Globally,mealtimes provide key insights into cultural and social values and practices.We examine mealtime environments and eating practices in two different African settings using quantitative observational and questi...Globally,mealtimes provide key insights into cultural and social values and practices.We examine mealtime environments and eating practices in two different African settings using quantitative observational and questionnaire data.Participating families(N=80)were recruited from two rural locations in Zambia and Kenya.Results following descriptive analysis showed that meals are typically taken as a family in a sociable context,providing opportunities to nurture children’s positive behaviours.In both communities,mothers(71.25%)were most likely to be present and typically prepared meals and provided the food.We observed a few distractions being used during mealtimes,and children finished their food with little to no conflict.Plate sharing varied across the two sites and was more common in Zambia,where we also observed more traditional practices such as eating with hands(as opposed to cutlery)and sitting on mats on the ground(as opposed to seated on chairs or sofas).Overall,our findings suggest more similarities in the cultural and social values across the two African contexts despite slight differences in mealtime practices.In particular,positive mealtime behaviours(little food refusal,lack of conflict)were common across all contexts,regardless of the extent to which traditional practices(such as plate-sharing and sitting on the floor)were used.Findings align with Family Systems theory,which states that the family is understood best by conceptualizing it as a complex,dynamic,and changing collection of parts,subsystems,and family members.展开更多
Although various Climate-Smart Agricultural(CSA) practices are promoted to safeguard agricultural production and food security in the Global South,their adoption remains limited.This study conducted a cross-sectional ...Although various Climate-Smart Agricultural(CSA) practices are promoted to safeguard agricultural production and food security in the Global South,their adoption remains limited.This study conducted a cross-sectional survey using a semi-structured questionnaire between March and April in 2023,with a sample of 231 smallholder farmers covering 5 villages(Purbo Karpara,Rampasa,Monohor Pur,Boro Isubpur,and Char Alapur) in Haor wetlands of Bangladesh.Then,this study examined smallholder farmers' adoption intention of floating farming practice in Haor wetlands of Bangladesh based on an extended Theory of Planned Behaviour(TPB) model.The result demonstrated moderate predictive power of the proposed model,where farmers' attitude,subjective norm,knowledge of floating farming practice,perceived behavioural control,and institutional accessibility jointly explained 11.50% of the total variance in adoption intention,with subjective norm and perceived behavioural control showing significant impact on smallholder farmers' adoption intention.However,key barriers reported by smallholder farmers included unavailability of resources,limited access to modern farming practices,input and credit unavailability,insufficient access to training,and limited access to market system.These findings indicated that improving smallholder farmers' access to extension services and credit facilities,raising awareness,providing training,and guaranteeing access to accurate and timely climate information and early warning systems could significantly improve their adaptive capacity.This study contributes to socio-psychological understanding of smallholder farmers' pro-environmental behaviour and emphasises the need for context-specific interventions to support sustainable livelihoods and resilient agri-food systems in climate-vulnerable regions.展开更多
