Cesium lead iodide perovskites offer promising stability and a bandgap near 1.7 eV,making them suitable as the top cell in tandem solar cells.However,the inorganic perovskite films suffer from a high defect density an...Cesium lead iodide perovskites offer promising stability and a bandgap near 1.7 eV,making them suitable as the top cell in tandem solar cells.However,the inorganic perovskite films suffer from a high defect density and substantial recombination losses,undermining their optoelectronic performances.Here,by activating the aromatic system,we develop 4-methoxybenzoylhydrazine(MeOBH)-modified CsPbI_(3) film with regulated crystallinity,suppressed non-radiative recombination,and improved interfacial energetic alignment.The resultant inorganic perovskite solar cells achieved a power conversion efficiency of 20.95%,along with enhanced phase stability owing to the strong coordination interaction between the lead cation and the hydrazide group.Encapsulated devices retain 90.4% of the initial performance after 624 h of maximum power point operation under the ISOS-L-1I protocol.展开更多
基金financially supported by the National Ten Thousand Talent Program (H.C.)。
文摘Cesium lead iodide perovskites offer promising stability and a bandgap near 1.7 eV,making them suitable as the top cell in tandem solar cells.However,the inorganic perovskite films suffer from a high defect density and substantial recombination losses,undermining their optoelectronic performances.Here,by activating the aromatic system,we develop 4-methoxybenzoylhydrazine(MeOBH)-modified CsPbI_(3) film with regulated crystallinity,suppressed non-radiative recombination,and improved interfacial energetic alignment.The resultant inorganic perovskite solar cells achieved a power conversion efficiency of 20.95%,along with enhanced phase stability owing to the strong coordination interaction between the lead cation and the hydrazide group.Encapsulated devices retain 90.4% of the initial performance after 624 h of maximum power point operation under the ISOS-L-1I protocol.
