Exact solutions of an Ising spin chain with a spin-1 impurity
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作者 黄旭初 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第3期515-521,共7页
An exact solution of a single impurity model is hard to derive since it breaks translation invariance symmetry. We present the exact solution of the spin-1/2 transverse Ising chain imbedded by a spin-1 impurity. Using... An exact solution of a single impurity model is hard to derive since it breaks translation invariance symmetry. We present the exact solution of the spin-1/2 transverse Ising chain imbedded by a spin-1 impurity. Using the hole decompo- sition scheme, we exactly solve the spin-1 impurity in two subspaces which are generated by a conserved hole operator. The impurity enlarges the energy deformation of the ground state above a pure transverse Ising system without impurity. The specific heat coefficient shows a small anomaly at low temperature for finite size. This indicates that the impurity can tune the ground state from a magnetic impurity space to a non-magnetic impurity space, which only exists for spin-1 impurity comparing with spin-1/2 impurity and a pure transverse Ising chain without impurity. These behaviors essentially come from adding impurity freedom, which induces a competition between hole and fermion excitation depending on the coupling strength with its neighbor and the single-ion anisotropy. 展开更多
关键词 exact solution spin chain IMPURITY
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Exact Solution to Spin Squeezing of the Arbitrary-Range Spin Interaction and Transverse Field Model
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作者 陈星 张振伟 +3 位作者 赵环 王暖让 杨仁福 冯克明 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第10期62-66,共5页
We investigate spin squeezing effects of trapped ions in an off-resonance optical potential system using the arbitrary range spin spin interaction and transverse field model. The collective spin noises at any time are... We investigate spin squeezing effects of trapped ions in an off-resonance optical potential system using the arbitrary range spin spin interaction and transverse field model. The collective spin noises at any time are analyzed exactly. The general expression of spin squeezing factor is presented for arbitrary-range spin interaction. For the nearest-neighbor and next-nearest neighbor spin interaction model, the analytic solutions are reduced from the general expressions. It is shown that the maximum spin squeezing is enhanced for the general arbitrary-range spin interaction compared with the nearest-neighbor interaction model as the long-range interaction with arbitrary sites enforces stronger correlation. 展开更多
关键词 of on for in Exact solution to spin Squeezing of the Arbitrary-Range spin Interaction and Transverse Field Model is
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Solution Space Coupling in the Random K-Satisfiability Problem 被引量:1
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作者 曾颖 周海军 《Communications in Theoretical Physics》 SCIE CAS CSCD 2013年第9期363-374,共12页
