Photocatalytic Z-scheme water splitting is considered as a promising approach to produce solar hydrogen.However,the forward hydrogen production reaction is often impeded by backward reactions.In the present study,in a...Photocatalytic Z-scheme water splitting is considered as a promising approach to produce solar hydrogen.However,the forward hydrogen production reaction is often impeded by backward reactions.In the present study,in a photosystem Ⅱ-integrated hybrid Z-scheme water splitting system,the backward hydrogen oxidation reaction was significantly suppressed by loading a PtCrOx cocatalyst on a ZrO2/TaON photocatalyst.Due to the weak chemisorption and activation of molecular hydrogen on PtCrOx,where Pt is stabilized in the oxidized forms,Pt^Ⅱ and Pt^Ⅳ,hydrogen oxidation is inhibited.However,it is remarkably well-catalyzed by the metallic Pt cocatalyst,thereby rapidly consuming the produced hydrogen.This work describes an approach to inhibit the backward reaction in the photosystem Ⅱ-integrated hybrid Z-scheme water splitting system using Fe(CN)6^3-/Fe(CN)6^4-redox couple as an electron shuttle.展开更多
Some analyses of the electromagnetic form factors of the nucleon and some analyses of the nucleon-nucleon potential favor a large coupling of the φ meson to nucleons. This is frequently quoted by advocates of a large...Some analyses of the electromagnetic form factors of the nucleon and some analyses of the nucleon-nucleon potential favor a large coupling of the φ meson to nucleons. This is frequently quoted by advocates of a large ss component of the nucleon. It is shown that such large OZI-violating couplings are incompatible with data on φproduction in backward direction via nucleon exchange.展开更多
Research on photocatalytic overall water splitting has attracted wide attention.Recently,a work has sys-tematically discussed the challenges for photocatalytic overall water splitting in terms of thermodynam-ics,kinet...Research on photocatalytic overall water splitting has attracted wide attention.Recently,a work has sys-tematically discussed the challenges for photocatalytic overall water splitting in terms of thermodynam-ics,kinetics,dissolved oxygen,and backward and side reactions.The critical analysis of the reaction pro-cess and reaction environment in the work contributes to an in-depth understanding of photocatalytic overall water splitting.展开更多
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences(XDB17000000)the Key Research Program of Frontier Sciences,CAS(QYZDY-SSW-JSC023)+1 种基金the National Natural Science Foundation of China(21603224,31470339)the National Key R&D Program of China(2017YFA0503700)~~
文摘Photocatalytic Z-scheme water splitting is considered as a promising approach to produce solar hydrogen.However,the forward hydrogen production reaction is often impeded by backward reactions.In the present study,in a photosystem Ⅱ-integrated hybrid Z-scheme water splitting system,the backward hydrogen oxidation reaction was significantly suppressed by loading a PtCrOx cocatalyst on a ZrO2/TaON photocatalyst.Due to the weak chemisorption and activation of molecular hydrogen on PtCrOx,where Pt is stabilized in the oxidized forms,Pt^Ⅱ and Pt^Ⅳ,hydrogen oxidation is inhibited.However,it is remarkably well-catalyzed by the metallic Pt cocatalyst,thereby rapidly consuming the produced hydrogen.This work describes an approach to inhibit the backward reaction in the photosystem Ⅱ-integrated hybrid Z-scheme water splitting system using Fe(CN)6^3-/Fe(CN)6^4-redox couple as an electron shuttle.
文摘Some analyses of the electromagnetic form factors of the nucleon and some analyses of the nucleon-nucleon potential favor a large coupling of the φ meson to nucleons. This is frequently quoted by advocates of a large ss component of the nucleon. It is shown that such large OZI-violating couplings are incompatible with data on φproduction in backward direction via nucleon exchange.
基金financially supported by the National Natural Foun-dation of China(No.52073034).
文摘Research on photocatalytic overall water splitting has attracted wide attention.Recently,a work has sys-tematically discussed the challenges for photocatalytic overall water splitting in terms of thermodynam-ics,kinetics,dissolved oxygen,and backward and side reactions.The critical analysis of the reaction pro-cess and reaction environment in the work contributes to an in-depth understanding of photocatalytic overall water splitting.
