The feasibility of using N,N,N＇,N＇-tetra（2-ethylhexyl）diglycolamide （TEHDGA） in 75 vol.% n-dodecane-25 vol.% n-octanol as agents for the extraction and separation ofNd（III）, Sm（III）, Dy（llI）, Fe（III）, Ni...The feasibility of using N,N,N＇,N＇-tetra（2-ethylhexyl）diglycolamide （TEHDGA） in 75 vol.% n-dodecane-25 vol.% n-octanol as agents for the extraction and separation ofNd（III）, Sm（III）, Dy（llI）, Fe（III）, Ni（II）, and Cs（I） from concentrated chlo- ride solution was investigated. Different extraction behaviors were obtained towards rare earth elements （REE） studied and Fe（IIl）, Ni（II） and Cs（I）. Efficient separation of Nd（III）, Sm（III） and Dy（III） from Fe（III）, Ni（II）, and Cs（I） was achieved by TEHDGA, depending on the HCI, HNO3 or H2SO4 concentration. A systematic investigation was carried out on the detailed extraction prop- erties of Nd（III）, Sm（III）, and Dy（III） with TEHDGA from chloride media. The IR spectra of the extracted species were investi- gated.展开更多
The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased i...The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased implantation time(dose),and more like a parabola at the low implantation pulse voltage.When implantation pulse voltage is increased,the implantation depth increased with the nitrogen distribution peak being deepened,widened and lowered somewhat.TiN,TiN+Ti 2N,or Ti 2N second phases were formed in the implanted layer.The relative percentage of nitrogen content in the form of TiN increases when going deeper into the implanted(TiN formed) layer.The increase of implantation pulse width and/or time is favourable for the formation of TiN rather than Ti 2N.It is unfavourable for formation of any nitrides when implantation pulse voltage is decreased to 30kV or less.Tiny crystalline particles (made mainly of Ti 2N and a smaller percentage of TiO 2 phases) of regular shapes such as triangle and tetragon, etc .(about 20 nm) are found distrbuted dispersively in the near surface region of samples implanted at the high implantation pulse voltage (75kV).展开更多
Diamond-like carbon （DLC） films were successfully deposited on Ti- 50.8 at% Ni using plasma based ion implantation （PBII） technique. The influence of the pulsed negative bias voltage applied to the substrate from...Diamond-like carbon （DLC） films were successfully deposited on Ti- 50.8 at% Ni using plasma based ion implantation （PBII） technique. The influence of the pulsed negative bias voltage applied to the substrate from 12 kV to 40 kV on the microstracture, nano-indentation hardness and Young＇ s modulus, the surface characteristics and corrosion resistant property as well as hemocompatibility were investigated. The experimental resalts showed that C 1 s peak depended heavily on the bias voltage. With the increase of bias voltage, the ratio of sp2 / sp3 first decreased, reaching a minimum value at 20 kV, and then increased. The DLC coating deposited at 20 kV showed the highest hardness and elastic modulus values as a result of lower sp2/sp3 ratio. The RMS values first decreased from 7.202nm（12 kV） to 5.279 nm（20 kV）, and then increased to 11.449 nm（30 kV） and 7.060 nm（ 40 kV）. The uncoated TiNi alloy showed severe pitting corrosion, due to the presence of Cl-ions in the solution. On the contrary, the DLC coated sample showed very little pitting corrosion and behaved better corrosion resistant property especially for the specimens deposited at 20 kV bias voltages. The platelet adhesion test show that the hemocompatibility of DLC coated TiNi alloy is much better than that of bare TiNi alloy, and the hemocompatibility performance of DLC coated TiNi alloy deposited at 20 kV is superior to that of other coated specimens.展开更多