The random K-satisfiability (K-SAT) problem is very diffcult when the clause density is close to the satisfiability threshold. In this paper we study this problem from the perspective of solution space coupling. We ... The random K-satisfiability (K-SAT) problem is very diffcult when the clause density is close to the satisfiability threshold. In this paper we study this problem from the perspective of solution space coupling. We divide a given difficult random K-SAT formula into two easy sub-formulas and let the two corresponding solution spaces to interact with each other through a coupling field x. We investigate the statistical mechanical property of this coupled system by mean field theory and computer simulations. The coupled system has an ergodicity-breaking (clustering) transition at certain critical value Xd of the coupling field. At this transition point, the mean overlap value between the solutions of the two solution spaces is very close to 1. The mean energy density of the coupled system at its clustering transition point is less than the mean energy density of the original K-SAT problem at the temperature-induced clustering transition point. The implications of this work for designing new heuristic K-SAT solvers are discussed. 展开更多
关键词 constraint satisfaction spin glass clustering transition belief propagation solution space
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On the Role of Differentiation Parameter in a Bound State Solution of the Klein-Gordon Equation
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作者 B.C.Lütfüo?lu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2019年第3期267-273,共7页
Recently, the bound state solutions of a confined Klein-Gordon particle under the mixed scalar-vector generalized symmetric Woods-Saxon potential in one spatial dimension have been investigated. The obtained results r... Recently, the bound state solutions of a confined Klein-Gordon particle under the mixed scalar-vector generalized symmetric Woods-Saxon potential in one spatial dimension have been investigated. The obtained results reveal that in the spin symmetric limit discrete spectrum exists, while in the pseudo-spin symmetric limit it does not.In this manuscript, new insights and information are given by employing an analogy of the variational principle. The role of the difference of the magnitudes of the vector and scalar potential energies, namely the differentiation parameter,on the energy spectrum is examined. It is observed that the differentiation parameter determines the measure of the energy spectrum density by modifying the confined particle's mass-energy in addition to narrowing the spectrum interval length. 展开更多
关键词 KLEIN-GORDON equation generalized symmetric Woods-Saxon potential BOUND st ate spectrum spin SYMMETRY limit ANALYTIC solutions
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Dynamic characteristics of multi-span spinning beams with elastic constraints under an axial compressive force
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作者 Xiaodong GUO Zhu SU Lifeng WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第2期295-310,共16页
A theoretical model for the multi-span spinning beams with elastic constraints under an axial compressive force is proposed.The displacement and bending angle functions are represented through an improved Fourier seri... A theoretical model for the multi-span spinning beams with elastic constraints under an axial compressive force is proposed.The displacement and bending angle functions are represented through an improved Fourier series,which ensures the continuity of the derivative at the boundary and enhances the convergence.The exact characteristic equations of the multi-span spinning beams with elastic constraints under an axial compressive force are derived by the Lagrange equation.The efficiency and accuracy of the present method are validated in comparison with the finite element method(FEM)and other methods.The effects of the boundary spring stiffness,the number of spans,the spinning velocity,and the axial compressive force on the dynamic characteristics of the multi-span