The coronavirus disease 2019(COVID-19)pandemic caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)affected health,economies,and lifestyles,but little is known about its impact on children.We aimed to...The coronavirus disease 2019(COVID-19)pandemic caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)affected health,economies,and lifestyles,but little is known about its impact on children.We aimed to investigate changes in 24-hour(h)movement behaviours of pre-school children before and during COVID-19,and factors that influenced these.Children aged 3-6 years were recruited in Beijing in 2019,and their movement behaviours over 24h assessed by questionnaire,as part of the International Study of Movement Behaviors in the Early Years(SUNRISE)study.We conducted the survey again during COVID-19,and compared the children’s movement behaviours before and during COVID-19 and associated factors.Overall,196 parents completed the survey at both time points.The percentage of children meeting movement guidelines decreased during the pandemic(p<0.01).Total physical activity decreased less among children getting good quality sleep or with more adults in the household(p<0.01).Children who were not cared for primarily by their mother had a greater decrease in moderate to vigorous intensity physical activity(p=0.02),but the decrease was smaller among children whose parents used the internet to support their physical activity and/or screen time(p<0.05).Children who used electronic screen devices in the 2h before bedtime or whose parents reported body temperature in webchats had a greater increase in sedentary screen time(p<0.05).Children spending more time outdoors showed a smaller decrease in sleep(p<0.01).Overall,children’s movement behaviours changed significantly during the pandemic.展开更多
Background The decreasing prevalence of physical activity(PA)among urban children in Sub-Saharan Africa is a growing public health concern.More emphasis should focus on examining the influence of parental PA behaviour...Background The decreasing prevalence of physical activity(PA)among urban children in Sub-Saharan Africa is a growing public health concern.More emphasis should focus on examining the influence of parental PA behaviour on the children’s PA patterns.We explored associations of 24hour(h)accelerometer-measured movement behaviours of guardian-child pairs in Nairobi City County,Kenya.Methods This cross-sectional study assessed 80 pairs consisting of children aged 9-14 years and their guardians in one area of low and one area of middle socioeconomic status(SES)(Embakasi Sub-County and Lang’ata Sub-County),in Nairobi City County,Kenya.The study used waist worn Tri-axial Actigraph(GT3X+and ActiSleep+)accelerometers to quantify PA and sedentary time(SED).Association between guardians'and children’s PA was examined using linear regression,adjusting for guardians'educational attainment and household wealth.Results Of the children,42(52.5%)and 76(96.2%)of the guardians were women.Children in low SES areas spent more time(p<0.001)in moderate-to-vigorous physical activity compared to children from middle SES area.The guardians in low SES area were younger and spent more time in light PA(p=0.036)while their counterparts had higher daily SED(p=0.049).Guardian’s SED associated with higher children’s SED(p=0.033)even after adjusting for guardians'educational attainment(p=0.032)and wealth(p=0.05).There was no association between guardians'and children’s MVPA.Conclusion Considered alongside the extant literature,these results suggest that health promotion strategies should aim to reduce parental SED time while also planning to increase children’s PA.展开更多
Laser debonding technology has been widely used in advanced chip packaging,such as fan-out integration,2.5D/3D ICs,and MEMS devices.Typically,laser debonding of bonded pairs(R/R separation)is typically achieved by com...Laser debonding technology has been widely used in advanced chip packaging,such as fan-out integration,2.5D/3D ICs,and MEMS devices.Typically,laser debonding of bonded pairs(R/R separation)is typically achieved by completely removing the material from the ablation region within the release material layer at high energy densities.However,this R/R separation method often results in a significant amount of release material and carbonized debris remaining on the surface of the device wafer,severely reducing product yields and cleaning efficiency for ultra-thin device wafers.Here,we proposed an interfacial separation strategy based on laser-induced hot stamping effect and thermoelastic stress wave,which enables stress-free separation of wafer bonding pairs at the interface of the release layer and the adhesive layer(R/A separation).By comprehensively analyzing the micro-morphology