In the experimental campaign of 2010 and 2011 on KSTAR, the NBI-1 system was equipped with one prototype ion source and operated successfully, providing a neutral beam power of 0.7-1.6 MW to the tokamak plasma. The ne...In the experimental campaign of 2010 and 2011 on KSTAR, the NBI-1 system was equipped with one prototype ion source and operated successfully, providing a neutral beam power of 0.7-1.6 MW to the tokamak plasma. The new ion source planned for the 2012 KSTAR campaign had a much more advanced performance compared with the previous one. The target performance of the new ion source was to provide a neutral deuterium beam of 2 MW to the tokamak plasma. The ion source was newly designed, fabricated, and assembled in 2011. The new ion source was then conditioned up to 64 A/100 keV over a 2-hour beam extraction and performance tested at the NB test stand （NBTS） at the Korea Atomic Energy Research Institute （KAERI） in 2012. The measured optimum perveance at which the beam divergence is a minimum was about 2.5μP, and the minimum beam divergent angle was under 1.0° at 60 keV. These results indicate that the 2.0 MW neutral beam power at 100 keV required for the heating of plasma in KSTAR can be delivered by the installation of the new ion source in the KSTAR NBI-1 system.展开更多
The implantation of Cu into Si substrate was carried out by plasma based ion implantation (PBII) using unbalanced magnetron sputtering (UBMS) cathode as the metal plasma source. The different pulse bias ( U p) and the...The implantation of Cu into Si substrate was carried out by plasma based ion implantation (PBII) using unbalanced magnetron sputtering (UBMS) cathode as the metal plasma source. The different pulse bias ( U p) and the distance between the cathode and the samples ( d s-t ) were chosen to research the characteristics of this method. The results show that the implantation of metal ions can be realized by the metal plasma source of UBMS cathode. The physical process such as the metal ion pure implantation, the gas ion implantation, the recoil implantation of the metal atoms, the deposition of the metal particles and the re sputtering of the metal film depend on the energy, dose and deposition rate of the ions (Cu +, Ar +). The metal plasma based ion implantation of Cu into Si substrate is favored by selecting higher U p (60 kV) and larger d s-t (200 mm). [展开更多
Since the Fukushima nuclear accident, the interest in securing a reliable emergency power has increased, and as follow-up measures, each country is conducting various studies for enhancement of safety such as re-exami...Since the Fukushima nuclear accident, the interest in securing a reliable emergency power has increased, and as follow-up measures, each country is conducting various studies for enhancement of safety such as re-examination of EDG （emergency diesel generator） capacity, securement of additional emergency power, etc. This study was performed to find the way to implement a reliable DC system in coping with 72 hours extended station blackout for APR1400 within the battery room size. By using the largest capacity battery in the market which satisfies the requirements for Class 1E to perform a duty cycle for 24 hours, after the decay of the qualified class-lE lead acid battery a Non-Class 1E Lithium ion based battery system can be used as a backup system for 48 hours.展开更多
To further increase the energy density of lithium-ion batteries(LIBs),various researches have been conducted on high-voltage and high-capacity cathode materials.In this perspective,monoclinic Li_(3)V_(2)(PO_(4))_(3) i...To further increase the energy density of lithium-ion batteries(LIBs),various researches have been conducted on high-voltage and high-capacity cathode materials.In this perspective,monoclinic Li_(3)V_(2)(PO_(4))_(3) is a promising candidate due to its promising theoretical discharge capacity of 197 mAh/g with complex phase transition in the voltage range of 3.0 to 4.8 V.However,such asymmetric phase transition behavior with 3 Li^(+)ion extraction/insertion is highly irreversible,resulting in an initial discharge capacity of 163 mAh/g with