spinning beams are studied.The results show that the present method can freely simulate any boundary constraints without modifying the solution process.The elastic range of linear springs is larger than that of torsion springs,and it is not affected by the number of spans.With an increase in the axial compressive force,the attenuation rate of the natural frequency of a spinning beam with a large number of spans becomes larger,while the attenuation rate with an elastic boundary is lower than that under a classic simply supported boundary. 展开更多
关键词 multi-span spinning beam elastic constraint improved Fourier series free vibration semi-analytical solution
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四乙烯五胺改性分级多孔碳纳米纤维复合膜的CO_(2)捕集性能研究
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作者 潘帅兴 王匀 +3 位作者 杨楷文 朱长顺 吴伟光 孟虎 《材料导报》 北大核心 2026年第7期255-260,共6页
二氧化碳(CO_(2))捕集是实现双碳目标的关键。本工作提出了一种四乙烯五胺(TEPA)功能化碳纳米纤维(CNFs)复合膜的制备工艺:结合溶液喷射纺丝(Solution blow spinning,SBS)和梯度碳化工艺制备出分级多孔CNFs骨架,并基于浸渍法利用TEPA溶... 二氧化碳(CO_(2))捕集是实现双碳目标的关键。本工作提出了一种四乙烯五胺(TEPA)功能化碳纳米纤维(CNFs)复合膜的制备工艺:结合溶液喷射纺丝(Solution blow spinning,SBS)和梯度碳化工艺制备出分级多孔CNFs骨架,并基于浸渍法利用TEPA溶液对CNFs骨架进行表面改性,成功构建了CNFs/TEPA复合膜。通过扫描电子显微镜(SEM)、傅里叶红外光谱仪(FTIR)、比表面积与孔径分析仪(BET)、热重分析仪(TGA)等表征手段探究了复合膜的比表面积、孔径分布以及CO_(2)吸附性能等关键参数。性能测试表明:CNFs/TEPA复合膜可有效协调TEPA的化学吸附机制与CNFs骨架的物理吸附特性,其吸附量符合“活性位点增益-结构损伤损耗”的竞争模型。当TEPA负载量为10%(质量分数)时,复合膜的吸附活性位点数量与比表面积、孔径达到平衡,在25℃、常压条件下的CO_(2)吸附容量可达2.41 mmol/g,较CNFs骨架提升了约10倍;此外,复合膜还展现出优异的选择吸附能力与可循环使用性能,分离因子高达30.125,且经15次吸脱附循环后仍能保持91%的初始吸附量,在CO_(2)捕集领域具有广阔的发展前景。 展开更多
关键词 溶液喷射纺丝 碳纳米纤维(CNFs) 四乙烯五胺(TEPA) 复合膜 CO_(2)吸附 协同机制
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有针和无针静电纺聚乙烯醇纳米纤维材料对比研究
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作者 余炎子 李思婧 +2 位作者 李雪璞 张久政 王洪 《产业用纺织品》 2026年第3期22-31,共10页
利用单针头静电纺丝技术和旋转式无针静电纺丝技术制备聚乙烯醇(PVA)纳米纤维材料。通过单因素试验调节制备过程中纺丝液质量分数、纺丝电压、纺丝液供给量和接收距离等工艺参数,对比PVA体系在2种技术中的可纺性,探究各参数对PVA纳米纤... 利用单针头静电纺丝技术和旋转式无针静电纺丝技术制备聚乙烯醇(PVA)纳米纤维材料。通过单因素试验调节制备过程中纺丝液质量分数、纺丝电压、纺丝液供给量和接收距离等工艺参数,对比PVA体系在2种技术中的可纺性,探究各参数对PVA纳米纤维形貌的影响。试验结果表明:PVA体系在2种静电纺丝技术中的可纺性存在差别,无针静电纺丝技术在PVA体系中的纺丝工艺窗口更窄,更容易出现纤维粘连等形貌瑕疵;同时,无针静电纺丝技术需要的纺丝电压远高于单针头静电纺丝技术,且受重力影响,无针静电纺丝技术更易得到粗纤维;多射流的同时形成使得无针静电纺丝技术具有更高的纳米纤维生产率,约为单针头静电纺丝技术的207倍。研究结果可为聚合物原料的静电纺纳米纤维的规模化生产提供参考。 展开更多
关键词 聚乙烯醇(PVA) 纳米纤维 有针静电纺丝 无针静电纺丝 纺丝液质量分数 纺丝电压 纺丝液供给量 接收距离
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Hasimoto曲面的运动及其相应的Spin方程的精确解(英文)
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作者 李翊神 陈春丽 《中国科学技术大学学报》 CAS CSCD 北大核心 2000年第3期253-262,共10页
利用测地坐标下的曲面运动与AKNS系统的关系 ,得到Hasimoto曲面运动的精确解 。
关键词 曲面运动 旋转方程 spin方程 Hasimoto曲面
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电纺丝液对PLGA纳米纤维制备的影响
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作者 杨凡 吴振刚 +1 位作者 魏恒勇 陈越军 《辽宁化工》 2026年第2期284-288,共5页
以N,N-二甲基乙酰胺(DMAc)和二氯甲烷(DCM)的混合液为溶剂,通过调节PLGA溶液质量分数和不同溶剂比,采用静电纺丝制备PLGA纳米纤维膜。通过扫描电子显微镜(SEM)对所制纳米纤维膜的微观形貌进行测试,采用表面张力仪、电导率仪对纺丝液进... 以N,N-二甲基乙酰胺(DMAc)和二氯甲烷(DCM)的混合液为溶剂,通过调节PLGA溶液质量分数和不同溶剂比,采用静电纺丝制备PLGA纳米纤维膜。通过扫描电子显微镜(SEM)对所制纳米纤维膜的微观形貌进行测试,采用表面张力仪、电导率仪对纺丝液进行测试。结果表明:PLGA溶液质量分数和溶剂比例对纤维膜的形貌及直径有较大影响;当DMAc和DCM体积比为1∶3、PLGA质量分数为18%时制备出的PLGA纤维形貌最佳,平均直径约为0.79μm,接触角为106.87°±0.47°,纤维膜材料的最大载荷量为(14.07±0.94)N,弹性模量为(103.14±6.46)MPa、拉伸断裂强度为(4.69±0.31)MPa、断裂伸长率为54.17%±0.27%。 展开更多
关键词 静电纺丝 PLGA 纺丝液
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具有螺旋项的耦合自旋极化系统整体弱解的存在性
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作者 席肖玉 许永麟 《广州大学学报(自然科学版)》 2026年第1期92-97,共6页
文章研究在三维空间中具有螺旋效应的耦合自旋极化系统,通过空间离散化,证明三维Cauchy问题弱解的整体存在性。
关键词 耦合自旋极化系统 全局弱解 螺旋项
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溶液喷纺PVA/CNT/CNC水凝胶微纳米纤维及其光热性能研究
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作者 李泽炜 王梓星 +1 位作者 张昌然 宗鲁 《化学研究》 2026年第1期68-75,共8页