and material composition of the release material,we elucidated the laser debonding behavior of bonded pairs under different separation modes.Additionally,we calculated the ablation threshold of the release material in the case of wafer bonding and established the processing window for different separation methods.This work offers a fresh perspective on the development and application of laser debonding technology.The proposed R/A interface separation method is versatile,controllable,and highly reliable,and does not leave release materials and carbonized debris on device wafers,demonstrating strong industrial adaptability,which greatly facilitates the application and development of advanced packaging for ultra-thin chips.展开更多
目的系统梳理行为理论和模型在药学实践研究中的应用现状,总结其应用特点、作用与价值。方法采用范围综述法,检索Web of Science、PubMed、Embase、Cochrane Library及中国知网、万方数据库、维普中文科技期刊数据库、中国生物医学数据...目的系统梳理行为理论和模型在药学实践研究中的应用现状,总结其应用特点、作用与价值。方法采用范围综述法,检索Web of Science、PubMed、Embase、Cochrane Library及中国知网、万方数据库、维普中文科技期刊数据库、中国生物医学数据库中所有使用行为理论或模型的药学实践相关文章,检索期限为建库至2025年3月31日。由2名研究者独立对纳入的文献数据进行汇总、筛选、归类及分析。结果共检索到文献1669篇,最终纳入110篇。通过文献分析,提取出药学实践中5个高频使用理论模型,依次为计划行为理论(TPB)、跨理论模型(TTM)、行为改变理论(COM-B)、健康信念模型(HBM)、社会认知理论(SCT),国内外药学实践研究常用理论模型及围绕主题存在一定差异。大多数研究采用单一理论模型,国内外最常见的组合分别是TPB与TTM、COM-B与理论领域框架(TDF)。研究多属于英国医学研究委员会(UK MRC)复杂干预研究框架中的前2个阶段。国外研究人员主要为药学人员及卫生管理部门,而我国主要为护理人员,其次为药学人员。结论我国药学实践研究尚处于起步阶段,有必要借鉴国际经验,明确研究问题并选择合适的理论模型,提高药学服务有效性和可持续性的同时提高研究的科学性和实用性,推动国内药学实践研究的发展。展开更多
Understanding the bubble behaviours and flow characteristics of large-capacity bottom-blowing electric arc furnace(EAF)is crucial for potential exogenous gas-induced slag foaming process and enhancement of molten bath...Understanding the bubble behaviours and flow characteristics of large-capacity bottom-blowing electric arc furnace(EAF)is crucial for potential exogenous gas-induced slag foaming process and enhancement of molten bath dynamics.A physical model and a 3D gas-slag-steel transient bottom-blowing numerical model of a 150 t EAF were established to investigate the bubble behaviour and flow characteristics throughout the molten steel bath and slag layer under bottom-blowing,with referring to gas flow rate,plug diameter,plug arrangement and injection angle.Results indicate that the average bubble sizes experience increase,dynamic stability and decrease in molten steel bath and then undergo decrease and increase after entering into slag layer for all bottom-blowing modes.The bubble numbers exhibit the opposing trends during the process.Increase in gas flow rate leads to a significant rise in average bubble size but a decrease in number,average dwelling time and the spread area of bubbles in slag layer.Increase in plug diameter causes an opposite impact.The effect of plug arrangement radii on bubbles is almost negligible.Increasing the injection angle results in an increase in bubble size and a decrease in both bubble number and dwelling time in slag layer.The slag foaming potential was discussed referring to the bubble size,number and dwelling time in slag layer.Increase in gas flow rate and plug diameters can significantly enhance the fluids flow through increasing average flow velocity,decreasing mixing time and dead zone ratio of molten bath.Plug arrangement radius and injection angle express nonlinear correlation with average flow velocity and dead zone ratio,and the plug arrangement radius of 0.5R(R represents the radius of bottom circle of EAF model)and injection angle of 15°perform better in enhancing dynamics of molten bath.A group of bottom-blowing parameters are proposed to achieve better comprehensive performance of bubble-induced slag foaming and molten bath dynamics.展开更多
To address the critical challenge of risk perception and assessment for autonomous vehicles in dynamic interactive envi-ronments,this study proposes a semi-supervised spatiotemporal interaction risk cognition network ...To address the critical challenge of risk perception and assessment for autonomous vehicles in dynamic interactive envi-ronments,this study proposes a semi-supervised spatiotemporal interaction risk cognition network with attention mecha-nism(SS-SIRCN),inspired by the behavioral adaptation patterns of biological groups under external threats.First,by thoroughly analyzing the dynamic interaction characteristics exhibited by typical biological collectives when exposed to risk,the study reveals the underlying patterns of trajectory changes influenced by external danger.Then,an attention-based spatiotemporal risk cognition network is designed to establish a mapping between driving behavior features and potential driving risks.Finally,a semi-supervised learning framework is employed to enable risk assessment for autono-mous vehicles using only a small amount of labeled data.Experimental results on real-world vehicle trajectory datasets demonstrate that the proposed method achieves a risk prediction accuracy of 90.76%,outperforming other baseline models in performance.展开更多