deteriorated capacity retention.We suggest that cycling Li_(3)V_(2)(PO_(4))_(3) in the voltage range of 3.0 to 4.5 V suppresses the irreversible phase transition and elution of transition metal.Hence,Li_(3)V_(2)(PO_(4))_(3) in the voltage range of 3.0 to 4.5 V delivers an initial discharge capacity of about 142 mAh/g and exhibits extremely long cycle retention(78.70%2,000 cycles),as when cycling in the voltage range of 3.0 to 4.3 V(81.67%2,000 cycles).Furthermore,we present the possibility of a Li_(3)V_(2)(PO_(4))_(3)||Li_(3)V_(2)(PO_(4))_(3) symmetric all-solid-state battery based on an N/P ratio and a cutoff voltage design,which is demonstrated in liquid electrolyte half-cells and symmetric full cells.展开更多
文摘The feasibility of using N,N,N＇,N＇-tetra（2-ethylhexyl）diglycolamide （TEHDGA） in 75 vol.% n-dodecane-25 vol.% n-octanol as agents for the extraction and separation ofNd（III）, Sm（III）, Dy（llI）, Fe（III）, Ni（II）, and Cs（I） from concentrated chlo- ride solution was investigated. Different extraction behaviors were obtained towards rare earth elements （REE） studied and Fe（IIl）, Ni（II） and Cs（I）. Efficient separation of Nd（III）, Sm（III） and Dy（III） from Fe（III）, Ni（II）, and Cs（I） was achieved by TEHDGA, depending on the HCI, HNO3 or H2SO4 concentration. A systematic investigation was carried out on the detailed extraction prop- erties of Nd（III）, Sm（III）, and Dy（III） with TEHDGA from chloride media. The IR spectra of the extracted species were investi- gated.
文摘The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased implantation time(dose),and more like a parabola at the low implantation pulse voltage.When implantation pulse voltage is increased,the implantation depth increased with the nitrogen distribution peak being deepened,widened and lowered somewhat.TiN,TiN+Ti 2N,or Ti 2N second phases were formed in the implanted layer.The relative percentage of nitrogen content in the form of TiN increases when going deeper into the implanted(TiN formed) layer.The increase of implantation pulse width and/or time is favourable for the formation of TiN rather than Ti 2N.It is unfavourable for formation of any nitrides when implantation pulse voltage is decreased to 30kV or less.Tiny crystalline particles (made mainly of Ti 2N and a smaller percentage of TiO 2 phases) of regular shapes such as triangle and tetragon, etc .(about 20 nm) are found distrbuted dispersively in the near surface region of samples implanted at the high implantation pulse voltage (75kV).
文摘Diamond-like carbon （DLC） films were successfully deposited on Ti- 50.8 at% Ni using plasma based ion implantation （PBII） technique. The influence of the pulsed negative bias voltage applied to the substrate from 12 kV to 40 kV on the microstracture, nano-indentation hardness and Young＇ s modulus, the surface characteristics and corrosion resistant property as well as hemocompatibility were investigated. The experimental resalts showed that C 1 s peak depended heavily on the bias voltage. With the increase of bias voltage, the ratio of sp2 / sp3 first decreased, reaching a minimum value at 20 kV, and then increased. The DLC coating deposited at 20 kV showed the highest hardness and elastic modulus values as a result of lower sp2/sp3 ratio. The RMS values first decreased from 7.202nm（12 kV） to 5.279 nm（20 kV）, and then increased to 11.449 nm（30 kV） and 7.060 nm（ 40 kV）. The uncoated TiNi alloy showed severe pitting corrosion, due to the presence of Cl-ions in the solution. On the contrary, the DLC coated sample showed very little pitting corrosion and behaved better corrosion resistant property especially for the specimens deposited at 20 kV bias voltages. The platelet adhesion test show that the hemocompatibility of DLC coated TiNi alloy is much better than that of bare TiNi alloy, and the hemocompatibility performance of DLC coated TiNi alloy deposited at 20 kV is superior to that of other coated specimens.