光热水凝胶是在水凝胶基质中加入光热转换材料制备的功能性复合材料,具有光热转换能力和性能可调的特点。然而碳纳米管(CNT)、石墨烯(GO)和炭黑等疏水光热填料,在亲水凝胶基体中分散性差,降低光热性能和力学性能,而且块状水凝胶传质传... 光热水凝胶是在水凝胶基质中加入光热转换材料制备的功能性复合材料,具有光热转换能力和性能可调的特点。然而碳纳米管(CNT)、石墨烯(GO)和炭黑等疏水光热填料,在亲水凝胶基体中分散性差,降低光热性能和力学性能,而且块状水凝胶传质传热效果不佳。对此,研究了溶液喷纺技术,以聚乙烯醇(PVA)、碳纳米管和纤维素纳米晶(CNC)为原料制备了光热水凝胶纳米纤维;对水凝胶纤维的微观形貌和力学性能进行测试,分析CNC分散碳纳米管的原理,并测试了其光热转换性能。结果表明,利用CNC的两亲性改善了碳纳米管在水性纺丝液中的分散性,纤维形貌光滑均匀且直径~0.55μm,喷纺的水凝胶纤维与流延成膜的样品相比,结晶度从21%提高到30%,加入CNC后拉伸强度从1.7 MPa提升到3.3 MPa,断裂伸长率从102.8%提升到215.3%,同时具有良好的光热转换能力,吸光率> 80%,在太阳光照射下水蒸发速率可达2.90 kg·m^(-2)·h^(-1)。 展开更多
关键词 溶液喷纺 水凝胶 微纳米纤维 光热性能 太阳能水蒸发
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Double-stretching as an effective and generalizable strategy towards thinner nanofibers in solution blow spinning 被引量:1
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作者 Baopu Zhang Ziwei Li +4 位作者 Zekun Cheng Lei Li Chong Yang Haiyang Wang Hui Wu 《Nano Research》 SCIE EI CSCD 2023年第4期5709-5714,共6页
Solution blow spinning(SBS)applies high-speed airflow to prepare fibers by generating a strong stretching force.It has the advantages of scalable production,tailorable morphologies,and wide applicability.Yet,the SBS s... Solution blow spinning(SBS)applies high-speed airflow to prepare fibers by generating a strong stretching force.It has the advantages of scalable production,tailorable morphologies,and wide applicability.Yet,the SBS strategy can hardly prepare fibers down to the sub-100 nanometers,which limits its performance in demanding applications.Herein,we overcome the limitation of SBS by introducing a second airflow.This novel strategy is termed double-stretching SBS(DS-SBS)because an extra stretching force is exerted on the fiber when it converges with the second airflow.Polyamide6 nanofibers with an average diameter of 80 nm are successfully prepared with the DS-SBS strategy,while the SBS strategy could only prepare submicron fibers with an average diameter of 120 nm.Further,the generality of the DS-SBS strategy to reduce fiber diameter is verified on numerous solute-solvent pairs. 展开更多
关键词 NANOFIBERS solution blow spinning double-stretching computational fluid dynamics
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Six types of spin solitons in three-component Bose-Einstein condensates
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作者 Yu-Hao Wang Ling-Zheng Meng Li-Chen Zhao 《Communications in Theoretical Physics》 SCIE CAS CSCD 2024年第6期57-65,共9页
Exact analytical solutions are good candidates for studying and explaining the dynamics of solitons in nonlinear systems.We further extend the region of existence of spin solitons in the nonlinearity coefficient space... Exact analytical solutions are good candidates for studying and explaining the dynamics of solitons in nonlinear systems.We further extend the region of existence of spin solitons in the nonlinearity coefficient space for the spin-1 Bose-Einstein condensate.Six types of spin soliton solutions can be obtained,and they exist in different regions.Stability analysis and numerical simulation results indicate that three types of spin solitons are stable against weak noise.The non-integrable properties of the model can induce shape oscillation and increase in speed after the collision between two spin solitons.These results further enrich the soliton family for non-integrable models and can provide theoretical references for experimental studies. 展开更多
关键词 Bose-Einstein condensate NON-INTEGRABLE spin soliton exact analytical solution
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Polycaprolactone/polyvinyl pyrrolidone nanofibers developed by solution blow spinning for encapsulation of chlorogenic acid