The structural changes in the CaO-SiO_(2)-Al_(2)O_(3)-MgO slag system with varying CaO contents were investigated through molecular dynamics(MD)simulations,and its effect on the dissolution behavior of alumina inclusi...The structural changes in the CaO-SiO_(2)-Al_(2)O_(3)-MgO slag system with varying CaO contents were investigated through molecular dynamics(MD)simulations,and its effect on the dissolution behavior of alumina inclusions was characterized by the Kullback-Leibler(KL)divergence.The slag structure analysis revealed that the[AlO]tetrahedral structure was the primary network structure in the slag.With increasing the CaO content,the non-bridge oxygen(NBO)content in the slag structure increases,and the bridge oxygen(BO)content decreases,thereby reducing the complexity of the slag network structure.Raman spectroscopy detection verifies the results of the MD simulations.The results indicated that the dissolution rate of alumina inclusions accelerates with increasing the CaO content in the slag,owing to the reduced complexity of the slag network structure and the enhanced interatomic interactions.The simulation results for the dissolution of alumina inclusions were consistent with theoretical calculations based on the slag inclusion capacity and the dimensionless dissolution rate of inclusions.Radial distribution function analysis demonstrated that the interaction between atoms in the slag system and alumina inclusions strengthens,increasing the dissolution rate of alumina inclusions.The[AlO_(6)]octahedral structure of the alumina inclusions is disrupted,forming BO structures,which in turn enhances the complexity of the slag network structure,slowing the dissolution rate of alumina inclusions.In contrast,the slag system with a higher CaO content has a relatively simpler network structure,promoting faster alumina inclusion dissolution.展开更多
基金funded by UKRI Global Challenges Research Fund through the Economic and Social Research Council(grant reference:ES/T004959/1)with additional partial support from the National Research Foundation of South Africa(grant CSUR230503101533)。
文摘Globally,mealtimes provide key insights into cultural and social values and practices.We examine mealtime environments and eating practices in two different African settings using quantitative observational and questionnaire data.Participating families(N=80)were recruited from two rural locations in Zambia and Kenya.Results following descriptive analysis showed that meals are typically taken as a family in a sociable context,providing opportunities to nurture children’s positive behaviours.In both communities,mothers(71.25%)were most likely to be present and typically prepared meals and provided the food.We observed a few distractions being used during mealtimes,and children finished their food with little to no conflict.Plate sharing varied across the two sites and was more common in Zambia,where we also observed more traditional practices such as eating with hands(as opposed to cutlery)and sitting on mats on the ground(as opposed to seated on chairs or sofas).Overall,our findings suggest more similarities in the cultural and social values across the two African contexts despite slight differences in mealtime practices.In particular,positive mealtime behaviours(little food refusal,lack of conflict)were common across all contexts,regardless of the extent to which traditional practices(such as plate-sharing and sitting on the floor)were used.Findings align with Family Systems theory,which states that the family is understood best by conceptualizing it as a complex,dynamic,and changing collection of parts,subsystems,and family members.