文摘In the experimental campaign of 2010 and 2011 on KSTAR, the NBI-1 system was equipped with one prototype ion source and operated successfully, providing a neutral beam power of 0.7-1.6 MW to the tokamak plasma. The new ion source planned for the 2012 KSTAR campaign had a much more advanced performance compared with the previous one. The target performance of the new ion source was to provide a neutral deuterium beam of 2 MW to the tokamak plasma. The ion source was newly designed, fabricated, and assembled in 2011. The new ion source was then conditioned up to 64 A/100 keV over a 2-hour beam extraction and performance tested at the NB test stand （NBTS） at the Korea Atomic Energy Research Institute （KAERI） in 2012. The measured optimum perveance at which the beam divergence is a minimum was about 2.5μP, and the minimum beam divergent angle was under 1.0° at 60 keV. These results indicate that the 2.0 MW neutral beam power at 100 keV required for the heating of plasma in KSTAR can be delivered by the installation of the new ion source in the KSTAR NBI-1 system.
文摘The implantation of Cu into Si substrate was carried out by plasma based ion implantation (PBII) using unbalanced magnetron sputtering (UBMS) cathode as the metal plasma source. The different pulse bias ( U p) and the distance between the cathode and the samples ( d s-t ) were chosen to research the characteristics of this method. The results show that the implantation of metal ions can be realized by the metal plasma source of UBMS cathode. The physical process such as the metal ion pure implantation, the gas ion implantation, the recoil implantation of the metal atoms, the deposition of the metal particles and the re sputtering of the metal film depend on the energy, dose and deposition rate of the ions (Cu +, Ar +). The metal plasma based ion implantation of Cu into Si substrate is favored by selecting higher U p (60 kV) and larger d s-t (200 mm). [
文摘Since the Fukushima nuclear accident, the interest in securing a reliable emergency power has increased, and as follow-up measures, each country is conducting various studies for enhancement of safety such as re-examination of EDG （emergency diesel generator） capacity, securement of additional emergency power, etc. This study was performed to find the way to implement a reliable DC system in coping with 72 hours extended station blackout for APR1400 within the battery room size. By using the largest capacity battery in the market which satisfies the requirements for Class 1E to perform a duty cycle for 24 hours, after the decay of the qualified class-lE lead acid battery a Non-Class 1E Lithium ion based battery system can be used as a backup system for 48 hours.
基金supported by the Technology Innovation Program(RS-2023-00256202,Development of MLCB design and manufacturing process technology for board mounting)funded by the Ministry of Trade,Industry and Energy(MOTIE,Korea)the Technology Innovation Program(or Industrial Strategic Technology Development Program-Public-Private joint investment semiconductor R&D program[K-CHIPS]to foster high-quality human resources)(RS-2023-00237003,High selectivity etching technology using cryoetch)funded by the Ministry of Trade,Industry and Energy(MOTIE,Korea)+1 种基金a 2022 Research Grant from Kangwon National University(No.202203080001)the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(RS-2023-00280367).
文摘To further increase the energy density of lithium-ion batteries(LIBs),various researches have been conducted on high-voltage and high-capacity cathode materials.In this perspective,monoclinic Li_(3)V_(2)(PO_(4))_(3) is a promising candidate due to its promising theoretical discharge capacity of 197 mAh/g with complex phase transition in the voltage range of 3.0 to 4.8 V.However,such asymmetric phase transition behavior with 3 Li^(+)ion extraction/insertion is highly irreversible,resulting in an initial discharge capacity of 163 mAh/g with deteriorated capacity retention.We suggest that cycling Li_(3)V_(2)(PO_(4))_(3) in the voltage range of 3.0 to 4.5 V suppresses the irreversible phase transition and elution of transition metal.Hence,Li_(3)V_(2)(PO_(4))_(3) in the voltage range of 3.0 to 4.5 V delivers an initial discharge capacity of about 142 mAh/g and exhibits extremely long cycle retention(78.70%2,000 cycles),as when cycling in the voltage range of 3.0 to 4.3 V(81.67%2,000 cycles).Furthermore,we present the possibility of a Li_(3)V_(2)(PO_(4))_(3)||Li_(3)V_(2)(PO_(4))_(3) symmetric all-solid-state battery based on an N/P ratio and a cutoff voltage design,which is demonstrated in liquid electrolyte half-cells and symmetric full cells.