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作者 Yang Cao Chaoyi Shen +3 位作者 Zhichao Yang Zihan Cai Zian Deng Di Wu 《Food Quality and Safety》 SCIE CSCD 2022年第2期265-274,共10页
Study on the application of nanofibers in food active packaging has been a research hotspot in recent years.In this work,solution blow spinning(SBS)was applied to rapidly fabricate the polycaprolactone(PCL),polyvinyl ... Study on the application of nanofibers in food active packaging has been a research hotspot in recent years.In this work,solution blow spinning(SBS)was applied to rapidly fabricate the polycaprolactone(PCL),polyvinyl pyrrolidone(PVP),and PCL/PVP nanofibrous films to encapsulate chlorogenic acid(CGA).All films showed uniform and smooth nanofibers,and the Fourier transform infrared spectroscopy and X-ray diffraction proved the success of mixed spinning of PCL and PVP.With the increase of PVP content,the thermal stability of the PCL/PVP nanofibrous films improved.The PCL/PVP(weight ratio of 4:1)film possessed better mechanical properties than PCL and PVP films be-cause of the stronger fiber-fiber interactions.The addition of PCL endowed the hydrophobic surfaces to the PCL/PVP films,and the PCL/PVP films had better water vapor barrier ability.The PCL/PVP(4:1)film exhibited the best long-term continuous release of CGA during 72 h.The PVP nanofibrous film exhibited no inhibition against Staphylococcus aureus and Escherichia coli due to the low encapsulation efficiency,but the PCL and PCL/PVP films exhibited good antimicrobial activity.The above results suggested that the nanofibrous fims developed by SBS possess promising prospects in food packaging. 展开更多
关键词 solution blow spinning POLYCAPROLACTONE polvinyl prrolidone chlorogenic acid long-term continuous release
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醇解度和纺丝液含量对聚乙烯醇静电纺纳米纤维隔膜性能的影响 被引量:1
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作者 毕谷帅 张锦中 +1 位作者 唐晓峰 查刘生 《化工新型材料》 北大核心 2025年第3期141-145,共5页
以聚乙烯醇(PVA)为成纤聚合物,以水为溶剂,通过静电纺丝技术制备了锂离子电池用纳米纤维隔膜,研究了PVA醇解度和纺丝液含量对隔膜孔隙率、吸液率、热尺寸稳定性、力学性能和电化学性能的影响。结果表明:在纺丝液含量相同的条件下,PVA的... 以聚乙烯醇(PVA)为成纤聚合物,以水为溶剂,通过静电纺丝技术制备了锂离子电池用纳米纤维隔膜,研究了PVA醇解度和纺丝液含量对隔膜孔隙率、吸液率、热尺寸稳定性、力学性能和电化学性能的影响。结果表明:在纺丝液含量相同的条件下,PVA的醇解度越高,隔膜的孔隙率、吸液率、抗拉强度、热尺寸稳定性和离子电导率呈逐渐增大的趋势;在PVA醇解度相同的条件下,随着纺丝液含量的增加,隔膜的孔隙率和离子电导率逐渐升高,抗拉强度呈下降趋势;PVA的醇解度和纺丝液含量对隔膜的电化学稳定性影响很小。 展开更多
关键词 锂离子电池 纳米纤维隔膜 聚乙烯醇 静电纺丝 醇解度 纺丝液含量
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丝胶蛋白与丙烯腈共聚纺丝液的制备及性能
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作者 朱金玉 马利杰 +2 位作者 刘蕴莹 程隆棣 张瑞云 《上海纺织科技》 2025年第3期66-71,共6页
以50wt%硫氰酸钠水溶液为溶剂,制备了不同丝胶蛋白/丙烯腈比例的丝胶蛋白/丙烯腈共聚纺丝原液。测定了聚合产物的特征峰、转化率、黏均分子量以及纺丝原液的稳态剪切流变性能。结果表明:共聚物同时具有丝胶蛋白的酰胺特征峰和聚丙烯腈... 以50wt%硫氰酸钠水溶液为溶剂,制备了不同丝胶蛋白/丙烯腈比例的丝胶蛋白/丙烯腈共聚纺丝原液。测定了聚合产物的特征峰、转化率、黏均分子量以及纺丝原液的稳态剪切流变性能。结果表明:共聚物同时具有丝胶蛋白的酰胺特征峰和聚丙烯腈的氰基特征峰;引发剂质量分数增加,共聚物转化率升高,最高为78.5%,黏均分子量则随之减小;丝胶蛋白/丙烯腈共聚纺丝原液的表观黏度会随剪切速率的增加而减小,属于切力变稀型的非牛顿流体;温度升高,纺丝液表观黏度减小,剪敏性降低。 展开更多
关键词 丝胶蛋白 丙烯腈 纺丝液 表观黏度
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密胺纤维的改性研究进展
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作者 何利华 刘志凌 +2 位作者 李慧霞 蒋凡顺 张建勋 《河南化工》 2025年第9期16-20,共5页
密胺纤维作为新型高效阻燃材料,凭借其原料成本低、无熔滴特性以及耐高温和耐化学腐蚀性能,在阻燃领域具有重要应用价值。然而,其前驱体密胺树脂作为典型的热固性高分子材料,存在可纺性差的技术瓶颈。研究表明,提升纺丝液的稳定性和成... 密胺纤维作为新型高效阻燃材料,凭借其原料成本低、无熔滴特性以及耐高温和耐化学腐蚀性能,在阻燃领域具有重要应用价值。然而,其前驱体密胺树脂作为典型的热固性高分子材料,存在可纺性差的技术瓶颈。研究表明,提升纺丝液的稳定性和成纤性是优化纤维基础性能的关键;而进一步增强纤维的力学性能和阻燃性则可有效拓展其在高附加值领域的应用范围。从提升纺丝液性能和纤维性能两方面,系统梳理了近年来国内外在密胺纤维改性领域的创新成果,为突破密胺纤维的产业化应用瓶颈提供理论依据和技术参考。 展开更多
关键词 密胺纤维 改性 纺丝液 力学性能 极限氧指数
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