基金Ghent University,Belgium,for providing the research support for this study。
文摘Although various Climate-Smart Agricultural(CSA) practices are promoted to safeguard agricultural production and food security in the Global South,their adoption remains limited.This study conducted a cross-sectional survey using a semi-structured questionnaire between March and April in 2023,with a sample of 231 smallholder farmers covering 5 villages(Purbo Karpara,Rampasa,Monohor Pur,Boro Isubpur,and Char Alapur) in Haor wetlands of Bangladesh.Then,this study examined smallholder farmers' adoption intention of floating farming practice in Haor wetlands of Bangladesh based on an extended Theory of Planned Behaviour(TPB) model.The result demonstrated moderate predictive power of the proposed model,where farmers' attitude,subjective norm,knowledge of floating farming practice,perceived behavioural control,and institutional accessibility jointly explained 11.50% of the total variance in adoption intention,with subjective norm and perceived behavioural control showing significant impact on smallholder farmers' adoption intention.However,key barriers reported by smallholder farmers included unavailability of resources,limited access to modern farming practices,input and credit unavailability,insufficient access to training,and limited access to market system.These findings indicated that improving smallholder farmers' access to extension services and credit facilities,raising awareness,providing training,and guaranteeing access to accurate and timely climate information and early warning systems could significantly improve their adaptive capacity.This study contributes to socio-psychological understanding of smallholder farmers' pro-environmental behaviour and emphasises the need for context-specific interventions to support sustainable livelihoods and resilient agri-food systems in climate-vulnerable regions.
基金upported by Public service development and reform pilot project of Beijing Medical Research Institute(BMR2021-3).
文摘The coronavirus disease 2019(COVID-19)pandemic caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)affected health,economies,and lifestyles,but little is known about its impact on children.We aimed to investigate changes in 24-hour(h)movement behaviours of pre-school children before and during COVID-19,and factors that influenced these.Children aged 3-6 years were recruited in Beijing in 2019,and their movement behaviours over 24h assessed by questionnaire,as part of the International Study of Movement Behaviors in the Early Years(SUNRISE)study.We conducted the survey again during COVID-19,and compared the children’s movement behaviours before and during COVID-19 and associated factors.Overall,196 parents completed the survey at both time points.The percentage of children meeting movement guidelines decreased during the pandemic(p<0.01).Total physical activity decreased less among children getting good quality sleep or with more adults in the household(p<0.01).Children who were not cared for primarily by their mother had a greater decrease in moderate to vigorous intensity physical activity(p=0.02),but the decrease was smaller among children whose parents used the internet to support their physical activity and/or screen time(p<0.05).Children who used electronic screen devices in the 2h before bedtime or whose parents reported body temperature in webchats had a greater increase in sedentary screen time(p<0.05).Children spending more time outdoors showed a smaller decrease in sleep(p<0.01).Overall,children’s movement behaviours changed significantly during the pandemic.
基金funded by the Finnish Ministry of Foreign Affairs through the Higher Education Institutions Institutional Cooperation Instrument,grant no.HEL7M0453-82(https://www.oph.fi/en/programmes/hei-ici-programme).
文摘Background The decreasing prevalence of physical activity(PA)among urban children in Sub-Saharan Africa is a growing public health concern.More emphasis should focus on examining the influence of parental PA behaviour on the children’s PA patterns.We explored associations of 24hour(h)accelerometer-measured movement behaviours of guardian-child pairs in Nairobi City County,Kenya.Methods This cross-sectional study assessed 80 pairs consisting of children aged 9-14 years and their guardians in one area of low and one area of middle socioeconomic status(SES)(Embakasi Sub-County and Lang’ata Sub-County),in Nairobi City County,Kenya.The study used waist worn Tri-axial Actigraph(GT3X+and ActiSleep+)accelerometers to quantify PA and sedentary time(SED).Association between guardians'and children’s PA was examined using linear regression,adjusting for guardians'educational attainment and household wealth.Results Of the children,42(52.5%)and 76(96.2%)of the guardians were women.Children in low SES areas spent more time(p<0.001)in moderate-to-vigorous physical activity compared to children from middle SES area.The guardians in low SES area were younger and spent more time in light PA(p=0.036)while their counterparts had higher daily SED(p=0.049).Guardian’s SED associated with higher children’s SED(p=0.033)even after adjusting for guardians'educational attainment(p=0.032)and wealth(p=0.05).There was no association between guardians'and children’s MVPA.Conclusion Considered alongside the extant literature,these results suggest that health promotion strategies should aim to reduce parental SED time while also planning to increase children’s PA.
基金the National Natural Science Foundation of China(62174170)the Natural Science Foundation of Guangdong Province(2024A1515010123)+4 种基金the Shenzhen Science and Technology Program(20220807020526001)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0670000)the Shenzhen Science and Technology Program(KJZD20230923114708018,KJZD20230923114710022)the Talent Support Project of Guangdong(2021TX06C101)the Shenzhen Basic Research(JCYJ20210324115406019).
文摘Laser debonding technology has been widely used in advanced chip packaging,such as fan-out integration,2.5D/3D ICs,and MEMS devices.Typically,laser debonding of bonded pairs(R/R separation)is typically achieved by completely removing the material from the ablation region within the release material layer at high energy densities.However,this R/R separation method often results in a significant amount of release material and carbonized debris remaining on the surface of the device wafer,severely reducing product yields and cleaning efficiency for ultra-thin device wafers.Here,we proposed an interfacial separation strategy based on laser-induced hot stamping effect and thermoelastic stress wave,which enables stress-free separation of wafer bonding pairs at the interface of the release layer and the adhesive layer(R/A separation).By comprehensively analyzing the micro-morphology and material composition of the release material,we elucidated the laser debonding behavior of bonded pairs under different separation modes.Additionally,we calculated the ablation threshold of the release material in the case of wafer bonding and established the processing window for different separation methods.This work offers a fresh perspective on the development and application of laser debonding technology.The proposed R/A interface separation method is versatile,controllable,and highly reliable,and does not leave release materials and carbonized debris on device wafers,demonstrating strong industrial adaptability,which greatly facilitates the application and development of advanced packaging for ultra-thin chips.
文摘目的系统梳理行为理论和模型在药学实践研究中的应用现状,总结其应用特点、作用与价值。方法采用范围综述法,检索Web of Science、PubMed、Embase、Cochrane Library及中国知网、万方数据库、维普中文科技期刊数据库、中国生物医学数据库中所有使用行为理论或模型的药学实践相关文章,检索期限为建库至2025年3月31日。由2名研究者独立对纳入的文献数据进行汇总、筛选、归类及分析。结果共检索到文献1669篇,最终纳入110篇。通过文献分析,提取出药学实践中5个高频使用理论模型,依次为计划行为理论(TPB)、跨理论模型(TTM)、行为改变理论(COM-B)、健康信念模型(HBM)、社会认知理论(SCT),国内外药学实践研究常用理论模型及围绕主题存在一定差异。大多数研究采用单一理论模型,国内外最常见的组合分别是TPB与TTM、COM-B与理论领域框架(TDF)。研究多属于英国医学研究委员会(UK MRC)复杂干预研究框架中的前2个阶段。国外研究人员主要为药学人员及卫生管理部门,而我国主要为护理人员,其次为药学人员。结论我国药学实践研究尚处于起步阶段,有必要借鉴国际经验,明确研究问题并选择合适的理论模型,提高药学服务有效性和可持续性的同时提高研究的科学性和实用性,推动国内药学实践研究的发展。
基金supported by the National Natural Science Foundation of China(Grant No.52374317).
文摘Understanding the bubble behaviours and flow characteristics of large-capacity bottom-blowing electric arc furnace(EAF)is crucial for potential exogenous gas-induced slag foaming process and enhancement of molten bath dynamics.A physical model and a 3D gas-slag-steel transient bottom-blowing numerical model of a 150 t EAF were established to investigate the bubble behaviour and flow characteristics throughout the molten steel bath and slag layer under bottom-blowing,with referring to gas flow rate,plug diameter,plug arrangement and injection angle.Results indicate that the average bubble sizes experience increase,dynamic stability and decrease in molten steel bath and then undergo decrease and increase after entering into slag layer for all bottom-blowing modes.The bubble numbers exhibit the opposing trends during the process.Increase in gas flow rate leads to a significant rise in average bubble size but a decrease in number,average dwelling time and the spread area of bubbles in slag layer.Increase in plug diameter causes an opposite impact.The effect of plug arrangement radii on bubbles is almost negligible.Increasing the injection angle results in an increase in bubble size and a decrease in both bubble number and dwelling time in slag layer.The slag foaming potential was discussed referring to the bubble size,number and dwelling time in slag layer.Increase in gas flow rate and plug diameters can significantly enhance the fluids flow through increasing average flow velocity,decreasing mixing time and dead zone ratio of molten bath.Plug arrangement radius and injection angle express nonlinear correlation with average flow velocity and dead zone ratio,and the plug arrangement radius of 0.5R(R represents the radius of bottom circle of EAF model)and injection angle of 15°perform better in enhancing dynamics of molten bath.A group of bottom-blowing parameters are proposed to achieve better comprehensive performance of bubble-induced slag foaming and molten bath dynamics.
基金the Jilin Provincial Department of Science and Technology Youth Science and Technology Talent Cultivation Project(20250602051RC)Fundamental Research Funds for the Central Universities(2025-JCXK-19)National Natural Science Foundation of China under Grant 52272417.
文摘To address the critical challenge of risk perception and assessment for autonomous vehicles in dynamic interactive envi-ronments,this study proposes a semi-supervised spatiotemporal interaction risk cognition network with attention mecha-nism(SS-SIRCN),inspired by the behavioral adaptation patterns of biological groups under external threats.First,by thoroughly analyzing the dynamic interaction characteristics exhibited by typical biological collectives when exposed to risk,the study reveals the underlying patterns of trajectory changes influenced by external danger.Then,an attention-based spatiotemporal risk cognition network is designed to establish a mapping between driving behavior features and potential driving risks.Finally,a semi-supervised learning framework is employed to enable risk assessment for autono-mous vehicles using only a small amount of labeled data.Experimental results on real-world vehicle trajectory datasets demonstrate that the proposed method achieves a risk prediction accuracy of 90.76%,outperforming other baseline models in performance.
基金supported by Special Funding Projects for Local Science and Technology Development guided by the Central Committee(No.YDZJSX2022C028)the Fundamental Research Program of Shanxi Province(Nos.20210302123218 and 202203021211187)+4 种基金Innovation and Entrepreneurship Training Program for College Students in Shanxi Province(202210109006)the National Natural Science Foundation(52474367)the Key Research and Development for University-Local Government Collaboration of Lvliang City(2024XDHZ01)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2025Q022)the Foundation of State Key Laboratory of Advanced Metallurgy,USTB(K22-10).
文摘The structural changes in the CaO-SiO_(2)-Al_(2)O_(3)-MgO slag system with varying CaO contents were investigated through molecular dynamics(MD)simulations,and its effect on the dissolution behavior of alumina inclusions was characterized by the Kullback-Leibler(KL)divergence.The slag structure analysis revealed that the[AlO]tetrahedral structure was the primary network structure in the slag.With increasing the CaO content,the non-bridge oxygen(NBO)content in the slag structure increases,and the bridge oxygen(BO)content decreases,thereby reducing the complexity of the slag network structure.Raman spectroscopy detection verifies the results of the MD simulations.The results indicated that the dissolution rate of alumina inclusions accelerates with increasing the CaO content in the slag,owing to the reduced complexity of the slag network structure and the enhanced interatomic interactions.The simulation results for the dissolution of alumina inclusions were consistent with theoretical calculations based on the slag inclusion capacity and the dimensionless dissolution rate of inclusions.Radial distribution function analysis demonstrated that the interaction between atoms in the slag system and alumina inclusions strengthens,increasing the dissolution rate of alumina inclusions.The[AlO_(6)]octahedral structure of the alumina inclusions is disrupted,forming BO structures,which in turn enhances the complexity of the slag network structure,slowing the dissolution rate of alumina inclusions.In contrast,the slag system with a higher CaO content has a relatively simpler network structure,promoting faster alumina inclusion dissolution.
